CN103084154A - Method for activated carbon regeneration by yeast combined chemical process - Google Patents
Method for activated carbon regeneration by yeast combined chemical process Download PDFInfo
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- CN103084154A CN103084154A CN2011103432319A CN201110343231A CN103084154A CN 103084154 A CN103084154 A CN 103084154A CN 2011103432319 A CN2011103432319 A CN 2011103432319A CN 201110343231 A CN201110343231 A CN 201110343231A CN 103084154 A CN103084154 A CN 103084154A
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- activated carbon
- carbon
- active carbon
- filter cake
- saccharomycete
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 97
- 238000000034 method Methods 0.000 title claims abstract description 32
- 240000004808 Saccharomyces cerevisiae Species 0.000 title claims abstract description 8
- 238000011069 regeneration method Methods 0.000 title claims description 13
- 230000008929 regeneration Effects 0.000 title claims description 6
- 238000001311 chemical methods and process Methods 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 21
- 239000002699 waste material Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000012065 filter cake Substances 0.000 claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000002002 slurry Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 239000004317 sodium nitrate Substances 0.000 claims abstract description 5
- 235000010344 sodium nitrate Nutrition 0.000 claims abstract description 5
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 5
- 229910000162 sodium phosphate Inorganic materials 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims abstract description 5
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims abstract description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 55
- 241000235342 Saccharomycetes Species 0.000 claims description 16
- 238000002386 leaching Methods 0.000 claims description 12
- 238000004140 cleaning Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 claims description 6
- 239000001433 sodium tartrate Substances 0.000 claims description 6
- 229960002167 sodium tartrate Drugs 0.000 claims description 6
- 235000011004 sodium tartrates Nutrition 0.000 claims description 6
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000005267 amalgamation Methods 0.000 claims description 4
- 239000003610 charcoal Substances 0.000 claims description 4
- 230000018044 dehydration Effects 0.000 claims description 4
- 238000006297 dehydration reaction Methods 0.000 claims description 4
- 238000007873 sieving Methods 0.000 claims description 4
- 241000894006 Bacteria Species 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 230000003213 activating effect Effects 0.000 claims 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000001172 regenerating effect Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000000813 microbial effect Effects 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 3
- 235000013736 caramel Nutrition 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000009854 hydrometallurgy Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
Landscapes
- Carbon And Carbon Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Water Treatment By Sorption (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
本发明提供了一种酵母菌联合化学法再生活性炭的方法，属于环境工程领域。其特征是：一、以糖生产过程产生的废活性炭为原料，用150目方孔筛进行筛分后取筛上部分；二、将活性炭、水、浸出剂按照质量比为1.0∶4.0～6.0∶0.02～0.12的比例混合，搅拌浸出2～5h，然后进行过滤，取滤饼备用；三、将步骤二制得的滤饼与水混合，控制活性炭/水(质量比)为3.0～10.0，并加入活性炭质量的3％～15％的酵母菌溶液、活性炭质量的0.01～0.05的硝酸钠和活性炭质量的0.005～0.02的磷酸钠并搅拌均匀，控制浆料温度在25℃～33℃之间、体系的pH值在5.5～7.0之间，之后反应3～12h；四、将步骤三制得的活性炭混合液过滤，取滤饼，用质量浓度为5％～15％的氢氧化钠溶液清洗活性炭；五、清洗后的活性炭经过脱水、干燥后即可得到再生活性炭。The invention provides a method for regenerating activated carbon with yeast combined with a chemical method, which belongs to the field of environmental engineering. Its characteristics are: 1. Use the waste activated carbon produced in the sugar production process as raw material, sieve it with a 150-mesh square hole sieve and take the part above the sieve; : mixed in a ratio of 0.02 to 0.12, stirred and leached for 2 to 5 hours, then filtered, and the filter cake was taken for subsequent use; 3, the filter cake prepared in step 2 was mixed with water, and the activated carbon/water (mass ratio) was controlled to be 3.0 to 10.0, And add 3% to 15% of the activated carbon mass of yeast solution, 0.01 to 0.05 of the activated carbon mass of sodium nitrate and 0.005 to 0.02 of the activated carbon mass of sodium phosphate and stir evenly, and control the temperature of the slurry between 25°C and 33°C 1. The pH value of the system is between 5.5 and 7.0, and then react for 3 to 12 hours; 4. Filter the activated carbon mixture obtained in step 3, take the filter cake, and wash it with a sodium hydroxide solution with a mass concentration of 5% to 15%. Activated carbon; 5. The cleaned activated carbon can be dehydrated and dried to obtain regenerated activated carbon.
