CN102516845A - Plastic gravure waterborne ink - Google Patents
Plastic gravure waterborne ink Download PDFInfo
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- CN102516845A CN102516845A CN201110397532XA CN201110397532A CN102516845A CN 102516845 A CN102516845 A CN 102516845A CN 201110397532X A CN201110397532X A CN 201110397532XA CN 201110397532 A CN201110397532 A CN 201110397532A CN 102516845 A CN102516845 A CN 102516845A
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Abstract
The invention discloses plastic gravure waterborne ink, which belongs to the technical field of waterborne ink, and is characterized in that: water-soluble synthetic resin is prepared from the following components in percentage by weight: 25-35 parts of polyamide, 7-15 parts of an acrylic monomer, 5-15 parts of soybean oil, 1-6 parts of pentaerythritol, 8-15 pats of maleic anhydride, 0.0-1 part of magnesia, 30-40 parts of rosin and 1-3 parts of a crosslinking agent; water-soluble oleoresin is prepared form the following components in parts by weight: 45-50 parts of water-soluble synthetic resin, 15-20 parts of ethanol, 30-40 parts of water and 3-6 parts of ammonia water; and a plastic gravure waterborne ink product is prepared from the following components in parts by weight: 50-60 parts of water-soluble oleoresin, 10-30 parts of a pigment, 10-20 parts of water and 1-8 parts of an aid consisting of an active agent, a deforming agent, a stabilizing agent, a dispersing agent, a flatting agent and a slipping agent. The plastic gravure waterborne ink is environmentally-friendly, safe, nontoxic, harmless, noncombustible and non-explosive, does not pollute the atmospheric environment, is accordant with the food sanitation safety, and has high adhesive firmness, i.e., high adhesion.
Description
Technical field
The invention belongs to the water color ink technical field, be specifically related to a kind of plastics gravure water-based ink.
Background technology
Subsequently Social Culture, science and technology, expanding economy; Printing industry develops at a speed unheard of before; And printing ink is the greatest contamination source of Printing industry, world's printing ink output reached 350 all ages ton, annual organic volatile (VOC) discharge amount of pollution that is caused by printing ink reaches more than 500,000 tons; Major polluting atmosphere environment, directly harm humans is healthy.Improving constantly of the environmental consciousness of Along with people's, environmental protection become the development topic of 21 century.Therefore research, development and application harm is little, it is few to pollute, so that non-harmful Green Packaging printing material becomes the inevitable requirement of Green Packaging development.Thus, the research and development of water color ink have become the main flow of printing industry.For this reason, people have worked out the technical scheme of many water color inks, as: like notification number: CN101029194, the patent No.: 200610057929.3 " plastic-film water intaglio printing inks "; Notification number: CN 101613472, the patent No.: 200910032093.5 " preparing methods of polyamide resin used for water color ink "; Publication number: CN 101613545, number of patent application: 200910162097.5 " a kind of water color ink and making methods that are used for intaglio printing "; But existing technical scheme all also exists in various degree can not alkali resistant, not anti-acetate, not anti-water, dry slow, low in glossiness, poor adhesive force, water color ink really in plastics intaglio printing industry actual the application in batches also fail to appear in the newspapers.
Summary of the invention
The objective of the invention is to provide a kind of plastics gravure water-based ink, its environmental protection, safe, nontoxic, harmless, do not fire not quick-fried, almost non-volatility organic gas, not pollutant atmosphere; Reduce the printed matter surface residual contaminants significantly, met food sanitation safe; Attachment fastness is a strong adhesion, anti-rubbing, and anti-drawing property, glossiness height, wear resistance is good, and rate of drying is fast; Its production process, the waste gas of discharging from reaction kettle drenches purifying treatment through water, reaches emission standard.
