CN102785432B - Function-shared three-composite-layer laminated flameproof fabric, preparation technology and application - Google Patents
Function-shared three-composite-layer laminated flameproof fabric, preparation technology and application Download PDFInfo
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- CN102785432B CN102785432B CN201210292693.7A CN201210292693A CN102785432B CN 102785432 B CN102785432 B CN 102785432B CN 201210292693 A CN201210292693 A CN 201210292693A CN 102785432 B CN102785432 B CN 102785432B
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- Laminated Bodies (AREA)
Abstract
The invention relates to a function-shared three-composite-layer laminated flameproof fabric, a preparation technology and application. The flameproof fabric consists of a reflection heat-insulation layer which faces to a flame and is mainly formed by a high-reflectivity metal foil, a heat-consumption temperature limiting layer which is intermediately arranged and is mainly formed by a high-heat-absorptivity energy-transduction phase-change material, and a heat-insulation comfortable layer which touches a human body and is mainly formed by a high-heat-insulation and high-heat-reflectivity composite film. The reflection heat-insulation layer can reflect and insulate most heat radiated by an open-fire strong heat flow environment; the heat-consumption temperature limiting layer cuts off temperature, absorbs heat and consumes energy through the phase change of a phase-change material; and the heat-insulation comfortable layer realizes heat insulation and comfort effects through heat insulation and reflection of a multilayer composite film and a lining flameproof comfortable base fabric. The reflection heat-insulation layer, the heat-consumption temperature limiting layer and the heat-insulation comfortable layer are composite layers and are sewn and bonded in a fully-closed manner to form the composite flameproof fabric. The natural thickness of the flameproof fabric is 5-15mm, the compact thickness of the flameproof fabric is 3-10mm and the weight per square meter of the flameproof fabric is 450-1500g/m<2>. The flameproof fabric can be used for human body protection and environmental heat insulation of high-radiated-heat special occasions such as firefighting, military, exploration and industry.
Description
Technical field
The present invention relates to a kind of human body or the heat insulation frivolous flexible composite technology with protecting of environment temperature, particularly relate to a kind of efficient, intelligent, long-acting composite fire-proof fabric of function sharing, the preparation technology of this composite fire-proof fabric and application, this composite fire-proof fabric is the heat insulation important materials of the physical protection of the special occasions such as fire-fighting, military affairs, exploration, industry and environment.
Background technology
In the high temperature heat-flash stream environment such as the naked light scene of a fire, heat radiation is the most important mode of carrying out heat exchange.Data shows, the hot-fluid produced by naked light burning things which may cause a fire disaster is except small part (lower than 30%) convection current, and the radiant heat propagated mainly with electromagnetic wave dispels the heat to surrounding.Because radiant heat penetration power is strong, be easy to cause human body burn or burn, the radiant heat protection therefore in the scene of a fire is the Important Problems of research always.According to physics radiation one reflectance mechanism, most effective method is the coating or the lamination that adopt surface reflection structure sheaf fabric face to be carried out to metal or metal oxide, is reflected as much as possible by the radiant heat in the scene of a fire.Aluminium foil, due to its excellent reflect radiation heat performance and workability, obtains applying comparatively widely in fire-proof and thermal-insulation field.
