A kind of automobile is with brake bush and preparation method thereof
Technical field
The invention belongs to automotive friction material technology field, be specifically related to a kind of automobile with brake bush and preparation method thereof.
Background technique
The automotive brake friction facing is the critical product of vehicle safety travel.Brake gland for vehicle adopts the semimetal material both at home and abroad, is characteristic to add Steel Fibre.Steel Fibre heat conduction certain intensity and wear resistance are arranged, but density is big, is prone to get rusty, and matter is hard, and the easy damaged antithesis is prone to produce brake noise.Domestic automobile with the material of brake strip because the problem of prescription is wear-resisting inadequately.
Summary of the invention
The object of the invention is exactly in order to remedy the defective of existing technology, to provide a kind of automobile with brake bush and preparation method thereof, and said brake bush has stable frictional behaviour and restorability.The brake drum temperature is lower, has greatly improved the durable working life of brake lining.
The present invention realizes through following technological scheme:
A kind of automobile is used brake bush, comprises following raw materials by weight percent:
The Bond of 10-20%; The reinforcing fiber of 20-40%; 10-20% increases the agent that rubs; The oiling agent of 10-20% and the filler of 20-40%.
Described Bond comprises phenolic resin.
Described reinforcing fiber is two or more the combination in compound mineral fiber, ceramic fiber, glass fibre, organic fiber and the Steel Fibre.Compound mineral fiber is to plant mineral in 1200 degree--the high temperature melting of 1800 degree by aluminium oxide, silica etc., and again through technological means, blowing at last forms, by those skilled in the art are familiar with.
Said reinforcing fiber is the composition of compound mineral fiber, ceramic fiber, glass fibre, organic fiber and Steel Fibre.
The weight portion ratio of said compound mineral fiber, ceramic fiber, glass fibre, organic fiber and Steel Fibre is 20: 6: 6: 5: 3.
Described to increase the agent that rubs be alumina powder with the friction powder in one or both combination.
Said to increase the agent that rubs be alumina powder and the composition of friction powder, and alumina powder is 1: 2 with the weight portion ratio of friction powder.
Said oiling agent is one or more the combination in graphite, calcined petroleum coke and the carbon black.
Said oiling agent is the composition of graphite, calcined petroleum coke and carbon black.
The weight ratio of said graphite, calcined petroleum coke and carbon black is 3: 2: 1.
Said filler is one or more the combination in nitrile rubber, tyre talc, barium sulphate and the expanded vermiculite.
Said filler is the composition of nitrile rubber, tyre talc, barium sulphate and expanded vermiculite.
The weight ratio of said nitrile rubber, tyre talc, barium sulphate and expanded vermiculite is 5: 5: 18: 3.
The present invention also provides the preparation method of a kind of automobile with brake bush, comprises the steps:
1) mixes according to take by weighing each raw material components to certainty ratio, mixture is placed on stirring and evenly mixing in the high speed mixer;
2) material with mixing places mould to heat compression moulding, and heating-up temperature 140-180 ℃, pressing pressure is 18-24MPa;
3) friction facing after the moulding is incubated 16~20 hours down at 140-180 ℃;
4) will be incubated that milling that the friction facing of typing carries out outer arced surface, intrados and end face is cut and finished product is processed in boring.(this step is meant that the milling of carrying out outer arced surface, intrados and end face earlier cuts, and then carries out the boring processing of friction facing)
The said time that adds hot pressing is 120-180S.
Preferred heating-up temperature is 160 ℃ during said heating compression moulding, and pressing pressure is 20MPa.
Employed releasing agent is a zine stearate in the said heating compression moulding.
Said raw material has been crushed to the setting granularity before mixing.
Friction facing after the said moulding is removed burr earlier before insulation.
Friction facing after the said moulding is incubated processing in baking oven.
Technological scheme of the present invention is with reference to increasing the various measures and the viewpoint of friction facing wear resistance: the compound viewpoint of out-phase, and the composite lubricated viewpoint of multistage, the friction resistance material production technology adopts dry technology for production.
Advantage of the present invention is:
The formula for raw stock of friction facing has guaranteed that friction facing has stable frictional behaviour and restorability, and production technology is simple, is convenient to operation.And, obtained the molding temperature and the molding pressure of optimum range through test of many times, guaranteed the successful property of die press technology for forming.
Description of drawings
Fig. 1 is a brake bush preparation process flow chart of the present invention;
Embodiment
Below in conjunction with accompanying drawing automobile of the present invention is set forth with brake bush in detail:
Embodiment 1
Automobile is with brake bush embodiment scheme, and its preparation method is as shown in Figure 1:
1) taking by weighing raw material prepares burden in proportion: 20% Bond; 20% reinforcing fiber; 10% increase the agent that rubs; 20% oiling agent and 30% filler, wherein, Bond comprises phenolic resin; Reinforcing fiber is the composition of compound mineral fiber, glass fibre and Steel Fibre; Increasing the agent that rubs is alumina powder or friction powder, and oiling agent is calcined petroleum coke and carbon black, and filler is barium sulphate and expanded vermiculite; All raw materials have been pulverized to setting granularity.
