CN102559112A - Thermoplastic elastomer styrene-butadiene-styrene (SBS) adhesive and preparation method thereof - Google Patents
Thermoplastic elastomer styrene-butadiene-styrene (SBS) adhesive and preparation method thereof Download PDFInfo
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- CN102559112A CN102559112A CN2011104459925A CN201110445992A CN102559112A CN 102559112 A CN102559112 A CN 102559112A CN 2011104459925 A CN2011104459925 A CN 2011104459925A CN 201110445992 A CN201110445992 A CN 201110445992A CN 102559112 A CN102559112 A CN 102559112A
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Abstract
The invention relates to a thermoplastic elastomer styrene-butadiene-styrene (SBS) adhesive and a preparation method thereof. The adhesive consists of the following components in part by weight: 23 parts of SBS, 5 to 50 parts of tackifying resin, 0 to 5 parts of plasticizer, 0 to 5 parts of stabilizing agent, 0 to 5 parts of ultraviolet absorber, 0 to 30 parts of filler and 30 to 100 parts of solvent. The preparation method comprises the following steps of: adding the SBS, the tackifying resin, the stabilizing agent and the ultraviolet absorber into a mixture of the organic solvent and the plasticizer sequentially and slowly, and stirring for 2 to 4 hours; and adding the filler, stirring at a constant speed for 2 to 4 hours, and vacuumizing for 10 to 30 minutes with stirring. The thermoplastic elastomer SBS adhesive can be in cold adhesion to the surfaces of pipes, plates, films made from polyolefins, which is not treated directly and has high adhesion strength.
Description
Technical field
The present invention relates to a kind of sizing agent, specifically, relate to a kind of thermoplastic elastomer SBS's sizing agent and preparation method thereof.
Background technology
Polyolefine is one of principal item of macromolecular material, is a kind of engineering plastics commonly used, has HS, characteristics such as corrosion-resistant, in light weight, is widely used in all trades and professions; The research of relevant polyolefins material gluing is the problem of being paid close attention to both at home and abroad always, because polyolefine (Vilaterm, Vestolen PP 7052) material molecule symmetrical configuration does not contain reactive group; Percent crystallinity is high, surface energy low (being lower than 50dyn/cm), and the surface is difficult for wetting; SP is big with the SP difference of general tackiness agent simultaneously, is difficult to any phase mutual diffusion between the interface, and this just is difficult to produce closely adhere to; Therefore, be considered to one of difficult jointing material, for example Vestolen PP 7052; Under the surface treatment situation, be difficult to by general wetting, the gluing of sizing agent, EVA (Injecatable EVA Copolymer) system hot melt adhesive; The kind that has can not handled polyolefin surfaces and carry out gluing, but needs special-purpose automatic double surface gluer, uses inconvenience.
The many gluing problems that run in industrial production, practical applications, the daily life need be without surface treatment, and are easy to use, cheaply the gluing mode.
Summary of the invention
The purpose of this invention is to provide a kind of thermoplastic elastomer SBS's sizing agent; Low to solve existing polyolefins material bonding action; Gluing process complicated problems; Sizing agent of the present invention is to the not treated direct cold gluing of tubing, sheet material, the film surface of polyolefins, and has higher bonding action.
For realizing the object of the invention, technical scheme of the present invention is:
A kind of thermoplastic elastomer SBS's sizing agent, form by the component of following weight part content:
23 parts of SBS,
Increase 5～50 parts of glutinous resins,
0～5 part in softening agent,
0～5 part of stablizer,
0～5 part of UV light absorber,
0～30 part of filler,
30～100 parts of solvents.
In a preferred embodiment of the present invention, said sizing agent is made up of the component of following weight part content:
23 parts of SBS,
Increase 23 parts of glutinous resins,
1.2 parts in softening agent,
0.3 part of stablizer,
0.2 part of UV light absorber,
3.3 parts of fillers,
49 parts of solvents.
In a preferred embodiment of the present invention, the SBS of said sizing agent is one or both mixing in line style or the hub-and-spoke configuration.
In a preferred embodiment of the present invention, said to increase glutinous resin be one or more the mixture in rosin, modified rosin resin, coumarone indene resin, terpine resin, terpene phenolic resin, tertiary butyl phenol resin, tertiary butyl phenol formaldehyde resin, coumarone indene resin, styron, the petroleum resin.
