CN102429833B - Environmentally-friendly hand sanitizer and preparation method thereof - Google Patents
Environmentally-friendly hand sanitizer and preparation method thereof Download PDFInfo
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- CN102429833B CN102429833B CN201110449959.XA CN201110449959A CN102429833B CN 102429833 B CN102429833 B CN 102429833B CN 201110449959 A CN201110449959 A CN 201110449959A CN 102429833 B CN102429833 B CN 102429833B
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- handwashing liquid
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Abstract
The invention relates provides an environmentally-friendly hand sanitizer and a preparation method thereof. The raw materials for the hand sanitizer comprise alkyl glycoside, coco oil amide propyl lycine, sodium fatty acid methyl ester sulfonate, coconut oil amide propyl amine oxide, glycerol, sodium citrate, lactic acid, hydroxypropyl cellulose, sodium chloride,1,2-benzoisothiazolizone-3-ketone, essence and deionized water. In the hand sanitizer and the preparation method thereof provided by the invention, sodium fatty acid methyl ester sulfonate with good detergency, calcium soap dispersibility, emulsibility, thickening property, hard water resistance, no toxicity and complete biodegradability is adopted, and amphoteric surfactants namely coconut oil amide propyl lycine and coconut oil amide propyl amine oxide with rich foam, mildness and low irritation are matched with alkyl glycoside to generate synergism, thus the hand sanitizer can defecate and clean hands and has the efficacy of mild protection on skin; and glycerol and lactic acid are adopted to improve moisture retention capability of the system, thus skin is not tight after the hand sanitizer is used.
Description
Technical field
The invention belongs to composition of detergent field, specifically a kind of environmental protection handwashing liquid and preparation method thereof.
Background technology
Conventional handwashing liquid is mainly used in clean hand skin in the market, and because it has, foam is abundant, fine and smooth, gentle, low stimulation, adopts the disposable liquid mode of getting, and can not cause the features such as user skin secondary pollution, and be liked by consumer.
But the safety of conventional handwashing liquid still has hidden danger.In August, 2010, " dioxanes " event has caused the fear of consumer, has started the concern of people to washing, cosmetic product safety.The clean object of handwashing liquid has particularity, and people use after handwashing liquid, if rinse not thorough, on hand skin, have a certain amount of residual, by touching the channel such as food, residual handwashing liquid composition very likely can tape entry in, so the safety of handwashing liquid also becomes one of focus.
Dioxanes, 1,4-dioxane, it is the surfactant by-product that oxirane generation dimerization produces in manufacture process containing polyoxyethylene ether structure, in usually said washing class shampoo, bath gel raw material, contain 1,4-dioxanes, actual be take oxirane or ethylene glycol in the surfactant of raw material production with.Dioxanes by sucking, eat, the approach such as percutaneous absorption enters in body, human body is had to anesthesia and stimulation, and has in vivo cumulative action.Human body contacts a large amount of dioxanes steams can cause that eye and upper respiratory tract stimulate, and with symptoms such as dizziness, headache, drowsiness, nauseating, vomitings, and can cause liver, skin lesion, and uremia even occurs.Dioxanes is irritant to skin, eye and respiratory system, and may cause damage to liver, kidney and nervous system, when acute poisoning, may cause death, is classified as carcinogen by the U.S..Late 1970s, U.S. FDA has just started 1 in cosmetics, 4-dioxane content to monitor.At present, due to raw-material technological problems, the overwhelming majority washes away class cosmetics and contains Isosorbide-5-Nitrae-dioxanes.Although these content that wash away the contained dioxanes of class cosmetics are lower, the accumulative effect that these products of life-time service cause is but very important, can impact health.
Therefore, need a kind of functional type handwashing liquid in daily life, this handwashing liquid can have the additional functions such as moist and handguard in clean spot, and does not contain dioxanes.
Summary of the invention
The object of this invention is to provide a kind of environmental protection handwashing liquid and preparation method thereof, in the raw material of this handwashing liquid, contain alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol, sodium citrate, lactic acid, hydroxypropyl cellulose, sodium chloride, BIT, essence, deionized water.This handwashing liquid is stopped to use any likely containing the raw material of the carcinogen such as dioxanes from raw material, the serviceability gentleness in generation, the raw material that zest is low, cost performance is high, this handwashing liquid is had use safe, by features such as rear skin moisturizing are smooth.