2) compression molding: all above-mentioned raw materials are placed on hot briquetting in the mould that mixing in the high speed mixer is placed on regulation, 140 ℃ of heating-up temperatures, pressing pressure is 24MPa, adds hot pressing 120S;
3) heat treatment: the friction facing after the moulding is removed burr be placed in the baking oven under 140 ℃ temperature baking 20 hours;
4) machining: friction facing after the heat treatment is carried out the processing that the milling of outer arced surface, intrados and end face is cut and holed;
5) Checking of finished products: at last with the friction facing test package after the processing.
Graphite is crystalline flake graphite.
The granularity of graphite and calcined petroleum coke powdered carbon is the 40-80 order;
The effect of said each material of instance is following:
The effect of reinforcing fiber: the polishing machine of having improved friction resistance material.
In the hot compression molding step, those skilled in the art will know that this step need carry out the demoulding, releasing agent is very important, and releasing agent adopts zine stearate: its granularity>=100 orders, fusing point≤120 ℃; Component content is about 80%; Stearic acid release agent zinc mainly is used as the oiling agent and the releasing agent of phenolic resin.Zine stearate mainly increases the lubricity behind the resin solidification, and makes it be easy to the demoulding;
Bond is that (weight ratio of phenolic resin and antimony sulphide can be 4: 1-6: 1), phenolic resin is for the resin material that solidifies through chemical reaction, like thermoset phenolic resin for the composition of phenolic resin or phenolic resin and antimony sulphide.
Embodiment 2
The preparation method is as shown in Figure 1:
1) taking by weighing raw material prepares burden in proportion: 10% Bond; 40% reinforcing fiber; 20% increase the agent that rubs; 10% oiling agent and 20% filler, wherein, Bond comprises phenolic resin; Reinforcing fiber is the composition of compound mineral fiber and glass fibre; Increasing the agent that rubs is alumina powder or friction powder, and oiling agent is graphite and calcined petroleum coke, and filler is nitrile rubber, tyre talc and barium sulphate; All raw materials have been pulverized to setting granularity.
2) compression molding: all above-mentioned raw materials are placed on hot briquetting in the mould that mixing in the high speed mixer is placed on regulation, 180 ℃ of heating-up temperatures, pressing pressure is 18MPa, adds hot pressing 180S;
3) heat treatment: the friction facing after the moulding is removed burr be placed in the baking oven under 180 ℃ temperature baking 16 hours;
4) machining: friction facing after the heat treatment is carried out the processing that the milling of outer arced surface, intrados and end face is cut and holed;
5) Checking of finished products: at last with the friction facing test package after the processing.
Embodiment 3
The preparation method is as shown in Figure 1:
1) taking by weighing raw material prepares burden in proportion: 13% Bond; 31% reinforcing fiber; 12% increase the agent that rubs; 13% oiling agent and 31% filler, wherein, Bond comprises phenolic resin; Reinforcing fiber is compound mineral fiber, ceramic fiber, glass fibre, organic fiber and Steel Fibre; Their weight portion ratio is 20: 6: 6: 5: 3, increasing the agent that rubs was the composition of alumina powder and friction powder, and alumina powder is 1: 2 with the weight ratio of friction powder; Oiling agent is the composition of graphite, calcined petroleum coke and carbon black, and the weight ratio of graphite, calcined petroleum coke and carbon black is 3: 2: 1; Filler is the composition of nitrile rubber, tyre talc, barium sulphate and expanded vermiculite, and the weight ratio of nitrile rubber, tyre talc, barium sulphate and expanded vermiculite is 5: 5: 18: 3.All raw materials have been pulverized to setting granularity.
2) compression molding: all above-mentioned raw materials are placed on hot briquetting in the mould that mixing in the high speed mixer is placed on regulation, 160 ℃ of heating-up temperatures, pressing pressure is 20MPa, adds hot pressing 160S;
3) heat treatment: the friction facing after the moulding is removed burr be placed in the baking oven under 160 ℃ temperature baking 18 hours;
4) machining: friction facing after the heat treatment is carried out the processing that the milling of outer arced surface, intrados and end face is cut and holed;
5) Checking of finished products: at last with the friction facing test package after the processing.
Graphite is crystalline flake graphite.
The granularity of graphite and calcined petroleum coke powdered carbon is the 40-80 order.
The effect of reinforcing fiber: the polishing machine of having improved friction resistance material.
In the hot compression molding step, those skilled in the art will know that this step need carry out the demoulding, releasing agent is very important, and releasing agent adopts zine stearate: its granularity>=100 orders, fusing point≤120 ℃; Component content is about 80%; Stearic acid release agent zinc mainly is used as the oiling agent and the releasing agent of phenolic resin.Zine stearate mainly increases the lubricity behind the resin solidification, and makes it be easy to the demoulding;
Bond is the composition of phenolic resin or phenolic resin and antimony sulphide, and phenolic resin is for the resin material that solidifies through chemical reaction, like thermoset phenolic resin.
The automobile of present embodiment is used brake bush, and its friction factor>=0.38 heats up 0.41; Cooling 0.42; Wear rate is time≤0.15 (10 in 300 ℃
-7Cm
3/ N.m); Weight per volume wearing and tearing≤5%.