CN103045081A - Anticorrosion flow for metal structure - Google Patents
Anticorrosion flow for metal structure Download PDFInfo
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- CN103045081A CN103045081A CN2012105381227A CN201210538122A CN103045081A CN 103045081 A CN103045081 A CN 103045081A CN 2012105381227 A CN2012105381227 A CN 2012105381227A CN 201210538122 A CN201210538122 A CN 201210538122A CN 103045081 A CN103045081 A CN 103045081A
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- coating method
- protective system
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- Preventing Corrosion Or Incrustation Of Metals (AREA)
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Abstract
The invention discloses an anticorrosion flow for a metal structure, comprising: mixing siloxane, a solvent, silica particles, rare earth compounds, deionized water, a catalyst, carbon fiber and polyimides, slaking the mixture, filtering the slaked mixture, then spraying, brushing or dipping the mixture on a surface of base material, and forming a coating on the surface of the base material after deposition, thereby implementing the surface anticorrosion treatment.
Description
Technical field
The present invention relates to a kind of protective system coating method, relate in particular to a kind of metal structure surface that is applicable to, have the coating method of the environmental protection coating material of excellent gloss and mechanical and physical performance and aromatic free solvent.
Background technology
In modern industry and daily life, corrosion of metal is seen everywhere, and the destruction of the forms such as crevice corrosion, stress corrosion and corrosion fatigue that especially occur in the storage vessel of a fuel oil dangerization product is caused great potential safety hazard for people's lives.
The metal protection method that adopts at present can roughly be divided three classes: a class is to carry out anodic oxidation treatment, namely form the anode oxide film of one deck tens micron thickness in the metallic surface, but because the anode oxidation process power consumption is large, and electrolyte solution is seriously polluted, be difficult to process, use its application to be restricted; Equations of The Second Kind is chemical conversion film, being about to metal parts is immersed in the solution of definite composition, rely at a certain temperature chemical reaction to form one deck chemical conversion film, now most widely used is the oxidation of chromic salt chemistry, but chromic salt is a kind of carcinogenic toxicant, and the world environments protective tissue has proposed restriction and used chromic salt and other to contain chromate compound; The 3rd class is organic coating, namely applies one deck organic coating in the metallic surface, with outward appearance and the physical and chemical performance that improves metal.People begin rare earth element is used in the aseptic technic of metallic surface in recent years.
The rare-earth conversion coatings film technique develops into today, and people have carried out a large amount of improvement to various film-forming process, and the performance of film also is improved.At present the rare-earth conversion coatings technology mainly is immersion treatment, and this technological operation is simple, be easy to safeguard; But its drawback is that the long period of soaking process treatment time is oversize, and formed rete is thinner and relatively poor with the sticking power of base material.Find through long-term exploratory development, add strong oxidizer in the soaking solution, such as H
2O
2, KMnO
4, (NH
4)
2S
2O
8Etc. strong oxide compound, rate of film build is improved greatly, the treatment time shortens dramatically, and the treatment soln temperature is not high yet simultaneously, can at room temperature use.But because the existence of strong oxidizer is so that the less stable for the treatment of process.
The problem that exists in order to solve the rare-earth conversion coatings treatment process, the present invention proposes a kind of improved protective system coating method.This method anticorrosion with low cost, remarkable in economical benefits can be carried out normal temperature and be spread, and coating processes is simple, and solution is environment friendly and pollution-free.
Summary of the invention
The objective of the invention is for the deficiencies in the prior art part, provide a kind of coating method of environment friendly corrosion protection coating, in order to solve the protection against corrosion difficult problem of the surfaces externally and internally applications such as steel, aluminium, especially aluminium alloy, and coating aromatic free solvent, do not contain strong oxidizer, without poisonous pigment, be fit to various constructional methods, application is not subject to seasonal restrictions, and construction technology is simple and convenient, and technical costs is cheap, good environmental protection.
The present invention is achieved by the following technical solutions:
(1) prepare following component (mass parts):
A 3-Racemic glycidol propyl-triethoxysilicane 1-10;
B propyl alcohol 40-60;
C SiO
2Particle 1-5;
The oxide compound 6-10 of d cerium;
E deionized water 5-25;
F acetic acid 1-3;
G carbon fiber 5-7;
H polyimide 1-3;
(2) with carrying out maturation process after the above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Embodiment
The present invention relates to the anticorrosion flow process of a kind of metal construction, after the various components of protective system are mixed, carry out maturation process, again the mixture after the slaking is filtered, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Described SiO
2The particle diameter of particle is the 50-100 nanometer.
Described maturation process is to leave standstill at normal temperatures 50-60 hour.
Described base material is steel or aluminium, preferred aluminium alloy.
Heat in the deposition process after spraying, brushing or dipping, Heating temperature is to heat 1 minute to 1 hour under 50 ℃ to the 150 ℃ temperature.
The thickness of described coating is 1 micron to 10 microns, preferred 1 micron to 5 microns.The preferred method that adopts spraying or brush forms coating at substrate surface.
Protective system coating method disclosed by the invention is simple, convenient, quick, reliable, and raw material is cheap, this method can be simply in conjunction with enter the existing pre-treatment that comprises coating and after in the conventional production line of other postprocessing working procedures of substrate material, substantially need not to carry out other adjustment on the equipment, is the Eco-power production technique of a kind of height.
