CN103131103A - Preparation method of wear-resistant and non-skid PVC (polyvinyl chloride) transparent sheet - Google Patents
Preparation method of wear-resistant and non-skid PVC (polyvinyl chloride) transparent sheet Download PDFInfo
- Publication number
- CN103131103A CN103131103A CN2013100885227A CN201310088522A CN103131103A CN 103131103 A CN103131103 A CN 103131103A CN 2013100885227 A CN2013100885227 A CN 2013100885227A CN 201310088522 A CN201310088522 A CN 201310088522A CN 103131103 A CN103131103 A CN 103131103A
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- China
- Prior art keywords
- preparation
- wear
- pvc
- controlled
- resisting antiskid
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
The invention provides a preparation method of a wear-resistant and non-skid PVC (polyvinyl chloride) transparent sheet. The preparation method comprises the following steps: firstly performing mixing, stirring and temperature control on PVC, a plasticizer, a stabilizer, inner and outer slipping agents, TPU (thermoplastic polyurethane) and ABS (acrylonitrile butadiene styrene); and then sequentially placing products into an extruding machine and a calendering machine, finally taking off, embossing and cooling, and then winding. The preparation method disclosed by the invention has the advantages that the TPU and the ABS are added, the cost of a produced product is upgraded to a small extent, the wear resistance and the anti-slip property are greatly increased and the service life of the product is further prolonged.
Description
Technical field
The present invention relates to a kind of preparation method of PVC clear sheet, relate in particular to a kind of preparation method of wear-resisting antiskid PVC slide, belong to field of high polymer material processing.
Background technology
Utilize the product that pure polyvinyl chloride (PVC) is produced to use at floor surface, can play the effect of anti-skid wearable, but DeGrain is because PVC thermostability and lower temperature resistance are poor, under effect of light, the flavescence etc. of can degrading gradually.The starting material of production polyvinyl chloride (PVC) sheets afterwards are improved to PVC, softening agent, stablizer and inside and outside lubrication prescription, the product wear-resisting antiskid property enhancement that these starting material is mixed, stirs again the explained hereafter such as process is extruded, calendering, certain promotion and application have been obtained, yet the place larger at flow of the people or wear-resisting requirement is higher, the said products still can not meet the demands.
Summary of the invention
Goal of the invention: the purpose of this invention is to provide a kind of preparation method that can strengthen wear-resisting antiskid performance PVC slide.
Technical scheme: the preparation method of wear-resisting antiskid PVC slide of the present invention comprises the steps:
(1) PVC90-100 part, softening agent 18-40 part, stablizer 1-5 part, inside and outside lubrication prescription 0.5-1 part, TPU1-5 part and ABS1-5 part are mixed, stirred, temperature is controlled at 80-100 ℃;
(2) product after stirring is placed in forcing machine and rolling press successively, and wherein, extrusion temperature is controlled at 170-200 ℃, and the rolling press temperature is controlled at 170-190 ℃;
(3) product after rolling through deflecting from, embossing, rolling after cooling can obtain described PVC slide.
Wherein, in step (1), can first PVC be mixed, stir with softening agent, then add stablizer, inside and outside lubrication prescription, TPU and ABS stir, and churning time is 1-3 minute.In step (2), product is prepended in mill through rolling after extruding, mixing temperature remains on 160-180 ℃, and effect is that the raw material that will mix carries out mixing, plasticizing, moulds more uniform melting charge for rolling press calendering formation plastics provide to mix to refine.Described product is prepended in filter through opening to roll after refining, and filtration temperature is controlled at 180-200 ℃, and filtration velocity is controlled at 5-15m/min.In step (2), forcing machine is planetary extruder or twin screw extruder, and rolling press is four-roll calender or five roll calendars.
Beneficial effect: the present invention compared with prior art, its remarkable advantage is for having increased by two components of thermoplastic polyurethane elastomer and acrylonitrile-butadiene-styrene (ABS) ABS, wherein, TPU is the family macromolecule material between rubber and plastics, can effectively improve thermostability and the low temperature kindliness of PVC after itself and PVC blend, simultaneously toughness and the impact of Reinforced PVC have improved the non-skid property of product; ABS possesses HI high impact, the high performance such as heat-resisting, fire-retardant, wear-resisting, therefore, TPU, ABS is added in PVC, and the product cost of producing promotes that amplitude is little, and wear-resisting antiskid increases greatly, thereby extends the work-ing life of product.