In a preferred embodiment of the present invention, said softening agent is 2,2,4-trimethylammonium-1, the mixture of one or more in 3-pentanediol diisobutyrate, the phthalate.
In a preferred embodiment of the present invention, said stablizer is an oil product oxidation inhibitor, for example 2, and 6-di-tert-butyl-4-methylphenol (BHT); Or Hinered phenols antioxidant, for example four [β-(3 ', 5 '-di-t-butyl-4 '-hydroxy phenyl) propionic acid] pentaerythritol ester (antioxidant 1010); Or phosphite ester kind antioxidant, for example tricresyl phosphite (2, the 4-di-tert-butyl-phenyl) esters (oxidation inhibitor 168); Or the composite antioxidant of forming by Hinered phenols antioxidant and phosphite ester kind antioxidant; Or thioesters kind antioxidant, for example Tyox B (DLTP); Or the mixture of above-mentioned several kinds of stablizers.
In a preferred embodiment of the present invention, said UV light absorber is salicylate class UV light absorber, for example salicylic acid phenyl ester; Or benzophenone class UV light absorber, for example 2-hydroxyl-4-methoxy benzophenone (UV-9), benzotriazole category for example 2-(2 '-hydroxyl-5 '-aminomethyl phenyl) benzotriazole; Or the triazines UV light absorber, for example 2,4,6-three (2 ' n-butoxy phenyl)-1,3,5-triazines; Or hindered amines UV light absorber, for example HMPA; Or the mixture of above-mentioned several kinds of UV light absorbers.
In a preferred embodiment of the present invention, said filler is one or more the mixture in lime carbonate, silicon powder, kaolin, permanent white, zeyssatite and the silicon-dioxide.
In a more preferred embodiment of the present invention, said lime carbonate is nano-calcium carbonate, light calcium carbonate or water-ground limestone.
In a preferred embodiment of the present invention, said solvent is toluene, YLENE, chlorobenzene, gasoline, solvent oil, raffinate oil, one or more the mixture in the normal hexane, hexanaphthene, isohexane, normal heptane, vinyl acetic monomer, N-BUTYL ACETATE, isoamyl acetate, methylene dichloride, ethylene dichloride, zellon, tetrachloroethane, tetracol phenixin, butanone, pimelinketone, methylcarbonate, ritalin.
The preparation method of thermoplastic elastomer SBS's sizing agent of the present invention is:
Under 20 ℃-40 ℃, in the mixture of SBS, solvent, after adding increases glutinous resin at a slow speed, get thermoplastic elastomer SBS's sizing agent behind stirring 2h～4h.
In preparation method of the present invention, can also, adding add stablizer again after increasing glutinous resin, get thermoplastic elastomer SBS's sizing agent behind stirring 2h～4h.
In preparation method of the present invention, can also after adding stablizer, add UV light absorber again, get thermoplastic elastomer SBS's sizing agent behind stirring 2h～4h.
In preparation method of the present invention, the thermoplastic elastomer SBS's sizing agent adding filler at gained stirs 2h～4h again under constant speed, under stirring state, vacuumize 10min～30min.
The advantage of thermoplastic elastomer SBS's sizing agent of the present invention is:
This sizing agent the adhesive material surface without the special processing condition under; Available cold gluing method is carried out gluing to it; The gluing method is simple, and is easy to use, and this sizing agent can be used for having the industrial polythene material of the more difficult gluing of ratio Vestolen PP 7052 of weak interface layer to carry out the HS gluing.
This sizing agent do as one likes matter, the multiple superpolymer composition that structure is different, multiple increasing sticks resin and multiple solvent composition, can be used for the non-structure gluing of most materials such as plastics, rubber, fiber, timber, pottery, glass and metal.
Embodiment
Further specify the present invention through embodiment below, but content of the present invention is not limited to this fully.
Embodiment 1:
Composition of raw materials:
SBS((S/B＝4/6)) 23g，
Ester gum 23g,
Coumarone indene resin 23g,
Witcizer 300 (DBP) 2g,
DBPC 2,6 ditertiary butyl p cresol (264) is 1.2g (BHT),
UV light absorber UV-9 0.5g,
Silicon-dioxide 5g,
Gasoline 16g,
Vinyl acetic monomer 16g,
Toluene 17g.
