CN102416735B - Hierarchical coating ultraviolet-resistant composite fabric - Google Patents
Hierarchical coating ultraviolet-resistant composite fabric Download PDFInfo
- Publication number
- CN102416735B CN102416735B CN2011102610484A CN201110261048A CN102416735B CN 102416735 B CN102416735 B CN 102416735B CN 2011102610484 A CN2011102610484 A CN 2011102610484A CN 201110261048 A CN201110261048 A CN 201110261048A CN 102416735 B CN102416735 B CN 102416735B
- Authority
- CN
- China
- Prior art keywords
- fabric
- warp
- fiber
- fibre
- ultra
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to a hierarchical coating ultraviolet-resistant composite fabric, which is used for overcoming the defects of no air permeability or moisture permeability, poor hygroscopicity, poor air permeability, poor ultraviolet resistance and poor comfort existing in the prior art. The invention aims to design a hierarchical coating ultraviolet-resistant composite fabric, which meets the special requirement of ultraviolet radiation resistance. Due to the adoption of a special hierarchical coating structural textile, superior air permeability, moisture permeability, hygroscopicity, resistance to static electricity, radiation and ultraviolet rays, and high comfort of the fabric can be realized.
Description
Technical field
The invention belongs to a kind of senior weaving face fabric technical field, relate to a kind of composite fabric, especially relate to a kind of hierarchical coating ultraviolet-resistant composite fabric.
Background technology
At present, due to the change of ecological environment, cause the amount of radiation on the ultraviolet ray arrival ground in sunshine to increase, and the serious health that affects human body of ultraviolet too much irradiation.Along with improving constantly that people's self-protection is realized, ultraviolet protection question comes on referred agenda gradually.People are more and more higher to the requirement of fabric and various protective materials, require fabric to have various functional; Require various protective articles except having its safeguard function that should have, also should be personalized, can be suitable for people to requirement attractive in appearance.Therefore the fiber that has the people will have the uv reflectance function is made into cloth, and this fabric has just had anti-ultraviolet performance, but this processing mode, all influential to fabrication processes and equipment, and cost is high, therefore up to the present, and the domestic industrialization product that there is not yet.Also there is the people to plate layer of metal film at polymer surfaces, change its anti-ultraviolet property, but the material feel that this mode makes is not good enough, outward appearance is single, and due to metal coating have not corrosion-resistant, easily lose reflective characteristic, transcalent shortcoming, so on the scope of application, be restricted, be difficult to large-scale popularization.
Ultraviolet ray in sunshine is a kind of not visible electromagnetic wave, by wavelength, is divided into tri-kinds of UVA, UVB, UVC.Destruction along with atmospheric ozone layer, the energy that harmful ultraviolet (UV) A, UVB arrives ground strengthens, as people be subjected to after this band ultraviolet radiation that skin is can be rapidly aging, skin turgor or play blister, even suffer from lupus erythematosus and skin cancer, be called as stealthy killer.The expert experiment showed, that solar keratosis 20% can develop the cutification cancer, how to change ecological environment, prevents that the radiation of ultraviolet (UV) B, UVA from becoming the focus of current life science.In addition, due to summer high temperature also can bring various diseases to the people, high temperature is mainly from visible light, near infrared ray, therefore how to have addressed these problems into a world-famous puzzle.
In the prior art, many patent documentations have all been done report and research to this, as JP4333661, JP-4-289268, JP-5-9871, JP-5-179568 etc., these patents can be divided into two large series, the one, reflective agent and absorbent are sneaked in fiber and made anti-ultraviolet fibre, the 2nd, absorbent etc. is coated on fabric with coating, these two kinds of methods all exist the eternal transmitance of fibre larger, and effect is poor and fastness is bad, the disadvantages such as feel is poor, thereby can not become colory garment material.
At present, the conventional method of stamp is a lot of on leather, silk, soft fabric face, and the product style is also many.The making very complex of traditional product, from retouching master proof, plate-making, stamp, drying, decatize, solidify, open washing, dryness finalization etc. are indispensable, as long as in these programs, have on a program and gone out mistake, product has namely become substandard products, or even become waste product, and finished product has destroyed original pattern soon through with large natural environment, contact and washing etc., causing to fade, and the color of product is fixed, and gives dull, blunt sensation.Add the three wastes that the overall process of manufacture causes quite serious, destroyed the Nature ecological environment.
As everyone knows, traditional cotton knitted fabric due to its existence crease easily distortion, fugitive color, easily shrink and the defect such as not wear-resisting; And general nylon knit fabric sense of touch is hard, moisture permeability is poor.
