CN102477245A - Ultraviolet-curing anticorrosive paint and preparation method thereof - Google Patents
Ultraviolet-curing anticorrosive paint and preparation method thereof Download PDFInfo
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- CN102477245A CN102477245A CN2010105607436A CN201010560743A CN102477245A CN 102477245 A CN102477245 A CN 102477245A CN 2010105607436 A CN2010105607436 A CN 2010105607436A CN 201010560743 A CN201010560743 A CN 201010560743A CN 102477245 A CN102477245 A CN 102477245A
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- ultraviolet light
- epoxy acrylate
- protective system
- light polymerization
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- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000003973 paint Substances 0.000 title description 10
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 45
- 238000000576 coating method Methods 0.000 claims abstract description 18
- 239000011248 coating agent Substances 0.000 claims abstract description 17
- 239000000178 monomer Substances 0.000 claims abstract description 9
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 52
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 44
- 230000001681 protective effect Effects 0.000 claims description 39
- 238000006116 polymerization reaction Methods 0.000 claims description 38
- 238000003756 stirring Methods 0.000 claims description 28
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 20
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 18
- 230000003647 oxidation Effects 0.000 claims description 18
- 238000007254 oxidation reaction Methods 0.000 claims description 18
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 17
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 16
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 14
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 14
- -1 phosphate ester Chemical class 0.000 claims description 14
- 239000004593 Epoxy Substances 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 239000010452 phosphate Substances 0.000 claims description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 11
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 8
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 8
- 239000007983 Tris buffer Substances 0.000 claims description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 7
- 229940043232 butyl acetate Drugs 0.000 claims description 7
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 claims description 7
- 229940090181 propyl acetate Drugs 0.000 claims description 7
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- HRPUANCEDYZMFT-UHFFFAOYSA-N 2-(1-hydroxycyclohexyl)-1-phenylethanone Chemical compound C=1C=CC=CC=1C(=O)CC1(O)CCCCC1 HRPUANCEDYZMFT-UHFFFAOYSA-N 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000008199 coating composition Substances 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract 2
- 239000000463 material Substances 0.000 description 52
- 238000002156 mixing Methods 0.000 description 27
- 238000005303 weighing Methods 0.000 description 26
- 239000012752 auxiliary agent Substances 0.000 description 13
- 238000001723 curing Methods 0.000 description 9
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 6
- 230000002421 anti-septic effect Effects 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000011161 development Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229920000767 polyaniline Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to an ultraviolet curing anticorrosive coating which is characterized by comprising the following components in percentage by mass: epoxy acrylate: 5-80%, polyfunctional group functional monomer: 1-40%, photoinitiator: 1-5%, solvent: 5-92%, adhesion promoter: 1-30%, and provides the ultraviolet curing coating with excellent adhesion and outstanding corrosion resistance for metal surface protection, and the obtained coating film can still maintain excellent corrosion resistance when the film thickness is as low as 1 mu m.
Description
One, technical field
The invention belongs to the protective system field, relate to a kind of ultraviolet light polymerization protective system and preparation method thereof.
Two, background technology
Along with the pay attention to day by day to environmental problem in the global range, traditional coatings industry is being faced with great challenge, and the research and development application of environmentally friendly coating is the direction that the our times various countries make great efforts development.Ultraviolet-curing paint is to begin a kind of novel environmental type coating researching and developing and use the sixties in 20th century; Have and do not contain advantages such as volatile organic compound, environmental pollution is little, curing speed is fast, obtained application comparatively widely at industry and high-technology field.But ultraviolet-curing paint is actually rare as the applied research and the product of anti-corrosion of metal, for example: Yu Feng, model continue " application of ultraviolet-curing paint and the development " that spare time etc. delivers at " Shanghai coating " (2006,44 (10), 19-21); Chinese invention patent ZL200810051457.X discloses a kind of UV curing polyaniline anti-corrosive paint, and it combines ultraviolet-curing paint with polyaniline, develops a kind of new coating, has stronger acid-proof alkaline, and antiseptic property is better.But the Application Research of existing ultraviolet-curing paint has a common defective, film generally thicker (generally greater than 10 μ m), and when filming thin (less than 2 μ m), the antiseptic property of coating is poor, thereby has limited the Application Areas of UV coating.Therefore, develop the antiseptic property that both has excellence, the new anti-corrosion coating that has characteristics such as coating thickness is little again is for being badly in need of.
Three, summary of the invention
The technical problem that the present invention will solve provides a kind of excellent, exsertile ultraviolet-curing paint of preservative property of sticking power that is used for protecting metallic surface.Gained is filmed still can keep excellent antiseptic property when thickness is low to moderate 1 μ m.