The object of the invention is to be realized by following technical proposals:
A kind of environmental protection handwashing liquid, in the raw material of this handwashing liquid, contain alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol, sodium citrate, lactic acid, hydroxypropyl cellulose, sodium chloride, BIT, deionized water; The weight ratio of each raw material of this handwashing liquid is:
Alkyl polyglucoside 4.0-10.0
Cocamido propyl betaine 5.0-20.0
Methyl sodiosul foaliphatate 2.0-5.0
Cocamidopropyl propyl amide amine oxide 6.0-20.0
Glycerol 0.5-1.5
Sodium citrate 0.5-2.0
Lactic acid 0.05-0.4
Hydroxypropyl cellulose 0.3-0.6
Sodium chloride 0.5-2.5
BIT 0.1
Essence 0.2
Deionized water 47-81;
The object of the invention is to be realized by following another technical scheme:
A kind of environmental protection handwashing liquid, in the raw material of this handwashing liquid, contain alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol, sodium citrate, lactic acid, hydroxypropyl cellulose, sodium chloride, BIT, essence, deionized water; The weight ratio of each raw material of this handwashing liquid is:
Alkyl polyglucoside 4.0-10.0
Cocamido propyl betaine 5.0-20.0
Methyl sodiosul foaliphatate 2.0-5.0
Cocamidopropyl propyl amide amine oxide 6.0-20.0
Glycerol 0.5-1.5
Sodium citrate 0.5-2.0
Lactic acid 0.05-0.4
Hydroxypropyl cellulose 0.3-0.6
Sodium chloride 0.5-2.5
BIT 0.1
Essence 0.2
Deionized water 47-81;
The step of this preparation method is as follows successively:
A, get 70%～85% in described deionized water according to above-mentioned weight proportion, add in material still, then add successively described alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol to dissolving completely according to said ratio respectively, obtain mixed liquor A;
B, according to above-mentioned weight proportion to adding described hydroxypropyl cellulose, sodium citrate, lactic acid, sodium chloride, BIT, essence, remaining described deionized water in described mixed liquor A, obtain described environmental protection handwashing liquid.
Compared with the prior art the present invention has following beneficial effect:
1, because the present invention select there is good soil release performance, calcium soap dispersibility, emulsibility, thickening property, stability in hard water, avirulence and the methyl sodiosul foaliphatate of biological degradability completely, foam is abundant, gentleness, the amphoteric surfactant cocamido propyl betaine of low stimulation, cocamidopropyl propyl amide amine oxide, coordinate with alkyl polyglucoside, synergism, so the present invention can, to hand decontamination, clean time, also have effect of gentle skin protection.
2, because the present invention selects glycerol, lactic acid to increase system moisture-retaining capacity, so the present invention uses rear skin not tight.
3, because good stability of the present invention, good water solubility, foam is abundant, easily rinses, moisturizing effect is remarkable, exists, so the present invention is environmentally friendly, nontoxic non-stimulated without dioxanes.
4, according to the detection method of standard GB/T/T 26388-2011 " the mensuration gas chromatography of dioxanes residual quantity in surfactant ", the present invention detects without dioxanes.
5, weigh detergency of the present invention and there is no national examination criteria.With reference to MILSTD: MIL-H-43606B(GL)-1977 nonaqueous lotion for hand 4.4.5.2 washing tests, with outstanding, good, medium, the inferior detergency of evaluating, detergency of the present invention is " outstanding ".
