CN102918190A - Non-woven fabric including elongated fibres and elastic fibres and having unevenness, and method for manufacturing non-woven fabric - Google Patents
Non-woven fabric including elongated fibres and elastic fibres and having unevenness, and method for manufacturing non-woven fabric Download PDFInfo
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- CN102918190A CN102918190A CN2011800268452A CN201180026845A CN102918190A CN 102918190 A CN102918190 A CN 102918190A CN 2011800268452 A CN2011800268452 A CN 2011800268452A CN 201180026845 A CN201180026845 A CN 201180026845A CN 102918190 A CN102918190 A CN 102918190A
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- nonwoven fabric
- fiber
- extensibility fiber
- recess
- extensibility
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- 239000000806 elastomer Substances 0.000 claims description 15
- 239000004814 polyurethane Substances 0.000 claims description 9
- 229920002635 polyurethane Polymers 0.000 claims description 9
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- 239000000463 material Substances 0.000 claims description 7
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
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Images
Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
- D04H1/495—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet for formation of patterns, e.g. drilling or rearrangement
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
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- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/02—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/14—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/14—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
- D04H3/147—Composite yarns or filaments
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/14—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
- D04H3/153—Mixed yarns or filaments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C3/00—Stretching, tentering or spreading textile fabrics; Producing elasticity in textile fabrics
- D06C3/06—Stretching, tentering or spreading textile fabrics; Producing elasticity in textile fabrics by rotary disc, roller, or like apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/266—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24446—Wrinkled, creased, crinkled or creped
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
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- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
- Y10T428/2457—Parallel ribs and/or grooves
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
Disclosed is a non-woven fabric which includes elongated fibres and elastic fibres, has unevenness, exhibits excellent texture and elasticity, and exhibits excellent breathability in both the planar and thickness direction. Further disclosed is a method for manufacturing the non-woven fabric. The disclosed non-woven fabric including elongated fibres and elastic fibres and having unevenness is characterised by having a plurality of convex and concave sections on a first surface thereof, with the elongation fibre ratio of the convex sections being greater than the elongation fibre ratio of the concave sections.
Description
Technical field
The present invention relates to comprise the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool, and the manufacture method of this nonwoven fabric.The invention still further relates to that skin feel and retractility are good, the good air permeability of in-plane and thickness direction, comprise the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool, and the manufacture method of this nonwoven fabric.
Background technology
Nonwoven fabric is used in absorbent commodities such as amenities and disposable diaper, such as the cleaning supplies such as wiper and such as the product of the medical supplies such as face shield, these products adopt the nonwoven fabric of the performance with suitable product purpose, employed position etc.
Absorbent commodity for example requires is to allow the user feel nonwoven fabric uncomfortable, that stretch according to the activity of health when wearing or when using.What in addition, disposable diaper required is the nonwoven fabric that has high scalability and have can not rupture such intensity, while skin feel and good air permeability when elongation.
As everyone knows, when using elastic fibre in order to make nonwoven fabric have retractility, because elastic fibre generally all has viscosity and has high frictional property, so the skin feel of nonwoven fabric is poor.
In addition, for example in patent documentation 1, delivered horizontal direction good air permeability, have the top flat of concaveconvex shape.Patent documentation 1 described top flat is characterised in that: have the first fibrage and the second fibrage that are comprised of fiber assembly; Lamination the first fibrage and the second fibrage carry out the localized heat bond vitrified with the regulation pattern; The position of the first fibrage beyond the first and second fibrolaminar heat fusing binding parts forms protrusion, in this protrusion and position above-mentioned heat fusing binding part adjacency, consist of fiber and carry out each other the heat fusing bonding, rigidity is higher than other positions in this protrusion; And, 10cN/cm
2Pressure under to see through capacity to the air of horizontal direction be 10mL/cm
2More than/second.
But the top flat of patent documentation 1 has following problem: (i) the first fibrolaminar protrusion forms by the second fibrolaminar heat-shrinkable, and therefore along with thermal contraction, the fiber spacing in the second fibrage is from diminishing, and the gas permeability of the thickness direction of sheet descends.And the top flat of patent documentation 1 also has following problem: (ii) comprise the second fibrage melting when thermal contraction of heat fusing viscose fibre, fiber is engaged with each other, so the top flat hardening, is difficult to follow the activity of health, the skin feel variation.
Technical literature formerly
Patent documentation
Patent documentation 1: TOHKEMY 2003-126147 communique
Summary of the invention
Invent problem to be solved
As mentioned above, the skin feel of nonwoven fabric that comprises elastic fibre is poor, and hard and skin feel is poor to the nonwoven fabric of the good air permeability of horizontal direction.
Therefore, the object of the present invention is to provide that skin feel and retractility are good, the good air permeability of in-plane and thickness direction, comprise the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool, and the manufacture method of this nonwoven fabric.
Be used for solving the means of problem
The present inventor conducts in-depth research in order to solve above-mentioned problem, found that by following nonwoven fabric and can solve above-mentioned problem and finish thus the present invention, that is: a kind of nonwoven fabric, comprise extensibility fiber and elastic fibre and have concavo-convex, it is characterized in that, first surface at above-mentioned nonwoven fabric has a plurality of protuberances and a plurality of recess, and the ratio of the extensibility fiber in the raised part is higher than the ratio of the extensibility fiber in the above-mentioned recess.
The present invention is specifically related to following several form.
[the first form]
A kind of nonwoven fabric, this nonwoven fabric comprise extensibility fiber and elastic fibre and have concavo-convexly, it is characterized in that,
First surface at described nonwoven fabric has a plurality of protuberances and a plurality of recess, and,
The ratio of the extensibility fiber in the described protuberance is higher than the ratio of the extensibility fiber in the described recess.
[the second form]
According to the described nonwoven fabric of the first form, described nonwoven fabric has a plurality of protuberances and a plurality of recess second of the opposition side of the first surface that is positioned at described nonwoven fabric, and the ratio of the extensibility fiber in second the protuberance is higher than the ratio of the extensibility fiber in second the recess.
[the third form]
According to the described nonwoven fabric of the second form, the protuberance of first surface and recess are parallel with first direction respectively, and alternately are configured in the direction with the first direction quadrature.
[the 4th form]
According to the described nonwoven fabric of the third form, second protuberance and recess are parallel with second direction respectively, and alternately are configured in the direction with the second direction quadrature.
[the 5th form]
According to the described nonwoven fabric of the 4th form, first direction and second direction quadrature.
[the 6th form]
According to the described nonwoven fabric of the 5th form, first direction is throughput direction, and second direction is the orthogonal direction with the throughput direction quadrature.
[the 7th form]
According to each described nonwoven fabric in the second to the 6th form, have one or more aperture portion that the recess with the recess of first surface and second links.
[the 8th form]
According to each described nonwoven fabric in the first to the 7th form, the material of described extensibility fiber is selected from the group that comprises polyolefin, polystyrene, polyester, polyamide, polyurethane, PLA and their combination.
[the 9th form]
According to each described nonwoven fabric in the first to the 8th form, the material of described elastic fibre is selected from the group that comprises polyurethanes elastomer, polystyrene type elastomer, ethylene octane copolymer, polyamide-based elastomer, polyester elastomer and their combination.
[the tenth form]
A kind of manufacture method of nonwoven fabric is made each described nonwoven fabric in the first to the 9th form, it is characterized in that, may further comprise the steps:
Preparation comprises the step of the nonwoven fabric of extensibility fiber and elastic fibre;
The step that stretches unevenly: the described nonwoven fabric that comprises extensibility fiber and elastic fibre that stretches unevenly, in order to form the nonwoven fabric with high stretch zones and low stretch zones; Then,
Form the described step that comprises extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool: described nonwoven fabric with high stretch zones and low stretch zones is configured on the supporter, then spray the fluid that is ejected to described nonwoven fabric with high stretch zones and low stretch zones, process thus, form the described irregular nonwoven fabric of extensibility fiber and elastic fibre and tool that comprises.
[the 11 form]
According to the described method of the tenth form, the described step that stretches is unevenly carried out in the following manner, that is: the described nonwoven fabric that comprises extensibility fiber and elastic fibre is passed through in the gap that has with a pair of discaling roll of the rotation of throughput direction quadrature, this simultaneously makes a plurality of teeth that are configured on this discaling roll outer peripheral face separately one side that is engaged with each other be rotated to discaling roll.
[the 12 form]
According to the described method of the 11 form, described a plurality of tooth and described rotation are located vertically on the described outer peripheral face, are formed on the orthogonal direction with the throughput direction quadrature alternately to have parallel with described throughput direction respectively high stretch zones and the nonwoven fabric of low stretch zones; Perhaps, described a plurality of teeth and described rotation are configured on the described outer peripheral face abreast, are formed on alternately to have parallel with the direction that is orthogonal to described throughput direction respectively high stretch zones and the nonwoven fabric of low stretch zones on the throughput direction.