The minimizing radiant heat that focuses on of current fire-fighting class heat-protective clothing penetrates, and reduces heat transfer, protective garment deep layer programming rate is slowed down, is not burnt to guarantee fire fighter to work long hours in the fire field environment of high temperature intense radiation hot-fluid.So fire-fighting class heat-protective clothing not only wants surface to have high reverse--bias and heat dissipation heat insulating function, and itself is fire-resistant, high temperature resistant, heat insulation, to realize the efficient isolated of burning things which may cause a fire disaster and the safe and effective protection to human body.Surface is had to the fire-fighting class clothes of function of heat reflection, have more research and patent in recent years.As heat insulation protective clothing fabric for firemen (patent No. CN200920211471.1) is made up of aluminium foil, PET polyester film and aramid fiber plain weaving machine ply ground fabric, wherein aluminium foil is 7 μm of thick rolling aluminum foils.This invention obtains good penetrating quality of anti radiant heat effect, but due to the restriction of thickness and PET polyester film fusing point, its thermal protection effect is very limited.Anti-heat radiation high-temperature-resistant flame-proof protective garment fabric (patent No. CN200920309275.8) adopts the composite construction of the overcoat of heat-resisting, flame-retardant textile fibrage, adhesive layer and thermal radiation resistance from inside to outside, and wherein thermal radiation resistance overcoat is the polyester aluminizer of 20 ~ 25 μm.The protective garment fabric of this invention has good thermal radiation resistance, and light weight, high temperature resistant, shrinkage factor is little, but polyester aluminizer resistance to elevated temperatures is limited.
The multi-layer compound fabric that aluminum-foil fire-resistant heat-proof gloves (patent No. CN201020276197.9) is made up of the layer of resistance to flame, thermal insulation layer and endonexine is made.Wherein the layer of resistance to flame is composited by aluminium foil layer with aramid fiber and antistatic cotton by the tissue layer of Ripstop rule blending woven; Thermal insulation layer adopts permanent fire retardant nonwoven fabric.Gloves reduce the danger contacted with thermal source, enhance the isolating and protecting to high temperature.
There is the heat insulating coat fabric (patent No. CN201020253770.4) of reflecting layer, radiating layer multiplet, obtained by Ji Bu and the heat-insulating slurry be coated on base cloth, wherein heat-insulating slurry is the double-layer structure of radiation function layer and the reflective functional layer containing hollow glass microballoon.Coated fabric can realize good fire-proof and thermal-insulation effect by the radiation function again by radiating layer after the reflection function in reflecting layer, but resistance to elevated temperatures is limited and usefulness is lower.
Fire-entry suit is with fire-retardant phase transformation thermal insulation layer fabric (patent No. CN201010233816.0), be by by the aramid fiber 1313 of 50 ~ 90%, the carbon fiber of 5 ~ 20% and 0 ~ 30% the nonwoven felt that combines of FRC immerse obtained fire-retardant phase transformation and fire in microcapsules working solution, be prepared from through two leaching two roll process processing.Though gained fabric has fire-retardant and temperature adjusting performance preferably, the restriction due to phase-change microcapsule is difficult to use under high temperature fire field environment.
Anti-photothermal radiation nanocomposite fabric coating material (patent No. CN200910181069.8), ceramic photothermal reflectance layer can be formed at fabric face by special process, nano-titanium compound reflecting layer and stabilized zone, play and reflect near infrared ray and visible ray.Test result shows that composite Nano fabric coating heat reflective radiation can reach more than 81%.
Oil, wash fast light and thin type fire-entry suit fabric and fire-entry suit (patent No. CN201110285062.8) can be refused, from outside to inside, be followed successively by and refuse oily washable layer, waterproof ventilative layer and thermal insulation layer and inner comfort liner by the obtained fire-retardant skin of meta-aramid, p-aramid fiber, Fypro and antistatic fiber, centre, make through suture and form.Though fabric has good fire-retardant conjunction antistatic performance, still can comparatively fast cause personnel to burn in the high temperature scene of a fire during actual use, burn.
Heat insulating compound film (patent No. CN200510024710.9) is the patent of invention before applicant, efficient, the lightweight of (-150 ~ 200 DEG C), flexible multi-functional thermal protection under adopting the structure be composited by the outer overlay film of the high polymer basement membrane of high-strength low heat conductivity coefficient, the metal level of high reverse--bias performance, the metal oxide layer of high thermal insulation and the heat bondable high polymer of low heat conductivity to realize high and low temperature environment, but this patent just solves heat insulation.