Supple is the specifically developed high strength of the softness of cotton products, smooth sense of touch and nylon and the fiber of durability of integrating of E.I.Du Pont Company, it has following characteristic: 1. tortuous rigidity, lower than most of fibers such as wool, terylene and cottons, has cotton general feel and submissive; 2. good hygroscopicity, be only second to viscose glue in chemical fibre; 3. quality is light, and intensity and wearability surpass terylene; 4. elasticity is recovered to be only second to wool and acrylic fibers, is better than other chemical fibre; 5. the clothes of making do not crease easily, shrink-proof, indeformable, easy drying, easily maintenance; 6. dyeability is better, not fugitive color etc.
Reported that poly-benzo-dioxazole (PBO) fiber and poly-two imidazoles are for anti-cutting, anti-nail hooking (spike resistant) or ballistic fiber.Total referring to U.S. Patent application 2005/0003727, PCT patent application WO2005002376, WO2004018754 and WO2005/001373.
U.S. Patent application 2003/0228812 discloses polybenzimidazoles (PBI) and the purposes of pbo fiber in protective clothes.PCT patent application WO2004023909 discloses polybenzimidazoles and poly-(to the phenylene benzo-dioxazole) fiber and the purposes of long filament in fabric.The mixture of aramid fibre and pbo fiber has been reported in a plurality of patents and patent application.Referring to U.S. Patent application 2005/0065146,2003/0228821 and 2003/0203690 and United States Patent (USP) 5,233,821,6,624,096 and 6,914,022.In addition, the general and aromatic polyamides blend of PBI fibre in commercially available fabric.But above-mentioned polybenzimidazoles is for gathering biphenyl imidazoles (polybibenzimidazole) polymer and not being the rigid rod polymer.Therefore, with the rigid rod polymer, compare, this fibre strength is low.
The heat-proof combustion-resistant protective clothes has been used for saving life and has reduced the injury that causes due to fiery and other incident heats by fire fighter, emergency worker, soldier and competition personnel.Although polyphenyl dioxazole fibre dimension has high strength and good anti-flammability, the impact that the fabric that is prepared by this fiber and clothes are subject to ultraviolet (UV) line very much, cause fibre strength seriously to reduce, the durability that therefore endangers fabric and clothes.Also wish the polypyridobisimidazo/e /e fiber is attached in fabric and clothes to utilize the fire-retardant and high strength of this fiber excellence.Therefore, need a kind of poly-benzo-dioxazole of UV resistant and fabric of polypyridobisimidazo/e /e fiber of comprising, the outer shell fabric as clothes is more durable thus, and excellent anti-flammability is provided simultaneously.
Up to now, there is a large amount of methods to be used for manufacturing that can clean and fabric anti-liquid, in order to make it more useful in the environment that liquid stains may occur.Vinyl coated fabric is widely used in these purposes due to relatively easy to clean and quite low cost most.These fabrics are generally by at the upper application of lax type fabric (open scrim-type fabric) vinyl coating, manufacturing, and this vinyl surface formation outer surface or the surface that contacts with the user.Yet this vinyl coated fabric is general to be touched somewhat hard, therefore lacks the desired outward appearance of some environment for use and sense of touch, and these environment are for example automobile, restaurant, sanatorium and similarly need to make user's sense of touch and the satisfied environment of vision.In addition, vinyl can make user's skin uncomfortable, and because it forms continuous, an air-locked surface, and it can cause gathering of sweat between user and seat.In addition, it is very hot that vinyl surface can become, and uncomfortable or be sitting in even in some cases above can agonize.
Surface laminated fabrics has been used to strengthen the aesthetic property of fabric, but because general separation property between laminated film and fabric itself is bonding, these products are tending towards peeling off, ftracture and delamination after long-term the use.Such laminate product also lacks the sense of touch of the general expectation of indoor ornament of standard.In addition, when application fluoride antifouling treatment agent, anti-liquid permeable membrane or coating are bonding more difficult to fabric, because this composition is tending towards repelling applied coating in essence.