The preparation method:
(1) in having the 1000ml there-necked flask of whisking appliance, condensing surface; By above weight, add DBP, solvent oil, vinyl acetic monomer and toluene, stirring state adds SBS (S/B=4/6) down; After room temperature or heating in water bath dissolve SBS fully; After adding ester gum, coumarone indene resin, BHT and UV light absorber UV-9, under 20 ℃～40 ℃, stir 2h～4h;
(2) in the solution of step (1), add silicon-dioxide 5g, under constant speed, stir 2h-4h again, vacuumize 10min-30min under the stirring state, close stirrer earlier and close vacuum again.
The thermoplastic elastomer SBS's sizing agent that present embodiment is prepared gained is used for the following material of gluing (the decontamination drying treatment is only carried out on the surface); According to " HG2-151-65 plastic bonding material shear strength test method " standard, the bonding action (23 ℃) of measuring the gluing thing is as shown in table 1:
Table 1
Other sizing agent slip resistance that is used for the polypropylene board gluing common on the market is up to 100N/2.5cm * 1.5cm; Can draw by the data in the table 1; The slip resistance of sizing agent of the present invention is up to 150N/2.5cm * 1.5cm, and visible sizing agent of the present invention is respond well to the gluing of polyolefine material.
Embodiment 2
Composition of raw materials:
SBS(S/B＝4/6) 23g，
Ester gum 18.4g,
Coumarone indene resin 18.4g,
Silicon-dioxide 2.3g,
Gasoline 16g,
Vinyl acetic monomer 16g,
Toluene 17g.
The preparation method:
(1) in the device identical with embodiment 1, add solvent oil, vinyl acetic monomer and toluene, stirring state adds SBS (S/B=4/6) down; After room temperature or heating in water bath dissolve SBS fully, add ester gum, coumarone indene resin; Under 20 ℃-40 ℃, stir 2h-4h;
(2) in the solution of step (1), add silicon-dioxide 5g, under constant speed, stir 2h-4h again, vacuumize 10min-30min under the stirring state, close stirrer earlier and close vacuum again.
The thermoplastic elastomer SBS's sizing agent that present embodiment is prepared gained is used for the following material of gluing (the decontamination drying treatment is only carried out on the surface); According to " mensuration of GB/T 532-2008 vulcanized rubber or TPR and fabric bond strength " standard, it is as shown in table 2 to measure bonding action (23 ℃) data of solidifying the gluing thing after 10 days:
Table 2
90 ° or 180 ° stripping strengths of other sizing agent that is used for the polypropylene board gluing commonly used on the market are along with gaining in strength of time reduced gradually; Gluing after 10 days strength degradation be 18N/2.5cm; Can be known that by table 2 the above four kinds of material cured of sizing agent gluing of the present invention are after 10 days, 90 ° or 180 ° of stripping strengths are minimum to be 32N/2.5cm; Be up to 55N/2.5cm, visible sizing agent of the present invention is respond well to the gluing of polyolefine material.
Embodiment 3
Composition of raw materials:
SBS (S/B=4/6:6 part; S/B=3/7:4 part) 23g,
Modified rosin resin 15g,
Petroleum resin 15g,
2,2,4-trimethylammonium-1,3-pentanediol diisobutyrate 1.2g,
Antioxidant 1010 0.3g,
UV light absorber UV-9 0.2g,
Nano-calcium carbonate 3.3g,
Solvent oil 16g,
Vinyl acetic monomer 16g,
Toluene 17g.
The preparation method:
(1) in the device identical with embodiment 1, add 2,2 by above weight, 4-trimethylammonium-1,3-pentanediol diisobutyrate, solvent oil, vinyl acetic monomer and toluene, stirring state add SBS (S/B=4/6:6 part down; S/B=3/7:4 part), after room temperature or heating in water bath dissolve SBS fully, adds modified rosin resin, petroleum resin, antioxidant 1010, UV light absorber UV-9, under 20 ℃-40 ℃, stir 2h-4h;
(2) in the solution of step (1), add silicon-dioxide 5g, under constant speed, stir 2h-4h again, vacuumize 10min-30min under the stirring state, close stirrer earlier and close vacuum again.
