CN102431255B - Composite material having solar cell and production method thereof - Google Patents
Composite material having solar cell and production method thereof Download PDFInfo
- Publication number
- CN102431255B CN102431255B CN201110279168.7A CN201110279168A CN102431255B CN 102431255 B CN102431255 B CN 102431255B CN 201110279168 A CN201110279168 A CN 201110279168A CN 102431255 B CN102431255 B CN 102431255B
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- China
- Prior art keywords
- resin glue
- layer
- solar cell
- transparent resin
- high transparent
- Prior art date
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- 239000002131 composite material Substances 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 5
- 229920005989 resin Polymers 0.000 claims abstract description 65
- 239000011347 resin Substances 0.000 claims abstract description 65
- 239000004744 fabric Substances 0.000 claims abstract description 46
- 239000003292 glue Substances 0.000 claims abstract description 43
- 239000010410 layer Substances 0.000 claims abstract description 43
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 34
- 239000004917 carbon fiber Substances 0.000 claims abstract description 33
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000000853 adhesive Substances 0.000 claims abstract description 7
- 230000001070 adhesive effect Effects 0.000 claims abstract description 7
- 239000000565 sealant Substances 0.000 claims abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 8
- 239000011229 interlayer Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 8
- 239000002344 surface layer Substances 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 238000007493 shaping process Methods 0.000 claims description 7
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 229920001567 vinyl ester resin Polymers 0.000 claims description 5
- 239000002390 adhesive tape Substances 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000011505 plaster Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000009736 wetting Methods 0.000 claims description 4
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 3
- 229920005749 polyurethane resin Polymers 0.000 claims description 2
- 238000002834 transmittance Methods 0.000 claims description 2
- 239000012790 adhesive layer Substances 0.000 abstract 2
- 238000005507 spraying Methods 0.000 abstract 2
- 238000000465 moulding Methods 0.000 abstract 1
- 238000005086 pumping Methods 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Laminated Bodies (AREA)
- Body Structure For Vehicles (AREA)
Abstract
The invention relates to a composite material having a solar cell for producing automobile components and a production method thereof. The composite material comprises a plurality of layers which are laminated layer upon layer and connected with each other, wherein, the layers successively comprise a high transparent resin adhesive layer and an enhancement layer from top to bottom, the solar cell is buried in the high transparent resin adhesive layer or embedded in the bottom surface. The composite material has the advantages of light weight, high strength, and low cost. The method for producing the composite material effectively and rapidly comprises the following steps: spraying a layer of glue on the surface of a die by using a high transparent resin adhesive; putting the solar cell in the die; spraying a layer of the adhesive on the superficial layer of the die again; paving carbon fibers or carbon fabrics in the die; pasting an adhesive sealant on the periphery and inner side of the die; successively paving a demolding cloth, a flow conducting cloth, and a vacuum bag film on the surface of the carbon fiber layer, and arranging a flow conducting pipe; carrying out vacuum pumping on the die, and detecting the degree of vacuum by using a leak detector; absorbing a common resin adhesive; after infiltrating the carbon fibers by the common resin adhesive and solidifying, molding a product.
Description
Technical field
The present invention relates to a kind of composite with solar cell for making automobile component and preparation method thereof.
Background technology
Increasingly serious due to global energy crisis and environmental problem, the demand of people to new forms of energy and non-pollution renewable energy is more and more urgent, and solar energy power generating is a technical field rising in new and renewable sources of energy.Solar energy, for automobile, is also that people seek assiduously as energy source of car.But; solar cell, in the unshielded situation in the external world, is easy to suffer breakage or destruction, causes its disabler; therefore solar cell must have strong protective device on the one hand; usual employing safety glass is as the protective layer of solar cell, and cost is higher, on the other hand; solar energy is as automobile power or its part source; necessarily require solar energy to be converted to the energy of automobile enough greatly, and vehicle weight is enough light, could meet the overall need for electricity of automobile like this.The practical application that existing above-mentioned phenomenon result in solar cell often hinders heavy, attends to one thing and lose sight of another, and cannot obtain the effect that two-phase is benefited.
Summary of the invention
Primary and foremost purpose of the present invention is to provide a kind of structure simply with the composite of solar cell, and to ensure to guarantee that its weight is light under the prerequisite that solar cell normally works, intensity is high, and cost is low.
For achieving the above object, present invention employs following technical scheme: a kind of composite with solar cell, by multiple stacked mutually and connect layer form, described each layer is from top to bottom followed successively by: high transparent resin glue-line, enhancement layer for increasing high transparent resin glue-line intensity, and described solar cell is embedded in high transparent resin glue-line or is embedded at its bottom face.