When overcoming many shortcomings of above-mentioned prior art material, the pliability of the fabric of producing with present method and the optimization requirement that pliability does not reach some final application have been found, the especially for example application of the seats of vehicle of complicated shape structure or analog.Although (above explanation relates to automobile and truck to a certain extent, term used herein " seats of vehicle " is seat or other surf zone that will comprise all types vehicles, and these vehicles include but not limited to machinery and the analog of ship, aircraft, helicopter, Bicycles and Motorcycles, train, for example tractor, bull-dozer).
for obtaining to have the fabric of some above-mentioned desirable characteristics, a kind of method of having developed is at the common transfer of being submitted to May 23 calendar year 2001 by people such as DeMott, common unsettled U.S. Patent application the 09/864th, explanation in No. 461, this application is the common unsettled U.S. Patent application the 09/625th of submitting on July 25th, 2000, the part of No. 474 continues, U.S. Patent application the 09/625th, No. 474 is the U.S. Patent application the 09/286th of submitting on April 6th, 1999, No. 797, and on October 24th, 2000, license to Kimbrell, Jr. wait people's United States Patent (USP) the 6th, 136, the continuation of No. 730, United States Patent (USP) the 6th, 136, No. 730 is the U.S. Patent application the 08/799th of submitting on February 12nd, 1997, No. 790, and on May 4th, 1999, license to Kimbrell, Jr. wait people's United States Patent (USP) the 5th, 899, the part of No. 783 continues.These documents all are incorporated herein by reference at this paper.
(that is, UV) stability is the problem that multiple indoor and outdoor utility wish solve, and for example, banner, indicate wall cloth, geotextile, and automobile and vessel inner fabric in order to make fabric obtain long-term ultraviolet ray.
A kind of method that makes fabric obtain long-term UV stability is in fiber is synthetic, the UV stabilizing agent being added to single fiber.Yet the amount that directly is added to the UV stabilizing agent in fiber is subject to for example fibrous, fiber thickness, the solubility in fibrous material, and with the compatibility of fibrous material in the restriction of one or more factors.In addition, a large amount of UV stabilizing agents is added in fiber and can weakens fiber by physics, and in some cases, the UV stabilizing agent can not stand to manufacture the processing conditions of fiber.For example, UV line stabilization agent can not stand common high temperature used in manufacturing melt-blown nonwoven fabric.
The another kind of method that makes fabric obtain stability is UV line stabilization agent to be applied into basically to fiber coat (for example, by saturated coating or spraying) uniformly on fiber or fabric.Yet, for obtaining long-term UV stability applies on fiber surface relatively a large amount of UV stabilizing agents, performance is changed, for example, afterwards the surface of coating (for example, printing ink) can and cohesive changed.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of hierarchical coating ultraviolet-resistant composite fabric, overcome ventilative poor, uvioresistant is poor, comfortableness the is poor shortcoming of airtight wet, moisture absorption of the prior art, the objective of the invention is by designing a kind of hierarchical coating ultraviolet-resistant composite fabric, not only make this fabric meet the radiation-resistant needs of its special uvioresistant, its special hierarchical coating construction fabric also can realize simultaneously that the good air-moisture-permeable of fabric, moisture absorption are ventilative, antistatic radiation proof uvioresistant, performance that comfortableness is good.
For achieving the above object, the present invention is achieved by the following technical solutions:
A kind of hierarchical coating ultraviolet-resistant composite fabric of the present invention, it is characterized in that: bottom is woven fabric, warp thread is that bamboo fibre, acid fiber by polylactic, milk protein fiber, chitin fiber are 1.5: 2.5: 1 according to fineness ratio respectively: 2, weight ratio is 24: 23: 49: 48, and to become the English number be that 22s, twist factor are 436 yarn for be 58～65N warping, sizing, denting blending through the winder tensile stress; Weft yarn is that bamboo fibre, superhigh molecular weight polyethylene fibers, milk protein fiber, anti pilling hollow chitin fiber are 2.5: 1.5: 2 according to fineness ratio respectively: 1, weight ratio is 23: 24: 48: 49, and to become the English number be 20 for be 67～85N warping, sizing, denting blending through the winder tensile stress
s, twist factor is 466 yarn; On the warp-wise of this woven fabric and broadwise, all every 6～8mm, being embedded with a specific insulation is 1.32 * 10
-316 plying ultra-high count yarns in Europe centimetre; Warp-wise density is 1050/10cm, and latitudinal density is 997/10cm, weight per square meter 65 grams;
Intermediate layer is double-deck warp-knitted fabric, and one deck of this bilayer warp-knitted fabric adopts eight line braidings, knitting needle odd numbers to classify a high position as and even number is classified room as separately, and cloth cover produces two every two ultra-thin tissue; Another layer adopts 18 line braidings, knitting needle to classify a high position as and even number is classified low level as separately at odd number, and cloth cover produces ultra-thin mesh tissue, and raw yarn is 1.26 * 10 by specific insulation