For realizing goal of the invention, technical scheme of the present invention is: a kind of ultraviolet light polymerization protective system is characterized in that this coating composition and mass percent are:
Epoxy acrylate 5～80%
Polyfunctional group function monomer 1～40%
Light trigger 1～5%
Solvent 5～92%
Adhesion promoter 1～30%
Said epoxy acrylate is the mixture of a kind of in bisphenol A epoxy acrylate, phenolic aldehyde epoxy acrylate, the modified by polyacid epoxy acrylate or at least two kinds.
Said polyfunctional group function monomer is at least a in trimethylolpropane tris first propenoate (TMPTMA), Viscoat 295 (TMPTA), tri (propylene glycol) diacrylate (TPGDA), SY-Monomer G (GMA), SULPHOSUCCINIC ACID ESTER function monomer, the methylacrylic acid.
Said light trigger is 2-methyl-2-hydroxyl-1-phenyl-acetone, 1-hydroxy-cyclohexyl methyl phenyl ketone, 2,4, at least a in 6-trimethylbenzoyl-diphenyl phosphate oxidation, the active ammonia.
Said solvent is at least a in butylacetate, propyl acetate, ETHYLE ACETATE, acetone, butanone, benzene,toluene,xylene, propyl carbinol, Virahol, the ethanol.
Said adhesion promoter is an epoxy phosphate ester class adhesion promoter.
The preparation method of a kind of ultraviolet light polymerization protective system according to the invention is: the preparation process of this coating is: with mixing such as epoxy acrylate, polyfunctional group function monomer, light trigger, solvent and adhesion promoters; Under 20 ℃-70 ℃, stir, the room temperature lucifuge stores and gets final product.
Ultraviolet light polymerization protective system of the present invention has following result through test and detection:
Coating thickness 1.0 μ m
Alkali resistance 10%NaOH solution＞10min does not have obvious hot spot
Acid resistance 10%HCl solution＞30min does not have obvious hot spot
Salt fog resistance 72h does not have obvious hot spot
The present invention also possesses following beneficial effect:
1, ultraviolet-curing paint of the present invention, its coating thickness are filmed to compare greatly with existing UV coating and are reduced, and still can keep excellent antiseptic property when coating thickness can be low to moderate 1 μ m.
2, ultraviolet-curing paint of the present invention has shown the outstanding adhesion performance in the metallic surface, and the flexibility of filming is much improved, and has the favorable mechanical processing characteristics.
Four, embodiment
Below in conjunction with embodiment the present invention is done further specific descriptions:
Embodiment 1:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 10 grams, trimethylolpropane tris first propenoate (TMPTMA) 2 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 1 gram, ETHYLE ACETATE 80 grams, ethylene glycol monobutyl ether 10 grams and epoxy phosphate ester 3 grams; With above material thorough mixing, under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 2:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 15 grams, Viscoat 295 (TMPTA) 50 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 1 gram, Virahol 30 grams and epoxy phosphate ester 4 grams; With above material thorough mixing, under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 3:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 20 grams, trimethylolpropane tris first propenoate (TMPTMA) 45 grams, 2-methyl-2-hydroxyl-1-phenyl-acetone 3 grams, propyl carbinol 26 grams and epoxy phosphate ester 6 grams; With above material thorough mixing; Under 50 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 4:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 15 grams, phenolic aldehyde epoxy acrylate 10 grams, tri (propylene glycol) diacrylate (TPGDA) 40 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 5 grams, YLENE 23 grams and epoxy phosphate ester 7 grams; With above material thorough mixing, under 50 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 5:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 30 grams, tri (propylene glycol) diacrylate (TPGDA) 25 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 4 grams, Virahol 33 grams and butanols 8 grams; With above material thorough mixing, under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 6:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 35 grams, Viscoat 295 (TMPTA) 40 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 3 grams, Virahol 12 grams and auxiliary agent 10 grams; With above material thorough mixing, under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 7:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 50 grams, Viscoat 295 (TMPTA) 34 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 2 grams, Virahol 5 grams and auxiliary