CN102757745B - Esterified-starch-modified waxy corn wet glue and preparation method thereof - Google Patents
Esterified-starch-modified waxy corn wet glue and preparation method thereof Download PDFInfo
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- CN102757745B CN102757745B CN201210150194.4A CN201210150194A CN102757745B CN 102757745 B CN102757745 B CN 102757745B CN 201210150194 A CN201210150194 A CN 201210150194A CN 102757745 B CN102757745 B CN 102757745B
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- starch
- esterification starch
- wet glue
- glutinous rice
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- 239000003292 glue Substances 0.000 title claims abstract description 73
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 240000008042 Zea mays Species 0.000 title abstract 7
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 title abstract 7
- 235000002017 Zea mays subsp mays Nutrition 0.000 title abstract 7
- 235000005822 corn Nutrition 0.000 title abstract 7
- 229920002472 Starch Polymers 0.000 claims abstract description 76
- 235000019698 starch Nutrition 0.000 claims abstract description 75
- 239000008107 starch Substances 0.000 claims abstract description 69
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 47
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004202 carbamide Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims abstract description 12
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 12
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 12
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920002261 Corn starch Polymers 0.000 claims abstract description 10
- 239000008120 corn starch Substances 0.000 claims abstract description 10
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 230000032050 esterification Effects 0.000 claims description 61
- 238000005886 esterification reaction Methods 0.000 claims description 61
- 230000004048 modification Effects 0.000 claims description 45
- 238000012986 modification Methods 0.000 claims description 45
- 241000209094 Oryza Species 0.000 claims description 41
- 235000007164 Oryza sativa Nutrition 0.000 claims description 41
- 235000009566 rice Nutrition 0.000 claims description 41
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 23
- 239000013530 defoamer Substances 0.000 claims description 19
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 14
- 229920002554 vinyl polymer Polymers 0.000 claims description 14
- 235000011128 aluminium sulphate Nutrition 0.000 claims description 13
- 229910052742 iron Inorganic materials 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 13
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims description 11
- 238000010792 warming Methods 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000012856 packing Methods 0.000 claims description 7
- 230000001954 sterilising effect Effects 0.000 claims description 7
- -1 2 parts Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 239000003643 water by type Substances 0.000 claims description 5
- 240000003183 Manihot esculenta Species 0.000 claims description 3
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 3
- 241000209140 Triticum Species 0.000 claims description 3
- 235000021307 Triticum Nutrition 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 3
- 239000002994 raw material Substances 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 5
- 241000196324 Embryophyta Species 0.000 abstract description 2
- 238000005034 decoration Methods 0.000 abstract description 2
- 208000003643 Callosities Diseases 0.000 abstract 1
- 206010020649 Hyperkeratosis Diseases 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 238000010668 complexation reaction Methods 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 239000004816 latex Substances 0.000 abstract 1
- 229920000126 latex Polymers 0.000 abstract 1
- 239000001254 oxidized starch Substances 0.000 abstract 1
- 235000013808 oxidized starch Nutrition 0.000 abstract 1
- 239000000047 product Substances 0.000 description 34
- 239000000084 colloidal system Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 8
- 229920000881 Modified starch Polymers 0.000 description 6
- 239000004368 Modified starch Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 235000019426 modified starch Nutrition 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
- 238000007710 freezing Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000008014 freezing Effects 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 150000003926 acrylamides Chemical class 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 230000008676 import Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229940100445 wheat starch Drugs 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 241001529246 Platymiscium Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
Starting material | Formula A | Formula B |
Deionized water | 760 | 760 |
Modification waxy corn starch | 160 | 50 |
Esterification starch A | / | 60 |
Esterification starch B | / | 35 |
Sumstar 190 | / | 50 |
White dextrin | 20 | / |
Acrylamide | / | 5 |
Urea | 20 | 20 |
Polyoxyethylene glycol | 8 | / |
Non-iron aluminium sulfate | 1.5 | 1 |
Sodium Benzoate | 4 | 4 |
Defoamer | 1 | 1 |
Ethylene glycol | 12 | 12 |
Glycerol | 20 | / |
Sterilant | 4 | 3 |
White glue with vinyl | 30 | 20 |