-4Europe centimetre, fineness are that carbon fiber and the specific insulation of 12D is 1.26 * 10
-6Europe centimetre, fineness are that the stainless steel fibre of 8D is that blending in 3.5: 5 forms according to weight ratio respectively;
skin is adhesive-bonded fabric, by polyester, polypropylene, benzimidazole, the polyarylene hydrocarbon, pi copolyesters separately jointly mixes and spins hollow fibre filament with graphite powder, this doughnut filament diameter is 0.4mm, aperture is 4um, then the alginate short fiber that by hollow fibre filament and calcium ion weight ratio is 44: 56 mixes, the gained composite fibre is carried out combing through carding machine and is formed the mat net, by lapping machine, mat stratum reticulare layer laying reached to the feltwork that thickness is 0.11mm～0.12mm, by needing machine, feltwork is carried out to acupuncture, making filament carry out 3～5 times connects fully mutually, by the hollow fibre filament felt heat hot phase-splitting after acupuncture, send into again leaching in the strong acid groove, then with the hollow fibre filament felt after 6～8 cleaning leachings of pure water, by containing neutralization solution, process again, dry, dried hollow fibre filament felt was carried out to sintering by heat-treatment furnace in 15～18 minutes 1150～1200 ℃ of heat treated,
Wherein bottom, intermediate layer and skin all will be interweaved and be connected by viscose fibre, before the connection that interweaves, bottom, intermediate layer and outer field fabric be applied by following step respectively successively:
One, by 6.0 grams 4,4 '-diaminodiphenyl ether and the full and uniform mixing of 14.48 gram DADPS, maintain the temperature at 65 ℃ and carried out uniform stirring 20 minutes, adds 18.0 gram magnesium hydrate powders, adopting rotating speed is the high-speed emulsifying machine high speed shear dispersion 45min of 150000r/min, add 4.18 gram pyromellitic acid anhydride powder, at 65 ℃ of temperature, stirring reaction is 35 minutes, cooling 5 minutes, standing 4 hours, filter, drying, obtain fire-retardant powder;
Two, the fire-retardant powder in step 1 is passed through to high-pressure spraying machine, evenly spray three layers of fire-retardant powder on bottom, intermediate layer and outer field fabric.
As preferred technical scheme:
On the warp-wise of bottom woven fabric and broadwise, all every 6.5mm, being embedded with a specific insulation is 1.32 * 10
-316 plying ultra-high count yarns in Europe centimetre.
On the warp-wise of bottom woven fabric and broadwise, all every 7mm, being embedded with a specific insulation is 1.32 * 10
-316 plying ultra-high count yarns in Europe centimetre.
On the warp-wise of bottom woven fabric and broadwise, all every 7.5mm, being embedded with a specific insulation is 1.32 * 10
-316 plying ultra-high count yarns in Europe centimetre.
The specific embodiment
Below in conjunction with the specific embodiment, further set forth the present invention.
Embodiment 1:
A kind of hierarchical coating ultraviolet-resistant composite fabric, it is characterized in that: bottom is woven fabric, warp thread is that bamboo fibre, acid fiber by polylactic, milk protein fiber, chitin fiber are 1.5: 2.5: 1 according to fineness ratio respectively: 2, weight ratio is 24: 23: 49: 48, and to become the English number be that 22s, twist factor are 436 yarn for be 58～65N warping, sizing, denting blending through the winder tensile stress; Weft yarn is that bamboo fibre, superhigh molecular weight polyethylene fibers, milk protein fiber, anti pilling hollow chitin fiber are 2.5: 1.5: 2 according to fineness ratio respectively: 1, weight ratio is 23: 24: 48: 49, and to become the English number be 20 for be 67～85N warping, sizing, denting blending through the winder tensile stress
s, twist factor is 466 yarn; On the warp-wise of this woven fabric and broadwise, all every 6mm, being embedded with a specific insulation is 1.32 * 10
-316 plying ultra-high count yarns in Europe centimetre; Warp-wise density is 1050/10cm, and latitudinal density is 997/10cm, weight per square meter 65 grams;
Intermediate layer is double-deck warp-knitted fabric, and one deck of this bilayer warp-knitted fabric adopts eight line braidings, knitting needle odd numbers to classify a high position as and even number is classified room as separately, and cloth cover produces two every two ultra-thin tissue; Another layer adopts 18 line braidings, knitting needle to classify a high position as and even number is classified low level as separately at odd number, and cloth cover produces ultra-thin mesh tissue, and raw yarn is 1.26 * 10 by specific insulation
-4Europe centimetre, fineness are that carbon fiber and the specific insulation of 12D is 1.26 * 10
-6Europe centimetre, fineness are that the stainless steel fibre of 8D is that blending in 3.5: 5 forms according to weight ratio respectively;