Above-mentioned goal of the invention realizes through following technical scheme, a kind of plastics gravure water-based ink, and its main points are by following components in portion by weight: 25～35 parts of polymeric amide; 7～15 parts of Acrylic Acid Monomers; 5～15 parts of VT 18s are defended 1～6 part of tetrol season, 8～15 parts of MALEIC ANHYDRIDEs; 0.01～1 part in Natural manganese dioxide, 30～40 parts of rosin, 1～3 part of preparation of linking agent water-soluble synthetic resin; Press following components in portion by weight: 45～50 parts of water-soluble synthetic resins, 15～20 parts of ethanol, 30～40 parts in water, 3～6 parts of preparations of ammoniacal liquor water soluble resin oil; By following components in portion by weight: water soluble resin oil 50-60 part, pigment 10-30 part, water 10-20 part, by promoting agent, skimmer, stablizer, dispersion agent,, auxiliary agent 1-8 part of forming of flow agent, slip(ping)agent makes plastics gravure water-based ink product.
Above-mentioned plastics gravure water-based ink, one of its technical scheme are by following components in portion by weight: 0 part of kymene, 10 parts of Acrylic Acid Monomers; 10 parts of VT 18s are defended 2 parts of tetrols season, 11 parts of MALEIC ANHYDRIDEs; 0.03 part in Natural manganese dioxide, 35 parts of rosin, 2 parts of preparations of linking agent water-soluble synthetic resin.
Above-mentioned plastics gravure water-based ink, one of its technical scheme are that polymeric amide is selected unsaturated two peaces and MALEIC ANHYDRIDE, C for use
16Dimeracid reaction is synthetic, and band contains unsaturated strong molecular weight less than 10,000 polymeric amide.
A kind of method for preparing the plastics gravure water-based ink, its main points are:
a, the following weight proportions of components: 25 to 35 parts of polyamide, 7 to 15 parts of an acrylic monomer, from 5 to 15 parts of soybean oil, season Shu tetraol 1 to 6 parts of maleic anhydride 8-15 parts of 0.01 to 1 part of magnesium oxide, 30 to 40 parts of rosin, 1 to 3 parts by crosslinking reaction kettle at a temperature of 250-270 ℃ stirring, and the polymerization reaction to form water-soluble synthetic resins;
B, with following components in portion by weight: 45～50 parts of water-soluble synthetic resins, 15～20 parts of ethanol, 30～40 parts in water, 3～6 parts of ammoniacal liquor stir, react under 70-80 ℃ temperature through reaction kettle, water soluble resin oil is processed in emulsification;
C, with following components in portion by weight: water soluble resin oil 50-60 part, pigment 10-30 part, water 10-20 part; Auxiliary agent 1-8 part of being made up of promoting agent, skimmer, stablizer, dispersion agent, flow agent, slip(ping)agent is through disperseing; Grind, filter, finally process plastics gravure water-based ink product.
The above-mentioned method for preparing the plastics gravure water-based ink, one of its method are with following components in portion by weight: 0 part of kymene, 10 parts of Acrylic Acid Monomers; 10 parts of VT 18s; Defend 2 parts of tetrols season, 11 parts of MALEIC ANHYDRIDEs, 0.03 part in Natural manganese dioxide; 2 parts of 35 parts of rosin, linking agent through reaction kettle under 260-265 ℃ temperature, stir, reaction and polymerization, process water-soluble synthetic resin.
The above-mentioned method for preparing the plastics gravure water-based ink, one of its method are that polymeric amide is selected unsaturated two peaces and MALEIC ANHYDRIDE, C for use
16Dimeracid reaction is synthetic, and band contains unsaturated strong molecular weight less than 10,000 polymeric amide.
Beneficial effect of the present invention: its product environmental protection, safe, nontoxic, harmless, do not fire not quick-fried, almost non-volatility organic gas, not pollutant atmosphere; Reduce the printed matter surface residual contaminants significantly, met the food sanitation safe requirement; Attachment fastness is a strong adhesion, anti-rubbing, and anti-drawing property, glossiness is high, and wear resistance is good, and rate of drying is fast; Its production process, the waste gas of discharging from reaction kettle drenches purifying treatment through water, reaches emission standard.
