CN102787487A - Application of nano transparent thermal insulation coating on textile fabrics - Google Patents
Application of nano transparent thermal insulation coating on textile fabrics Download PDFInfo
- Publication number
- CN102787487A CN102787487A CN2012102398974A CN201210239897A CN102787487A CN 102787487 A CN102787487 A CN 102787487A CN 2012102398974 A CN2012102398974 A CN 2012102398974A CN 201210239897 A CN201210239897 A CN 201210239897A CN 102787487 A CN102787487 A CN 102787487A
- Authority
- CN
- China
- Prior art keywords
- nano
- heat
- application
- coating
- insulating coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 72
- 238000000576 coating method Methods 0.000 title claims abstract description 52
- 239000004744 fabric Substances 0.000 title claims abstract description 41
- 239000004753 textile Substances 0.000 title claims abstract description 17
- 238000009413 insulation Methods 0.000 title abstract description 20
- 239000002775 capsule Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 7
- 238000001132 ultrasonic dispersion Methods 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims abstract description 3
- 239000002904 solvent Substances 0.000 claims abstract description 3
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 15
- 229920002545 silicone oil Polymers 0.000 claims description 10
- 238000003760 magnetic stirring Methods 0.000 claims description 9
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims description 6
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 claims description 6
- 229910000497 Amalgam Inorganic materials 0.000 claims description 4
- 244000048199 Hibiscus mutabilis Species 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 2
- 235000005206 Hibiscus Nutrition 0.000 claims 1
- 235000007185 Hibiscus lunariifolius Nutrition 0.000 claims 1
- 235000003973 Hibiscus mutabilis Nutrition 0.000 claims 1
- 244000284380 Hibiscus rosa sinensis Species 0.000 claims 1
- 239000008199 coating composition Substances 0.000 claims 1
- 238000011056 performance test Methods 0.000 claims 1
- 239000011268 mixed slurry Substances 0.000 abstract description 11
- 239000002270 dispersing agent Substances 0.000 abstract description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 4
- 230000000694 effects Effects 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 6
- 238000013019 agitation Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000004447 silicone coating Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses an application of a nano transparent thermal insulation coating on textile fabrics, characterized by selecting a certain proportion of nano ATO and nano TiO2 as powder, adding a solvent to prepare a mixed slurry of nano ATO and nano TiO2, then mixing the mixed slurry with an organosilicon coating agent, and adding a certain amount of dispersant and thermal insulation capsules, stirring uniformly and then conducting ultrasonic dispersion to obtain a nano transparent thermal insulation coating, and testing the thermal insulation performance of the coating on textile fabrics. According to the invention, the coating has good thermal insulation performance, and the transparency solves the problem that previous thermal insulation coatings influence the color of the fabrics.
Description
Technical field
The present invention relates to a kind of insulating moulding coating, the application of particularly a kind of nano transparent heat-insulating coating on textile cloth.
Background technology
Nowadays at present; Development of science and technology has rapidly been brought the convenience and the comfortableness of people's lives; Increasing heat-barrier material is widely used on building and the industrial equipment; But heat-barrier material is also narrow in relating to of field of textiles, and people are burning hot day by day to the demand with textiles heat insulation and attractive in appearance, so the market space of heat insulation textiles and prospect are comparatively wide.
Insulating moulding coating mainly comprises isolation-type insulating moulding coating, reflection type thermal insulation coating and radiation type heat-insulation coating.Though isolation-type insulating moulding coating effect is better, the application on textiles is not too practical, because this type of coating belongs to the coating of coloured muddiness; After coating on the cloth, can have a strong impact on the outward appearance and the feel of cloth; For example Lv Haitao (patent publication No.: CN101648794) disclose a kind of dry-type heat-insulating waterproof coating, this kind coating has certain effect of heat insulation on fabric, but since coating this as white; If cloth is non-white, will influence the color of cloth itself after the coating; Radiation type heat-insulation coating, is also treated more in depth to study though significantly technology is very complicated for effect with the external distribute heat of thermal-radiating form.The basic principle of nano transparent heat-insulating coating is to utilize the nano semiconductor material that mixes that infrared light is absorbed and reflects, thereby reaches not only heat insulation but also transparent effect.At present; This type of coating is used on building glass and the precision instrument mostly; Zhao Shilin etc. (patent publication No.: CN 1563231A) disclose a kind of by the ITO powder, nano ATO, the coating that auxiliary agent and diluent are formed; Experiment finds that this kind coating is coated in glass surface certain effect of heat insulation is arranged, but in textiles, come off easily and effect of heat insulation limited; (patent publication No.: CN 102241937A) disclose a kind of POSS modified water-soluble nano transparent insulating coating and preparation method thereof, this kind technology comparatively suitable commercial production of complicacy and cost is higher for Dai Lizong etc.