skin is adhesive-bonded fabric, by polyester, polypropylene, benzimidazole, the polyarylene hydrocarbon, pi copolyesters separately jointly mixes and spins hollow fibre filament with graphite powder, this doughnut filament diameter is 0.4mm, aperture is 4um, then the alginate short fiber that by hollow fibre filament and calcium ion weight ratio is 44: 56 mixes, the gained composite fibre is carried out combing through carding machine and is formed the mat net, by lapping machine, mat stratum reticulare layer laying reached to the feltwork that thickness is 0.11mm～0.12mm, by needing machine, feltwork is carried out to acupuncture, making filament carry out 3～5 times connects fully mutually, by the hollow fibre filament felt heat hot phase-splitting after acupuncture, send into again leaching in the strong acid groove, then with the hollow fibre filament felt after 6～8 cleaning leachings of pure water, by containing neutralization solution, process again, dry, dried hollow fibre filament felt was carried out to sintering by heat-treatment furnace in 15～18 minutes 1150～1200 ℃ of heat treated,
Wherein bottom, intermediate layer and skin all will be interweaved and be connected by viscose fibre, before the connection that interweaves, bottom, intermediate layer and outer field fabric be applied by following step respectively successively:
One, by 6.0 grams 4,4 '-diaminodiphenyl ether and the full and uniform mixing of 14.48 gram DADPS, maintain the temperature at 65 ℃ and carried out uniform stirring 20 minutes, adds 18.0 gram magnesium hydrate powders, adopting rotating speed is the high-speed emulsifying machine high speed shear dispersion 45min of 150000r/min, add 4.18 gram pyromellitic acid anhydride powder, at 65 ℃ of temperature, stirring reaction is 35 minutes, cooling 5 minutes, standing 4 hours, filter, drying, obtain fire-retardant powder;
Two, the fire-retardant powder in step 1 is passed through to high-pressure spraying machine, evenly spray three layers of fire-retardant powder on bottom, intermediate layer and outer field fabric.
Embodiment 2:
A kind of hierarchical coating ultraviolet-resistant composite fabric, it is characterized in that: bottom is woven fabric, warp thread is that bamboo fibre, acid fiber by polylactic, milk protein fiber, chitin fiber are 1.5: 2.5: 1 according to fineness ratio respectively: 2, weight ratio is 24: 23: 49: 48, and to become the English number be that 22s, twist factor are 436 yarn for be 58～65N warping, sizing, denting blending through the winder tensile stress; Weft yarn is that bamboo fibre, superhigh molecular weight polyethylene fibers, milk protein fiber, anti pilling hollow chitin fiber are 2.5: 1.5: 2 according to fineness ratio respectively: 1, weight ratio is 23: 24: 48: 49, and to become the English number be 20 for be 67～85N warping, sizing, denting blending through the winder tensile stress
s, twist factor is 466 yarn; On the warp-wise of this woven fabric and broadwise, all every 6.5mm, being embedded with a specific insulation is 1.32 * 10
-316 plying ultra-high count yarns in Europe centimetre; Warp-wise density is 1050/10cm, and latitudinal density is 997/10cm, weight per square meter 65 grams;
Intermediate layer is double-deck warp-knitted fabric, and one deck of this bilayer warp-knitted fabric adopts eight line braidings, knitting needle odd numbers to classify a high position as and even number is classified room as separately, and cloth cover produces two every two ultra-thin tissue; Another layer adopts 18 line braidings, knitting needle to classify a high position as and even number is classified low level as separately at odd number, and cloth cover produces ultra-thin mesh tissue, and raw yarn is 1.26 * 10 by specific insulation
-4Europe centimetre, fineness are that carbon fiber and the specific insulation of 12D is 1.26 * 10
-6Europe centimetre, fineness are that the stainless steel fibre of 8D is that blending in 3.5: 5 forms according to weight ratio respectively;
skin is adhesive-bonded fabric, by polyester, polypropylene, benzimidazole, the polyarylene hydrocarbon, pi copolyesters separately jointly mixes and spins hollow fibre filament with graphite powder, this doughnut filament diameter is 0.4mm, aperture is 4um, then the alginate short fiber that by hollow fibre filament and calcium ion weight ratio is 44: 56 mixes, the gained composite fibre is carried out combing through carding machine and is formed the mat net, by lapping machine, mat stratum reticulare layer laying reached to the feltwork that thickness is 0.11mm～0.12mm, by needing machine, feltwork is carried out to acupuncture, making filament carry out 3～5 times connects fully mutually, by the hollow fibre filament felt heat hot phase-splitting after acupuncture, send into again leaching in the strong acid groove, then with the hollow fibre filament felt after 6～8 cleaning leachings of pure water, by containing neutralization solution, process again, dry, dried hollow fibre filament felt was carried out to sintering by heat-treatment furnace in 15～18 minutes 1150～1200 ℃ of heat treated,
Wherein bottom, intermediate layer and skin all will be interweaved and be connected by viscose fibre, before the connection that interweaves, bottom, intermediate layer and outer field fabric be applied by following step respectively successively:
One, by 6.0 grams 4,4 '-diaminodiphenyl ether and the full and uniform mixing of 14.48 gram DADPS, maintain the temperature at 65 ℃ and carried out uniform stirring 20 minutes, adds 18.0 gram magnesium hydrate powders, adopting rotating speed is the high-speed emulsifying machine high speed shear dispersion 45min of 150000r/min, add 4.18 gram pyromellitic acid anhydride powder, at 65 ℃ of temperature, stirring reaction is 35 minutes, cooling 5 minutes, standing 4 hours, filter, drying, obtain fire-retardant powder;
Two, the fire-retardant powder in step 1 is passed through to high-pressure spraying machine, evenly spray three layers of fire-retardant powder on bottom, intermediate layer and outer field fabric.
