CN103053534B - Synergistic insecticidal composition containing tolfenpyrad and chlorantraniliprole and application - Google Patents
Synergistic insecticidal composition containing tolfenpyrad and chlorantraniliprole and application Download PDFInfo
- Publication number
- CN103053534B CN103053534B CN201110317270.1A CN201110317270A CN103053534B CN 103053534 B CN103053534 B CN 103053534B CN 201110317270 A CN201110317270 A CN 201110317270A CN 103053534 B CN103053534 B CN 103053534B
- Authority
- CN
- China
- Prior art keywords
- tolfenpyrad
- rynaxypyr
- synergistic insecticidal
- insecticidal compositions
- rice
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a synergistic insecticidal composition containing tolfenpyrad and chlorantraniliprole and an application, the synergistic insecticidal composition takes tolfenpyrad and chlorantraniliprole as main effective components, wherein the weight ratio of tolfenpyrad to chlorantraniliprole is 0.1-80:0.5-80. The insecticidal composition has effects for enlarging the prevention and cure scope and synergia, and the medication cost is reduced, and the synergistic insecticidal composition can be prepared to a missible oil, a wettable powder, a microemulsion, an emulsion in water, a suspending agent and a water dispersible granule, and the synergistic insecticidal composition can be used for preventing and treating various pests such as Lepidoptera, Homoptera, Hymenoptera, thysanoptera and coleopteran.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of Synergistic insecticidal compositions and application thereof containing Tolfenpyrad and Rynaxypyr.
Background technology
Tolfenpyrad (Tolfenpyrad), the chloro-3-ethyl-1-of chemical name: 4-methyl-N-{[4-(4-methylphenoxy) phenyl]-methyl }-1H pyrazoles-5-carboxylic acid amides, for off-white color pressed powder, density (25 ℃): 1.18g/cm, vapour pressure (25 ℃): <5 * 10Pa.Solvability (25 ℃): water 0.037mg/L, n-hexane 7.41g/L, toluene 366g/L, methyl alcohol 59.6g/L.Distribution coefficient (n-octyl alcohol/water) (25 ℃): log Pow5.61.Structural formula is:
The acute toxicity of Tolfenpyrad preparation is: rat oral LD50102 (hero), 83 (female) mg/kg; Its mouse oral LD50104 (hero), 108 (female) mg/kg.Acute dermal toxicity is relatively low, to rat, the equal >2000mg/kg of mouse LD50.Lagophthalmos eyeball and skin are had to moderate spread effect.
The novel pyrazole heterocyclic insecticidal/acaricidal agent of Tolfenpyrad Shi Yuan Mitsubishi chemical company (its agricultural chemicals partly now belong to Japanese agricultural chemicals company) exploitation, its main mechanism is the oxidative phosphorylation that stops insect, also has ovicidal, presses down food, oviposition deterrence and bactericidal action.
Rynaxypyr (chlorantraniliprole), the bromo-N-[4-chloro-2-methyl-6-[(of chemical name: 3-methyl-carbamoyl) benzene]-1-(3-chloropyridine-2-yl)-1-hydrogen-pyridine-5-formamide, structural formula is:
Rynaxypyr belongs to O-formammidotiazol-benzamide insecticide.Be mainly to activate blue Buddhist nun's alkali acceptor, discharge the calcium ion of storing in smooth muscle and striated muscle cell, cause that muscle regulates weak, paralysis, until last insect is dead.This active ingredient shows mammal and the extremely significant selective difference of the blue Buddhist nun's alkali of insect acceptor, has greatly improved mammal and other vertebrate safeties.
Often there is defect in the insecticide variety containing single component: use is easily developed immunity to drugs continuously, and insecticidal spectrum is narrow, can not provide comprehensive protection for crop, and peasant's drug cost is high in agricultural chemicals control of insect.By two kinds or being combined in to a certain extent of two or more active components, can overcome to a certain extent above-mentioned shortcoming.There is two kinds of synergistic effect or the combination of two or more active components and be mixed, can improve preventive effect, reduce active ingredient ground dosage, cost-saving, slow down pest resistance occur, and can expanding prevention spectrum, play that many worms are double to be controlled, reduce peasant's use cost.