Heat insulation soft thin composite fabric (patent No. CN200410066650.2) is also the patent of invention before applicant, one side adopts the high performance coated fabric of high-and low-temperature resistance, another side adopts soft, comfortable, frost prevention, anti-condensation coated fabric, the middle compound fabric adopting the high polymer of multilayer insulation and metal composite film to form, between MULTILAYER COMPOSITE can tape thickness, dimensionally stable lining meshi fabric, realize one side and can bear high temperature, low temperature or high and low temperature compound action, one side keeps 5 ~ 35 DEG C of nearly room temperature states; The natural thickness of compound fabric of the present invention is at 3 ~ 12mm, and weight per square meter is at 150 ~ 550g/m
2, the heat insulation and protection under-130 ~ 120 DEG C of conditions can be realized.Though widely applicable, effect of heat insulation is limited.This patent is not fire resistance applications, and both flames of anger height heat emission layers, also without decalescence layer.
Although Thermal Protective Fabric or clothes obtained by above patented technology have good radioresistance thermal break-through performance, but in actual applications, owing to being subject to the restriction of foil polymer matrix and heat conductivility, still can there is burn in very short time or burn in human body in the actual dress use in the high temperature scene of a fire of 800 DEG C.
Summary of the invention
An object of the present invention is to provide the flameproof fabric that a kind of three composite beds collecting the function sharings such as reflective insulation, transducing heat dissipation and thermal insulation be comfortable are laminated.Another object of the present invention is to provide a kind of preparation method of the above-mentioned laminated flameproof fabric of three composite beds.Another object of the present invention is to provide a kind of application of the above-mentioned laminated flameproof fabric of three composite beds.
In order to achieve the above object, principle of the present invention is by function sharing and directive reflective insulation layer, heat dissipation limit composite construction and the complex method thereof of the composite laminated of warm layer and adiabatic comfort liner three, and the Function Decomposition realizing fire-proof heat-insulating is shared and dissipates.Wherein, realize the photothermal reflection in the large portion of naked light heat-flash stream environment and completely isolated to high temperature gas flow based on the reflective insulation layer of the metal forming of high reflectance; Warm layer is limit to realize completely cutting off the dissipation of fabric infiltration radiant heat and heat by conduction based on the heat dissipation of the transducing phase-change material that absorbs heat; Realize the isolated of after-heat with adiabatic comfort liner and ensure that human contact's is comfortable, and keep nearly human body skin≤safe temperature of 50 DEG C.The laminated flameproof fabric of three composite beds has the features such as lightweight, flexibility, high high-temp stability and radiant heat barrier propterty are excellent, reusable.
The flameproof fabric that three composite beds that a concrete technical scheme of the present invention there is provided a kind of function sharing are laminated, is characterized in that: ecto-entad is made up of following functional structure layer successively: play the reflective insulation layer of radiant heat high reverse--bias and air-flow insulating effect, play the limitting warm layer containing the heat dissipation of phase-change material and play the adiabatic comfort liner of thermal isolation and comfortable effect of heat absorption transduction.
Preferably, described reflective insulation layer strengthens base fabric by the metal forming of high reflectance and high-temperature fibre and is composited; Described heat dissipation is limit warm layer by high temperature resistant non-woven felt, is formed at 200 ~ 400 DEG C of solid-liquid phase change materials undergone phase transition and leakproof base fabric Compound Machining; Described adiabatic comfort liner is by composite aluminium film, air buffer and comfortable base fabric ecto-entad is laminated successively forms.
Preferably, described metal forming to be thickness be pure aluminum foil or the alloy foil of 5 ~ 10 μm; Described high-temperature fibre strengthens base fabric and is obtained by basalt fibre or glass fibre, for the enhancing, stable and smooth of described metal forming; Described high temperature resistant non-woven felt is made up of high-temperature fibre, and the attachment for described solid-liquid phase change material is fixed; Described solid-liquid phase change material is used for the absorption and the dissipation that conduct to fabric heat; Described leakproof base fabric is for preventing the leakage of phase transformation powder in processing and use and the second humidification layer of flameproof fabric; Described composite aluminium film is by smooth surface high-polymer membrane, aluminium coated and rough surface high-polymer membrane three layers of composite membrane be composited; Described air buffer is support through netting to be formed; Described comfortable base fabric is retardant cotton or flame-resistant terylene cloth.