[the 13 form]
According to each described method in the tenth to the 12 form, implement the described step that stretches unevenly twice.
[the 14 form]
According to each described method in the tenth to the 13 form, in forming the described step that comprises extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool, described supporter has protruding part and the depressed part of pre-determined shape and arrangement at the face that contacts with nonwoven fabric.
[the 15 form]
According to the described method of the 14 form, the protruding part of described pre-determined shape and arrangement and depressed part are parallel to respectively the orthogonal direction with the throughput direction quadrature, and alternately are configured on the throughput direction.
[the 16 form]
According to each described method in the tenth to the 15 form, described fluid is selected from the group that comprises air, steam and water.
The effect of invention
Skin feel and the retractility that comprises extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool of the present invention is good.
In addition, the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool that comprises of the present invention is at the good air permeability of in-plane and thickness direction.
Description of drawings
Fig. 1 is the schematic diagram that comprises a form of extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool of the present invention.
Fig. 2 is the schematic diagram that comprises another form of extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool of the present invention.
Fig. 3 is the again schematic diagram of a form that comprises extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool of the present invention.
Fig. 4 is the other forms of schematic diagram that comprises extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool of the present invention.
Fig. 5 is the schematic diagram that stretches for the explanation tooth.
Fig. 6 is the schematic diagram that stretches for the explanation tooth.
Fig. 7 is the schematic diagram that stretches for the explanation tooth.
Fig. 8 is the figure of an example of employed supporter for supporting nonwoven fabric on the expression conveyer.
Fig. 9 is the figure that utilizes the irregular nonwoven fabric of tool of supporter formation shown in Figure 8 for explanation.
Figure 10 is the figure of another example of employed supporter for supporting nonwoven fabric on the expression conveyer.
Figure 11 is that the nonwoven fabric 2 of formation among the embodiment 1 is at the microphotograph in the cross section of direction MD.
The specific embodiment
Below, comprise the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool with regard to of the present invention, and the manufacture method of this nonwoven fabric is elaborated.
[comprising the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool]
The irregular nonwoven fabric of extensibility fiber and elastic fibre and tool (below be sometimes referred to as " nonwoven fabric of the present invention ") that comprises of the present invention, have a plurality of protuberances and a plurality of recess at first surface, and the ratio of the extensibility fiber in the raised part is higher than the ratio of the extensibility fiber in the above-mentioned recess.
Fig. 1 is the schematic diagram that comprises a form of extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool of the present invention.The irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool that comprises shown in Figure 1 has a plurality of protuberances 3 and a plurality of recess 4 at first surface 2.In shown in Figure 1 comprising in the irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool, because protuberance 3 is rich in extensibility fiber EX, and recess 4 is rich in elastic fibre EL, and therefore, the ratio of the extensibility fiber in the protuberance 3 is higher than the ratio of the extensibility fiber in the recess 4.In addition, in shown in Figure 1 comprising in the irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool, protuberance 3 is parallel with first direction A separately with recess 4, and alternately is configured in the direction with first direction A quadrature.In the form of Fig. 1, in protuberance 3, extensibility fiber EX has along the trend of first direction A configuration, and in recess 4, elastic fibre EL does not have special orientation.
At this, " ratio of extensibility fiber " refers to that the extensibility Fiber Phase at this position is to the ratio of whole fibers.So long as can measure the method for extensibility proportion of fibers, then this ratio is not particularly limited, and can enumerate following solvent method as an example.
(1) collects fiber and the measurement quality of the protuberance of first surface from nonwoven fabric of the present invention.
(2) the collected fiber of dissolving in the solvent of either party dissolving that can make extensibility fiber or elastic fibre leaves standstill for example 30 minutes stipulated time.
(3) filtering solution cleans remaining fiber as required, then makes remaining fiber drying.
(4) dry mass of measurement residual fiber, the ratio of calculating fiber.
Can suitably select above-mentioned solvent, be that polyolefin and elastic fibre are in the elastomeric situation of polyurethanes at the extensibility fiber for example, can select the polyurethanes elastomer is solvable and polyolefin is insoluble dimethylacetylamide, dimethyl formamide etc.In addition, if elastic fibre is the polystyrene type elastomer, the solubility solvent can use the solvents such as toluene, dimethylbenzene.
Also carry out identical measurement for the recess of first surface and second protuberance as required with recess.
In addition, in above-mentioned solvent method, ratio refers to mass ratio.
Measure the additive method of the ratio of above-mentioned extensibility fiber and for example can enumerate following decoration method.
(1) use to the dyeability of extensibility fiber with the different dyestuff of the dyeability of elastic fibre is come nonwoven fabric of the present invention is dyeed.
(2) utilize light microscope etc. to take the projected image of the protuberance of first surface.
(3) according to above-mentioned image, by the ratio of visual valuation extensibility fiber, or above-mentioned image carried out binaryzation so that difference extensibility fiber and elastic fibre, then calculate the ratio of extensibility fiber.
For the nonwoven fabric of inapplicable above-mentioned solvent method, above-mentioned decoration method is fit to measure the ratio of extensibility fiber.
The recess of first surface and second protuberance are as required also carried out identical measurement with recess.
In addition, in above-mentioned decoration method, ratio refers to the Area Ratio in the projected image.
From effect of the present invention, especially skin feel and retractility and the viewpoint of depositing, the ratio of the extensibility fiber in the protuberance of first surface preferably exceeds at least 1 quality % than the ratio of the extensibility fiber in the recess of first surface, further preferably exceed at least 2 quality %, further preferably exceed at least 3 quality %, more preferably exceed at least 5 quality %.
From effect of the present invention, especially skin feel and retractility and the viewpoint of depositing, the ratio of the extensibility fiber in second the protuberance preferably ratio of the extensibility fiber in the recess than second exceeds at least 2 quality %, further preferably exceed at least 4 quality %, further preferably exceed at least 6 quality %, more preferably exceed at least 8 quality %.
As shown in Figure 1 comprise the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool because the ratio of extensibility fiber in the protuberance of first surface is higher than the ratio of the extensibility fiber in the recess of first surface, therefore, skin feel is good and retractility is good.It is the reasons are as follows.
In general, although the elastic fibre retractility is good, there is the poor shortcoming of skin feel such as have viscosity, friction is large, in addition, although extensibility fiber skin feel is good, has the poor shortcoming of extensibility.Nonwoven fabric of the present invention is owing to being with retractility is poor but the extensibility fiber that skin feel is good is configured in the protuberance that contacts with the people, so skin feel is good.And, nonwoven fabric of the present invention because with skin feel is poor but the elastic fibre that retractility is good roughly be configured in equably in the protuberance that is difficult for the recess contact with the people and nonwoven fabric, so retractility is good.
As shown in Figure 1 comprise the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool owing to also having a plurality of recesses, therefore compare with the nonwoven fabric that does not have recess, the good air permeability of the thickness direction of nonwoven fabric, and owing to have a plurality of protuberances and a plurality of recess, so the good air permeability of the in-plane of nonwoven fabric.
In this manual, " elastic fibre " but refer to the meaning of the fiber of elastic elongation.More specifically, above-mentioned elastic fibre, but refer to have when forming and suffered stress is large during the use of supposition elastic region, the fiber of elastic elongation in the scope of suffered stress when forming and during the use of supposition.The material of above-mentioned elastic fibre for example can use polyurethanes elastomer, polystyrene type elastomer, ethylene octane copolymer, polyamide-based elastomer, polyester elastomer and their combination.Distortion after elongation less, the viewpoint such as heat resistance height, above-mentioned elastic fibre optimization polyurethane class elastomer.
The fibre diameter of above-mentioned elastic fibre is preferably in the scope of 2 ~ 50 μ m, further preferably in the scope of 15 ~ 30 μ m.
In this manual, " extensibility fiber " refers to that elastic region is less than the fiber of the elastic region of above-mentioned elastic fibre.More specifically, above-mentioned extensibility fiber, the fiber of the elastic region of suffered stress, suffered stress energy plastic deformation when passing through to form when referring to have less than formation.Above-mentioned extensibility fiber becomes not only thin but also long by carrying out plastic deformation.In addition, in this manual, sometimes will be when forming suffered stress extensibility fiber that plastic deformation occured be called " the extensibility fiber after the elongation ".The example of the extensibility fiber after the elongation can comprise the formation with homogeneous diameter, or has the formation of inhomogeneous diameter, for example has the formation of the thinner part (necking part) in part.
Example as the material of above-mentioned extensibility fiber comprises by polyolefin, for example polyethylene and polypropylene, polystyrene, polyester, polyamide, polyurethane, PLA or their fiber that is combined to form.Above-mentioned extensibility fiber also can be the composite fibres such as core-sheath-type fiber, bilateral fibre.