Major advantage of the present invention is: be easy to machine-shaping, lighter weight and the splendid feature of light transmission because high transparent resin itself has, there is insulating properties, high-impact performance simultaneously, can be used as good solar cell overcoat to use, and the easy deformation of itself and the lower defect of intensity can overcome according to the enhancement layer being attached to its back side, finally make that the present invention has lightweight, high strength, high-modulus, resistance to creep, self lubricity is good, wearability is good, shaping shrinkage rate is little, easy machine-shaping and the aspect advantage such as cost is low.
Another object of the present invention is to provide a kind of preparation method of the composite with solar cell, can effectively and fast produce the composite with solar cell of the present invention.
For achieving the above object, present invention employs following technical scheme:
This technical scheme comprises the following steps:
One piece of automobile component mould is provided, uses high transparent resin glue to spray one deck glue at its die surface, as the first high transparent resin glue-line;
Solar cell is placed on request the upper surface layer of the first high transparent resin glue-line of mould;
Re-use high transparent resin glue and spray one deck glue at above-mentioned upper surface layer, make its overall formation high transparent resin glue-line;
Carbon fiber or carbon fibre fabric are laid the high transparent resin Jiao Shangbiaomiancengchu in mould, according to requirement design carbon fiber thickness or the carbon fibre fabric number of plies also laying formation carbon fiber layer of product;
Paste sealant tape in mould periphery, double faced adhesive tape is pasted in inner side, for lower step operation is got ready;
Lay release cloth on carbon fiber layer surface and entirety is carried out to it and cover, then lay on release cloth and overall covering flow-guiding cloth, after laying, according to product size, its redundance is cut out;
Integral coating vacuum bag film outside flow-guiding cloth top layer, arranges in mould periphery the mozzle being used for water conservancy diversion ordinary resin glue, and described mozzle is communicated with external equipment and the interlayer between carbon fiber layer surface and release cloth;
Carried out by mould vacuumizing process and checking vacuum with leak detector, now vacuum bag film integral plaster invests flow-guiding cloth top layer;
Ordinary resin glue is inhaled in the interlayer between carbon fiber layer surface and release cloth;
Treat ordinary resin glue complete wetting carbon fiber and solidify, peelling off vacuum bag film, remove release cloth and flow-guiding cloth, derive product, Total Product is shaping.
Major advantage of the present invention is: according to the preparation method of above-mentioned composite, effectively and efficiently can produce the composite with solar cell of the present invention.
Accompanying drawing explanation
Fig. 1 is cross-sectional view of the present invention;
Fig. 2 is the plan view of using state of the present invention;
Fig. 3-11 is for being Making programme figure of the present invention.
Detailed description of the invention
A kind of composite with solar cell, by multiple stacked mutually and connect layer form, described each layer is from top to bottom followed successively by: high transparent resin glue-line 10, enhancement layer 20 for increasing high transparent resin glue-line 10 intensity, described solar cell 30 is embedded in high transparent resin glue-line 10 or is embedded at its bottom face, as shown in Figure 1-2.
As present invention further optimization scheme: as shown in Figure 1, described enhancement layer 20 comprises ordinary resin glue-line 21, described ordinary resin glue-line 21 be folded with between high transparent resin glue-line 10 and the stacked carbon fiber layer 22 be connected between the two.Like this, rely on carbon fiber high-strength degree, easy deformation that the feature of lightweight makes up high transparent resin and the lower defect of intensity, guarantee its unitarily formed lightweight simultaneously, further meet the lightweight demand of vehicle.
Further, as shown in Figure 1-2, described solar cell 30 is crystal silicon cell or hull cell, and described solar cell 30 is embedded in high transparent resin glue-line 10 and its battery sensitive surface parallel high transparent resin glue-line 10 aspect is arranged.