Embodiment 3:
A kind of hierarchical coating ultraviolet-resistant composite fabric, it is characterized in that: bottom is woven fabric, warp thread is that bamboo fibre, acid fiber by polylactic, milk protein fiber, chitin fiber are 1.5: 2.5: 1 according to fineness ratio respectively: 2, weight ratio is 24: 23: 49: 48, and to become the English number be that 22s, twist factor are 436 yarn for be 58～65N warping, sizing, denting blending through the winder tensile stress; Weft yarn is that bamboo fibre, superhigh molecular weight polyethylene fibers, milk protein fiber, anti pilling hollow chitin fiber are 2.5: 1.5: 2 according to fineness ratio respectively: 1, weight ratio is 23: 24: 48: 49, and to become the English number be 20 for be 67～85N warping, sizing, denting blending through the winder tensile stress
s, twist factor is 466 yarn; On the warp-wise of this woven fabric and broadwise, all every 7mm, being embedded with a specific insulation is 1.32 * 10
-316 plying ultra-high count yarns in Europe centimetre; Warp-wise density is 1050/10cm, and latitudinal density is 997/10cm, weight per square meter 65 grams;
Intermediate layer is double-deck warp-knitted fabric, and one deck of this bilayer warp-knitted fabric adopts eight line braidings, knitting needle odd numbers to classify a high position as and even number is classified room as separately, and cloth cover produces two every two ultra-thin tissue; Another layer adopts 18 line braidings, knitting needle to classify a high position as and even number is classified low level as separately at odd number, and cloth cover produces ultra-thin mesh tissue, and raw yarn is 1.26 * 10 by specific insulation
-4Europe centimetre, fineness are that carbon fiber and the specific insulation of 12D is 1.26 * 10
-6Europe centimetre, fineness are that the stainless steel fibre of 8D is that blending in 3.5: 5 forms according to weight ratio respectively;
skin is adhesive-bonded fabric, by polyester, polypropylene, benzimidazole, the polyarylene hydrocarbon, pi copolyesters separately jointly mixes and spins hollow fibre filament with graphite powder, this doughnut filament diameter is 0.4mm, aperture is 4um, then the alginate short fiber that by hollow fibre filament and calcium ion weight ratio is 44: 56 mixes, the gained composite fibre is carried out combing through carding machine and is formed the mat net, by lapping machine, mat stratum reticulare layer laying reached to the feltwork that thickness is 0.11mm～0.12mm, by needing machine, feltwork is carried out to acupuncture, making filament carry out 3～5 times connects fully mutually, by the hollow fibre filament felt heat hot phase-splitting after acupuncture, send into again leaching in the strong acid groove, then with the hollow fibre filament felt after 6～8 cleaning leachings of pure water, by containing neutralization solution, process again, dry, dried hollow fibre filament felt was carried out to sintering by heat-treatment furnace in 15～18 minutes 1150～1200 ℃ of heat treated,
Wherein bottom, intermediate layer and skin all will be interweaved and be connected by viscose fibre, before the connection that interweaves, bottom, intermediate layer and outer field fabric be applied by following step respectively successively:
One, by 6.0 grams 4,4 '-diaminodiphenyl ether and the full and uniform mixing of 14.48 gram DADPS, maintain the temperature at 65 ℃ and carried out uniform stirring 20 minutes, adds 18.0 gram magnesium hydrate powders, adopting rotating speed is the high-speed emulsifying machine high speed shear dispersion 45min of 150000r/min, add 4.18 gram pyromellitic acid anhydride powder, at 65 ℃ of temperature, stirring reaction is 35 minutes, cooling 5 minutes, standing 4 hours, filter, drying, obtain fire-retardant powder;
Two, the fire-retardant powder in step 1 is passed through to high-pressure spraying machine, evenly spray three layers of fire-retardant powder on bottom, intermediate layer and outer field fabric.