The viewpoint low from crystallinity, that percentage elongation is high, above-mentioned extensibility fiber preferably comprises polypropylene and poly fiber.
The fibre diameter of above-mentioned extensibility fiber is preferably in the scope of the 40 μ m of about 1 μ m ~ approximately, further preferably in the scope of the 25 μ m of about 5 μ m ~ approximately.In addition, the fibre diameter of above-mentioned extensibility fiber is preferably less than the fibre diameter of above-mentioned elastic fibre.This is owing to can give nonwoven fabric of the present invention with flexibility, bulkiness, disguise etc.
In shown in Figure 1 comprising in the irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool, protuberance 3 is parallel with first direction A separately with recess 4, alternately be configured in the direction with first direction A quadrature, but for nonwoven fabric of the present invention, a plurality of protuberances on the first surface and the pattern of a plurality of recesses are not particularly limited, and nonwoven fabric of the present invention can have a plurality of protuberances and a plurality of recess that forms pre-determined pattern by manufacture method described later etc. at first surface.
In addition, in the form of Fig. 1, the second face of the opposition side of first surface is the plane, but as other forms of the present invention, as shown in Figure 2, also can exist concavo-convex at second.
In addition, in the form of Fig. 1, in protuberance 3, extensibility fiber EX has along the trend of first direction A configuration, but for nonwoven fabric of the present invention, is not limited, and the extensibility fiber also can not have special orientation.
In addition, if the second face is the plane, then the second mask has the good advantage of cementability when bonding with other nonwoven fabric.
In other forms of the present invention, nonwoven fabric of the present invention has a plurality of protuberances and a plurality of recess second of the opposition side of first surface, and the ratio of the extensibility fiber in second the protuberance is higher than the ratio of the extensibility fiber in second the recess.
The ratio of the extensibility fiber in second and the situation of first surface are same, can measure by solvent method, decoration method etc.
Fig. 2 is the schematic diagram that comprises another form of extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool.The irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool that comprises shown in Figure 2 have second 5 at the opposition side of first surface 2, and second 5 has a plurality of protuberances 6 and a plurality of recess 7.In the form of Fig. 2, first surface can be identical with the first surface of Fig. 1, also can be different.
In shown in Figure 2 comprising in the irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool, because protuberance 6 is rich in extensibility fiber EX, and recess 7 is rich in elastic fibre EL, and therefore, the ratio of the extensibility fiber in the protuberance 6 is higher than the ratio of the extensibility fiber in the recess 7.In addition, in shown in Figure 2 comprising in the irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool, protuberance 6 is parallel with second direction B separately with recess 7, and alternately is configured in the direction with second direction B quadrature.In addition, in the form of Fig. 2, there are not special orientation in the extensibility fiber EX in the protuberance 6 and the elastic fibre EL in the recess 7.And, comprise in the irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool first direction A and second direction B quadrature in shown in Figure 2.
Shown in Figure 2 comprise the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool because the ratio of the extensibility fiber in second the protuberance is higher than the ratio of the extensibility fiber in second the recess, therefore same with first surface, skin feel is good and retractility is good.
In addition, shown in Figure 2 comprise the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool since have a plurality of recesses on the first surface and second on a plurality of recesses, so good air permeability of the thickness direction of nonwoven fabric, and owing to have a plurality of protuberances and a plurality of recess on a plurality of protuberances on the first surface and a plurality of recess and second, so the good air permeability of the in-plane of nonwoven fabric, especially first direction and second direction.
In shown in Figure 2 comprising in the irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool, protuberance 3 is parallel with first direction A separately with recess 4, alternately be configured in the direction with first direction A quadrature, but in nonwoven fabric of the present invention, a plurality of protuberances on the first surface and the pattern of a plurality of recesses are not particularly limited.
In addition, in shown in Figure 2 comprising in the irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool, protuberance 6 is parallel with second direction B separately with recess 7, alternately be configured in the direction with second direction B quadrature, but in nonwoven fabric of the present invention, a plurality of protuberances on second and the pattern of a plurality of recesses are not particularly limited, and nonwoven fabric of the present invention can have a plurality of protuberances and a plurality of recess that forms pre-determined pattern by manufacture method described later etc. at second.
And then, in the form of Fig. 2, extensibility fiber EX in the protuberance 6 and the elastic fibre EL in the recess 7 do not have special orientation, but nonwoven fabric of the present invention is not limited, in protuberance 6, extensibility fiber EX also can have along the trend of second direction B configuration, and/or, in recess 7, elastic fibre EL also can have along the trend of second direction B configuration.
And, in shown in Figure 2 comprising in the irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool, first direction A and second direction B quadrature, but the present invention is not particularly limited the relation between first direction A and the second direction B, and first direction and second direction can have arbitrarily angle.For example, first direction is parallel with second direction, i.e. the angle of both direction formation can be 0 °.For such form, for example good with the retractility of the direction of first direction (and second direction) quadrature, and the in-plane good air permeability of first direction (and second direction) especially.
The preferred first direction of nonwoven fabric of the present invention and second direction quadrature.And, nonwoven fabric of the present invention more preferably, first direction is throughput direction (below be sometimes referred to as " direction MD "), and second direction is and the orthogonal direction of throughput direction quadrature (following sometimes will be called with the orthogonal direction of throughput direction quadrature " orthogonal direction " or " direction CD ").
In other forms of the present invention, nonwoven fabric of the present invention can have one or more aperture portion, and more specifically, nonwoven fabric of the present invention can have one or more aperture portion of the recess that links first surface and second 's recess.
Fig. 3 and Fig. 4 are the other forms of schematic diagrames that comprises extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool of the present invention.Fig. 3 and the irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool that comprises shown in Figure 4 have first surface 2, and first surface 2 alternately has parallel with first direction A separately protuberance 3 and recess 4 in the direction with first direction A quadrature, and second 5 alternately has parallel with second direction B separately protuberance 6 and recess 7 in the direction with second direction B quadrature.The irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool that comprises shown in Figure 3 also has the aperture portion 8 that links recess 4 and recess 7.
On the first surface 2 that comprises the irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool shown in Figure 3, because protuberance 3 is rich in extensibility fiber EX, and recess 4 is rich in elastic fibre EL, therefore, the ratio of the extensibility fiber in the protuberance 3 is higher than the ratio of the extensibility fiber in the recess 4.In protuberance 3, extensibility fiber EX has along the trend of first direction A configuration.
In addition, comprise on second 5 of the irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool shown in Figure 4, protuberance 6 is rich in extensibility fiber EX, and, recess 7 is rich in elastic fibre EL, therefore, the ratio of the extensibility fiber in the protuberance 6 is higher than the ratio of the extensibility fiber in the recess 7.
And, the recess 4 in Fig. 3 and Fig. 4 and recess 7, the 8 ground configuration elastic fibre EL of around opening section.
Fig. 3 and the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool that comprises shown in Figure 4, owing to having a plurality of recesses and one or more aperture portion on a plurality of recesses on the first surface and second, therefore, the gas permeability of the thickness direction of nonwoven fabric is good especially, in addition, owing to having a plurality of protuberances and a plurality of recess on a plurality of protuberances on the first surface and a plurality of recess and second, therefore, the in-plane of the nonwoven fabric good air permeability of first direction and second direction especially.In addition, Fig. 3 and the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool that comprises shown in Figure 4 have one or more aperture portion, can make structural change when elongation, and therefore, the intensity the when initial stage extends is low, easily follows the activity of health.
In addition, in Fig. 3, the protuberance 3 of first surface and recess 4 and second 's protuberance 6 and recess 7 are towards specific direction, but nonwoven fabric of the present invention is not particularly limited these directions, configuration etc.In addition, the orientation of extensibility fiber and elastic fibre is arbitrarily, extensibility fiber and/or elastic fibre in a plurality of recesses on a plurality of protuberances on a plurality of protuberances on the first surface, a plurality of recesses on the first surface, second and/or second both can have orientation, also orientation not.
[manufacture method that comprises extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool]
The manufacture method that comprises extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool of the present invention comprises that preparation comprises the step of the nonwoven fabric of extensibility fiber and elastic fibre.
As the above-mentioned nonwoven fabric that comprises extensibility fiber and elastic fibre, just be not particularly limited so long as comprise the nonwoven fabric of above-mentioned extensibility fiber and above-mentioned elastic fibre, for example can comprise the nonwoven fabric of making by various well-known methods, for example hot-wind nonwoven cloth, spun-bonded non-woven fabrics, some bonded non-woven fabrics, spunlace non-woven cloth, air-laid nonwoven fabrics, melt spraying non-woven fabrics, comprise the nonwoven fabric of nanofiber.