Embodiment
Embodiment 1: at first, PVC90 part, 18 parts of plasticizer DOTPs, 1 part of calcium zinc stabilizer, 0.5 part of adipic acid pentaerythritol ester, TPU1 part and ABS1 part are mixed, stirred, temperature is controlled at 80 ℃; Secondly, product is placed in planetary extruder and four-roll calender successively, wherein, extrusion temperature is controlled at 170 ℃, and the rolling press temperature is controlled at 170 ℃; At last, with product through deflecting from, embossing, rolling after cooling can obtain described PVC slide.
Test result
| Wearing layer thickness | Common wearing layer | The test wearing layer | Testing standard |
| 0.3mm | 0.030g/1000 turn | 0.016g/1000 turn | GB4085 |
PVC slide by above explained hereafter is according to GB GB4085 test, and rate of wear turns from 0.030g/1000 and drops to 0.016g/1000 and turn, and effect promoting is obvious.
Embodiment 2 is basic identical with embodiment 1 step, and difference is: PVC100 part, DOTP40 part, 5 parts of calcium zinc stabilizers, 1 part of stearic acid, TPU5 part, ABS5 part, and whipping temp is controlled at 100 ℃; Extrusion temperature is controlled at 200 ℃, and the rolling press temperature is controlled at 190 ℃.
Test result
| Wearing layer thickness | Common wearing layer | The test wearing layer | Testing standard |
| 0.3mm | 0.030g/1000 turn | 0.016g/1000 turn | GB4085 |
PVC slide by above explained hereafter is according to GB GB4085 test, and rate of wear turns from 0.030g/1000 and drops to 0.016g/1000 and turn, and effect promoting is obvious.
Embodiment 3: at first 1 minute is mixed, stirred to PVC95 part with DOTP32 part, then add 3 parts of calcium zinc stabilizers, 0.8 part of adipic acid pentaerythritol ester, TPU3 part, ABS3 part to stir, mixed 3 minutes, temperature is controlled at 90 ℃; Secondly, product is placed in twin screw extruder, mill and five roll calendars successively, wherein, extrusion temperature is controlled at 180 ℃, and mixing temperature remains on 160 ℃, and the rolling press temperature is controlled at 180 ℃; At last, with product through deflecting from, embossing, rolling after cooling can obtain described PVC slide.
Test result
| Wearing layer thickness | Common wearing layer | The test wearing layer | Testing standard |
| 0.3mm | 0.030g/1000 turn | 0.017g/1000 turn | GB4085 |
PVC slide by above explained hereafter is according to GB GB4085 test, and rate of wear turns from 0.030g/1000 and drops to 0.017g/1000 and turn, and effect promoting is obvious.
Embodiment 4 is basic identical with embodiment 3 steps, and difference is: material is through after mill, before rolling press, also pass through filter, and filtration temperature is controlled at 180 ℃, and filtration velocity is controlled at 5m/min, and mixing temperature remains on 180 ℃.
Test result
| Wearing layer thickness | Common wearing layer | The test wearing layer | Testing standard |
| 0.3mm | 0.030g/1000 turn | 0.014g/1000 turn | GB4085 |
PVC slide by above explained hereafter is according to GB GB4085 test, and rate of wear turns from 0.030g/1000 and drops to 0.014g/1000 and turn, and effect promoting is obvious.
Embodiment 5 is basic identical with embodiment 4 steps, and difference is: filtration temperature is controlled at 200 ℃, and filtration velocity is controlled at 15m/min, and mixing temperature remains on 170 ℃.
Test result
| Wearing layer thickness | Common wearing layer | The test wearing layer | Testing standard |
| 0.3mm | 0.030g/1000 turn | 0.017g/1000 turn | GB4085 |
PVC slide by above explained hereafter is according to GB GB4085 test, and rate of wear turns from 0.030g/1000 and drops to 0.017g/1000 and turn, and effect promoting is obvious.