Embodiment
Below be an embodiment of the present invention-plastics gravure water-based ink, it presses following components in portion by weight: 0 part of kymene, 10 parts of Acrylic Acid Monomers; 10 parts of VT 18s; Defend 2 parts of tetrols season, 11 parts of MALEIC ANHYDRIDEs, 0.03 part in Natural manganese dioxide; 35 parts of rosin, 2 parts of preparations of linking agent water-soluble synthetic resin, polymeric amide is selected unsaturated two Anshun maleic acid anhydrides, C for use
16Dimeracid reaction is synthetic, and band contains unsaturated strong molecular weight less than 10,000 polymeric amide; Press following components in portion by weight: 48 parts of water-soluble synthetic resins, 17 parts of ethanol, 35 parts in water, 4 parts of preparations of ammoniacal liquor water soluble resin oil; By following components in portion by weight: 55 parts of water soluble resin oil, 20 parts of pigment, 15 parts in water, by promoting agent, skimmer, stablizer, dispersion agent,, the auxiliary agent formed of flow agent, slip(ping)agent makes plastics gravure water-based ink product for 3 parts.
Below be the present invention-prepare embodiment of the method for plastics gravure water-based ink, promptly produce the foregoing description product with present embodiment:
A, with following components in portion by weight: 0 part of kymene; 10 parts of Acrylic Acid Monomers, 10 parts of VT 18s are defended 2 parts of tetrols season; 11 parts of MALEIC ANHYDRIDEs; 0.03 part in Natural manganese dioxide, 2 parts of 35 parts of rosin, linking agent through reaction kettle under 260-265 ℃ temperature, stir, reaction and polymerization, process water-soluble synthetic resin; Polymeric amide is wherein selected unsaturated two Anshun maleic acid anhydrides, C for use
16Dimeracid reaction is synthetic, and band contains unsaturated strong molecular weight less than 10,000 polymeric amide.
B, with following components in portion by weight: 48 parts of water-soluble synthetic resins, 17 parts of ethanol, 35 parts in water, 4 parts of ammoniacal liquor through reaction kettle under 70-80 ℃ temperature, stir, reaction, emulsification process water soluble resin oil;
C, with following components in portion by weight: 55 parts of water soluble resin oil; 20 parts of pigment; 15 parts in water; By promoting agent, skimmer, stablizer, dispersion agent,, 3 parts of the auxiliary agents formed of flow agent, slip(ping)agent, through in high speed dispersor, sand mill equipment, disperseing, grind, filter, finally process plastics gravure water-based ink product.
The foregoing description, through " national chemical building material quality surveillance " center " detects, and its examining report is following:
Examining report
Claims (6)
1. plastics gravure water-based ink; It is characterized in that by following components in portion by weight: 25～35 parts of polymeric amide, 7～15 parts of Acrylic Acid Monomers, 5～15 parts of VT 18s; Defend 1～6 part of tetrol season; 8～15 parts of br dilute anhydrides, 0.01～1 part in Natural manganese dioxide, 30～40 parts of rosin, 1～3 part of preparation of linking agent water-soluble synthetic resin; Press following components in portion by weight: 45～50 parts of water-soluble synthetic resins, 15～20 parts of ethanol, 30～40 parts in water, 3～6 parts of preparations of ammoniacal liquor water soluble resin oil; Press following components in portion by weight: water soluble resin oil 50-60 part, pigment 10-30 part, water 10-20 part, auxiliary agent 1-8 part of being made up of promoting agent, skimmer, stablizer, dispersion agent, flow agent, slip(ping)agent makes plastics gravure water-based ink product.
2. plastics gravure water-based ink according to claim 1; It is characterized in that by following components in portion by weight: 0 part of kymene, 10 parts of Acrylic Acid Monomers, 10 parts of VT 18s; Defend 2 parts of tetrols season; 11 parts of MALEIC ANHYDRIDEs, 0.03 part in Natural manganese dioxide, 35 parts of rosin, 2 parts of preparations of linking agent water-soluble synthetic resin.
3. plastics gravure water-based ink according to claim 1 and 2 is characterized in that polymeric amide selects unsaturated two peaces and MALEIC ANHYDRIDE, C for use
16Dimeracid reaction is synthetic, and band contains unsaturated strong molecular weight less than 10,000 polymeric amide.