The specific embodiment
Embodiment 1:
A kind of environmental protection handwashing liquid, in the raw material of this handwashing liquid, contain alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol, sodium citrate, lactic acid, hydroxypropyl cellulose, sodium chloride, BIT, essence, deionized water; The weight ratio of each raw material of this handwashing liquid is:
Alkyl polyglucoside 4.0-10.0
Cocamido propyl betaine 5.0-20.0
Methyl sodiosul foaliphatate 2.0-5.0
Cocamidopropyl propyl amide amine oxide 6.0-20.0
Glycerol 0.5-1.5
Sodium citrate 0.5-2.0
Lactic acid 0.05-0.4
Hydroxypropyl cellulose 0.3-0.6
Sodium chloride 0.5-2.5
BIT 0.1
Essence 0.2
Deionized water 47-81;
The step of this preparation method is as follows successively:
A, get 70%～85% in described deionized water according to above-mentioned weight proportion, add in material still, then under agitation add successively described alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol to dissolving completely according to said ratio respectively, obtain mixed liquor A;
B, according to above-mentioned weight proportion to adding described hydroxypropyl cellulose, sodium citrate, lactic acid, sodium chloride, 1 in described mixed liquor A, 2-benzisothiazole-3-ketone, essence, remaining described deionized water, stir, obtain described environmental protection handwashing liquid.
The present embodiment unit of weight used is kilogram, can be also gram;
Essence described in the present embodiment is food stage, and other each raw materials are technical grade;
Each component described in the present embodiment is the conventional products of selling on market;
In the present embodiment, the each component in described detergent with sterilizing can be in the ratio range providing flexible combination, do not enumerate one by one at this.
The present embodiment select there is good soil release performance, calcium soap dispersibility, emulsibility, thickening property, stability in hard water, avirulence and the methyl sodiosul foaliphatate of biological degradability completely, foam is abundant, gentleness, the amphoteric surfactant cocamido propyl betaine of low stimulation, cocamidopropyl propyl amide amine oxide, coordinate with alkyl polyglucoside, synergism, so the handwashing liquid of the present embodiment can, to hand decontamination, clean time, also have effect of gentle skin protection.
The present embodiment selects glycerol, lactic acid to increase system moisture-retaining capacity, so the handwashing liquid of the present embodiment uses rear skin not tight.
The present embodiment good stability, good water solubility, foam is abundant, easily rinses, moisturizing effect is remarkable, exists, so the handwashing liquid of the present embodiment is environmentally friendly, nontoxic non-stimulated without dioxanes.
According to the detection method of standard GB/T/T 26388-2011 " the mensuration gas chromatography of dioxanes residual quantity in surfactant ", the handwashing liquid of the present embodiment detects without dioxanes.
The detergency of weighing the present embodiment there is no national examination criteria.With reference to MILSTD: MIL-H-43606B(GL)-1977 nonaqueous lotion for hand 4.4.5.2 washing tests, with outstanding, good, medium, the inferior detergency of evaluating, the detergency of the present embodiment is " outstanding ".
Embodiment 2:
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this handwashing liquid is:
Alkyl polyglucoside 10
Cocamido propyl betaine 10
Methyl sodiosul foaliphatate 3
Cocamidopropyl propyl amide amine oxide 6
Glycerol 1.5
Sodium citrate 2
Lactic acid 0.2
Hydroxypropyl cellulose 0.6
Sodium chloride 2.5
BIT 0.1
Essence 0.2
Deionized water 63.9.
The present embodiment unit of weight used is kilogram, can be also gram.
According to the detection method of standard GB/T/T 26388-2011 " the mensuration gas chromatography of dioxanes residual quantity in surfactant ", the handwashing liquid of the present embodiment detects without dioxanes.
The detergency of weighing the present embodiment there is no national examination criteria.With reference to MILSTD: MIL-H-43606B(GL)-1977 nonaqueous lotion for hand 4.4.5.2 washing tests, with outstanding, good, medium, the inferior detergency of evaluating, the detergency of the present embodiment is " outstanding ".
The preparation method of the present embodiment refers to embodiment 1.
Embodiment 3:
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this handwashing liquid is:
Alkyl polyglucoside 5
Cocamido propyl betaine 20
Methyl sodiosul foaliphatate 2
Cocamidopropyl propyl amide amine oxide 8
Glycerol 1.0
Sodium citrate 2
Lactic acid 0.4
Hydroxypropyl cellulose 0.3
Sodium chloride 2.0
BIT 0.1
Essence 0.2
Deionized water 59;
The present embodiment unit of weight used is kilogram, can be also gram.
According to the detection method of standard GB/T/T 26388-2011 " the mensuration gas chromatography of dioxanes residual quantity in surfactant ", the handwashing liquid of the present embodiment detects without dioxanes.