Summary of the invention
The object of this invention is to provide a kind of Synergistic insecticidal compositions containing Tolfenpyrad and Rynaxypyr.
Another object of the present invention is to provide containing the Synergistic insecticidal compositions of Tolfenpyrad and Rynaxypyr and prevents and treats the application in the insecticidal materials of one or more insects in resistance Lepidoptera, Homoptera, Hymenoptera, thrips or coleoptera in preparation.
Said composition can be used for preventing and treating various agricultural insect, for example paddy rice rice leaf roller, striped rice borer, paddy stem borer, pink rice borer, rice plant skipper, rice fulgorid, vegetables thrips, cotton bollworm, aleyrodid, leafhopper, rice silk worm are first-class, can reach the effect that a drug is prevented and treated dissimilar insect.
The present invention adopts following technical scheme:
Containing a Synergistic insecticidal compositions for Tolfenpyrad and Rynaxypyr, it take Tolfenpyrad and Rynaxypyr is main active ingredient, and wherein, the weight ratio of Tolfenpyrad and Rynaxypyr is 0.1～80:0.5～80.Be preferably 1～60:1～70, more preferably 1～30:1～30.The effective ingredient of above-mentioned Insecticidal combinations is present in composition with synergy effective dose.
At the Synergistic insecticidal compositions containing Tolfenpyrad and Rynaxypyr of the present invention, the two weight percentage in this Synergistic insecticidal compositions of Tolfenpyrad and Rynaxypyr is 2%～80%, is preferably 8%～60%, and optimum is 20%～40%.
The above-mentioned Synergistic insecticidal compositions containing Tolfenpyrad and Rynaxypyr be take Tolfenpyrad and Rynaxypyr and is mixed with any one formulation allowing on agricultural chemicals as main active ingredient (active component) and insecticides adjuvant, excipients.The preferred missible oil of formulation, wetting powder, microemulsion, aqueous emulsion, suspending agent or water dispersible granules.
Described auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33
#), polyoxyethylene nonylphenol ether etc., excipient comprises cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and the upper known auxiliary material of other agricultural can alone or and use.
Application in the insecticidal materials of the above-mentioned Synergistic insecticidal compositions containing Tolfenpyrad and Rynaxypyr one or more insects in preparation control Lepidoptera, Homoptera, Hymenoptera, thrips or coleoptera, reaches the effect that a medicine is controlled more.Especially the effect in the first-class insecticidal materials of paddy rice rice leaf roller, striped rice borer, paddy stem borer, pink rice borer, rice plant skipper, rice fulgorid, vegetables thrips, cotton bollworm, aleyrodid, leafhopper or the rice silk worm of the easy generation of preparation control resistance is remarkable, and suppresses the pesticide resistance generation of insect to unitary agent (Tolfenpyrad or Rynaxypyr).
Pesticidal combination of the present invention compared with prior art, produces following beneficial effect: (1) is compared with single dose, and said composition insect has notable synergistic, has obviously improved control efficiency; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost; (3) alternative high-toxic pesticide, and significantly reduce field dosage, effectively reduce environmental pollution and residue of pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with Tolfenpyrad single dose, produce and use cost reduction; (6) suppressing insect strengthens the resistance of agricultural chemicals;
Embodiment
Embodiments of the invention are the methods that adopt indoor bioassay and field trial to combine.First by indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage; On this basis, then carry out field trial.
Embodiment 1:
Taking Tolfenpyrad, Rynaxypyr adopts conventional formulation method to be mixed with by different proportion the Tolfenpyrad Rynaxypyr missible oil that main active ingredient weight percentage is 30%.Concrete ratio is in Table 1.