agent 9 grams; With above material thorough mixing, under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 8:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 45 grams, Viscoat 295 (TMPTA) 9 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 1 gram, Virahol 40 grams and auxiliary agent 5 grams; With above material thorough mixing, under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 9:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 33 grams, Viscoat 295 (TMPTA) 10 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 5 grams, Virahol 50 grams and auxiliary agent 2 grams; With above material thorough mixing, under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 10:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 55 grams, Viscoat 295 (TMPTA) 15 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 4 grams, Virahol 25 grams and auxiliary agent 1 gram; With above material thorough mixing, under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 11:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 60 grams, Viscoat 295 (TMPTA) 20 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 3 grams, Virahol 15 grams and auxiliary agent 2 grams; With above material thorough mixing, under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 12:
Take by weighing following material by weight percentage: modified by polyacid epoxy acrylate 10 grams, methylacrylic acid (MAA) 5 grams, 1-hydroxy-cyclohexyl methyl phenyl ketone 2 grams, YLENE 80 grams and ethanol 3 grams; With above material thorough mixing; Under 55 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 13:
Take by weighing following material by weight percentage: modified by polyacid epoxy acrylate 15 grams, SY-Monomer G (GMA) 15 grams, Viscoat 295 (TMPTA) 25 grams, tri (propylene glycol) diacrylate (TPGDA) 10 grams, 2-methyl-2-hydroxyl-1-phenyl-acetone 1 gram, propyl acetate 10 grams, butanone 20 grams and auxiliary agent 4 grams; With above material thorough mixing; Under 60 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 14:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 10 grams, modified by polyacid epoxy acrylate 10 grams, Viscoat 295 (TMPTA) 5 grams, SY-Monomer G (GMA) 20 grams, methylacrylic acid (MAA) 20 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 2 grams, active ammonia 1 gram, Virahol 26 grams and auxiliary agent 6 grams; With above material thorough mixing; Under 50 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 15:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 20 grams, modified by polyacid epoxy acrylate 5 grams, trimethylolpropane tris first propenoate (TMPTMA) 10 grams, Viscoat 295 (TMPTA) 5 grams, tri (propylene glycol) diacrylate (TPGDA) 10 grams, SY-Monomer G (GMA) 10 grams, methylacrylic acid (MAA) 5 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 3 grams, 2-methyl-2-hydroxyl-1-phenyl-acetone 2 grams, Virahol 23 grams, ethanol 3 grams and butanols 4 grams; With above material thorough mixing; Under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 16:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 30 grams, SY-Monomer G (GMA) 15 grams, methylacrylic acid (MAA) 10 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 4 grams, YLENE 10 grams, propyl carbinol 10 grams, Virahol 13 grams and auxiliary agent 8 grams; With above material thorough mixing, under 30 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 17:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 35 grams, trimethylolpropane tris first propenoate (TMPTMA) 10 grams, Viscoat 295 (TMPTA) 20 grams, tri (propylene glycol) diacrylate (TPGDA) 10 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 3 grams, Virahol 12 grams and auxiliary agent 10 grams; With above material thorough mixing, under 35 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 18:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 40 grams, modified by polyacid epoxy acrylate 10 grams, Viscoat 295 (TMPTA) 10 grams, tri (propylene glycol) diacrylate (TPGDA) 10 grams, SY-Monomer G (GMA) 14 grams, 2-methyl-2-hydroxyl-1-phenyl-acetone 2 grams, Virahol 5 grams and auxiliary agent 9 grams; With above material thorough mixing; Under 40 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 19:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 45 grams, Viscoat 295 (TMPTA) 9 grams, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) 1 gram, butylacetate 10 grams, ETHYLE ACETATE 10 grams, butanone 10 grams, ethanol 10 grams and auxiliary agent 5 grams; With above material thorough mixing, under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 20:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 33 grams, Viscoat 295 (TMPTA) 10 grams, 2-methyl-2-hydroxyl-1-phenyl-acetone 