A manufacture method for the above-mentioned composite with solar cell, comprises the following steps:
One piece of automobile component mould 40 is provided, uses high transparent resin glue at its mould 40 surface spray one deck glue, as the first high transparent resin glue-line 11, as shown in Figure 3;
Solar cell 30 is placed on request the upper surface layer of the first high transparent resin glue-line 11 of mould 40, as shown in Figure 4;
Re-use high transparent resin glue and spray one deck glue at above-mentioned upper surface layer, make its overall formation high transparent resin glue-line 10, as shown in Figure 5;
Carbon fiber or carbon fibre fabric are laid the high transparent resin Jiao Shangbiaomiancengchu in mould 40, according to requirement design carbon fiber thickness or the carbon fibre fabric number of plies also laying formation carbon fiber layer 22 of product, as shown in Figure 6;
Paste sealant tape in mould 40 periphery, double faced adhesive tape is pasted in inner side, for lower step operation is got ready;
Lay release cloth 50 on carbon fiber layer 22 surface and entirety is carried out to it and cover, then lay on release cloth 50 and overall covering flow-guiding cloth 60, after laying, according to product size, its redundance is cut out, as shown in Figure 7;
Integral coating vacuum bag film 70 outside flow-guiding cloth 60 top layer, arranges in mould 40 periphery the mozzle 80 being used for water conservancy diversion ordinary resin glue, and described mozzle 80 is communicated with external equipment and the interlayer between carbon fiber layer 22 surface and release cloth 50, as shown in Figure 8;
Carried out by mould 40 vacuumizing process and checking vacuum with leak detector, now vacuum bag film 70 integral plaster invests flow-guiding cloth 60 top layer, as shown in Figure 9;
Ordinary resin glue is inhaled in the interlayer between carbon fiber layer 22 surface and release cloth 50, as shown in Figure 10;
Treat ordinary resin glue complete wetting carbon fiber and solidify, peelling off vacuum bag film 70, remove release cloth 50 and flow-guiding cloth 60, derive product, Total Product is shaping, as shown in figure 11.
Further, as shown in Figure 9 in step, vacuumize process and check vacuum level requirements >=0.095Mpa with leak detector.
Do following specializing to high transparent resin glue and ordinary resin glue herein to limit: described high transparent resin glue is that light transmittance has a resin glue of insulating properties, high-impact, high strength, high ageing-resistant performance higher than 70%.Described ordinary resin glue is epoxide-resin glue or vinyl ester resin glue or unsaturated-resin glue or polyurethane resin adhesive etc.
Below in conjunction with accompanying drawing 3-11, a preferred embodiment of the present invention is described, not as a limitation of the invention.
Solar cell: crystal silicon cell;
Carbon fiber: 3k twill 200g/m2 carbon fibre fabric;
Resin glue: epoxy resin+curing agent, vinyl ester resin;
Automobile component: covering for roofs.
Carbon fiber automobile top-cap procedure of processing with solar cell is as follows:
One piece of automobile top cover die is provided, uses epoxy resin+curing agent glue at the glue of automobile top cover die surface spray one deck 0.5mm left and right thickness, as the first high transparent resin glue-line;
Crystal silicon cell is placed on request the upper surface layer of the first high transparent resin glue-line of mould;
Re-use the glue that use epoxy resin+curing agent glue sprays one deck 0.3mm left and right thickness thereon, make its overall formation high transparent resin glue-line;
3k twill 200g/m2 carbon fibre fabric is laid the upper surface layer place of the high transparent resin glue-line in mould, lay 8 layers altogether to form carbon fiber layer;
Paste sealant tape in mould periphery, double faced adhesive tape is pasted in inner side, for lower step operation is got ready;
Lay release cloth on carbon fiber layer surface and entirety is carried out to it and cover, then lay on release cloth and overall covering flow-guiding cloth, after laying, according to product size, its redundance is cut out;
Integral coating vacuum bag film outside flow-guiding cloth top layer, arranges in mould periphery the mozzle being used for water conservancy diversion ordinary resin glue, and mozzle is communicated with external equipment and the interlayer between carbon fiber layer surface and release cloth;
Carried out by mould vacuumizing process and checking vacuum with leak detector, vacuum level requirements >=0.095Mpa, now vacuum bag film integral plaster invests flow-guiding cloth top layer;
Open external equipment, vinyl ester resin glue is sucked in the interlayer between carbon fiber layer surface and release cloth;
Treat vinyl ester resin glue complete wetting carbon fiber and solidify, peelling off vacuum bag film, remove release cloth and flow-guiding cloth, derive product, Total Product is shaping.