Embodiment 6 is basic identical with embodiment 5 steps, and difference is: filtration temperature is controlled at 190 ℃, and filtration velocity is controlled at 10m/min.
Test result
| Wearing layer thickness | Common wearing layer | The test wearing layer | Testing standard |
| 0.3mm | 0.030g/1000 turn | 0.016g/1000 turn | GB4085 |
PVC slide by above explained hereafter is according to GB GB4085 test, and rate of wear turns from 0.030g/1000 and drops to 0.016g/1000 and turn, and effect promoting is obvious.
Claims (8)
1. the preparation method of a wear-resisting antiskid PVC slide, comprise the steps:
(1) PVC90-100 part, softening agent 18-40 part, stablizer 1-5 part, inside and outside lubrication prescription 0.5-1 part, TPU1-5 part and ABS1-5 part are mixed, stirred, temperature is controlled at 80-100 ℃;
(2) product after stirring is placed in forcing machine and rolling press successively, and wherein, extrusion temperature is controlled at 170-200 ℃, and the rolling press temperature is controlled at 170-190 ℃;
(3) product after rolling through deflecting from, embossing, rolling after cooling can obtain described PVC slide.
2. the preparation method of wear-resisting antiskid PVC slide according to claim 1, is characterized in that: in step (1), first PVC is mixed, stirs with softening agent, then add stablizer, inside and outside lubrication prescription, TPU and ABS to stir.
3. the preparation method of wear-resisting antiskid PVC slide according to claim 2, it is characterized in that: described churning time is 1-3 minute.
4. the preparation method of wear-resisting antiskid PVC slide according to claim 1 is characterized in that: in step (2), product is prepended in mill through rolling after extruding, and mixing temperature remains on 160-180 ℃.
5. the preparation method of wear-resisting antiskid PVC slide according to claim 4 is characterized in that: described product is prepended in filter through opening to roll after refining, and filtration temperature is controlled at 180-200 ℃.
6. the preparation method of wear-resisting antiskid PVC slide according to claim 5, it is characterized in that: described filtration velocity is controlled at 5-15m/min.
7. the preparation method of wear-resisting antiskid PVC slide according to claim 1, it is characterized in that: in step (2), forcing machine is planetary extruder or twin screw extruder.
8. the preparation method of wear-resisting antiskid PVC slide according to claim 1, it is characterized in that: in step (2), rolling press is four-roll calender or five roll calendars.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100885227A CN103131103A (en) | 2013-03-19 | 2013-03-19 | Preparation method of wear-resistant and non-skid PVC (polyvinyl chloride) transparent sheet |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100885227A CN103131103A (en) | 2013-03-19 | 2013-03-19 | Preparation method of wear-resistant and non-skid PVC (polyvinyl chloride) transparent sheet |
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| CN103131103A true CN103131103A (en) | 2013-06-05 |
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| CN2013100885227A Pending CN103131103A (en) | 2013-03-19 | 2013-03-19 | Preparation method of wear-resistant and non-skid PVC (polyvinyl chloride) transparent sheet |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105295257A (en) * | 2015-12-03 | 2016-02-03 | 泰州市华丽塑料有限公司 | Scraping-resisting super wear-resisting PVC (polyvinyl chloride) transparent sheet and manufacturing method thereof |
| CN106064489A (en) * | 2016-06-29 | 2016-11-02 | 芜湖市佳谷豆工贸有限公司 | A kind of production technology of wear-resisting PVC rubber |