Adopt feed to add malicious method and measure Tolfenpyrad and Rynaxypyr and the virulence of composite sample to rice-stem borer thereof, every processing repeats 3 times, and every concentration is processed 30, uses LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 1 Tolfenpyrad, Rynaxypyr and composite sample thereof are to the toxicity test of rice-stem borer and co-toxicity coefficient
In table, data show, after Tolfenpyrad and Rynaxypyr are mixed, rice-stem borer are had to synergistic effect, and four proportioning co-toxicity coefficients listed in table are all much larger than 120, so Tolfenpyrad and Rynaxypyr are mixed and have significant synergies.Wherein when the ratio of Rynaxypyr and Tolfenpyrad is 5:1, be mixed and kill the synergistic effect maximum of rice-stem borer, co-toxicity coefficient is 207.52.
Embodiment 2:
Taking Tolfenpyrad, Rynaxypyr adopts conventional formulation method to be mixed with by different proportion the Tolfenpyrad Rynaxypyr missible oil that main active ingredient weight percentage is 30%.Concrete ratio is in Table 2.
Adopt rice stem infusion process to measure Tolfenpyrad and Rynaxypyr and the virulence of composite sample to paddy rice rice leaf roller thereof, every processing repeats 3 times, uses LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 2 Tolfenpyrad, Rynaxypyr and composite sample thereof are to the toxicity test of paddy rice rice leaf roller and co-toxicity coefficient
In table, data show, after Tolfenpyrad and Rynaxypyr are mixed, rice leaf roller are had to synergistic effect, and four proportioning co-toxicity coefficients listed in table are all much larger than 120, so Tolfenpyrad and Rynaxypyr are mixed and have significant synergies.Wherein when the ratio of Tolfenpyrad and Rynaxypyr is 1:10, be mixed and kill the synergistic effect maximum of paddy rice rice leaf roller, co-toxicity coefficient is 216.14.
Embodiment 3:
Take 5g Tolfenpyrad, 20g Rynaxypyr, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, add dimethylbenzene to 100g, the method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Tolfenpyrad Rynaxypyr missible oil that main active ingredient weight percentage is 25%.
Adopt 3 sample product of embodiment to carry out the field trial of control in field paddy rice rice leaf roller, contrast medicament is 15% Tolfenpyrad EC(missible oil) and 22% Rynaxypyr SC(suspending agent), concrete consumption is in Table 3, every mu of water consumption is 30kg, looks into 7 days after medicine 3 days, 14 days, 28 days results.With clear water, do blank, result of the test is in Table 3:
The field test results of table 3 example 3 samples to paddy rice rice leaf roller
3 pairs of paddy rice rice leaf roller of example have fabulous quick-acting as can be seen from Table 3, and the lasting period is more intense, in field performance well, are the outstanding medicaments of control paddy rice rice leaf roller.
Embodiment 4:
Adopt 3 sample product of embodiment to carry out the field trial of control in field cotton cotton bollworm, contrast medicament is 15% Tolfenpyrad EC and 22% Rynaxypyr SC, and concrete consumption is in Table 3, and every mu of water consumption is 30kg, after medicine, look into 3 days, and 7 days, 14 days, 28 days results.With clear water, do blank, result of the test is in Table 4:
The field test results of table 4 example 3 samples to cotton cotton bollworm
Example 3 samples have fabulous effect to cotton cotton bollworm as can be seen from Table 4, and the lasting period is long, in field performance well, are the outstanding medicaments that prevents cotton cotton bollworm.
Through indoor synergism test, measure and show: by Tolfenpyrad and Rynaxypyr built agent, paddy rice rice leaf roller and cotton cotton bollworm are all had to significant synergistic insecticidal action; Field control effectiveness test equally also shows that all built agents of the present invention are all significantly higher than the effect of corresponding single dose agricultural chemicals to the insecticidal effect of rice leaf roll snout moth's larva and cotton cotton bollworm.