Can from above-mentioned fiber, select above-mentioned extensibility fiber and elastic fibre, and, consider that the extensibility fiber can by subsequently step so that fibre diameter attenuates, preferably select fibre diameter.
Above-mentioned fiber is not particularly limited its fibre length, for example can comprise staple fibre and continuous filament.If mix two or more fibers, then the fibre length of these fibers both can be identical, also can be different.
The above-mentioned nonwoven fabric that comprises extensibility fiber and elastic fibre preferably has hydrophilic nonwoven fabric.This be because with hydrophily excreta (urine, sweat, stool etc.) when contacting, this excreta can not rest on the surface of nonwoven fabric and easily be penetrated into nonwoven fabric inside.
In the above-mentioned nonwoven fabric that comprises extensibility fiber and elastic fibre, as having hydrophilic nonwoven fabric, such as comprise nonwoven fabric by utilizing hydrophilizing agent that the hydrophobicity nonwoven fabric is processed to make, by rub into hydrophilizing agent the fiber manufacturing nonwoven fabric, be coated with the nonwoven fabric of interfacial agent etc.In addition, in the above-mentioned nonwoven fabric that comprises extensibility fiber and elastic fibre, as having hydrophilic nonwoven fabric, also can comprise having in essence hydrophilic fiber, the nonwoven fabric of for example being made by the fiber of natural class and/or half-natural class.
Method of the present invention comprises the above-mentioned nonwoven fabric that comprises extensibility fiber and elastic fibre being stretched unevenly in order to form the step (below be sometimes referred to as " uneven pulling step ") of the nonwoven fabric with high stretch zones and low stretch zones.
Above-mentioned uneven pulling step is carried out for following purpose, that is: in the above-mentioned nonwoven fabric that comprises extensibility fiber and elastic fibre, (i) destroys each abutment of the fiber in the nonwoven fabric partly, fixing fiber is formed net state partly, and/or (ii) form the extensibility fiber after the elongation between each abutment of the fiber in nonwoven fabric.Therefore extensibility fiber after the above-mentioned elongation easily forms concavo-convex at nonwoven fabric owing to becoming easily mobile when processing with fluid.
In addition, above-mentioned elastic fibre is owing to having than the high elastic region of stress that applies when the uneven pulling step, and therefore, when the uneven pulling step, the elastic fibre that is temporarily extended can return to the original length subsequently.
As above-mentioned abutment, in the situation that hot-wind nonwoven cloth is the heat fusing bonding point, in the situation that spun-bonded non-woven fabrics is the hot pressing contact with the some bonded non-woven fabrics, and in the situation that spunlace non-woven cloth is the fiber interweaving point.
In this manual, " high stretch zones " refers to stretch and so that the elongation degree of extensibility fiber after the elongation is higher than the zone of low stretch zones, and, " low stretch zones " refers to stretch and so that the elongation degree of the extensibility fiber after the elongation is lower than the zone of high stretch zones, comprise the zone that forms the extensibility fiber after the elongation, i.e. stretch zones not.
In this manual, " uneven pulling " refers to stretch and forms the nonwoven fabric with high stretch zones and low stretch zones, and namely referring to stretch, it is different and so that also different nonwoven fabric of the elongation degree of the extensibility fiber that is stretched to form according to the position.
Above-mentioned uneven pulling step then is not particularly limited if can form the means of the nonwoven fabric with high stretch zones and low stretch zones, can implement by means arbitrarily, for example, utilization has a pair of discaling roll with the rotation of throughput direction quadrature, the a plurality of teeth that are configured in this discaling roll outer peripheral face separately simultaneously are engaged with each other simultaneously to be rotated, make the above-mentioned nonwoven fabric that comprises extensibility fiber and elastic fibre by this gap to discaling roll (below be sometimes referred to as " tooth stretching "), carry out thus the uneven pulling step.
Fig. 5 is the schematic diagram that stretches for the explanation tooth.Tooth stretching device 9 shown in Figure 5 has a pair of discaling roll 10 and 10 '.Outer peripheral face 11 and 11 ' the upper a plurality of teeth 12 and 12 ' of each self-configuring discaling roll 10 and 10 '.In addition, in tooth stretching device 9 shown in Figure 5, the throughput direction MD with nonwoven fabric is vertical separately with 10 ' rotation for discaling roll 10.And a plurality of teeth 12 and 12 ' are configured on outer peripheral face 11 and 11 ' abreast with above-mentioned rotation separately.
In tooth stretching device 9 shown in Figure 5, the nonwoven fabric 13 that comprises extensibility fiber and elastic fibre is passed through in the roller gap of a pair of discaling roll 10 and 10 ', by discaling roll 10 and 10 ' time, by the discaling roll 10 that is engaged with each other and a plurality of teeth 12 and 12 ' of 10 ', the nonwoven fabric 13 that will comprise extensibility fiber and elastic fibre stretches according to the principle of three-point bending, forms the nonwoven fabric 14 with high stretch zones and low stretch zones.Nonwoven fabric 14 with high stretch zones and low stretch zones alternately has the high stretch zones parallel with orthogonal direction and low stretch zones at throughput direction MD.
In the nonwoven fabric 13 that comprises extensibility fiber and elastic fibre, in the zone that contacts with 12 ' leading section with a plurality of teeth 12, because the cloth of nonwoven fabric is fixed, hang down stretch zones so not too be stretched or in fact form with being stretched.On the other hand, in the zone that does not contact with 12 ' leading section with a plurality of teeth 12, significantly stretched and formed high stretch zones.
In addition, can use tooth stretching device shown in Figure 6 to carry out tooth stretches.
Fig. 6 is the schematic diagram that stretches for the explanation tooth.Tooth stretching device 9 shown in Figure 6 has a pair of discaling roll 10 and 10 '.On the outer peripheral face 11 and 11 ' of discaling roll 10 and 10 ', a plurality of teeth 12 and 12 ' of each self-configuring.In addition, in tooth stretching device 9 shown in Figure 6, a plurality of teeth 12 are vertical with 10 ' rotation with discaling roll 10 separately with 12 ', are configured in respectively on outer peripheral face 11 and 11 '.By a plurality of teeth 12 and 12 ' of such configuration, can be formed on orthogonal direction and alternately have parallel with throughput direction MD separately high stretch zones and the nonwoven fabric of low stretch zones.
And tooth stretches to utilize and shown in Figure 7 a plurality of teeth is implemented with respect to the tooth stretching device that the rotation of discaling roll configures obliquely at the outer peripheral face of discaling roll.Fig. 7 is the schematic diagram that stretches for the explanation tooth.Tooth stretching device 9 shown in Figure 7 has a pair of discaling roll 10 and 10 '.On the outer peripheral face 11 and 11 ' of discaling roll 10 and 10 ', a plurality of teeth 12 and 12 ' of each self-configuring.In addition, in tooth stretching device 9 shown in Figure 7, the throughput direction MD with nonwoven fabric is vertical separately with 10 ' rotation for discaling roll 10.And a plurality of teeth 12 and 12 ' are configured in respectively on outer peripheral face 11 and 11 ', in order to have the angle θ of regulation with respect to rotation.
Can suitably select above-mentioned tooth stretching device according to the desirable performance of nonwoven fabric that wish is formed.
If need high scalability, just can utilize a plurality of Fig. 5 to stretch to tooth stretching device shown in Figure 7 and comprise the nonwoven fabric of extensibility fiber and elastic fibre.
In above-mentioned tooth stretching device, tooth pitch is preferably approximately the 10mm of 1mm ~ approximately, more preferably the about 6mm of 2mm ~ approximately.If tooth pitch then needs to make the thickness of land thinner less than about 1mm, nonwoven fabric is blocked by the part sometimes, if tooth pitch greater than about 10mm, then stretching ratio reduces, and sometimes is difficult to form the extensibility fiber that is extended.
Tooth pitch, refer in Fig. 6 15 that represent with Reference numeral, from a tooth to the interval another tooth.
In above-mentioned tooth stretching device, the tooth depth of engagement is preferably approximately more than the 0.5mm.If the tooth depth of engagement is lower than approximately 0.5mm, then the stretching of nonwoven fabric is just insufficient, sometimes is difficult to form high stretch zones.
The tooth depth of engagement, refer in Fig. 6 16 that represent with Reference numeral, above discaling roll tooth with below the degree of depth of the overlapping part of the tooth of discaling roll.
In the nonwoven fabric with high stretch zones and low stretch zones, the stretching ratio that stretches of tooth is preferably approximately 30% ~ approximately 400% each time, and more preferably approximately 50% ~ approximately 200%.If stretching ratio is lower than approximately 30%, then sometimes do not form the extensibility fiber that is extended, and, if stretching ratio is higher than approximately 400%, the intensity that then has the nonwoven fabric of high stretch zones and low stretch zones weakens sometimes, extensibility fiber after the elongation easily comes off mostly, be difficult to carry, and/or the extensibility fiber ruptures sometimes.