1 gram, 1-hydroxy-cyclohexyl methyl phenyl ketone 1 gram, 2; 4; 6-trimethylbenzoyl-diphenyl phosphate oxidation 2 grams, active ammonia 1 gram, butylacetate 5 grams, propyl acetate 5 grams, ETHYLE ACETATE 5 grams, acetone 5 grams, butanone 5 grams, benzene 5 grams, toluene 5 grams, YLENE 9 grams, Virahol 5 grams and auxiliary agent 2 grams; With above material thorough mixing; Under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 21:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 5 grams, Viscoat 295 (TMPTA) 1 gram, 2-methyl-2-hydroxyl-1-phenyl-acetone 1 gram, butylacetate 10 grams, propyl acetate 10 grams, ETHYLE ACETATE 10 grams, acetone 10 grams, butanone 10 grams, benzene 20 grams, toluene 15 grams, YLENE 5 grams, Virahol 2 grams and epoxy phosphate ester 1 gram; With above material thorough mixing; Under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 22:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 30 grams, phenolic aldehyde epoxy acrylate 30 grams, modified by polyacid epoxy acrylate 20 grams, Viscoat 295 (TMPTA) 10 grams, 2-methyl-2-hydroxyl-1-phenyl-acetone 2 grams, ETHYLE ACETATE 5 grams and epoxy phosphate ester 3 grams; With above material thorough mixing; Under 70 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 23:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 20 grams, Viscoat 295 (TMPTA) 40 grams, 2-methyl-2-hydroxyl-1-phenyl-acetone 5 grams, butylacetate 10 grams, propyl acetate 10 grams, ETHYLE ACETATE 10 grams and epoxy phosphate ester 5 grams; With above material thorough mixing; Under 20 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 24:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 10 grams, Viscoat 295 (TMPTA) 26 grams, 2-methyl-2-hydroxyl-1-phenyl-acetone 4 grams, butylacetate 10 grams, propyl acetate 10 grams, ETHYLE ACETATE 10 grams and epoxy phosphate ester 30 grams; With above material thorough mixing; Under 50 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 25:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 15 grams, trimethylolpropane tris first propenoate (TMPTMA) 10 grams, Viscoat 295 (TMPTA) 5 grams, tri (propylene glycol) diacrylate (TPGDA) 5 grams, 2-methyl-2-hydroxyl-1-phenyl-acetone 5 grams, ETHYLE ACETATE 10 grams, acetone 10 grams, butanone 10 grams, benzene 10 grams and epoxy phosphate ester 20 grams; With above material thorough mixing; Under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Embodiment 26:
Take by weighing following material by weight percentage: bisphenol A epoxy acrylate 5 grams, trimethylolpropane tris first propenoate (TMPTMA) 10 grams, Viscoat 295 (TMPTA) 10 grams, tri (propylene glycol) diacrylate (TPGDA) 10 grams, 2-methyl-2-hydroxyl-1-phenyl-acetone 5 grams, ETHYLE ACETATE 10 grams, acetone 10 grams, butanone 10 grams, benzene 20 grams and epoxy phosphate ester 10 grams; With above material thorough mixing; Under 45 ℃, stir, the room temperature lucifuge stores can obtain the ultraviolet light polymerization protective system.
Claims (7)
1. a ultraviolet light polymerization protective system is characterized in that, this coating composition and mass percent are:
Epoxy acrylate 5～80%
Polyfunctional group function monomer 1～40%
Light trigger 1～5%
Solvent 5～92%
Adhesion promoter 1～30%
2. a kind of ultraviolet light polymerization protective system according to claim 1; It is characterized in that said epoxy acrylate is the mixture of a kind of in bisphenol A epoxy acrylate, phenolic aldehyde epoxy acrylate, the modified by polyacid epoxy acrylate or at least two kinds.
3. a kind of ultraviolet light polymerization protective system according to claim 1; It is characterized in that said polyfunctional group function monomer is at least a in trimethylolpropane tris first propenoate (TMPTMA), Viscoat 295 (TMPTA), tri (propylene glycol) diacrylate (TPGDA), SY-Monomer G (GMA), SULPHOSUCCINIC ACID ESTER function monomer, the methylacrylic acid (MAA).
4. a kind of ultraviolet light polymerization protective system according to claim 1; It is characterized in that; Said light trigger is 2-methyl-2-hydroxyl-1-phenyl-acetone, 1-hydroxy-cyclohexyl methyl phenyl ketone, 2,4, at least a in 6-trimethylbenzoyl-diphenyl phosphate oxidation, the active ammonia.
5. a kind of ultraviolet light polymerization protective system according to claim 1; It is characterized in that said solvent is at least a in butylacetate, propyl acetate, ETHYLE ACETATE, second-glycol monobutyl ether, ethylene glycol monomethyl ether, acetone, butanone, benzene,toluene,xylene, propyl carbinol, Virahol, the ethanol.
6. a kind of ultraviolet light polymerization protective system according to claim 1 is characterized in that said adhesion promoter is an epoxy phosphate ester.