Embodiment 5:
Take 0.2g Tolfenpyrad, 19.8g Rynaxypyr, lignin 10g, Negel 2g, with kaolin, add to 100g, above raw material is mixed in micronizer, form the Tolfenpyrad Rynaxypyr wetting powder that main active ingredient weight percentage is 20%.
Embodiment 6:
Take 78g Tolfenpyrad, 0.5g Rynaxypyr, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, dimethylbenzene and add to 100g, the method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Tolfenpyrad Rynaxypyr missible oil that main active ingredient weight percentage is 78.5%.
Embodiment 7:
Take 2g Tolfenpyrad, 10g Rynaxypyr, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butanol 3g, the dimethylbenzene of 30g and the pyrrolidones of 20g, the xanthans of 0.1g, all the other waters are supplied 100g, n-butanol and water-soluble solution form water, all the other component mix and blends form oil phase, slowly water is added to oil phase under clipper effect in, go, and continue to shear 10～30 minutes, form the Tolfenpyrad chlorantraniliprole water emulsion that main active ingredient weight percentage is 12%.
Embodiment 8:
Take 10g Tolfenpyrad, 30g Rynaxypyr, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, the solvent xylene of 30g and the pyrrolidones of 15g, all the other waters complement to 100g, former medicine, solvent, emulsifier, cosolvent mix and blend form homogeneous phase transparent solution, then slowly add water and stir to form clear solution, be the Tolfenpyrad Rynaxypyr microemulsion that main active ingredient weight percentage is 40%.
Embodiment 9:
Take 4g Tolfenpyrad, 4g Rynaxypyr, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Tolfenpyrad Rynaxypyr missible oil that main active ingredient weight percentage is 8%.
Embodiment 10:
Take 3g Tolfenpyrad, 30g Rynaxypyr, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, water is supplied 100g, forms the Tolfenpyrad Rynaxypyr suspending agent that main active ingredient weight percentage is 33% under the effect of sand mill.
Embodiment 11:
Take 5g Tolfenpyrad, 55g Rynaxypyr, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Tolfenpyrad Rynaxypyr missible oil that main active ingredient weight percentage is 60%.
Embodiment 12:
Take 45g Tolfenpyrad, 5g Rynaxypyr, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 28g, forms by the method for water dispersion granule the Tolfenpyrad Rynaxypyr water dispersible granules that main active ingredient weight percentage is 50% by above raw material.
Embodiment 13:
Take 30g Tolfenpyrad, 1g Rynaxypyr, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Tolfenpyrad Rynaxypyr missible oil that main active ingredient weight percentage is 31%.
Embodiment 14:
Take 60g Tolfenpyrad, 1g Rynaxypyr, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Tolfenpyrad Rynaxypyr missible oil that main active ingredient weight percentage is 31%.
Embodiment 15:
Take 1g Tolfenpyrad, 70g Rynaxypyr, alkylphenol polyoxyethylene 10g, phenethyl phenol polyethenoxy ether 10g, dimethylbenzene to 100g, the method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and forms the Tolfenpyrad Rynaxypyr missible oil that main active ingredient weight percentage is 71%.
Claims (7)
1. the Synergistic insecticidal compositions containing Tolfenpyrad and Rynaxypyr, it is characterized in that it is active ingredient that this Synergistic insecticidal compositions be take Tolfenpyrad and Rynaxypyr, wherein, the weight ratio of Tolfenpyrad and Rynaxypyr is 10:1,5:1,2.5:1,1:1.
2. the Synergistic insecticidal compositions containing Tolfenpyrad and Rynaxypyr according to claim 1, is characterized in that the two weight percentage in this Synergistic insecticidal compositions of Tolfenpyrad and Rynaxypyr is 2%～80%.
3. the Synergistic insecticidal compositions containing Tolfenpyrad and Rynaxypyr according to claim 2, is characterized in that the two weight percentage in this Synergistic insecticidal compositions of Tolfenpyrad and Rynaxypyr is 8%～60%.