Summary of the invention
Influence the problem of cloth color and luster in order to solve heat insulating coat in the past, the present invention uses nano ATO and nano-TiO
2Two kinds of nanometer heat insulation materials combine with the SILICONE COATING AGENT methyl-silicone oil, make a kind of nano transparent heat-insulating coating.
The present invention realizes in the following manner:
A kind of nano transparent heat-insulating coating, component is in the described coating: represent nano ATO and nano-TiO with mass percent
2Amalgam is 20～40%, DMF is 20～35%, PEG400 is 2.5%, 46
#The heat storing and heat preserving capsule be 3% with methyl-silicone oil be 15～45%.Wherein nano ATO and nano-TiO
2Mass ratio be 2: 1,1.5: 1 and 1: 1; Nano ATO and nano-TiO
2Amalgam is 30%; DMF is 30%; Methyl-silicone oil is 35%.
Described heat insulating coat preparation method comprises following step:
(1) preparation of nanometer mixed slurry: elder generation is with the nano ATO and the nano-TiO of aequum
2Mix by a certain percentage, mixed-powder joins in the solvent DMF, uses magnetic stirring apparatus to carry out magnetic agitation 30min, promptly makes the nanometer mixed slurry;
(2) get a certain amount of methyl-silicone oil, join lentamente in the above-mentioned nanometer mixed slurry, continue to open magnetic stirring apparatus, stir 20min, promptly make the mixed coating agent;
(3) in above-mentioned mixed coating agent, add dispersant and heat storing and heat preserving capsule, and carry out ultrasonic dispersion 2h, promptly make the nano transparent heat-insulating coating agent.
Nano transparent heat-insulating coating agent to preparing carries out coating to cloth, and the process of coating is the single face coating for scraping the skill in using a kitchen knife in cookery, the cloth that coating is good is dried 2min down at 150 ℃, and use coated fabric heat-proof quality tester to carry out the heat-proof quality test.
Advantage of the present invention:
1. have the infrared effect of good obstruct owing to nano ATO, and nano-TiO
2The ultraviolet-resistant effect also better, effectively intercept infrared and ultraviolet so both mix physical efficiency, the effect of heat insulation of coating strengthens.
2. use SILICONE COATING AGENT to combine, make that nanometer thermal insulation coating is a transparence, solved the problem that heat insulating coat in the past influences the cloth color and luster with nanometer heat insulation material.
3. technology of the present invention is simple, is easy to produce, and pollution-free, be a kind of technology of environmental protection.
The specific embodiment
Embodiment 1
(1) with nano ATO and nano-TiO
2Press mass ratio and mix at 2: 1, nano ATO is got 40g, nano-TiO
2Get 20g, in beaker, add 60g DMF, use magnetic stirring apparatus to carry out magnetic agitation 30min, promptly make the nanometer mixed slurry;
(2) get the methyl-silicone oil of 70g again, join lentamente in the nanometer mixed slurry, continue to open magnetic stirring apparatus, stir 20min, promptly make the mixed coating agent;
(3) in the coating agent of above mixing, add 5g dispersant PEG400 and 6g 46
#The heat storing and heat preserving capsule carries out ultrasonic dispersion 2h to the coating agent that mixes, and promptly makes the nano transparent heat-insulating coating agent.
Selecting a cottonrose hibiscus silk fabric for use is cloth, is of a size of 30cm * 30cm, uses and scrapes the skill in using a kitchen knife in cookery to its single face coating, and the cloth that coating is good is dried 2min down at 150 ℃, uses coated fabric heat-proof quality tester to carry out the heat-proof quality test, and the result sees table 1.
Embodiment 2
(1) with nano ATO and nano-TiO
2Mixed by 1.5: 1, nano ATO is got 36g, nano-TiO
2Get 24g, in beaker, add 60g DMF, use magnetic stirring apparatus to carry out magnetic agitation 30min, promptly make the nanometer mixed slurry;
(2) get the methyl-silicone oil of 70g again, join lentamente in the nanometer mixed slurry, continue to open magnetic stirring apparatus, stir 20min, promptly make the mixed coating agent;
(3) in above mixed coating agent, add 5g dispersant PEG400 and 6g46
#The heat storing and heat preserving capsule carries out ultrasonic dispersion 2h to the coating agent that mixes, and promptly makes the nano transparent heat-insulating coating agent.
Selecting a cottonrose hibiscus silk fabric for use is cloth, is of a size of 30cm * 30cm, uses and scrapes the skill in using a kitchen knife in cookery to its single face coating, and the cloth that coating is good is dried 2min down at 150 ℃, uses coated fabric heat-proof quality tester to carry out the heat-proof quality test, and the result sees table 1.