| US20180294071A1 (en) * | 2014-11-11 | 2018-10-11 | Autonetworks Technologies, Ltd. | Composition for electric wire coating material and insulated electric wire |
| CN110591246A (en) * | 2019-07-09 | 2019-12-20 | 潍坊吉昌塑业有限公司 | Transparent sheet free of UV paint and coating after floor and wallboard forming |
| CN112996607A (en) * | 2018-11-26 | 2021-06-18 | 美国阿拉丁制造公司 | Composition and flooring product comprising such a composition |
| CN114872352A (en) * | 2022-04-25 | 2022-08-09 | 浙江晶通新材料集团有限公司 | Anti-aging wear-resistant PVC (polyvinyl chloride) transparent sheet, floor and manufacturing method of transparent sheet |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4183777A (en) * | 1976-12-13 | 1980-01-15 | The B.F. Goodrich Company | Method of making weather resistant composites |
| CN101381434A (en) * | 2007-06-18 | 2009-03-11 | 沂源瑞丰高分子材料有限公司 | Non-flow lines crack high twice processing thermo-elastic resin composition applied in PVC transparent sheet |
| CN101538393A (en) * | 2009-04-23 | 2009-09-23 | 福建思嘉环保材料科技有限公司 | High-elastic wearproof athletic floor material and preparation method thereof |
| CN102286181A (en) * | 2010-06-21 | 2011-12-21 | 国家复合改性聚合物材料工程技术研究中心 | Formula of high-liquidity polyvinyl chloride alloy and preparation method |
| CN102344622A (en) * | 2010-08-03 | 2012-02-08 | 苏州富通电器塑业有限公司 | Outdoor high-molecular co-extrusion floor and its preparation method |
| CN102966231A (en) * | 2011-09-01 | 2013-03-13 | 深圳市建辰实业有限公司 | Ceramic-plastic floor and processing method thereof |
-
2013
- 2013-03-19 CN CN2013100885227A patent/CN103131103A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4183777A (en) * | 1976-12-13 | 1980-01-15 | The B.F. Goodrich Company | Method of making weather resistant composites |
| CN101381434A (en) * | 2007-06-18 | 2009-03-11 | 沂源瑞丰高分子材料有限公司 | Non-flow lines crack high twice processing thermo-elastic resin composition applied in PVC transparent sheet |
| CN101538393A (en) * | 2009-04-23 | 2009-09-23 | 福建思嘉环保材料科技有限公司 | High-elastic wearproof athletic floor material and preparation method thereof |
| CN102286181A (en) * | 2010-06-21 | 2011-12-21 | 国家复合改性聚合物材料工程技术研究中心 | Formula of high-liquidity polyvinyl chloride alloy and preparation method |
| CN102344622A (en) * | 2010-08-03 | 2012-02-08 | 苏州富通电器塑业有限公司 | Outdoor high-molecular co-extrusion floor and its preparation method |
| CN102966231A (en) * | 2011-09-01 | 2013-03-13 | 深圳市建辰实业有限公司 | Ceramic-plastic floor and processing method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20180294071A1 (en) * | 2014-11-11 | 2018-10-11 | Autonetworks Technologies, Ltd. | Composition for electric wire coating material and insulated electric wire |
| US10418149B2 (en) * | 2014-11-11 | 2019-09-17 | Autonetworks Technologies, Ltd. | Composition for electric wire coating material and insulated electric wire |
| CN105295257A (en) * | 2015-12-03 | 2016-02-03 | 泰州市华丽塑料有限公司 | Scraping-resisting super wear-resisting PVC (polyvinyl chloride) transparent sheet and manufacturing method thereof |
| CN106064489A (en) * | 2016-06-29 | 2016-11-02 | 芜湖市佳谷豆工贸有限公司 | A kind of production technology of wear-resisting PVC rubber |
| CN112996607A (en) * | 2018-11-26 | 2021-06-18 | 美国阿拉丁制造公司 | Composition and flooring product comprising such a composition |
| CN112996607B (en) * | 2018-11-26 | 2023-10-03 | 美国阿拉丁制造公司 | Composition and flooring product comprising such a composition |
| CN110591246A (en) * | 2019-07-09 | 2019-12-20 | 潍坊吉昌塑业有限公司 | Transparent sheet free of UV paint and coating after floor and wallboard forming |
| CN114872352A (en) * | 2022-04-25 | 2022-08-09 | 浙江晶通新材料集团有限公司 | Anti-aging wear-resistant PVC (polyvinyl chloride) transparent sheet, floor and manufacturing method of transparent sheet |
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Application publication date: 20130605 |