4. the Synergistic insecticidal compositions containing Tolfenpyrad and Rynaxypyr according to claim 3, is characterized in that the two weight percentage in this Synergistic insecticidal compositions of Tolfenpyrad and Rynaxypyr is 20%～40%.
5. the Synergistic insecticidal compositions containing Tolfenpyrad and Rynaxypyr according to claim 1, is characterized in that this Synergistic insecticidal compositions take Tolfenpyrad and Rynaxypyr and be mixed with missible oil, wetting powder, microemulsion, aqueous emulsion, suspending agent or water dispersible granules as active ingredient and insecticides adjuvant, excipients.
6. the application in the insecticidal materials of the Synergistic insecticidal compositions containing Tolfenpyrad and Rynaxypyr claimed in claim 1 one or more insects in preparation control Lepidoptera, Homoptera, Hymenoptera, thrips or coleoptera.
7. application according to claim 6, is characterized in that described lepidoptera pest is paddy rice rice leaf roller, striped rice borer, paddy stem borer, pink rice borer, rice plant skipper, cotton bollworm; Described homoptera pest is rice fulgorid, aleyrodid, leafhopper; Described thrips insect is vegetables thrips; Described coleopteran pest is rice silk worm first.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110317270.1A CN103053534B (en) | 2011-10-18 | 2011-10-18 | Synergistic insecticidal composition containing tolfenpyrad and chlorantraniliprole and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110317270.1A CN103053534B (en) | 2011-10-18 | 2011-10-18 | Synergistic insecticidal composition containing tolfenpyrad and chlorantraniliprole and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103053534A CN103053534A (en) | 2013-04-24 |
| CN103053534B true CN103053534B (en) | 2014-03-05 |
Family
ID=48096680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110317270.1A Active CN103053534B (en) | 2011-10-18 | 2011-10-18 | Synergistic insecticidal composition containing tolfenpyrad and chlorantraniliprole and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103053534B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017140563A1 (en) | 2016-02-19 | 2017-08-24 | Basf Se | Pesticidally active mixtures comprising anthranilamide compounds |
| CN105685050B (en) * | 2016-03-31 | 2017-11-07 | 杭州宇龙化工有限公司 | A kind of agricultural pesticide composition and application thereof |
| WO2023073566A1 (en) | 2021-10-29 | 2023-05-04 | Pi Industries Ltd. | Oil dispersion formulation |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1541063A (en) * | 2001-08-13 | 2004-10-27 | ��Ļ���Ű˾ | Method for controlling particular insects by applying anthranilamide compounds |
| WO2007082841A2 (en) * | 2006-01-20 | 2007-07-26 | Basf Se | Pesticidal mixtures |
| CN101557710A (en) * | 2006-12-14 | 2009-10-14 | 石原产业株式会社 | Pesticidal compositions |
| CN101669500A (en) * | 2009-08-23 | 2010-03-17 | 山东兆丰年生物科技有限公司 | Synergistic pesticide composition |
| CN101801191A (en) * | 2007-07-30 | 2010-08-11 | 纳幕尔杜邦公司 | Fly control method |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010047478A (en) * | 2006-12-19 | 2010-03-04 | Mitsui Chemicals Inc | Pest control composition |
-
2011
- 2011-10-18 CN CN201110317270.1A patent/CN103053534B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1541063A (en) * | 2001-08-13 | 2004-10-27 | ��Ļ���Ű˾ | Method for controlling particular insects by applying anthranilamide compounds |
| WO2007082841A2 (en) * | 2006-01-20 | 2007-07-26 | Basf Se | Pesticidal mixtures |
| CN101557710A (en) * | 2006-12-14 | 2009-10-14 | 石原产业株式会社 | Pesticidal compositions |
| CN101801191A (en) * | 2007-07-30 | 2010-08-11 | 纳幕尔杜邦公司 | Fly control method |
| CN101669500A (en) * | 2009-08-23 | 2010-03-17 | 山东兆丰年生物科技有限公司 | Synergistic pesticide composition |
Non-Patent Citations (3)