Description
Affiliated technical field
The present invention relates to the method for a Yeasts amalgamation method regenerated carbon, belong to field of environment engineering.
Background technology
Active carbon is a kind of Powdered or granular black solid, has very flourishing pore structure and high specific area, and acid and alkali-resistance corrodes, and to biologically inert, is a kind of good sorbing material.Be widely used in the fields such as chemical industry, environmental protection, food and pharmacy, hydrometallurgy, catalyst carrier, electrode material and military chemistry protection.Himself is contaminated after having adsorbed organic matter for active carbon, need to regenerate to process or discarded.China reaches 10000 ton/years because of the waste active carbon that sugar industry produces, and owing to containing a large amount of nutrients in waste active carbon, bacterial reproduction is serious, and smell makes us suffocating.It is carried out recycling have important environmental protection meaning and the meaning that economizes on resources.
With organic matter leaching, decomposition or in-situ carburization with the way of having adsorbed organic Regenevating Waste Activated Carbon.At present, regeneration method of active carbon mainly contains hot method of reproduction, bio-regeneration method, wet air regeneration method, solvent regeneration process, chemical regeneration method, ultrasonic regeneration method and Photocatalytic Regeneration method etc.In numerous regeneration method of active carbon, hot regeneration technology is the most ripe, but its regenerative process duration, energy consumption is high, unstable product quality.Use the method regenerated carbon of microbial degradation, pore structure and pore-size distribution capable of reducing energy consumption, as to guarantee active carbon.Microbial method has been widely used in the fields such as sewage disposal, fabrication of new materials.Along with the development of modern science and technology, microbial method is applied in various fields such as food, space flight, heavy metal-polluted soil processing.The present invention uses saccharomycete to be the method for advanced treating active carbon hole internal sugar part, method in conjunction with the sugar part in Chemical Leaching activated carbon surface and macropore is regenerated to the useless activated carbon that sugar industry produces, microbial degradation and solvent reclamation are organically combined, their performances usefulness separately, and complement each other, improve the percent reduction of waste active carbon, guaranteed the original pore structure of active carbon and pore-size distribution.
Summary of the invention
The method that the purpose of this invention is to provide a Yeasts amalgamation method regenerated carbon.It is that the waste active carbon that produces take sugar industry is as raw material.In sugared production process, need to decolour with active carbon, the filter aids such as diatomite filter, and therefore, contain a small amount of sand in waste active carbon.After first dividing through 150 mesh sieves, the present invention removes the inorganic particles such as the sand that adulterates in active carbon, clay, then utilize the sodium tartrate aqueous solution or sodium citrate aqueous solution that the organic components such as caramel in activated carbon granule surface and macropore are leached, leachate contains a large amount of sugar parts, leaching agent also can be used as the animal foodstuff raw material, so leachate can be used as animal feed or feed-mixing water uses; In active carbon after leaching is processed, most of impurity is removed, then adding water mixes and adds saccharomycete solution, be equipped with the necessary nitrogen P elements of saccharomycete existence, control to control slurry temperature between 25 ℃～33 ℃, the pH value of system between 5.5～7.0, make saccharomycete degrade residual sugar part in the duct; With diluted sodium hydroxide solution, saccharomycete, small organic molecule being cleaned out rear filtration, drying after degraded is completed can make active carbon realize regeneration.
The present invention has made regenerated carbon by following measures:
(1) waste active carbon that produces take the caramel production process is got sieve and is gone up part as raw material after sieving with 150 order square hole screens;
(2) active carbon, water, leaching agent are mixed according to certain mass ratio, then leaching 2～5h filters, and gets filter cake standby;
(3) filter cake that step 2 is made mixes with water, controlling active carbon/water (mass ratio) is 3.0～10.0, and add saccharomycete solution, sodium nitrate and sodium phosphate and stir, control slurry temperature between 25 ℃～33 ℃, the pH value of system between 5.5～7.0, react afterwards 3～12h;
(4) the active carbon mixed liquor that step 3 is made filters, and gets filter cake, is 5%～15% sodium hydroxide solution cleaning active charcoal with mass concentration;
(5) can obtain regenerated carbon after the dehydration of the process of the active carbon after the cleaning, drying.
The saccharomycete associating chemical method regenerated carbon of the present invention's preparation has carried out good protection due to the method for using saccharomycete degraded and medicament stripping to combine to the original pore structure of active carbon and pore-size distribution.Contain a large amount of sugar parts and a small amount of sodium tartrate, natrium citricum in process in leachate, the mixing water that can be used as animal feed uses, and is favourable to the growth of animal.Without poisonous and harmful substance discharging, be a resource-conserving, environmentally friendly complete set technology in production process.