Preferably, described high-temperature fibre is glass fibre or aramid fiber.
Preferably, the natural thickness of this flameproof fabric is 5 ~ 15mm, and actual compression thickness is 3 ~ 10mm; Weight per square meter is at 450 ~ 1500g/m
2;
Preferably, the weight per square meter≤250g/m of described reflective insulation layer
2; Described heat dissipation limits the thickness≤4mm of warm layer, weight per square meter≤500g/m
2; Thickness≤the 2mm of described adiabatic comfort liner, weight per square meter≤250g/m
2.
Another technical scheme of the present invention there is provided the preparation technology of the laminated flameproof fabric of a kind of three composite beds of above-mentioned function sharing, it is characterized in that: first through high-temperature agglomerant bonding or sew up mode forms reflective insulation layer, heat dissipation limits warm layer and adiabatic comfort liner, then reflective insulation layer, heat dissipation limit warm layer and adiabatic comfort liner to be bondd by high-temperature agglomerant or the mode composite laminated sewed up is shaped.
Another technical scheme of the present invention there is provided the application of the laminated flameproof fabric of a kind of three composite beds of above-mentioned function sharing, it is characterized in that: for the physical protection that uses under high temperature intense radiation hot-fluid fire field environment condition and heat-barrier material.
The use of flameproof fabric has directionality, its order towards thermal source is: the high-reflectivity metal paper tinsel towards flame is main reflective insulation layer, central height heat absorption transducing phase-change material is that main heat dissipation limits the heat insulation anti-thermal compound film of warm layer and height contact human body to be main adiabatic comfort liner, and three composite beds form efficient, lightweight, flexible fire-proof heat-insulating system and realization is protected the highly effective and safe of human body thus.
Compared with prior art, tool of the present invention has the following advantages:
1, flameproof fabric is three composite laminated composite constructions of function sharing, integrates the functions such as the heat insulation and thermal insulation of reflective insulation, heat dissipation is comfortable, can realize the safe and effective protection to human body under high temperature heat-flash stream fire field environment;
2, flameproof fabric function is reasonable, complete: reflective insulation layer, heat dissipation limit each functional structure layers such as warm layer and adiabatic comfort liner to realize reasonably decomposing and sharing to the high temperature heat-flash stream in the scene of a fire;
3, flameproof fabric is frivolous, flexible material, and processing is simple, can be used for the scene of a fire, battlefield etc. and to speedily carry out rescue work the clothes of life-saving environmental, also can be used for Aero-Space protective materials.
Accompanying drawing explanation
Fig. 1 is the layer structure schematic diagram of the laminated flameproof fabric of three composite beds of function sharing.
In figure:
1-reflective insulation layer, towards open flame source, comprising 11-metal forming, 12-strengthens base fabric;
2-heat dissipation limits warm layer, and it comprises 21-non-woven felt, 22-phase transformation powder, 23-leakproof base fabric;
The adiabatic comfort liner of 3-, it comprises 31-composite aluminium film, 32-air buffer, the comfortable base fabric of 33-.
Detailed description of the invention
For making the present invention become apparent, hereby with preferred embodiment, and accompanying drawing is coordinated to be described in detail below.Should be understood that these embodiments are only not used in for illustration of the present invention to limit the scope of the invention.In addition should be understood that those skilled in the art can make various changes or modifications the present invention, and these equivalent form of values fall within the application's appended claims limited range equally after the content of having read the present invention's instruction.