Claims (15)
1. thermoplastic elastomer SBS's sizing agent, form by the component of following weight part content:
23 parts of SBS,
Increase 5～50 parts of glutinous resins,
0～5 part in softening agent,
0～5 part of stablizer,
0～5 part of UV light absorber,
0～30 part of filler,
30～100 parts of solvents.
2. sizing agent according to claim 1 is characterized in that, said sizing agent is made up of the component of following weight part content:
23 parts of SBS,
Increase 23 parts of glutinous resins,
1.2 parts in softening agent,
0.3 part of stablizer,
0.2 part of UV light absorber,
3.3 parts of fillers,
49 parts of solvents.
3. according to claim 1 or 2 said sizing agents, it is characterized in that the SBS of said sizing agent is one or both mixing in line style or the hub-and-spoke configuration.
4. according to claim 1 or 2 said sizing agents; It is characterized in that said to increase glutinous resin be one or more the mixture in rosin, modified rosin resin, coumarone indene resin, terpine resin, terpene phenolic resin, tertiary butyl phenol resin, tertiary butyl phenol formaldehyde resin, coumarone indene resin, styron, the petroleum resin.
5. according to claim 1 or 2 said sizing agents, it is characterized in that said softening agent is 2,2,4-trimethylammonium-1, the mixture of one or more in 3-pentanediol diisobutyrate, the phthalate.
6. according to claim 1 or 2 said sizing agents; It is characterized in that the composite antioxidant that said stablizer is oil product oxidation inhibitor, Hinered phenols antioxidant, phosphite ester kind antioxidant, be made up of Hinered phenols antioxidant and phosphite ester kind antioxidant, one or more the mixture in the thioesters kind antioxidant.
7. according to claim 1 or 2 said sizing agents, it is characterized in that said UV light absorber is one or more the mixture in salicylate class, benzophenone class, benzotriazole category, triazines, the hindered amines.
8. according to claim 1 or 2 said sizing agents, it is characterized in that said filler is one or more the mixture in lime carbonate, silicon powder, kaolin, permanent white, zeyssatite and the silicon-dioxide.
9. said according to Claim 8 sizing agent is characterized in that said lime carbonate is nano-calcium carbonate, light calcium carbonate or water-ground limestone.
10. according to claim 1 or 2 said sizing agents; It is characterized in that said solvent is toluene, YLENE, chlorobenzene, gasoline, solvent oil, raffinate oil, one or more the mixture in the normal hexane, hexanaphthene, isohexane, normal heptane, vinyl acetic monomer, N-BUTYL ACETATE, isoamyl acetate, methylene dichloride, ethylene dichloride, zellon, tetrachloroethane, tetracol phenixin, butanone, pimelinketone, methylcarbonate, ritalin.
11. the preparation method of the described thermoplastic elastomer SBS's sizing agent of claim 1 is characterized in that, is under 20 ℃-40 ℃, in the mixture of SBS, solvent, after adding increases glutinous resin at a slow speed, gets thermoplastic elastomer SBS's sizing agent behind stirring 2h～4h.
12. preparation method as claimed in claim 11 is characterized in that, after adding increases glutinous resin, adds stablizer again, gets thermoplastic elastomer SBS's sizing agent behind stirring 2h～4h.
13. preparation method as claimed in claim 11 is characterized in that, after adding stablizer, adds UV light absorber again, gets thermoplastic elastomer SBS's sizing agent behind stirring 2h～4h.
14. preparation method as claimed in claim 11 is characterized in that, the thermoplastic elastomer SBS's sizing agent adding filler at gained stirs 2h～4h again under constant speed, under stirring state, vacuumize 10min～30min.
15. the preparation method of the described thermoplastic elastomer SBS's sizing agent of claim 2-10 is characterized in that, is made up of following steps:
Under (1) 20 ℃-40 ℃, in the mixture of SBS, organic solvent and softening agent, after adding increases glutinous resin, stablizer and UV light absorber successively, stir 2h-4h;
(2) in the mixture of step (1) gained, add filler, under constant speed, stir 2h-4h again, vacuumize 10min-30min under the stirring state.
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| CN115627152B (en) * | 2022-10-09 | 2024-05-07 | 浙江伟星实业发展股份有限公司 | Adhesive material for film-covered rainbow shellfish effect button and preparation method and application thereof |
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