The detergency of weighing the present embodiment there is no national examination criteria.With reference to MILSTD: MIL-H-43606B(GL)-1977 nonaqueous lotion for hand 4.4.5.2 washing tests, with outstanding, good, medium, the inferior detergency of evaluating, the detergency of the present embodiment is " outstanding ".
The preparation method of the present embodiment refers to embodiment 1.
Embodiment 4:
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this handwashing liquid is:
Alkyl polyglucoside 5
Cocamido propyl betaine 10
Methyl sodiosul foaliphatate 5
Cocamidopropyl propyl amide amine oxide 6
Glycerol 1.5
Sodium citrate 1
Lactic acid 0.2
Hydroxypropyl cellulose 0.4
Sodium chloride 1.5
BIT 0.1
Essence 0.2
Deionized water 69.1;
The present embodiment unit of weight used is kilogram, can be also gram.
According to the detection method of standard GB/T/T 26388-2011 " the mensuration gas chromatography of dioxanes residual quantity in surfactant ", the handwashing liquid of the present embodiment detects without dioxanes.
The detergency of weighing the present embodiment there is no national examination criteria.With reference to MILSTD: MIL-H-43606B(GL)-1977 nonaqueous lotion for hand 4.4.5.2 washing tests, with outstanding, good, medium, the inferior detergency of evaluating, the detergency of the present embodiment is " outstanding ".
The preparation method of the present embodiment refers to embodiment 1.
Embodiment 5:
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this handwashing liquid is:
Alkyl polyglucoside 4
Cocamido propyl betaine 5
Methyl sodiosul foaliphatate 2
Cocamidopropyl propyl amide amine oxide 20
Glycerol 0.5
Sodium citrate 1
Lactic acid 0.05
Hydroxypropyl cellulose 0.3
Sodium chloride 1.5
BIT 0.1
Essence 0.2
Deionized water 65.35;
The present embodiment unit of weight used is kilogram, can be also gram.
According to the detection method of standard GB/T/T 26388-2011 " the mensuration gas chromatography of dioxanes residual quantity in surfactant ", the handwashing liquid of the present embodiment detects without dioxanes.
The detergency of weighing the present embodiment there is no national examination criteria.With reference to MILSTD: MIL-H-43606B(GL)-1977 nonaqueous lotion for hand 4.4.5.2 washing tests, with outstanding, good, medium, the inferior detergency of evaluating, the detergency of the present embodiment is " outstanding ".
The preparation method of the present embodiment refers to embodiment 1.
Embodiment 6:
The present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this handwashing liquid is:
Alkyl polyglucoside 10
Cocamido propyl betaine 20
Methyl sodiosul foaliphatate 5
Cocamidopropyl propyl amide amine oxide 6
Glycerol 1.5
Sodium citrate 1
Lactic acid 0.05
Hydroxypropyl cellulose 0.4
Sodium chloride 1.5
BIT 0.1
Essence 0.2
Deionized water 54.25.
The present embodiment unit of weight used is kilogram, can be also gram.
According to the detection method of standard GB/T/T 26388-2011 " the mensuration gas chromatography of dioxanes residual quantity in surfactant ", the handwashing liquid of the present embodiment detects without dioxanes.
The detergency of weighing the present embodiment there is no national examination criteria.With reference to MILSTD: MIL-H-43606B(GL)-1977 nonaqueous lotion for hand 4.4.5.2 washing tests, with outstanding, good, medium, the inferior detergency of evaluating, the detergency of the present embodiment is " outstanding ".
The preparation method of the present embodiment refers to embodiment 1.
Claims (5)
1. an environmental protection handwashing liquid, it is characterized in that: this handwashing liquid is made up of alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol, sodium citrate, lactic acid, hydroxypropyl cellulose, sodium chloride, BIT, essence, deionized water; The weight ratio of each raw material of this handwashing liquid is:
Alkyl polyglucoside 10
Cocamido propyl betaine 10
Methyl sodiosul foaliphatate 3
Cocamidopropyl propyl amide amine oxide 6
Glycerol 1.5
Sodium citrate 2
Lactic acid 0.2
Hydroxypropyl cellulose 0.6
Sodium chloride 2.5
BIT 0.1
Essence 0.2
Deionized water 63.9;
Described essence is food stage;
The preparation method of this handwashing liquid is:
A, get 70%～85% in described deionized water according to above-mentioned weight proportion, add in material still, then add successively described alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol to dissolving completely according to said ratio respectively, obtain mixed liquor A;
B, according to above-mentioned weight proportion to adding described hydroxypropyl cellulose, sodium citrate, lactic acid, sodium chloride, BIT, essence, remaining described deionized water in described mixed liquor A, obtain described environmental protection handwashing liquid.