The concrete grammar of saccharomycete associating chemical method regenerated carbon of the present invention is:
Raw material selection:
1. waste active carbon, fineness 5 orders～200 orders can be dried waste active carbons, also the new waste active carbon of discharging of sugared production line;
2. sodium tartrate, natrium citricum, food-grade; The mixture of sodium tartrate and natrium citricum, both food-grade raw materials mix according to arbitrary proportion all can;
3. NaOH, technical grade;
4. saccharomycete, food-grade.
The concrete steps of principle production process are:
A. the waste active carbon that produces take the caramel production process is got sieve and is gone up part as raw material after sieving with 150 order square hole screens;
B. be that 1.0: 4.0～6.0: 0.02～0.12 ratio is mixed with active carbon, water, leaching agent according to mass ratio, then leaching 2～5h filters, and gets filter cake standby;
C. the filter cake that step 2 is made mixes with water, controlling active carbon/water (mass ratio) is 3.0～10.0, and add 0.005～0.02 sodium phosphate of 0.01～0.05 the sodium nitrate of 3%～15% saccharomycete solution, quality of activated carbon of quality of activated carbon and quality of activated carbon and stir, control slurry temperature between 25 ℃～33 ℃, the pH value of system between 5.5～7.0, react afterwards 3～12h;
D. the active carbon mixed liquor that step 3 is made filters, and gets filter cake, is 5%～15% sodium hydroxide solution cleaning active charcoal with mass concentration;
E. can obtain regenerated carbon after the active carbon process dehydration after cleaning, drying.
The specific embodiment
Embodiment 1:
1) take the waste active carbon 150g that dry sugared production process produces, get the upper part of sieve after sieving with 150 order square hole screens, obtain the waste active carbon that 114.8g removes sand;
2) waste active carbon that step 1 is obtained is placed in the beaker of 1L, adds water 500ml, sodium tartrate .50g, and leaching 4h then at vacuum filtration, gets filter cake standby;
3) filter cake that step 2 is made mixes with 700ml water, and adds 13ml saccharomycete solution, 2g sodium nitrate and 0.012g sodium phosphate and stir, and controlling slurry temperature is 30 ℃ ± 2.℃, the pH value of system is 6.5, reacts afterwards 3.5h;
4) the active carbon mixed liquor that step 3 is made filters, and gets filter cake, is 7% sodium hydroxide solution cleaning active charcoal with mass concentration;
E. can obtain regenerated carbon after the dehydration of the process of the active carbon after irradiation, drying.
The active carbon specific area that embodiment 1 obtains is 1118.5m
2/ g, iodine sorption value are 808.1mg/g, and methylene blue adsorption value is 210.5mg/g, and regeneration rate is 90%.
Claims (4)
1. the method for a Yeasts amalgamation method regenerated carbon is characterized in that: the waste active carbon that, produces take sugared production process is got sieve and is gone up part as raw material after sieving with 150 order square hole screens; Two, be that 1.0: 4.0～6.0: 0.02～0.12 ratio is mixed with active carbon, water, leaching agent according to mass ratio, then leaching 2～5h filters, and gets filter cake standby; Three, the filter cake that step 2 is made mixes with water, controlling active carbon/water (mass ratio) is 3.0～10.0, and add 0.005～0.02 sodium phosphate of 0.01～0.05 the sodium nitrate of 3%～15% saccharomycete solution, quality of activated carbon of quality of activated carbon and quality of activated carbon and stir, control slurry temperature between 25 ℃～33 ℃, the pH value of system between 5.5～7.0, react afterwards 3～12h; Four, the active carbon mixed liquor that step 3 is made filters, and gets filter cake, is 5%～15% sodium hydroxide solution cleaning active charcoal with mass concentration; Five, can obtain regenerated carbon after the dehydration of the process of the active carbon after the cleaning, drying;
2. the method for microwave-assisted regeneration active carbon according to claim 1, is characterized in that in step 2, leaching agent used is natrium citricum, sodium tartrate or their mixture;