In this manual, " stretching ratio " refers in the situation that to establish tooth pitch be P and to establish the tooth depth of engagement be the value that D calculates by following formula:
The uncoiling speed that comprises the nonwoven fabric of extensibility fiber and elastic fibre also changes according to desirable stretching ratio etc., for example approximately more than 10m/ minute.The rolling speed that alternately has the nonwoven fabric of high stretch zones and low stretch zones changes according to stretching ratio etc., in the situation of the nonwoven fabric comprise extensibility fiber and elastic fibre that stretches to throughput direction, the value that uncoiling speed multiply by stretching ratio should become the benchmark of rolling speed.
Method of the present invention may further comprise the steps, that is: the nonwoven fabric that will have high stretch zones and a low stretch zones is configured on the supporter, then the fluid with ejection sprays to the nonwoven fabric with high stretch zones and low stretch zones, process thus, form and to comprise the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool (below be sometimes referred to as " fluid manipulation steps ").
At least a portion of extensibility fiber in the uneven pulling step after the fiber of net state that form, that be present in high stretch zones and/or the elongation, with the face (hereinafter referred to as " liquid collision face ") of liquid collision, liquid collision with ejection, then along with by being hit back, to in-plane for example orthogonal direction be sorted.More particularly, in the part that the fluid that is ejected sprays, the extensibility fiber after the elongation is local mobile to other, mainly stays elastic fibre, forms a plurality of recesses at first surface thus.Elastic fibre is stressed by the collision of fluid, but only rests on the degree of the stress that applies not enough elastic region, so, after having sprayed fluid, mostly turn back to the old place.Therefore, a plurality of recesses on first surface are rich in elastic fibre.The two ends of a plurality of recesses of extensibility fiber on first surface after the elongation form protuberance.Therefore, a plurality of protuberances on first surface are rich in the extensibility fiber.In addition, the liquid collision face is equivalent to comprise the first surface of extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool sometimes, and the direction of the track of injected fluid is equivalent to first direction.
In addition, at the face (hereinafter referred to as " nonfluid impingement area ", being equivalent to the second face) of the opposition side of liquid collision face, at least a portion of the extensibility fiber after the fiber of net state and/or the elongation moves along the mobile of fluid through nonwoven fabric.
As the fluid that in above-mentioned fluid manipulation steps, uses, can enumerate air for example through air, steam or the water hot water for example of heating.
Can spray above-mentioned fluid to the nonwoven fabric with high stretch zones and low stretch zones from fixing fluid tip, perhaps can be from spraying at the reciprocal fluid tip of orthogonal direction.In addition, can spray above-mentioned fluid to the nonwoven fabric with high stretch zones and low stretch zones continuously or off and on from fluid tip.By the combination said method, can form a plurality of protuberances and a plurality of recess with the various patterns that comprise pre-determined pattern at first surface.
Can suitably select above-mentioned fluid according to the form of the nonwoven fabric with high stretch zones and low stretch zones.For example, in the situation of processing the nonwoven fabric that tooth pitch is little, stretching ratio is large, can make with lower energy the extensibility fiber after the elongation most of mobile, therefore preferred air or the steam selected is as fluid.In addition, in the situation of processing the many nonwoven fabric of large, the low stretch zones of tooth pitch, because the abutment of each fiber is many, so need higher energy for the mobile extensibility fiber that is stretched, therefore preferably select water or steam as fluid, and further preferred water steam.This is because be not easy remaining moisture in the many parts of fibre weight, and the situation at abutment of destroying the many parts of fibre weight is few, and the extensibility fiber after the elongation of the part that should move is moved.
Above-mentioned fluid manipulation steps can be used at well-known in the art device, and utilizes well-known method to carry out.
In a form of method of the present invention, have the supporter of the nonwoven fabric of high stretch zones and low stretch zones in order to support, can be at normally used in the art supporter, such as metal, plastic transmission net, copy gauze etc.Above-mentioned supporter generally has fluid permeability.
In other forms of method of the present invention, for the gas permeability that further improves nonwoven fabric, skin feel (such as low contact area), liquid guided bone etc., can use the supporter with protruding part and depressed part.
In the present invention, " protruding part " is in order to second part that forms a plurality of recesses at nonwoven fabric, and " depressed part " is in order to second part that forms a plurality of protuberances at nonwoven fabric.
Fig. 8 is the figure that is illustrated in an example of the supporter that uses on the conveyer belt.
In Fig. 8, supporter 17 has the protruding part parallel with orthogonal direction CD 18 and depressed part 19, and protruding part 18 and depressed part 19 alternately are configured in throughput direction MD.In Fig. 8, also shown fluid tip 20, and, below supporter 17, in the bottom of fluid tip 20, the suction section (not shown) that receives fluid is set.In Fig. 8, protruding part 18 and depressed part 19 have cubic shaped and alternative arrangement.
In Fig. 8, protruding part is parallel with orthogonal direction with depressed part and alternately be configured in throughput direction, but method of the present invention is to the shape of protruding part and depressed part, arrange to wait and be not particularly limited, for example protruding part and depressed part also can be that (i) protruding part parallel with throughput direction and depressed part alternately are configured in formation on the orthogonal direction separately, perhaps (ii) have the protruding part of inclination and depressed part with respect to throughput direction separately and alternately be configured in formation on the direction with the direction quadrature of this inclination, perhaps (iii) determined in advance shape (cubic shaped for example, cylindrical shape, semi-spherical shape etc.) protruding part and/or depressed part are (for example heart-shaped with pre-determined arrangement, the arrangements such as star) formation that is configured.
If use the supporter with protruding part and depressed part, then compare with using the supporter that does not have protruding part and depressed part, can form the nonwoven fabric with a plurality of large protuberances and a plurality of dark recess (being one or more aperture portion in some cases).
Utilize Fig. 8 that above-mentioned phenomenon is described.In a single day collide with protruding part 18 from the fluid of fluid tip 20 ejections, just in entering to flow to depressed part 19.As a result, the extensibility fiber after the high elongation of the free degree just moves to the direction of depressed part 19 along flowing of fluid, therefore, at the position that fluid and protruding part 18 intersect, main remaining elastic fibre, the fibre weight of unit are reduces, at second a plurality of recess of formation of nonwoven fabric.Although elastic fibre extends by the power of fluid temporarily, only rest on the degree of the stress that applies not enough elastic region, therefore, disappear and do not have mostly to restore to the original state after stress applies at fluid.Therefore, in a plurality of recesses on second, is rich in elastic fibre.If it is strong to spray the power of fluid, then elastic fibre also can carry out movement to a certain degree, one or more aperture portion of the recess of formation link first surface and second recess.
At the position that fluid and depressed part 19 intersect, because the extensibility fiber after the elongation is concentrated, therefore, the fiber quantitative change of unit are is many, forms a plurality of protuberances second of nonwoven fabric, and a plurality of protuberances on second are rich in the extensibility fiber.In the situation that Fig. 8, second direction is that the direction of protruding part 18 and depressed part 19 is orthogonal direction.In a plurality of protuberances on second, at the thickness direction of nonwoven fabric, the extensibility fiber after the elongation has the trend that erects, and therefore, has given nonwoven fabric with resistance to compression, and the liquid guided bone further improves.In addition, comprise the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool 1 owing at the second mask a plurality of protuberances being arranged, therefore, gas permeability is the good air permeability of in-plane especially, and contact area reduces, so skin feel is good.
Use has the nonwoven fabric of the supporter formation of protruding part and depressed part, compare with the situation of not using supporter to form, at the second mask the high protuberance of a plurality of height and the dark recess of a plurality of degree of depth are arranged, thus gas permeability especially gas permeability, resistance to compression, liquid guided bone, the skin feel of in-plane is good.A plurality of protuberances on second are mainly formed by the higher extensibility fiber of fibre strength, so intensity is high, and are not yielding.If use has the nonwoven fabric of the supporter formation of protruding part and depressed part and has one or more aperture portion, then the good air permeability of thickness direction.
In addition, use nonwoven fabric that supporter shown in Figure 8 the forms good air permeability of orthogonal direction especially among the gas permeability of in-plane.This is because among above-mentioned nonwoven fabric, can become the path of gas with the position corresponding to protruding part (second recess of nonwoven fabric) of supporter.
Preferably, above-mentioned protruding part has the fluid permeability lower than the fluid permeability of depressed part.This is because have low fluid permeability by protruding part, mobile to the direction of depressed part with the fluid of protruding part collision, in comprising on extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool second of forming by method of the present invention, can form the higher protuberance of a plurality of height.
As the raw material of above-mentioned protruding part, can enumerate metal, plastics etc.
Above-mentioned protruding part and depressed part are not particularly limited, such as can as the supporter of fluid permeability the making such as normally used metal, plastics transmission net, copy on gauze, the punched-plate etc., the ground such as interval of maintenance regulation configure the metal of cubic shaped, tubular etc. according to pre-determined arrangement, form thus protruding part and depressed part.