| Title |
|---|
| JP特开2010-47478A 2010.03.04 |
| 徐尚成 等.新杀虫剂氯虫苯甲酰胺及其研究开发进展.《现代农药》.2008,第7卷(第5期),参见第8-11页. |
| 新杀虫剂氯虫苯甲酰胺及其研究开发进展;徐尚成 等;《现代农药》;20081031;第7卷(第5期);参见第8-11页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103053534A (en) | 2013-04-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103621535A (en) | Synergistic insect disinfestation composition containing clothianidin and chlorantraniliprole, and application thereof | |
| CN103039457B (en) | Synergistic insecticidal composition containing tolfenpxrad and flubendiamide and application thereof | |
| CN102017992A (en) | Synergistic insecticidal composition containing chlorfluazuron and chlorpyrifos-methyl and application thereof | |
| CN103053534B (en) | Synergistic insecticidal composition containing tolfenpyrad and chlorantraniliprole and application | |
| CN103621546A (en) | Synergistic insecticidal composition containing clothianidin and imidacloprid and applications thereof | |
| CN103621532A (en) | Synergistic insecticidal composition containing thiamethoxam and tolfenpyrad and application thereof | |
| CN103039456B (en) | Synergistic insecticidal composition containing tolfenpxrad and S-fenvalerate and application thereof | |
| CN103651497A (en) | Synergistic insecticidal composition containing clothianidin and flubendiamide and application of synergistic insecticidal composition | |
| CN103039458A (en) | Insecticidal composition containing tolfenpxrad and pyridalyl and application thereof | |
| CN103039500A (en) | Synergistic insecticidal composition containing tolfenpxrad and cyfloxylate and application thereof | |
| CN103053594A (en) | Synergistic insecticidal composition containing tolfenpyrad and theta-cypermethrin and its application | |
| CN103053577A (en) | Synergistic insecticidal composition containing tolfenpyrad and indoxacarb and application | |
| CN103039455B (en) | Synergistic insecticidal composition containing tolfenpxrad and flonicamid and application thereof | |
| CN103053596A (en) | Synergistic insecticidal composition containing tolfenpyrad and cypermethrin and application | |
| CN103039475A (en) | Synergistic insecticidal composition containing tolfenpxrad and chlorfluazuron and application thereof | |
| CN103053595A (en) | Synergistic insecticidal composition containing tolfenpyrad and beta-cyfluthrin and application | |
| CN102017949A (en) | Synergistic pesticidal composition containing nitenpyram and ethofenprox and application thereof | |
| CN103053570A (en) | Synergistic insecticidal composition containing tolfenpyrad and metaflumizone and application | |
| CN103621537A (en) | Synergistic insecticidal composition containing clothianidin and banleptm and applications thereof | |
| CN103621538A (en) | Synergistic insecticidal composition containing clothianidin and imidaclothiz and applications thereof | |
| CN103621540B (en) | Synergistic insecticidal composition containing clothianidin and chlorfluazuron and applications thereof | |
| CN103053536A (en) | Synergistic insecticidal composition containing tolfenpyrad and ethofenprox and application | |
| CN103053592A (en) | Synergistic insecticidal composition containing Tolfenpyrad and alpha-cypermethrin and its application | |
| CN103053593A (en) | Synergistic insecticidal composition containing Tolfenpyrad and fenpropathrin and its application | |
| CN102017993A (en) | Synergistic insecticidal compound containing pymetrozine and chlorpyrifos-methyl and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180516 Address after: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Co-patentee after: Nanjing Redsun Co., Ltd. Patentee after: Nanjing Huazhou Pharmaceutical Co., Ltd. Address before: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Patentee before: Nanjing Huazhou Pharmaceutical Co., Ltd. |