3. the method for saccharomycete associating chemical method regenerated carbon according to claim 1, is characterized in that in step 3, activating agent used is absolute ethyl alcohol, Sodium Polyacrylate, natrium citricum or their mixture;
4. the method for saccharomycete according to claim 1 associating chemical method regenerated carbon is characterized in that in step 2 in used yeast bacterium solution that saccharomycete content is 10000/ml～100000/ml.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201110343231.9A CN103084154B (en) | 2011-11-03 | 2011-11-03 | The method of one Yeasts amalgamation method regenerated carbon |
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| CN201110343231.9A CN103084154B (en) | 2011-11-03 | 2011-11-03 | The method of one Yeasts amalgamation method regenerated carbon |
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| CN103084154A true CN103084154A (en) | 2013-05-08 |
| CN103084154B CN103084154B (en) | 2016-07-06 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103721692A (en) * | 2014-01-22 | 2014-04-16 | 呼伦贝尔东北阜丰生物科技有限公司 | Recycling method of waste powdered activated carbon |
| CN104415736A (en) * | 2013-09-09 | 2015-03-18 | 龚芯 | Active carbon regeneration method and active carbon regeneration device |
| CN105457617A (en) * | 2013-12-18 | 2016-04-06 | 帝斯曼江山制药（江苏）有限公司 | Activated carbon recovery technology |
| CN106242028A (en) * | 2016-08-08 | 2016-12-21 | 上海市政工程设计研究总院（集团）有限公司 | A kind of biological powder activated carbon purification method of water supply factory |
| CN107051415A (en) * | 2017-04-13 | 2017-08-18 | 福建省荔元活性炭实业有限公司 | A kind of method of gluconacetobacter regenerated carbon |
| CN108855022A (en) * | 2018-07-19 | 2018-11-23 | 深圳市环球绿地新材料有限公司 | A kind of preparation and regeneration method suitable for big partial size and the active carbon of absorption heavy metal ion |
| CN111518600A (en) * | 2019-12-23 | 2020-08-11 | 新疆中宇金盾碳基研究院(有限公司) | Saltpetering inhibitor, semi-coke type carbon containing saltpetering inhibitor and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60829A (en) * | 1983-06-20 | 1985-01-05 | Nankai Kako Kk | Regeneration of active carbon for purifying citrus juice |
| CN1218835A (en) * | 1997-12-02 | 1999-06-09 | 中国科学院新疆化学研究所 | Regenerating method for powdered active carbon in sugar making by enzymolysis of starch |
-
2011
- 2011-11-03 CN CN201110343231.9A patent/CN103084154B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60829A (en) * | 1983-06-20 | 1985-01-05 | Nankai Kako Kk | Regeneration of active carbon for purifying citrus juice |
| CN1218835A (en) * | 1997-12-02 | 1999-06-09 | 中国科学院新疆化学研究所 | Regenerating method for powdered active carbon in sugar making by enzymolysis of starch |
Non-Patent Citations (1)
| Title |
|---|
| 孟宪庭: ""活性炭的吸附与微生物再生"", 《水处理技术》 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104415736A (en) * | 2013-09-09 | 2015-03-18 | 龚芯 | Active carbon regeneration method and active carbon regeneration device |
| CN105457617A (en) * | 2013-12-18 | 2016-04-06 | 帝斯曼江山制药（江苏）有限公司 | Activated carbon recovery technology |
| CN103721692A (en) * | 2014-01-22 | 2014-04-16 | 呼伦贝尔东北阜丰生物科技有限公司 | Recycling method of waste powdered activated carbon |
| CN103721692B (en) * | 2014-01-22 | 2015-12-09 | 呼伦贝尔东北阜丰生物科技有限公司 | A kind of regeneration method of waste-powder active carbon |
| CN106242028A (en) * | 2016-08-08 | 2016-12-21 | 上海市政工程设计研究总院（集团）有限公司 | A kind of biological powder activated carbon purification method of water supply factory |
| CN107051415A (en) * | 2017-04-13 | 2017-08-18 | 福建省荔元活性炭实业有限公司 | A kind of method of gluconacetobacter regenerated carbon |
| CN107051415B (en) * | 2017-04-13 | 2021-05-28 | 福建省荔元活性炭实业有限公司 | Method for regenerating activated carbon by using gluconacetobacter |
| CN108855022A (en) * | 2018-07-19 | 2018-11-23 | 深圳市环球绿地新材料有限公司 | A kind of preparation and regeneration method suitable for big partial size and the active carbon of absorption heavy metal ion |
| CN111518600A (en) * | 2019-12-23 | 2020-08-11 | 新疆中宇金盾碳基研究院(有限公司) | Saltpetering inhibitor, semi-coke type carbon containing saltpetering inhibitor and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103084154B (en) | 2016-07-06 |
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