As configured the protruding part of having determined in advance shape (such as cubic shaped, cylindrical shape, semi-spherical shape etc.) and/or the supporter of depressed part according to pre-determined arrangement (such as the arrangement of heart, star etc.), the formation according to the metal of pre-determined arrangement (for example heart-shaped) configuration semi-spherical shape is for example arranged on pressed sheet.If use this supporter, just can have second formation the nonwoven fabric of the recess of pre-determined pattern (for example heart-shaped).
In addition, for example when use on pressed sheet according to pre-determined arrangement (for example heart-shaped) configured hemispheric concave shape, when having the supporter of protruding part and depressed part, can form the have pre-determined pattern nonwoven fabric with a plurality of protuberances of (for example heart-shaped) at second.
In the situation that roller carries out fluid manipulation steps, can use the supporter of roller shape, its periphery waits the fluid permeability material to consist of by net, and has configured protruding part and the depressed part of having determined in advance shape and arrangement at outer peripheral face.This pre-determined shape and arrangement can be above-mentioned shape and arrangements.
Fig. 9 is that expression utilizes supporter shown in Figure 8 17 figure that form, that comprise the irregular nonwoven fabric 1 of extensibility fiber and elastic fibre and tool.Fig. 9 is equivalent to the cross section shown in the Z-Z among Fig. 8.In Fig. 9, form protuberances 6 at the depressed part 19 of supporter 17, and form recesses 7 at the protruding part 18 of supporter 17.
In other forms of the present invention, can use supporter shown in Figure 10.In supporter shown in Figure 10 17, protruding part 18 and depressed part 19 have cubic shaped and lattice shape separately, and, protruding part 18 with alignment arrangements with predetermined distance at throughput direction and orthogonal direction.
In the supporter with protruding part and depressed part, characteristic that the nonwoven fabric that its width forms according to wish is required etc. and different, for example in supporter shown in Figure 8, the width of protruding part is preferably in the scope of 10mm of about 0.5mm ~ approximately, and the width of depressed part is preferably in the scope of 10mm of about 1mm ~ approximately.
The above-mentioned air permeability that comprises the thickness direction of extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool is preferably approximately 500m
3/ m
2/ minute more than, about 1000m more preferably
3/ m
2/ minute more than, and be preferably the most approximately 2000m
3/ m
2/ minute more than.The air permeability of thickness direction is higher, then just more is not easy to produce sultry in the situation of the part that is used to contact with human body.
In addition, the above-mentioned air permeability that comprises the in-plane of extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool is preferably approximately 5m
3/ m
2/ minute more than, about 10m more preferably
3/ m
2/ minute more than, and more be preferably approximately 20m
3/ m
2/ minute more than.The air permeability of horizontal direction is higher, and the air that then humidity is high just more is not easy to be trapped near the skin, easilier discharges to the outside.
Nonwoven fabric of the present invention is useful to absorbent commodity such as amenities and disposable diaper, cleaning supplies such as wiper and medical supplies such as face shield etc.
Nonwoven fabric of the present invention can be used for skin contact (with the face of user's skin butt) in absorbent commodity.Absorbent commodity for example has egative film and the absorber between two sheets of the top flat of liquid permeability, non-liquid permeability, makes the effluents such as urine, menses infiltration top flat and absorbs and remain in absorber.
Embodiment
Below, enumerate embodiment and comparative example and describe with regard to the present invention, but the present invention is not subjected to the restriction of these embodiment.
The measuring condition of the project of estimating in embodiment and comparative example is as follows.
[weight per unit area]
5.2 measurement unit's area weight according to JIS L 1906.
[highly]
(Co., Ltd.) the Daiei science of utilization essence mechanism is made made THICKNESS GAUGEUF-60 measuring height.
[air permeability]
Utilize the KES-F8-AP1 air permeability tester of KATO TECH Corporation to measure air permeability, then unit conversion is become " m
3/ m
2/ minute ".
The air permeability of the thickness direction of nonwoven fabric is measured by nonwoven fabric being cut into the size of 100mm * 100mm, being placed on the air permeability tester afterwards.
The air permeability of the in-plane of nonwoven fabric by nonwoven fabric being cut into the size of 100mm * 100mm, is placed on the air permeability tester afterwards, and the acrylic panel with 100mm * 100mm size is placed on it again, at 3.5mN/cm
2The condition that increases the weight of under measure.
[expansion performance]
Use the Autograph type cupping machine of (Co., Ltd.) Shimadzu Seisakusho Ltd. system, model AG-KNI loops measurement according to following.
The-the first circulation (Cy)-
The test portion of width 50mm is fixed on the chuck according to distance between the chuck of 100mm, with 100mm/ minute speed (going to) extensibility to 100% that stretches, then recovers (returning) to the original length with 100mm/ minute speed.The intensity of the every 50mm width during elongation 50% that evaluation is gone to.
The-the second circulation (the 2nd Cy)-
Then, repeat the first circulation, the intensity of the every 50mm width when estimating the elongation 50% of returning.
In addition, in elongation 50% the time, the percentage elongation when being equivalent to be used to wearing in the situation of disposable diaper.
The intensity of the every 50mm width during as the elongation 50% of going to, the following scope of preferred 10N.If this intensity surpasses 10N, then for example in the situation that be used to disposable diaper, diaper is not easy to launch when dressing, and is difficult to peel.In addition, in this manual, sometimes the intensity (N) of every 50mm width is abbreviated as N/50mm.
The intensity of the every 50mm width during elongation 50% when returning, the scope of 5.0N of preferred approximately 0.1N ~ approximately.If this intensity is lower than approximately 0.1N, then for example in the situation that be used to disposable diaper, the sometimes easily changing of the relative positions of diaper when wearing diaper, and if be higher than approximately 5.0N, then the pressure to skin uprises when wearing, and stays red seal, pleat trace etc. at skin sometimes.
[ratio of extensibility fiber]
Nonwoven fabric is cut into the size of 50mm * 50mm, cuts near the fiber (hereinafter referred to as " fiber of protuberance ") second the top of protuberance with cutter.Then, measure the fiber of protuberance, be immersed in the dimethylacetylamide of 20mL, at room temperature left standstill 30 minutes.Then, filter remaining fiber, with dry after the ethanol washing.Calculate the ratio of extensibility fiber according to the dry mass of remaining fiber.
In addition, equally also calculate the ratio of extensibility fiber with regard near the fiber the bottom of second recess.
[embodiment 1 ~ 3]
The manufacturing of-nonwoven fabric-
Utilize spun-bond process to make polyamide fiber (fibre diameter 21 μ m) and polyurethane fiber (fibre diameter 25 μ m), the polyamide fiber and the polyurethane fiber that mix manufacturing, making mass ratio is 50:50, manufacture fiber web, then this fiber web is carried out hot rolling flower and process, produce thus as the extensibility fiber and comprise polyamide fiber and comprise the nonwoven fabric of polyurethane fiber as elastic fibre.
The stretch processing of-tooth-
With the speed uncoiling with 10m/ minute of the reel of the above-mentioned nonwoven fabric that comprises polyamide fiber and polyurethane fiber, process is preheating to four preheat rolls of 80 ℃, utilize tooth stretching device shown in Figure 6 (tooth pitch: 2.5mm, the engaging-in degree of depth of tooth: 3.0mm, stretching ratio: 160%) carry out tooth and stretch, then utilize tooth stretching device shown in Figure 5 (tooth pitch: 4.9mm, the engaging-in degree of depth of tooth: 7.0mm, stretching ratio: 202%) carry out tooth and stretch, form as the nonwoven fabric 1 with nonwoven fabric of high stretch zones and low stretch zones.The tooth temperature of two tooth stretching devices is 55 ℃.
In nonwoven fabric 1, with low stretch zones that the leading section of tooth contacts in, residual have a cotton ginning part.In addition, not with high stretch zones that the leading section of tooth contacts in, the cotton ginning part has been formed web area by local failure.
-steam treatment-
Pressure in the table 1 expression steam treatment system and the condition of steam temperature represent the characteristic of nonwoven fabric 2 ~ 4 simultaneously.
In addition, estimate the ratio as the polyamide fiber of extensibility fiber in the nonwoven fabric 2 ~ 4 by decoration method.
Utilization is dyed redness with polyurethane fiber and to the achromophil dyestuff of polyamide fiber, nonwoven fabric 2 ~ 4 is dyeed, and carries out visual valuation by light microscope.Its result with regard to whole nonwoven fabric 2 ~ 4, confirms first surface and second respectively as shown in Figure 3 and Figure 4, as the polyamide fiber of extensibility fiber and inhomogeneous as the polyurethane fiber of elastic fibre.More specifically, confirmed, the ratio of the polyamide fiber in the protuberance of first surface is higher than the ratio of the polyurethane fiber in the recess of first surface, and the ratio of the polyamide fiber in second the protuberance is higher than the ratio of the polyurethane fiber in second the recess.