Embodiment 4:
A kind of hierarchical coating ultraviolet-resistant composite fabric, it is characterized in that: bottom is woven fabric, warp thread is that bamboo fibre, acid fiber by polylactic, milk protein fiber, chitin fiber are 1.5: 2.5: 1 according to fineness ratio respectively: 2, weight ratio is 24: 23: 49: 48, and to become the English number be that 22s, twist factor are 436 yarn for be 58～65N warping, sizing, denting blending through the winder tensile stress; Weft yarn is that bamboo fibre, superhigh molecular weight polyethylene fibers, milk protein fiber, anti pilling hollow chitin fiber are 2.5: 1.5: 2 according to fineness ratio respectively: 1, weight ratio is 23: 24: 48: 49, and to become the English number be 20 for be 67～85N warping, sizing, denting blending through the winder tensile stress
s, twist factor is 466 yarn; On the warp-wise of this woven fabric and broadwise, all every 7.5mm, being embedded with a specific insulation is 1.32 * 10
-316 plying ultra-high count yarns in Europe centimetre; Warp-wise density is 1050/10cm, and latitudinal density is 997/10cm, weight per square meter 65 grams;
Intermediate layer is double-deck warp-knitted fabric, and one deck of this bilayer warp-knitted fabric adopts eight line braidings, knitting needle odd numbers to classify a high position as and even number is classified room as separately, and cloth cover produces two every two ultra-thin tissue; Another layer adopts 18 line braidings, knitting needle to classify a high position as and even number is classified low level as separately at odd number, and cloth cover produces ultra-thin mesh tissue, and raw yarn is 1.26 * 10 by specific insulation
-4Europe centimetre, fineness are that carbon fiber and the specific insulation of 12D is 1.26 * 10
-6Europe centimetre, fineness are that the stainless steel fibre of 8D is that blending in 3.5: 5 forms according to weight ratio respectively;
skin is adhesive-bonded fabric, by polyester, polypropylene, benzimidazole, the polyarylene hydrocarbon, pi copolyesters separately jointly mixes and spins hollow fibre filament with graphite powder, this doughnut filament diameter is 0.4mm, aperture is 4um, then the alginate short fiber that by hollow fibre filament and calcium ion weight ratio is 44: 56 mixes, the gained composite fibre is carried out combing through carding machine and is formed the mat net, by lapping machine, mat stratum reticulare layer laying reached to the feltwork that thickness is 0.11mm～0.12mm, by needing machine, feltwork is carried out to acupuncture, making filament carry out 3～5 times connects fully mutually, by the hollow fibre filament felt heat hot phase-splitting after acupuncture, send into again leaching in the strong acid groove, then with the hollow fibre filament felt after 6～8 cleaning leachings of pure water, by containing neutralization solution, process again, dry, dried hollow fibre filament felt was carried out to sintering by heat-treatment furnace in 15～18 minutes 1150～1200 ℃ of heat treated,
Wherein bottom, intermediate layer and skin all will be interweaved and be connected by viscose fibre, before the connection that interweaves, bottom, intermediate layer and outer field fabric be applied by following step respectively successively:
One, by 6.0 grams 4,4 '-diaminodiphenyl ether and the full and uniform mixing of 14.48 gram DADPS, maintain the temperature at 65 ℃ and carried out uniform stirring 20 minutes, adds 18.0 gram magnesium hydrate powders, adopting rotating speed is the high-speed emulsifying machine high speed shear dispersion 45min of 150000r/min, add 4.18 gram pyromellitic acid anhydride powder, at 65 ℃ of temperature, stirring reaction is 35 minutes, cooling 5 minutes, standing 4 hours, filter, drying, obtain fire-retardant powder;
Two, the fire-retardant powder in step 1 is passed through to high-pressure spraying machine, evenly spray three layers of fire-retardant powder on bottom, intermediate layer and outer field fabric.