Embodiment 3
(1) with nano ATO and nano-TiO
2Mixed by 1: 1, nano ATO is got 30g, nano-TiO
2Get 30g, in beaker, add 60g DMF, use magnetic stirring apparatus to carry out magnetic agitation 30min, promptly make the nanometer mixed slurry;
(2) get the methyl-silicone oil of 70g again, join lentamente in the above-mentioned nanometer mixed slurry, continue to open magnetic stirring apparatus, stir 20min, promptly make the mixed coating agent;
(3) in above mixed coating agent, add 5g dispersant PEG400 and 6g 46
#The heat storing and heat preserving capsule carries out ultrasonic dispersion 2h to the coating agent that mixes, and promptly makes the nano transparent heat-insulating coating agent.
Selecting a cottonrose hibiscus silk fabric for use is cloth, is of a size of 30cm * 30cm, uses and scrapes the skill in using a kitchen knife in cookery to its single face coating, and the cloth that coating is good is dried 2min down at 150 ℃, uses coated fabric heat-proof quality tester to carry out the heat-proof quality test, and the result sees table 1.
Can know that from the result of table 1 effect of heat insulation of nano transparent heat-insulating coating of the present invention on fabric is better, and ATO and nano-TiO
2Ratio be that 1: 1 o'clock effect of heat insulation is best.
Table 1
| Embodiment | Temperature before passing through/℃ | Temperature after passing through/℃ | The temperature difference/℃ |
| 1 | 60 | 44 | 16 |
| 2 | 60 | 45 | 15 |
| 3 | 60 | 42 | 18 |
Claims (7)
1. the application of nano transparent heat-insulating coating on textile cloth selected for use blending method that coating agent is mixed, and on cloth, carried out performance test, it is characterized in that: coating composition is represented with mass percent, nano ATO and nano-TiO
2Amalgam is 20～40%, DMF is 20～35%, PEG400 is 2.5%, 46
#The heat storing and heat preserving capsule be 3% with methyl-silicone oil be 15～45%.
2. the application of a kind of nano transparent heat-insulating coating according to claim 1 on textile cloth is characterized in that nano ATO and nano-TiO
2Mass ratio be 2:1,1.5:1 and 1:1.
3. the application of a kind of nano transparent heat-insulating coating according to claim 1 on textile cloth is characterized in that nano ATO and nano-TiO
2Amalgam is 30%.
4. the application of a kind of nano transparent heat-insulating coating according to claim 1 on textile cloth is characterized in that DMF is 30%.
5. the application of a kind of nano transparent heat-insulating coating according to claim 1 on textile cloth is characterized in that methyl-silicone oil is 35%.
6. the application of a kind of nano transparent heat-insulating coating according to claim 1 on textile cloth is characterized in that the preparation method of nano transparent heat-insulating coating agent is following:
Earlier with a certain proportion of nano ATO and nano-TiO
2For powder mixes, add solvent DMF, under magnetic stirring apparatus, mix and stir 30min, and slowly add methyl-silicone oil, after continuing to stir 20min, add PEG400 and 46
#The heat storing and heat preserving capsule carries out ultrasonic dispersion 2h to the coating agent that mixes, and can make the nano transparent heat-insulating coating agent.