7. the preparation method of a ultraviolet light polymerization protective system; It is characterized in that; The preparation process of this coating is: epoxy acrylate, polyfunctional group function monomer, light trigger, solvent and adhesion promoter are mixed, under 20 ℃-70 ℃, stir, the room temperature lucifuge stores and gets final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105607436A CN102477245A (en) | 2010-11-26 | 2010-11-26 | Ultraviolet-curing anticorrosive paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105607436A CN102477245A (en) | 2010-11-26 | 2010-11-26 | Ultraviolet-curing anticorrosive paint and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN102477245A true CN102477245A (en) | 2012-05-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010105607436A Pending CN102477245A (en) | 2010-11-26 | 2010-11-26 | Ultraviolet-curing anticorrosive paint and preparation method thereof |
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| Country | Link |
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| CN (1) | CN102477245A (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977739A (en) * | 2012-11-29 | 2013-03-20 | 广东汇龙涂料有限公司 | Ultraviolet (UV) curing electrostatic spraying transparent primer wood coating and construction method |
| CN103013203A (en) * | 2012-08-09 | 2013-04-03 | 江苏科技大学 | Compound type ultraviolet light-cured anticorrosive paint and preparation method thereof |
| CN103030748A (en) * | 2013-01-08 | 2013-04-10 | 石狮市新力元反光材料有限公司 | UV (ultraviolet) resin for producing reflective membrane and preparation method of UV resin |
| CN103897576A (en) * | 2012-12-25 | 2014-07-02 | 比亚迪股份有限公司 | Paint, preparation method thereof, electronic product shell and preparation method thereof |
| CN105295669A (en) * | 2015-11-19 | 2016-02-03 | 广州聚注专利研发有限公司 | UV-curing coating |
| CN105969102A (en) * | 2016-07-12 | 2016-09-28 | 无锡市华东电力设备有限公司 | Coating and preparation method thereof |
| CN108300171A (en) * | 2017-09-26 | 2018-07-20 | 成都优品化工有限公司 | A kind of LED-UV photocurings anticorrosive paint and preparation method thereof |
| CN108359400A (en) * | 2018-03-22 | 2018-08-03 | 江苏冠达通电子科技有限公司 | A kind of environment-friendly type UV curing adhesives and preparation method thereof |
| CN109486367A (en) * | 2018-11-14 | 2019-03-19 | 泓源兴防腐科技(天津)有限公司 | A kind of anticorrosive paint |
| CN113717616A (en) * | 2021-10-19 | 2021-11-30 | 成都君子兰涂料有限公司 | Polishing-free UV (ultraviolet) adhesion primer for pasting melamine paper on medium density fiberboard and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101445679A (en) * | 2008-12-25 | 2009-06-03 | 四川大学 | UV-light solidifying paint having decorative effect and preparation method thereof |
| CN101591484A (en) * | 2009-06-23 | 2009-12-02 | 浜二（宜昌）涂料有限公司 | A kind of photocureable coating for pianos |
-
2010
- 2010-11-26 CN CN2010105607436A patent/CN102477245A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101445679A (en) * | 2008-12-25 | 2009-06-03 | 四川大学 | UV-light solidifying paint having decorative effect and preparation method thereof |
| CN101591484A (en) * | 2009-06-23 | 2009-12-02 | 浜二（宜昌）涂料有限公司 | A kind of photocureable coating for pianos |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103013203A (en) * | 2012-08-09 | 2013-04-03 | 江苏科技大学 | Compound type ultraviolet light-cured anticorrosive paint and preparation method thereof |
| CN102977739A (en) * | 2012-11-29 | 2013-03-20 | 广东汇龙涂料有限公司 | Ultraviolet (UV) curing electrostatic spraying transparent primer wood coating and construction method |
| CN103897576A (en) * | 2012-12-25 | 2014-07-02 | 比亚迪股份有限公司 | Paint, preparation method thereof, electronic product shell and preparation method thereof |
| CN103030748A (en) * | 2013-01-08 | 2013-04-10 | 石狮市新力元反光材料有限公司 | UV (ultraviolet) resin for producing reflective membrane and preparation method of UV resin |
| CN105295669A (en) * | 2015-11-19 | 2016-02-03 | 广州聚注专利研发有限公司 | UV-curing coating |
| CN105969102A (en) * | 2016-07-12 | 2016-09-28 | 无锡市华东电力设备有限公司 | Coating and preparation method thereof |
| CN108300171A (en) * | 2017-09-26 | 2018-07-20 | 成都优品化工有限公司 | A kind of LED-UV photocurings anticorrosive paint and preparation method thereof |
| CN108359400A (en) * | 2018-03-22 | 2018-08-03 | 江苏冠达通电子科技有限公司 | A kind of environment-friendly type UV curing adhesives and preparation method thereof |
| CN109486367A (en) * | 2018-11-14 | 2019-03-19 | 泓源兴防腐科技(天津)有限公司 | A kind of anticorrosive paint |
| CN113717616A (en) * | 2021-10-19 | 2021-11-30 | 成都君子兰涂料有限公司 | Polishing-free UV (ultraviolet) adhesion primer for pasting melamine paper on medium density fiberboard and preparation method thereof |
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Application publication date: 20120530 |