4. method for preparing the plastics gravure water-based ink is characterized in that:
a, the following weight proportions of components: 25 to 35 parts of polyamide, 7 to 15 parts of an acrylic monomer, from 5 to 15 parts of soybean oil, season Shu tetraol 1 to 6 parts of maleic anhydride 8-15 parts of 0.01 to 1 part of magnesium oxide, 30 to 40 parts of rosin, 1 to 3 parts by crosslinking reaction kettle at a temperature of 250-270 ℃ stirring, and the polymerization reaction to form water-soluble synthetic resins;
B, with following components in portion by weight: 45～50 parts of water-soluble synthetic resins, 15～20 parts of ethanol, 30～40 parts in water, 3～6 parts of ammoniacal liquor stir, react under 70-80 ℃ temperature through reaction kettle, water soluble resin oil is processed in emulsification;
C, with following components in portion by weight: water soluble resin oil 50-60 part, pigment 10-30 part, water 10-20 part; Auxiliary agent 1-8 part of being made up of promoting agent, skimmer, stablizer, dispersion agent, flow agent, slip(ping)agent is through disperseing; Grind, filter, finally process plastics gravure water-based ink product.
5. the method for preparing the plastics gravure water-based ink according to claim 4 is characterized in that following components in portion by weight: 0 part of kymene, 10 parts of Acrylic Acid Monomers; 10 parts of VT 18s; Defend 2 parts of tetrols season, 11 parts of MALEIC ANHYDRIDEs, 0.03 part in Natural manganese dioxide; 2 parts of 35 parts of rosin, linking agent through reaction kettle under 260-265 ℃ temperature, stir, reaction and polymerization, process water-soluble synthetic resin.
6. according to claim 4 or the 5 described methods that prepare the plastics gravure water-based ink, it is characterized in that polymeric amide selects unsaturated two peaces and MALEIC ANHYDRIDE, C for use
16Dimeracid reaction is synthetic, and band contains unsaturated strong molecular weight less than 10,000 polymeric amide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110397532 CN102516845B (en) | 2011-12-05 | 2011-12-05 | Plastic gravure waterborne ink |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110397532 CN102516845B (en) | 2011-12-05 | 2011-12-05 | Plastic gravure waterborne ink |
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| CN102516845A true CN102516845A (en) | 2012-06-27 |
| CN102516845B CN102516845B (en) | 2013-12-18 |
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| CN 201110397532 Active CN102516845B (en) | 2011-12-05 | 2011-12-05 | Plastic gravure waterborne ink |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104031468A (en) * | 2014-06-30 | 2014-09-10 | 柳江县联华纸制品厂 | Water-based gravure ink |
| CN104292966A (en) * | 2014-11-11 | 2015-01-21 | 合肥皖为电气设备工程有限责任公司 | Printing ink with good oxidation resistance and high color and lustrousness as well as preparation method for printing ink |
| CN104804528A (en) * | 2015-03-31 | 2015-07-29 | 安徽省嘉信包装印务有限公司 | Water-based plastic printing ink |
| CN109321031A (en) * | 2018-05-23 | 2019-02-12 | 江苏唐彩油墨科技股份有限公司 | Heat shrink films aqueous intaglio printing ink and preparation method thereof |
| CN109593398A (en) * | 2017-11-22 | 2019-04-09 | 广东华年颖异新材料科技有限责任公司 | Composite water soluble ink and preparation method thereof is printed in a kind of PE, OPP intaglio plate |
| CN110643219A (en) * | 2019-11-14 | 2020-01-03 | 云南开放大学 | Gravure ink for printing PET aluminum-plated film |
| CN110669379A (en) * | 2019-10-16 | 2020-01-10 | 江苏科技大学 | Quick-drying water-based ink composition and preparation method and application thereof |