As shown in Figure 1, the invention provides the flameproof fabric that a kind of three composite beds of function sharing are laminated, its ecto-entad is made up of following functional structure layer successively: play the reflective insulation layer 1 of radiant heat high reverse--bias and air-flow insulating effect, play the limitting warm layer 2 containing the heat dissipation of phase-change material and play the adiabatic comfort liner 3 of thermal isolation and comfortable effect of heat absorption transduction.The natural thickness of this flameproof fabric is 5 ~ 15mm, and actual compression thickness is 3 ~ 10mm; Weight per square meter is at 450 ~ 1500g/m
2.More preferred scheme is: the weight per square meter≤250g/m of reflective insulation layer 1
2; Described heat dissipation limits the thickness≤4mm of warm layer 2, weight per square meter≤500g/m
2; Thickness≤the 2mm of described adiabatic comfort liner 3, weight per square meter≤250g/m
2.
Reflective insulation layer 1 strengthens base fabric 12 by the metal forming 11 of high reflectance and high-temperature fibre and is composited.Metal forming 11 is pure aluminum foil or the alloy foil of 5 ~ 10 μm for thickness, has excellent reflecting properties and air-flow isolation performance to the light of scene of a fire high temperature intense radiation hot-fluid environment, heat radiation.It is room temperature ~ 800 DEG C that high-temperature fibre strengthens the thermal adaptability of base fabric 12, is obtained by basalt fibre or glass fibre, for the enhancing, stable and smooth of metal forming 11.Strengthen and ensure that material is by survivable when hooking, puncture, makes whole fire-proof fabric function not lose efficacy; Stable and smooth guarantee fund belongs to the high reverse--bias efficiency of paper tinsel 11 and direct reflection function, avoids the multiple reflections of light in metal forming 11 and influx and translocation heat energy burden phenomenon occurs.
Heat dissipation is limit warm layer 2 by high temperature resistant non-woven felt 21, is formed at 200 ~ 400 DEG C of solid-liquid phase change materials undergone phase transition 22 and leakproof base fabric 23 Compound Machining.High temperature resistant non-woven felt 21 is made up of high-temperature fibre, and contain a large amount of small holes on the surface of high-temperature fibre and inside, the attachment for solid-liquid phase change material 22 is fixed.High-temperature fibre is glass fibre or aramid fiber etc.Solid-liquid phase change material 22 is for the absorption and the dissipation that conduct to fabric heat.Leakproof base fabric 23 is for preventing the leakage of phase transformation powder in processing and use and the second humidification layer of flameproof fabric, with the existence of the heat dissipation function of ensureing to absorb heat and the anti-puncture of flameproof fabric, the destruction of hooking, be unlikely to damage inactivation in the complex environment of speedily carrying out rescue work in the scene of a fire to make flameproof fabric and jeopardize the safety of rescuer.
Adiabatic comfort liner 3 is by composite aluminium film 31, air buffer 32 and comfortable base fabric 33 ecto-entad is laminated successively forms.Composite aluminium film 31 is by smooth surface high-polymer membrane, aluminium coated and rough surface high-polymer membrane three layers of composite membrane be composited, and refers to patent heat insulating compound film (patent No. CN200510024710.9); Air buffer 32 is support through netting to be formed, and ensureing that air layer does not disappear because bending and compress, affecting effect of heat insulation, referring to patent heat insulation soft thin composite fabric (patent No. CN200410066650.2); Comfortable base fabric 33 is retardant cotton or flame-resistant terylene cloth, can moisture absorption and low heat conductivity well, again can be heat-resisting and do not fire, to keep the comfortable and safety of wearing.
Present invention also offers the preparation technology of the laminated flameproof fabric of a kind of above-mentioned three composite beds, the steps include: first through high-temperature agglomerant bonding or sew up mode forms reflective insulation layer 1, heat dissipation limits warm layer 2 and adiabatic comfort liner 3, then reflective insulation layer 1, heat dissipation limit warm layer 2 and adiabatic comfort liner 3 to be bondd by high-temperature agglomerant or the mode composite laminated sewed up is shaped.