And then, utilize the ratio of polyamide fiber of second the protuberance of nonwoven fabric 4 of solvent method Evaluation operation example 3 and second 's recess.Second protuberance and second 's recess is gathered respectively 67.7mg and 39.8mg, use the dimethylacetylamide of 20mL as solvent, after estimating, the ratio of the polyamide fiber of second protuberance and second 's recess is respectively 54 quality % and 43 quality %.According to this results verification, in nonwoven fabric 4, the ratio of the polyamide fiber in second the protuberance is higher than the ratio of the polyamide fiber in second the recess.
In addition, in the nonwoven fabric before the tooth of embodiment 1 ~ 3 stretches, the ratio of the polyamide fiber that measures is 50 quality %.
Figure 11 represents the electron micrograph in cross section of the MD direction of nonwoven fabric 2.
[comparative example 1]
With the nonwoven fabric 1 of embodiment 1 ~ 31 test portion as a comparative example.Characteristic is as shown in table 1.
[comparative example 2]
The nonwoven fabric that will form according to the embodiment 1 of patent documentation 1 is as nonwoven fabric 5, and its expansion performance is as shown in table 1.
Table 1
* the value of MD direction.
According to embodiment 1 to 3 and comparative example 1 as can be known, by carrying out steam treatment, highly increase, and thickness direction and horizontal direction both sides' air permeability improves a lot.This is because pass through steam treatment in embodiment 1 to 3, has formed a plurality of protuberances and a plurality of recess on the first surface at nonwoven fabric, and a plurality of protuberances on second and a plurality of recess.In addition, be higher than with the ratio of the extensibility fiber in second the protuberance headed by the nonwoven fabric 4 of embodiment 3 of ratio of the extensibility fiber in second the recess, the viscosity that comes from elastic fibre of the nonwoven fabric 2 of embodiment 1 and the nonwoven fabric 3 of embodiment 2 is little, and skin feel is good.
The nonwoven fabric of comparative example 1 is concavo-convex owing to not having, so the air permeability of thickness direction is low, and owing to do not form the air flue of in-plane, so the air permeability of in-plane is also low.In addition, skin feel is poorer than nonwoven fabric 2 ~ 4.
Although the air permeability of the nonwoven fabric in-plane of comparative example 2 is good, the air permeability of thickness direction is low.
According to embodiment 1 to 3 and comparative example 1 as can be known, the intensity of the every 50mm width during for the elongation 50% of going to of the first circulation, by steam treatment, retractility does not vary widely.This is because the nonwoven fabric of embodiment 1 to 3 has a plurality of aperture portion, and before fibre deformation, recurring structure distortion in nonwoven fabric can be eliminated the recruitment because of the caused TENSILE STRENGTH that interweaves of interfibrous bond vitrified that heat treatment forms, fiber.
The nonwoven fabric of comparative example 2 is hard, in the first circulation, is approximately 90% time fracture at degree of drawing.
Be expression protuberance 6 and recess 7 among Figure 11 in the cross section of direction MD, the many and fiber of the fibre weight of unit are erects in protuberance 6 as can be known, and as can be known in recess 7 few the and fiber of the fibre weight of unit are fall down.
Description of reference numerals
1 comprises the irregular nonwoven fabric of extensibility fiber and elastic fibre and tool, 2 first surfaces, 3 protuberances, 4 recesses, 5 second, 6 protuberances, 7 recesses, 8 aperture portion, 9 tooth stretching devices, 10,10 ' discaling roll, 11,11 ' outer peripheral face, 12,12 ' a plurality of teeth, 13 comprise the nonwoven fabric of extensibility fiber and elastic fibre, and 14 have the nonwoven fabric of high stretch zones and low stretch zones, 15 tooth pitches, the engaging-in degree of depth of 16 teeth, 17 supporters, 18 protruding parts, 19 depressed parts, 20 fluid tips, EX extensibility fiber, EL elastic fibre, the A first direction, the B second direction, MD throughput direction, CD orthogonal direction.
Claims (16)
1. nonwoven fabric, this nonwoven fabric comprise extensibility fiber and elastic fibre and have concavo-convexly, it is characterized in that,
First surface at described nonwoven fabric has a plurality of protuberances and a plurality of recess, and,
The ratio of the extensibility fiber in the described protuberance is higher than the ratio of the extensibility fiber in the described recess.
2. nonwoven fabric according to claim 1, it is characterized in that, described nonwoven fabric has a plurality of protuberances and a plurality of recess second of the opposition side of the first surface that is positioned at described nonwoven fabric, and the ratio of the extensibility fiber in second the protuberance is higher than the ratio of the extensibility fiber in second the recess.
3. nonwoven fabric according to claim 2 is characterized in that, the protuberance of first surface and recess are parallel with first direction respectively, and alternately is configured in the direction with the first direction quadrature.
4. nonwoven fabric according to claim 3 is characterized in that, second protuberance and recess are parallel with second direction respectively, and alternately is configured in the direction with the second direction quadrature.
5. nonwoven fabric according to claim 4 is characterized in that, first direction and second direction quadrature.
6. nonwoven fabric according to claim 5 is characterized in that, first direction is throughput direction, and second direction is the orthogonal direction with the throughput direction quadrature.
7. each described nonwoven fabric in 6 according to claim 2 is characterized in that, has one or more aperture portion that the recess with the recess of first surface and second links.
8. each described nonwoven fabric in 7 according to claim 1 is characterized in that, the material of described extensibility fiber is selected from the group that comprises polyolefin, polystyrene, polyester, polyamide, polyurethane, PLA and their combination.
9. each described nonwoven fabric in 8 according to claim 1, it is characterized in that, the material of described elastic fibre is selected from the group that comprises polyurethanes elastomer, polystyrene type elastomer, ethylene octane copolymer, polyamide-based elastomer, polyester elastomer and their combination.
10. the manufacture method of a nonwoven fabric is made according to claim 1 each described nonwoven fabric in 9, it is characterized in that, may further comprise the steps:
Preparation comprises the step of the nonwoven fabric of extensibility fiber and elastic fibre;
The step that stretches unevenly: the described nonwoven fabric that comprises extensibility fiber and elastic fibre that stretches unevenly, in order to form the nonwoven fabric with high stretch zones and low stretch zones; Then,
Form the described step that comprises extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool: described nonwoven fabric with high stretch zones and low stretch zones is configured on the supporter, then spray the fluid that is ejected to described nonwoven fabric with high stretch zones and low stretch zones, process thus, form the described irregular nonwoven fabric of extensibility fiber and elastic fibre and tool that comprises.
11. the manufacture method of nonwoven fabric according to claim 10, it is characterized in that, the described step that stretches is unevenly carried out in the following manner, that is: the described nonwoven fabric that comprises extensibility fiber and elastic fibre is passed through in the gap that has with a pair of discaling roll of the rotation of throughput direction quadrature, this simultaneously makes a plurality of teeth that are configured on this discaling roll outer peripheral face separately one side that is engaged with each other be rotated to discaling roll.
12. the manufacture method of nonwoven fabric according to claim 11, it is characterized in that, described a plurality of tooth and described rotation are located vertically on the described outer peripheral face, are formed on the orthogonal direction with the throughput direction quadrature alternately to have parallel with described throughput direction respectively high stretch zones and the nonwoven fabric of low stretch zones; Perhaps, described a plurality of teeth and described rotation are configured on the described outer peripheral face abreast, are formed on alternately to have parallel with the direction that is orthogonal to described throughput direction respectively high stretch zones and the nonwoven fabric of low stretch zones on the throughput direction.
13. the manufacture method of each described nonwoven fabric in 12 is characterized in that according to claim 10, implements the described step that stretches unevenly twice.
14. the manufacture method of each described nonwoven fabric in 13 according to claim 10, it is characterized in that, in forming the described step that comprises extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool, described supporter has protruding part and the depressed part of pre-determined shape and arrangement at the face that contacts with nonwoven fabric.
15. the manufacture method of nonwoven fabric according to claim 14 is characterized in that, the protruding part of described pre-determined shape and arrangement and depressed part are parallel to respectively the orthogonal direction with the throughput direction quadrature, and alternately are configured on the throughput direction.