2. an environmental protection handwashing liquid, it is characterized in that: this handwashing liquid is made up of alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol, sodium citrate, lactic acid, hydroxypropyl cellulose, sodium chloride, BIT, essence, deionized water; The weight ratio of each raw material of this handwashing liquid is:
Alkyl polyglucoside 5
Cocamido propyl betaine 20
Methyl sodiosul foaliphatate 2
Cocamidopropyl propyl amide amine oxide 8
Glycerol 1.0
Sodium citrate 2
Lactic acid 0.4
Hydroxypropyl cellulose 0.3
Sodium chloride 2
BIT 0.1
Essence 0.2
Deionized water 59;
Described essence is food stage;
The preparation method of this handwashing liquid is:
A, get 70%～85% in described deionized water according to above-mentioned weight proportion, add in material still, then add successively described alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol to dissolving completely according to said ratio respectively, obtain mixed liquor A;
B, according to above-mentioned weight proportion to adding described hydroxypropyl cellulose, sodium citrate, lactic acid, sodium chloride, BIT, essence, remaining described deionized water in described mixed liquor A, obtain described environmental protection handwashing liquid.
3. an environmental protection handwashing liquid, it is characterized in that: this handwashing liquid is made up of alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol, sodium citrate, lactic acid, hydroxypropyl cellulose, sodium chloride, BIT, essence, deionized water; The weight ratio of each raw material of this handwashing liquid is:
Alkyl polyglucoside 5
Cocamido propyl betaine 10
Methyl sodiosul foaliphatate 5
Cocamidopropyl propyl amide amine oxide 6
Glycerol 1.5
Sodium citrate 1
Lactic acid 0.2
Hydroxypropyl cellulose 0.4
Sodium chloride 1.5
BIT 0.1
Essence 0.2
Deionized water 69.1;
Described essence is food stage;
The preparation method of this handwashing liquid is:
A, get 70%～85% in described deionized water according to above-mentioned weight proportion, add in material still, then add successively described alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol to dissolving completely according to said ratio respectively, obtain mixed liquor A;
B, according to above-mentioned weight proportion to adding described hydroxypropyl cellulose, sodium citrate, lactic acid, sodium chloride, BIT, essence, remaining described deionized water in described mixed liquor A, obtain described environmental protection handwashing liquid.
4. an environmental protection handwashing liquid, it is characterized in that: this handwashing liquid is made up of alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol, sodium citrate, lactic acid, hydroxypropyl cellulose, sodium chloride, BIT, essence, deionized water; The weight ratio of each raw material of this handwashing liquid is:
Alkyl polyglucoside 4
Cocamido propyl betaine 5
Methyl sodiosul foaliphatate 2
Cocamidopropyl propyl amide amine oxide 20
Glycerol 0.5
Sodium citrate 1
Lactic acid 0.05
Hydroxypropyl cellulose 0.3
Sodium chloride 1.5
BIT 0.1
Essence 0.2
Deionized water 65.35.
5. an environmental protection handwashing liquid, it is characterized in that: this handwashing liquid is made up of alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol, sodium citrate, lactic acid, hydroxypropyl cellulose, sodium chloride, BIT, essence, deionized water; The weight ratio of each raw material of this handwashing liquid is:
Alkyl polyglucoside 10
Cocamido propyl betaine 20
Methyl sodiosul foaliphatate 5
Cocamidopropyl propyl amide amine oxide 6
Glycerol 1.5
Sodium citrate 1
Lactic acid 0.05
Hydroxypropyl cellulose 0.4
Sodium chloride 1.5
BIT 0.1
Essence 0.2
Deionized water 54.25;
Described essence is food stage;
The preparation method of this handwashing liquid is:
A, get 70%～85% in described deionized water according to above-mentioned weight proportion, add in material still, then add successively described alkyl polyglucoside, cocamido propyl betaine, methyl sodiosul foaliphatate, cocamidopropyl propyl amide amine oxide, glycerol to dissolving completely according to said ratio respectively, obtain mixed liquor A;
B, according to above-mentioned weight proportion to adding described hydroxypropyl cellulose, sodium citrate, lactic acid, sodium chloride, BIT, essence, remaining described deionized water in described mixed liquor A, obtain described environmental protection handwashing liquid.