Embodiment one
Adopt the flameproof fabric that three composite beds of function sharing of the present invention are laminated.Wherein reflective insulation layer adopts the metal aluminum foil of 6 μm (weight per square meter is 15.7g/m
2) and basalt fibre strengthens base fabric, and (thickness is 0.26mm, and weight per square meter is 212.8g/m
2) be composited through adhesive; Heat dissipation limits the natural thickness of warm layer to be 2.32mm, and weight per square meter is 318.2g/m
2; Adiabatic comfort liner nature thickness is 0.59mm, and weight per square meter is 194.6g/m
2.The compression thickness of final obtained flameproof fabric is 2.76mm, and weight per square meter is 821.5g/m
2, under the naked light high temperature heat-flash stream environment of 1000 DEG C, continue 8min outside it, can keep inner side temperature below 45 DEG C.
Embodiment two
Adopt the flameproof fabric that three composite beds of function sharing of the present invention are laminated.Wherein reflective insulation layer adopts the metal aluminum foil of 9 μm (weight per square meter is 20.4g/m
2) and glass fiber reinforcement base fabric (thickness is 0.23mm, and weight per square meter is 196.9g/m
2) be composited through adhesive; Heat dissipation limits the natural thickness of warm layer to be 2.51mm, and weight per square meter is 325.1g/m
2; Adiabatic comfort liner nature thickness is 0.52mm, and weight per square meter is 188.3g/m
2.The compression thickness of final obtained flameproof fabric is 2.84mm, and weight per square meter is 803.6g/m
2, under the naked light high temperature heat-flash stream environment of 800 DEG C, continue 10min outside it, can keep inner side temperature below 50 DEG C.
Claims (7)
1. the flameproof fabric that three composite beds of function sharing are laminated, is characterized in that: ecto-entad is made up of following functional structure layer successively: play the reflective insulation layer (1) of radiant heat high reverse--bias and air-flow insulating effect, play the limitting warm layer (2) containing the heat dissipation of phase-change material and play the adiabatic comfort liner (3) of thermal isolation and comfortable effect of heat absorption transduction; Described reflective insulation layer (1) strengthens base fabric (12) by the metal forming (11) of high reflectance and high-temperature fibre and is composited; Described heat dissipation is limit warm layer (2) by high temperature resistant non-woven felt (21), is formed 200 ~ 400 DEG C of solid-liquid phase change materials undergone phase transition (22) and leakproof base fabric (23) Compound Machining; Described adiabatic comfort liner (3) is by composite aluminium film (31), air buffer (32) and comfortable base fabric (33) ecto-entad is laminated successively forms.
2. the flameproof fabric that three composite beds of a kind of function sharing as claimed in claim 1 are laminated, is characterized in that: described metal forming (11) for thickness be pure aluminum foil or the alloy foil of 5 ~ 10 μm; Described high-temperature fibre strengthens base fabric (12) and is obtained by basalt fibre or glass fibre, for the enhancing, stable and smooth of described metal forming (11); Described high temperature resistant non-woven felt (21) is made up of high-temperature fibre, and the attachment for described solid-liquid phase change material (22) is fixed; Described solid-liquid phase change material (22) is for the absorption and the dissipation that conduct to fabric heat; Described leakproof base fabric (23) is for preventing the leakage of phase transformation powder in processing and use and the second humidification layer of flameproof fabric; Described composite aluminium film (31) is by smooth surface high-polymer membrane, aluminium coated and rough surface high-polymer membrane three layers of composite membrane be composited; Described air buffer (32) is support through netting to be formed; Described comfortable base fabric (33) is retardant cotton or flame-resistant terylene cloth.
3. the flameproof fabric that three composite beds of a kind of function sharing as claimed in claim 2 are laminated, is characterized in that: described high-temperature fibre is glass fibre or aramid fiber.