16. the manufacture method of each described nonwoven fabric in 15 is characterized in that according to claim 10, described fluid is selected from the group that comprises air, steam and water.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010-095246 | 2010-04-16 | ||
| JP2010095246A JP5506520B2 (en) | 2010-04-16 | 2010-04-16 | A nonwoven fabric having irregularities, including an extensible fiber and a stretchable fiber, and a method for producing the nonwoven fabric |
| PCT/JP2011/059770 WO2011129466A1 (en) | 2010-04-16 | 2011-04-14 | Non-woven fabric including elongated fibres and elastic fibres and having unevenness, and method for manufacturing non-woven fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102918190A true CN102918190A (en) | 2013-02-06 |
| CN102918190B CN102918190B (en) | 2015-10-21 |
Family
ID=44798826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180026845.2A Active CN102918190B (en) | 2010-04-16 | 2011-04-14 | Comprise extensibility fiber and elastic fibre and the irregular nonwoven fabric of tool, and the manufacture method of this nonwoven fabric |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8974890B2 (en) |
| EP (1) | EP2559794B1 (en) |
| JP (1) | JP5506520B2 (en) |
| CN (1) | CN102918190B (en) |
| WO (1) | WO2011129466A1 (en) |
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| MX2019001220A (en) | 2016-08-02 | 2019-07-04 | Fitesa Germany Gmbh | System and process for preparing polylactic acid nonwoven fabrics. |
| US11441251B2 (en) | 2016-08-16 | 2022-09-13 | Fitesa Germany Gmbh | Nonwoven fabrics comprising polylactic acid having improved strength and toughness |
| EP3525611B1 (en) * | 2016-09-28 | 2023-10-25 | Under Armour, Inc. | Apparel for athletic activities |
| DE112018000617T5 (en) * | 2017-01-31 | 2019-11-07 | The Procter & Gamble Company | Molded nonwovens and articles containing them |
| RU2713351C1 (en) | 2017-02-28 | 2020-02-04 | Кимберли-Кларк Ворлдвайд, Инк. | Method of producing laminar webs with hollow ledges and holes subjected to jet bonding |
| WO2018182601A1 (en) | 2017-03-30 | 2018-10-04 | Kimberly-Clark Worldwide, Inc. | Incorporation of apertured area into an absorbent article |
| BR112019023938A2 (en) * | 2017-05-17 | 2020-06-09 | Berry Global Inc | lamination system |
| EP3645775B1 (en) | 2017-06-30 | 2021-07-21 | The Procter & Gamble Company | Method for making a shaped nonwoven |
| WO2019005906A1 (en) | 2017-06-30 | 2019-01-03 | The Procter & Gamble Company | Shaped nonwoven |
| EP3425099A1 (en) * | 2017-07-03 | 2019-01-09 | Axel Nickel | Meltblown non-woven fabric with improved stackability and storage |
| US10792199B2 (en) * | 2018-02-23 | 2020-10-06 | The Procter & Gamble Company | Substrates and laminates for absorbent articles |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5274893A (en) * | 1991-04-26 | 1994-01-04 | Nippon Filcon Co., Ltd. | Belt for fabricating a non-woven fabric with projections and method for fabricating a non-woven fabric with patterns |
| CN1681986A (en) * | 2002-09-09 | 2005-10-12 | 花王株式会社 | Nonwoven fabric |
| JP2009062650A (en) * | 2007-09-07 | 2009-03-26 | Kao Corp | Non-woven fabric and method for producing the same |
| CN101535549A (en) * | 2006-12-25 | 2009-09-16 | 尤妮佳股份有限公司 | Method of producing stretchable sheet |
| JP2009228145A (en) * | 2008-03-19 | 2009-10-08 | Uni Charm Corp | Method for producing elastic sheet |
| CN101652508A (en) * | 2007-03-30 | 2010-02-17 | 尤妮佳股份有限公司 | Nonwoven stretch fabric |
| JP2010084317A (en) * | 2010-01-06 | 2010-04-15 | Kao Corp | Surface sheet of absorbent article |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4209563A (en) | 1975-06-06 | 1980-06-24 | The Procter & Gamble Company | Method for making random laid bonded continuous filament cloth |
| JPH10165343A (en) * | 1996-12-06 | 1998-06-23 | Oji Paper Co Ltd | Cleaning sheet and its manufacture |
| EP1283028B1 (en) | 2001-08-10 | 2008-03-05 | Kao Corporation | Topsheet for absorbent article |
| JP3587831B2 (en) | 2001-08-10 | 2004-11-10 | 花王株式会社 | Surface sheet for absorbent articles |
| KR101237367B1 (en) | 2005-04-25 | 2013-02-28 | 가오 가부시키가이샤 | Stretch sheet and process for producing the same |
| JP2007321287A (en) * | 2006-05-31 | 2007-12-13 | Kao Corp | Stretchable nonwoven fabric |
| JP5069890B2 (en) * | 2006-06-23 | 2012-11-07 | ユニ・チャーム株式会社 | Non-woven |
| JP5506519B2 (en) * | 2010-04-16 | 2014-05-28 | ユニ・チャーム株式会社 | A method for easily manufacturing a nonwoven fabric having irregularities, and a method for easily processing a nonwoven fabric |
-
2010
- 2010-04-16 JP JP2010095246A patent/JP5506520B2/en active Active
-
2011
- 2011-04-14 CN CN201180026845.2A patent/CN102918190B/en active Active
- 2011-04-14 EP EP11768982.8A patent/EP2559794B1/en active Active
- 2011-04-14 US US13/640,368 patent/US8974890B2/en not_active Expired - Fee Related
- 2011-04-14 WO PCT/JP2011/059770 patent/WO2011129466A1/en active Application Filing
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5274893A (en) * | 1991-04-26 | 1994-01-04 | Nippon Filcon Co., Ltd. | Belt for fabricating a non-woven fabric with projections and method for fabricating a non-woven fabric with patterns |
| CN1681986A (en) * | 2002-09-09 | 2005-10-12 | 花王株式会社 | Nonwoven fabric |
| CN101535549A (en) * | 2006-12-25 | 2009-09-16 | 尤妮佳股份有限公司 | Method of producing stretchable sheet |
| CN101652508A (en) * | 2007-03-30 | 2010-02-17 | 尤妮佳股份有限公司 | Nonwoven stretch fabric |
| JP2009062650A (en) * | 2007-09-07 | 2009-03-26 | Kao Corp | Non-woven fabric and method for producing the same |
| JP2009228145A (en) * | 2008-03-19 | 2009-10-08 | Uni Charm Corp | Method for producing elastic sheet |
| JP2010084317A (en) * | 2010-01-06 | 2010-04-15 | Kao Corp | Surface sheet of absorbent article |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103140616A (en) * | 2010-09-30 | 2013-06-05 | 尤妮佳股份有限公司 | Nonwoven fabric, absorbent article comprising the same, and method of forming the same |
| CN103140616B (en) * | 2010-09-30 | 2016-01-06 | 尤妮佳股份有限公司 | The formation method of bondedfibre fabric, the absorbent article comprising bondedfibre fabric and bondedfibre fabric |
| CN105026633A (en) * | 2013-03-11 | 2015-11-04 | 花王株式会社 | Stretchable sheet manufacturing method and manufacturing device |
| CN105120819A (en) * | 2013-03-26 | 2015-12-02 | 尤妮佳股份有限公司 | Absorbent article |
| CN107109734B (en) * | 2014-12-26 | 2019-03-08 | 尤妮佳股份有限公司 | The manufacturing method of flexible nonwoven fabrics |
| CN107109734A (en) * | 2014-12-26 | 2017-08-29 | 尤妮佳股份有限公司 | The manufacture method of flexible nonwoven fabrics |
| CN111212938A (en) * | 2017-12-28 | 2020-05-29 | 尤妮佳股份有限公司 | Fibrous nonwoven fabric sheet |
| CN111328355A (en) * | 2017-12-28 | 2020-06-23 | 尤妮佳股份有限公司 | Fibrous nonwoven fabric sheet |
| CN111212938B (en) * | 2017-12-28 | 2022-07-26 | 尤妮佳股份有限公司 | Fibrous nonwoven fabric sheet |
| CN114960031A (en) * | 2017-12-28 | 2022-08-30 | 尤妮佳股份有限公司 | Fibrous nonwoven fabric sheet |
| CN111328355B (en) * | 2017-12-28 | 2022-09-27 | 尤妮佳股份有限公司 | Fibrous nonwoven fabric sheet |
| CN109281060A (en) * | 2018-10-29 | 2019-01-29 | 稳健医疗用品股份有限公司 | Spunlace non-woven cloth and its product |
| CN115279960A (en) * | 2020-03-13 | 2022-11-01 | 尤妮佳股份有限公司 | Stretchable nonwoven fabric, method for producing same, and mask and absorbent article using same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5506520B2 (en) | 2014-05-28 |
| JP2011226011A (en) | 2011-11-10 |
| US8974890B2 (en) | 2015-03-10 |
| EP2559794B1 (en) | 2015-09-16 |
| EP2559794A4 (en) | 2014-10-01 |
| WO2011129466A1 (en) | 2011-10-20 |
| US20130034686A1 (en) | 2013-02-07 |
| CN102918190B (en) | 2015-10-21 |
| EP2559794A1 (en) | 2013-02-20 |
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