Priority Applications (1)
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| CN201110449959.XA CN102429833B (en) | 2011-12-29 | 2011-12-29 | Environmentally-friendly hand sanitizer and preparation method thereof |
Applications Claiming Priority (1)
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| CN201110449959.XA CN102429833B (en) | 2011-12-29 | 2011-12-29 | Environmentally-friendly hand sanitizer and preparation method thereof |
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| CN102429833A CN102429833A (en) | 2012-05-02 |
| CN102429833B true CN102429833B (en) | 2014-05-14 |
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| CN103194328B (en) * | 2013-04-28 | 2014-12-24 | 北京绿伞化学股份有限公司 | Cosolvent-free high-power concentrated detergent and preparation method thereof |
| AU2014271195A1 (en) * | 2013-05-23 | 2016-01-21 | Cafetto Pty Ltd | Milk frother cleaning composition |
| CN104257563A (en) * | 2014-10-16 | 2015-01-07 | 李正梅 | Creeping falsepimpernel herb hand sanitizer and preparation method thereof |
| GB2534355B (en) | 2015-01-09 | 2017-04-05 | Ryan Sy Von | A composition, method, apparatus for a sprayable cleaning product |
| CN104983588B (en) * | 2015-07-13 | 2018-04-06 | 于文 | Children's bacteriostatic skin-care hand cleanser containing soft pearl and preparation method thereof |
| US20170044471A1 (en) * | 2015-08-14 | 2017-02-16 | The Sun Products Corporation | Sulfate-Free Liquid Laundry Detergent |
| CN108434006A (en) * | 2017-02-16 | 2018-08-24 | 天津国际生物医药联合研究院 | A kind of leakage of liquid and preparation method thereof of prevention hand-foot-and-mouth disease |
| WO2019166865A1 (en) * | 2018-02-28 | 2019-09-06 | Clensta International Private Limited | Rinse-free bathing composition |
| CN108721129A (en) * | 2018-08-24 | 2018-11-02 | 上海理工大学 | A kind of antibacterial moisturizing Non-water washing hand cleanser and preparation method thereof |
| CN110664623A (en) * | 2019-11-18 | 2020-01-10 | 浙江绿岛科技有限公司 | Aerosol type alcohol-free wash-free antibacterial hand sanitizer and preparation method thereof |
| CN113512474A (en) * | 2021-08-17 | 2021-10-19 | 山东洁立来生态科技有限公司 | Ecological and environment-friendly washing composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1003242B (en) * | 1987-01-03 | 1989-02-08 | 唐伯飞 | Hand sanitizer and preparation method thereof |
| US5994383A (en) * | 1997-11-18 | 1999-11-30 | Woodward Laboratories, Inc. | Surfactant-based antimicrobial compositions and methods for using the same |
| CN1103367C (en) * | 1998-08-14 | 2003-03-19 | 凌沛学 | Sterilizing liquid containing transparent sodium hyaluronate for washing hand and its preparing process |
| DE19916036A1 (en) * | 1999-04-09 | 2000-10-12 | Cognis Deutschland Gmbh | Hand washing pastes |
| WO2002038714A1 (en) * | 2000-11-08 | 2002-05-16 | Nof Corporation | Detergent composition |
| US7776346B2 (en) * | 2003-05-22 | 2010-08-17 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Personal product compositions comprising structured benefit agent premix or delivery vehicle |
| US8043637B2 (en) * | 2009-06-15 | 2011-10-25 | The Dial Corporation | Combinations of herb extracts having synergistic antioxidant effect, and methods relating thereto |
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