7. the application of a kind of nano transparent heat-insulating coating according to claim 1 on textile cloth; It is characterized in that selecting for use a cottonrose hibiscus silk fabric is cloth; Be of a size of 30cm * 30cm; Use is scraped the skill in using a kitchen knife in cookery to its single face coating, and the cloth that coating is good is dried 2min down at 150 ℃, uses coated fabric heat-proof quality tester to carry out the heat-proof quality test.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102398974A CN102787487B (en) | 2012-07-11 | 2012-07-11 | Application of nano transparent thermal insulation coating on textile fabrics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102398974A CN102787487B (en) | 2012-07-11 | 2012-07-11 | Application of nano transparent thermal insulation coating on textile fabrics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102787487A true CN102787487A (en) | 2012-11-21 |
| CN102787487B CN102787487B (en) | 2013-12-04 |
Family
ID=47153062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012102398974A Expired - Fee Related CN102787487B (en) | 2012-07-11 | 2012-07-11 | Application of nano transparent thermal insulation coating on textile fabrics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102787487B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108677548A (en) * | 2018-08-08 | 2018-10-19 | 相里海霞 | A kind of nano heat-insulating glove fabric |
| CN109082884A (en) * | 2018-08-10 | 2018-12-25 | 苏州市天翱特种织绣有限公司 | A kind of anti-flaming thermal-insulation fabric |
| CN115418864A (en) * | 2022-08-15 | 2022-12-02 | 浙江中纯新材料有限公司 | Heat-insulating warp-knitted fabric and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1563231A (en) * | 2004-04-16 | 2005-01-12 | 南京工业大学 | Nano transparent heat-insulation composite coating and heat-insulation effect testing device thereof |
| CN101108946A (en) * | 2007-07-12 | 2008-01-23 | 深圳清华大学研究院 | Nano transparent insulating paint and its preparing process |
| CN101219859A (en) * | 2007-11-30 | 2008-07-16 | 华南理工大学 | Nano-oiliness ATO heat-insulating slurry, production method and uses thereof |
-
2012
- 2012-07-11 CN CN2012102398974A patent/CN102787487B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1563231A (en) * | 2004-04-16 | 2005-01-12 | 南京工业大学 | Nano transparent heat-insulation composite coating and heat-insulation effect testing device thereof |
| CN101108946A (en) * | 2007-07-12 | 2008-01-23 | 深圳清华大学研究院 | Nano transparent insulating paint and its preparing process |
| CN101219859A (en) * | 2007-11-30 | 2008-07-16 | 华南理工大学 | Nano-oiliness ATO heat-insulating slurry, production method and uses thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张向雨: "有机硅功能涂料的研制", 《工程科技I辑》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108677548A (en) * | 2018-08-08 | 2018-10-19 | 相里海霞 | A kind of nano heat-insulating glove fabric |
| CN109082884A (en) * | 2018-08-10 | 2018-12-25 | 苏州市天翱特种织绣有限公司 | A kind of anti-flaming thermal-insulation fabric |
| CN115418864A (en) * | 2022-08-15 | 2022-12-02 | 浙江中纯新材料有限公司 | Heat-insulating warp-knitted fabric and preparation method thereof |
| CN115418864B (en) * | 2022-08-15 | 2024-03-12 | 浙江中纯新材料有限公司 | Heat-insulating warp knitting cloth and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102787487B (en) | 2013-12-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105113285B (en) | A kind of pulp-shaped dispersed dyes and preparation method and application | |
| CN107129752B (en) | A kind of graphene silver nanowires composite mortar and preparation method thereof | |
| CN102320662A (en) | Cesium tungsten bronze powder and preparation method thereof | |
| CN102787487B (en) | Application of nano transparent thermal insulation coating on textile fabrics | |
| CN103821012A (en) | Disperse dye efficient embossing technology for steaming and washing-free dacron fabrics | |
| CN103013172A (en) | Preparation method of modified pigment yellow 12 | |
| CN103937291B (en) | A kind of stamp Disperse black azo dye mixture and preparation method thereof | |
| CN107189581A (en) | A kind of graphene is except aldehyde heating wallpaper, wall paper and preparation method | |
| CN102864652A (en) | Silk dyeing and painting method | |
| CN104928954A (en) | Printing method for polyester-cotton blended waterproof and moisture permeable fabric | |
| CN107189532A (en) | A kind of graphene formaldehyde-removing wallpaper, wall paper and preparation method | |
| CN103540199B (en) | A kind of method utilizing waste to prepare nano flame retardant coating | |
| CN103897577A (en) | Glass paint and preparation method thereof | |
| CN102391730B (en) | Nano functional coating | |
| CN103642262A (en) | Method for preparing easily-dispersed phthalocyanine blue pigment | |
| CN105040477A (en) | Reactive dye printing technology of pure cotton cloth | |
| CN106146563A (en) | A kind of preparation method for PLASTIC LAMINATED fire retardant | |
| CN103275604A (en) | Phosphorous alkyd resin transparent fire retardant coating and preparation method thereof | |
| CN103643505A (en) | Processing technology of jeans wear | |
| CN106244003A (en) | A kind of preparation method of ageing-resistant oil colour | |
| CN102352550A (en) | Fire retardant used for wool-acrylic fabric | |
| CN106328242A (en) | Carbon nitride-coated superconductive graphene electrode material and preparation method thereof | |
| Huang et al. | Preparation and application of carboxymethyl starch | |
| CN111621998A (en) | Preparation method of heating color paste | |
| CN104260468A (en) | Conductive plastic board and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Liu Yunshu Inventor before: Zhang Yu |
|
| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160525 Address after: Baiyun District of Guangzhou City, Guangdong province 510430 Huangshi West Village Stone Industrial Zone, Dagang District Patentee after: Guangzhou King Cotton Knitting Clothing Co., Ltd. Address before: 215417 Taicang city of Jiangsu province Shaxi Zhen Zhi village sixteen Group No. 3 Patentee before: Zhang Yu |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20131204 Termination date: 20180711 |