| CN111334119A (en) * | 2020-04-16 | 2020-06-26 | 佛山市珂宁装饰材料有限公司 | Water-based ink for paper cup |
| CN111373003A (en) * | 2017-08-17 | 2020-07-03 | 太阳化学公司 | Water-based inks with high renewable content |
| CN115477872A (en) * | 2022-10-11 | 2022-12-16 | 深圳市四鼎华悦科技有限公司 | Environment-friendly ink paint for water-based paint |
| CN116376356A (en) * | 2023-05-09 | 2023-07-04 | 张家港市黎明化工有限公司 | Gravure printing ink and preparation method thereof |
Citations (2)
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| US6734280B1 (en) * | 2000-09-14 | 2004-05-11 | Meadwestvaco Corporation | Rosin-fatty acid vinylic polyamide polymer resins |
| CN101250350A (en) * | 2008-03-26 | 2008-08-27 | 中国印钞造币总公司 | Soybean oil based protruding printing ink |
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2011
- 2011-12-05 CN CN 201110397532 patent/CN102516845B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6734280B1 (en) * | 2000-09-14 | 2004-05-11 | Meadwestvaco Corporation | Rosin-fatty acid vinylic polyamide polymer resins |
| CN101250350A (en) * | 2008-03-26 | 2008-08-27 | 中国印钞造币总公司 | Soybean oil based protruding printing ink |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104031468A (en) * | 2014-06-30 | 2014-09-10 | 柳江县联华纸制品厂 | Water-based gravure ink |
| CN104292966A (en) * | 2014-11-11 | 2015-01-21 | 合肥皖为电气设备工程有限责任公司 | Printing ink with good oxidation resistance and high color and lustrousness as well as preparation method for printing ink |
| CN104804528A (en) * | 2015-03-31 | 2015-07-29 | 安徽省嘉信包装印务有限公司 | Water-based plastic printing ink |
| CN111373003A (en) * | 2017-08-17 | 2020-07-03 | 太阳化学公司 | Water-based inks with high renewable content |
| US11352522B2 (en) | 2017-08-17 | 2022-06-07 | Sun Chemical Corporation | Water-based inks with high renewable content |
| CN111373003B (en) * | 2017-08-17 | 2022-03-29 | 太阳化学公司 | Water-based inks with high renewable content |
| CN109593398A (en) * | 2017-11-22 | 2019-04-09 | 广东华年颖异新材料科技有限责任公司 | Composite water soluble ink and preparation method thereof is printed in a kind of PE, OPP intaglio plate |
| CN109321031B (en) * | 2018-05-23 | 2021-12-07 | 江苏唐彩新材料科技股份有限公司 | Water-based gravure printing ink for heat shrinkable film and preparation method thereof |
| CN109321031A (en) * | 2018-05-23 | 2019-02-12 | 江苏唐彩油墨科技股份有限公司 | Heat shrink films aqueous intaglio printing ink and preparation method thereof |
| CN110669379A (en) * | 2019-10-16 | 2020-01-10 | 江苏科技大学 | Quick-drying water-based ink composition and preparation method and application thereof |
| CN110643219A (en) * | 2019-11-14 | 2020-01-03 | 云南开放大学 | Gravure ink for printing PET aluminum-plated film |
| CN111334119A (en) * | 2020-04-16 | 2020-06-26 | 佛山市珂宁装饰材料有限公司 | Water-based ink for paper cup |
| CN115477872A (en) * | 2022-10-11 | 2022-12-16 | 深圳市四鼎华悦科技有限公司 | Environment-friendly ink paint for water-based paint |
| CN116376356A (en) * | 2023-05-09 | 2023-07-04 | 张家港市黎明化工有限公司 | Gravure printing ink and preparation method thereof |
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| CN102516845B (en) | 2013-12-18 |
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Effective date of registration: 20191218 Address after: 312000 Paitou Zhen Xin Sheng Cun, Zhuji City, Shaoxing City, Zhejiang Province Patentee after: Zhejiang Weihang New Material Technology Co., Ltd Address before: Yiwu City, Zhejiang province 322000 Chouzhou West Road, Jinhua City, No. 176 (Yiwu wellhand Water Ink Co. Ltd.) Patentee before: Yiwu Weihang Water-based Ink Co., Ltd. |