The below elaborates with embodiment to the present invention, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1
(1) prepare following component (mass parts):
A 3-Racemic glycidol propyl-triethoxysilicane 1;
B propyl alcohol 40;
C SiO
2Particle 1;
The oxide compound 6 of d cerium;
E deionized water 5;
F acetic acid 1;
G carbon fiber 5;
H polyimide 1;
(2) with carrying out maturation process after the above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Embodiment 2
(1) prepare following component (mass parts):
A 3-Racemic glycidol propyl-triethoxysilicane 10;
B propyl alcohol 60;
C SiO
2Particle 5;
The oxide compound 10 of d cerium;
E deionized water 25;
F acetic acid 3;
G carbon fiber 7;
H polyimide 3;
(2) with carrying out maturation process after the above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Embodiment 3
(1) prepare following component (mass parts):
A 3-Racemic glycidol propyl-triethoxysilicane 5;
B propyl alcohol 50;
C SiO
2Particle 3;
The oxide compound 8 of d cerium;
E deionized water 15;
F acetic acid 2;
G carbon fiber 6;
H polyimide 2;
(2) with carrying out maturation process after the above component mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
Claims (9)
1. anticorrosion flow process of metal construction comprises:
(1) prepare following component (mass parts):
A 3-Racemic glycidol propyl-triethoxysilicane 1-10;
B propyl alcohol 40-60;
C SiO
2Particle 1-5;
The oxide compound 6-10 of d cerium;
E deionized water 5-25;
F acetic acid 1-3;
G carbon fiber 5-7;
H polyimide 1-3;
(2) with carrying out maturation process after the said components mixing, then spray, brush or be immersed in substrate surface, form coating at substrate surface after the deposition, realize the surface anticorrosion processing.
2. the coating method of described protective system according to claim 1 is characterized in that described SiO
2The particle diameter of particle is the 50-100 nanometer.
3. the coating method of described protective system according to claim 1 is characterized in that described maturation process is to leave standstill at normal temperatures 50-60 hour.
4. the coating method of described protective system according to claim 1 is characterized in that described base material is steel or aluminium.
5. the coating method of described protective system according to claim 1 is characterized in that described base material is aluminium alloy.
6. the coating method of described protective system according to claim 1 is characterized in that heat, Heating temperature is 50 ℃ to 150 ℃, 1 minute to 1 hour heat-up time in described deposition process.
7. the coating method of described protective system according to claim 1 is characterized in that described coat-thickness is 1 micron to 10 microns.
8. the coating method of described protective system according to claim 7 is characterized in that described coat-thickness is 1 micron to 5 microns.
9. the coating method of described protective system according to claim 1 is characterized in that, adopts spraying in the described step (2) or the method for brushing forms coating at substrate surface.
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CN2012105381227A CN103045081A (en) | 2012-12-13 | 2012-12-13 | Anticorrosion flow for metal structure |
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CN2012105381227A CN103045081A (en) | 2012-12-13 | 2012-12-13 | Anticorrosion flow for metal structure |
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CN103045081A true CN103045081A (en) | 2013-04-17 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103232809A (en) * | 2013-04-22 | 2013-08-07 | 上海华篷防爆科技有限公司 | Coating process of copper alloy foil explosion-proof material |
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CN1078735A (en) * | 1992-05-11 | 1993-11-24 | 中国科学院上海有机化学研究所 | Fluoro plastic coating, manufacturing and application thereof |
KR100730414B1 (en) * | 2005-12-29 | 2007-06-19 | 제일모직주식회사 | Antibacterial and antistatic multifunctional hard coating composition, its coating method and hard coating transparent sheet using it |
KR20070070613A (en) * | 2005-12-29 | 2007-07-04 | 엘지전자 주식회사 | Manufacturing method for surface conduction electronemission display |
CN101717930A (en) * | 2009-12-25 | 2010-06-02 | 华烁科技股份有限公司 | Environment-friendly nano water-based silane treatment agent capable of improving anti-corrosion performance of metal surface |
CN102174289A (en) * | 2011-02-25 | 2011-09-07 | 上海交通大学 | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof |
-
2012
- 2012-12-13 CN CN2012105381227A patent/CN103045081A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1078735A (en) * | 1992-05-11 | 1993-11-24 | 中国科学院上海有机化学研究所 | Fluoro plastic coating, manufacturing and application thereof |
KR100730414B1 (en) * | 2005-12-29 | 2007-06-19 | 제일모직주식회사 | Antibacterial and antistatic multifunctional hard coating composition, its coating method and hard coating transparent sheet using it |
KR20070070613A (en) * | 2005-12-29 | 2007-07-04 | 엘지전자 주식회사 | Manufacturing method for surface conduction electronemission display |
CN101717930A (en) * | 2009-12-25 | 2010-06-02 | 华烁科技股份有限公司 | Environment-friendly nano water-based silane treatment agent capable of improving anti-corrosion performance of metal surface |
CN102174289A (en) * | 2011-02-25 | 2011-09-07 | 上海交通大学 | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103232809A (en) * | 2013-04-22 | 2013-08-07 | 上海华篷防爆科技有限公司 | Coating process of copper alloy foil explosion-proof material |
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Application publication date: 20130417 |