Appraisal unit/T | 2010 | 1670 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210150194.4A CN102757745B (en) | 2012-05-16 | 2012-05-16 | Esterified-starch-modified waxy corn wet glue and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210150194.4A CN102757745B (en) | 2012-05-16 | 2012-05-16 | Esterified-starch-modified waxy corn wet glue and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102757745A CN102757745A (en) | 2012-10-31 |
CN102757745B true CN102757745B (en) | 2014-03-05 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201210150194.4A Active CN102757745B (en) | 2012-05-16 | 2012-05-16 | Esterified-starch-modified waxy corn wet glue and preparation method thereof |
Country Status (1)
Country | Link |
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CN (1) | CN102757745B (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103614099B (en) * | 2013-10-28 | 2017-02-08 | 杭州美嘉保新材料科技有限公司 | Freeze-thaw resistant starch glue and preparation method thereof |
CN104004469A (en) * | 2014-02-28 | 2014-08-27 | 邱顺建 | Preparation method for glutinous rice glue |
CN104559829A (en) * | 2014-11-21 | 2015-04-29 | 桐乡嘉力丰实业股份有限公司 | Sticky rice wet glue added with emulsion stabilizer and preparation method thereof |
CN105838283B (en) * | 2016-03-03 | 2019-02-12 | 嘉力丰科技股份有限公司 | A kind of wallpaper with can high temperature packing glutinous rice glue and preparation method |
CN106349971A (en) * | 2016-08-26 | 2017-01-25 | 桐乡嘉力丰实业股份有限公司 | Natural environment-friendly mildew-proof and damp-proof glutinous rice glue and preparation process thereof |
CN106366975A (en) * | 2016-08-26 | 2017-02-01 | 桐乡嘉力丰实业股份有限公司 | High-viscosity mould-proof glutinous rice glue and preparation process thereof |
CN106281109A (en) * | 2016-08-26 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | A kind of high stability mildew-resistant environmental protection Oryza glutinosa glue and preparation technology thereof |
CN106349970A (en) * | 2016-08-26 | 2017-01-25 | 桐乡嘉力丰实业股份有限公司 | High-viscosity mildew-proof wallpaper wet glue and preparation process thereof |
CN106398584A (en) * | 2016-08-31 | 2017-02-15 | 桐乡嘉力丰实业股份有限公司 | Rose aroma type glutinous-rice wet adhesive and preparation method thereof |
CN106381090A (en) * | 2016-08-31 | 2017-02-08 | 桐乡嘉力丰实业股份有限公司 | Mildew-resistant and environment-friendly glutinous rice wet glue and production method thereof |
CN106995642A (en) * | 2017-05-22 | 2017-08-01 | 安徽三义和能源科技有限公司 | A kind of environmental protection aging resistant coating |
CN106957596A (en) * | 2017-05-22 | 2017-07-18 | 安徽三义和能源科技有限公司 | A kind of furniture Environmental Protective Water-paint |
CN107629725A (en) * | 2017-09-26 | 2018-01-26 | 芜湖县双宝建材有限公司 | A kind of Glutinous rice wet glue of high bond strength |
CN107903842A (en) * | 2017-12-07 | 2018-04-13 | 山东梦想与家智能科技有限公司 | A kind of wallpaper glue and preparation method thereof |
CN108276724A (en) * | 2018-03-02 | 2018-07-13 | 广州禾工材料科技有限公司 | A kind of thickening master batch and preparation method thereof for protective film |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN100519926C (en) * | 2006-12-12 | 2009-07-29 | 天津工业大学 | Ice printing adhesive cement and ice printing fabric production method |
CN102140768B (en) * | 2010-12-20 | 2012-04-18 | 杭州杭化播磨造纸化学品有限公司 | Novel cationic surface sizing agent and preparation method thereof |
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PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: TONGXIANG JIALIFENG INDUSTRY CO., LTD. Free format text: FORMER OWNER: HANGZHOU JIALIFENG CHEMICAL CO., LTD. Effective date: 20140107 |
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C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 310019 HANGZHOU, ZHEJIANG PROVINCE TO: 314500 JIAXING, ZHEJIANG PROVINCE |
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TA01 | Transfer of patent application right |
Effective date of registration: 20140107 Address after: 314500 Tongxiang West Road, Zhejiang, No. 106 Applicant after: TONGXIANG GAREFU INDUSTRIAL Co.,Ltd. Address before: Jianggan District Jiubao town nine Chang Road Hangzhou City, Zhejiang province 310019 No. 55 Applicant before: HANGZHOU GAREFU GROUP Co.,Ltd. |
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GR01 | Patent grant | ||
GR01 | Patent grant | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Wu Tongming Inventor before: Zhou Chunsheng Inventor before: Zhang Zhihui |
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CP03 | Change of name, title or address | ||
CP03 | Change of name, title or address |
Address after: 314500 Tongxiang Economic Development Zone, Zhejiang City, West Ring Road, No. 106, No. Patentee after: GAREFU TECHNOLOGY CO.,LTD. Address before: 314500 Tongxiang West Road, Zhejiang, No. 106 Patentee before: TONGXIANG GAREFU INDUSTRIAL Co.,Ltd. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A Kind of Esterified Starch Modified Glutinous Rice Wet Adhesive and Its Preparation Method Effective date of registration: 20230802 Granted publication date: 20140305 Pledgee: Bank of Hangzhou Limited by Share Ltd. Tongxiang branch Pledgor: GAREFU TECHNOLOGY CO.,LTD. Registration number: Y2023330001608 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20140305 Pledgee: Bank of Hangzhou Limited by Share Ltd. Tongxiang branch Pledgor: GAREFU TECHNOLOGY CO.,LTD. Registration number: Y2023330001608 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right |