4. the flameproof fabric that three composite beds of a kind of function sharing as claimed in claim 1 are laminated, is characterized in that: the natural thickness of this flameproof fabric is 5 ~ 15mm, and actual compression thickness is 3 ~ 10mm; Weight per square meter is at 450 ~ 1500g/m
2.
5. the flameproof fabric that three composite beds of a kind of function sharing as claimed in claim 1 are laminated, is characterized in that: weight per square meter≤250 g/m of described reflective insulation layer (1)
2; Described heat dissipation limits the thickness≤4mm of warm layer (2), weight per square meter≤500 g/m
2; Thickness≤the 2mm of described adiabatic comfort liner (3), weight per square meter≤250 g/m
2.
6. the preparation technology of the flameproof fabric that three composite beds of a function sharing as claimed in claim 1 are laminated, it is characterized in that: first through high-temperature agglomerant bonding or sew up mode forms reflective insulation layer (1), heat dissipation limits warm layer (2) and adiabatic comfort liner (3), then mode composite laminated shaping reflective insulation layer (1), heat dissipation limit warm layer (2) and adiabatic comfort liner (3) to be bondd by high-temperature agglomerant or sew up.
7. an application for the flameproof fabric that three composite beds of function sharing as claimed in claim 1 are laminated, is characterized in that: for the physical protection that uses under high temperature intense radiation hot-fluid fire field environment condition and heat-barrier material.
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| CN201210292693.7A CN102785432B (en) | 2012-08-16 | 2012-08-16 | Function-shared three-composite-layer laminated flameproof fabric, preparation technology and application |
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| CN201210292693.7A CN102785432B (en) | 2012-08-16 | 2012-08-16 | Function-shared three-composite-layer laminated flameproof fabric, preparation technology and application |
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| CN102785432B true CN102785432B (en) | 2015-07-08 |
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| CN104191737B (en) * | 2014-09-18 | 2016-02-17 | 江苏红豆实业股份有限公司 | Based on the preparation method of the extraordinary composite material of fire-retardant basalt fibre |
| CN105342043B (en) * | 2015-11-04 | 2017-01-04 | 中原工学院 | A kind of composite material for fireman's protective clothing for proximity fire fighting and preparation method thereof |
| CA3011354A1 (en) * | 2016-01-14 | 2017-07-20 | Southern Mills, Inc. | Improved flame resistant thermal liners and garments made with same |
| CN110558646A (en) * | 2019-09-10 | 2019-12-13 | 北京科技大学 | Fireproof suit based on silicon dioxide aerogel composite material and preparation method |
| CN113147111A (en) * | 2021-05-07 | 2021-07-23 | 太仓高腾复合材料有限公司 | Sterilizing and antibacterial composite material and preparation method thereof |
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| US6004662A (en) * | 1992-07-14 | 1999-12-21 | Buckley; Theresa M. | Flexible composite material with phase change thermal storage |
| CN1586884A (en) * | 2004-09-24 | 2005-03-02 | 东华大学 | Heat insulation soft thin composite fabric, preparing method and its use |
| CN102337673A (en) * | 2010-07-22 | 2012-02-01 | 中原工学院 | Preparation method of fire resistant phase transition thermal insulation layered fabric for firefighter clothing |
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| US6004662A (en) * | 1992-07-14 | 1999-12-21 | Buckley; Theresa M. | Flexible composite material with phase change thermal storage |
| CN1586884A (en) * | 2004-09-24 | 2005-03-02 | 东华大学 | Heat insulation soft thin composite fabric, preparing method and its use |
| CN102337673A (en) * | 2010-07-22 | 2012-02-01 | 中原工学院 | Preparation method of fire resistant phase transition thermal insulation layered fabric for firefighter clothing |
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| 柔性防火绝热材料及结构的研究进展;郝立才、于伟东;《产业用纺织品》;20090228(第2期);第5页左栏第3部分结语,第3页右栏1-11行 * |
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