Claims (1)
1. with a manufacture method for the composite of solar cell, it is characterized in that, it comprises the following steps:
One piece of automobile component mould (40) is provided, uses high transparent resin glue at its mould (40) surface spray one deck glue, as the first high transparent resin glue-line (11);
Solar cell (30) is placed on request the upper surface layer of the first high transparent resin glue-line (11) of mould (40);
Re-use high transparent resin glue and spray one deck glue at above-mentioned upper surface layer, make its overall formation high transparent resin glue-line (10);
Carbon fiber or carbon fibre fabric are laid the high transparent resin Jiao Shangbiaomiancengchu in mould (40), according to requirement design carbon fiber thickness or the carbon fibre fabric number of plies also laying formation carbon fiber layer (22) of product;
Paste sealant tape in mould (40) periphery, double faced adhesive tape is pasted in inner side, for lower step operation is got ready;
Lay release cloth (50) on carbon fiber layer (22) surface and entirety covering is carried out to it, more above laying and overall covering flow-guiding cloth (60) at release cloth (50), after laying, according to product size, its redundance being cut out;
Integral coating vacuum bag film (70) outside flow-guiding cloth (60) top layer, arrange in mould (40) periphery the mozzle (80) being used for water conservancy diversion ordinary resin glue, described mozzle (80) is communicated with external equipment and the interlayer between carbon fiber layer (22) surface and release cloth (50);
Carried out by mould (40) vacuumizing process and checking vacuum with leak detector, now vacuum bag film (70) integral plaster invests flow-guiding cloth (60) top layer;
Ordinary resin glue is inhaled in the interlayer between carbon fiber layer (22) surface and release cloth (50);
Treat ordinary resin glue complete wetting carbon fiber and solidify, peelling off vacuum bag film (70), remove release cloth (50) and flow-guiding cloth (60), derive product, Total Product is shaping.
2
.the preparation method of the composite with solar cell according to claim 1, is characterized in that: described high transparent resin glue be light transmittance higher than 70% resin glue.
3
.the preparation method of the composite with solar cell according to claim 1, is characterized in that: described vacuum level requirements>=0.095Mpa.
4
.the preparation method of the composite with solar cell according to claim 1, is characterized in that: described ordinary resin glue is epoxide-resin glue or vinyl ester resin glue or polyurethane resin adhesive.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201110279168.7A CN102431255B (en) | 2011-09-20 | 2011-09-20 | Composite material having solar cell and production method thereof |
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CN201110279168.7A CN102431255B (en) | 2011-09-20 | 2011-09-20 | Composite material having solar cell and production method thereof |
Publications (2)
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CN102431255A CN102431255A (en) | 2012-05-02 |
CN102431255B true CN102431255B (en) | 2014-12-24 |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103387011A (en) * | 2012-05-10 | 2013-11-13 | 王洪举 | Carbon fiber solar panel car roof |
CN105810776B (en) * | 2014-12-31 | 2018-06-29 | 北京创昱科技有限公司 | A kind of preparation method of carbon fiber solar panels and its carbon fiber solar panels |
CN107804177A (en) * | 2017-10-26 | 2018-03-16 | 张娜 | A kind of solar electrically propelled vehicle |
CN109830543B (en) * | 2019-01-31 | 2021-08-10 | 光之科技发展(昆山)有限公司 | Photovoltaic building material and preparation method thereof |
CN110416340A (en) * | 2019-08-02 | 2019-11-05 | 灵翼飞航(天津)科技有限公司 | A kind of packaging technology of solar panel |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN2646870Y (en) * | 2003-08-25 | 2004-10-06 | 无锡尚德太阳能电力有限公司 | Solar battery skylight |
CN1807492A (en) * | 2005-12-29 | 2006-07-26 | 复旦大学 | Method for preparing inorganic semi-conductor/ conducting polymer composite film by photocatalyzed polymerization |
CN1836899A (en) * | 2006-04-29 | 2006-09-27 | 梁晓斌 | Liquid crystal screen protection paste made of titanium oxide film coating by high vacuum optical plating |
CN101719523A (en) * | 2009-11-18 | 2010-06-02 | 常熟阿特斯阳光电力科技有限公司 | Solar energy battery panel for automobile |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2485276A3 (en) * | 2008-10-31 | 2012-09-26 | Dow Corning Corporation | Photovoltaic Cell Module and Method of Forming |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN2646870Y (en) * | 2003-08-25 | 2004-10-06 | 无锡尚德太阳能电力有限公司 | Solar battery skylight |
CN1807492A (en) * | 2005-12-29 | 2006-07-26 | 复旦大学 | Method for preparing inorganic semi-conductor/ conducting polymer composite film by photocatalyzed polymerization |
CN1836899A (en) * | 2006-04-29 | 2006-09-27 | 梁晓斌 | Liquid crystal screen protection paste made of titanium oxide film coating by high vacuum optical plating |
CN101719523A (en) * | 2009-11-18 | 2010-06-02 | 常熟阿特斯阳光电力科技有限公司 | Solar energy battery panel for automobile |
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