Embodiment 5:
A kind of hierarchical coating ultraviolet-resistant composite fabric, it is characterized in that: bottom is woven fabric, warp thread is that bamboo fibre, acid fiber by polylactic, milk protein fiber, chitin fiber are 1.5: 2.5: 1 according to fineness ratio respectively: 2, weight ratio is 24: 23: 49: 48, and to become the English number be that 22s, twist factor are 436 yarn for be 58～65N warping, sizing, denting blending through the winder tensile stress; Weft yarn is that bamboo fibre, superhigh molecular weight polyethylene fibers, milk protein fiber, anti pilling hollow chitin fiber are 2.5: 1.5: 2 according to fineness ratio respectively: 1, weight ratio is 23: 24: 48: 49, and to become the English number be that 20s, twist factor are 466 yarn for be 67～85N warping, sizing, denting blending through the winder tensile stress; On the warp-wise of this woven fabric and broadwise, all every 8mm, being embedded with a specific insulation is 1.32 * 10
-316 plying ultra-high count yarns in Europe centimetre; Warp-wise density is 1050/10cm, and latitudinal density is 997/10cm, weight per square meter 65 grams;
Intermediate layer is double-deck warp-knitted fabric, and one deck of this bilayer warp-knitted fabric adopts eight line braidings, knitting needle odd numbers to classify a high position as and even number is classified room as separately, and cloth cover produces two every two ultra-thin tissue; Another layer adopts 18 line braidings, knitting needle to classify a high position as and even number is classified low level as separately at odd number, and cloth cover produces ultra-thin mesh tissue, and raw yarn is 1.26 * 10 by specific insulation
-4Europe centimetre, fineness are that carbon fiber and the specific insulation of 12D is 1.26 * 10
-6Europe centimetre, fineness are that the stainless steel fibre of 8D is that blending in 3.5: 5 forms according to weight ratio respectively;
skin is adhesive-bonded fabric, by polyester, polypropylene, benzimidazole, the polyarylene hydrocarbon, pi copolyesters separately jointly mixes and spins hollow fibre filament with graphite powder, this doughnut filament diameter is 0.4mm, aperture is 4um, then the alginate short fiber that by hollow fibre filament and calcium ion weight ratio is 44: 56 mixes, the gained composite fibre is carried out combing through carding machine and is formed the mat net, by lapping machine, mat stratum reticulare layer laying reached to the feltwork that thickness is 0.11mm～0.12mm, by needing machine, feltwork is carried out to acupuncture, making filament carry out 3～5 times connects fully mutually, by the hollow fibre filament felt heat hot phase-splitting after acupuncture, send into again leaching in the strong acid groove, then with the hollow fibre filament felt after 6～8 cleaning leachings of pure water, by containing neutralization solution, process again, dry, dried hollow fibre filament felt was carried out to sintering by heat-treatment furnace in 15～18 minutes 1150～1200 ℃ of heat treated,
Wherein bottom, intermediate layer and skin all will be interweaved and be connected by viscose fibre, before the connection that interweaves, bottom, intermediate layer and outer field fabric be applied by following step respectively successively:
One, by 6.0 grams 4,4 '-diaminodiphenyl ether and the full and uniform mixing of 14.48 gram DADPS, maintain the temperature at 65 ℃ and carried out uniform stirring 20 minutes, adds 18.0 gram magnesium hydrate powders, adopting rotating speed is the high-speed emulsifying machine high speed shear dispersion 45min of 150000r/min, add 4.18 gram pyromellitic acid anhydride powder, at 65 ℃ of temperature, stirring reaction is 35 minutes, cooling 5 minutes, standing 4 hours, filter, drying, obtain fire-retardant powder;
Two, the fire-retardant powder in step 1 is passed through to high-pressure spraying machine, evenly spray three layers of fire-retardant powder on bottom, intermediate layer and outer field fabric.
Claims (4)
1. hierarchical coating ultraviolet-resistant composite fabric, it is characterized in that: bottom is woven fabric, warp thread is that bamboo fibre, acid fiber by polylactic, milk protein fiber, chitin fiber are that 1.5:2.5:1:2, weight ratio are 24:23:49:48 according to fineness ratio respectively, and to become the English number be 22 for be 58 ~ 65N warping, sizing, denting blending through the winder tensile stress
s, twist factor is 436 yarn; Weft yarn is that bamboo fibre, superhigh molecular weight polyethylene fibers, milk protein fiber, anti pilling hollow chitin fiber are that 2.5:1.5:2:1, weight ratio are 23:24:48:49 according to fineness ratio respectively, and to become the English number be 20 for be 67 ~ 85N warping, sizing, denting blending through the winder tensile stress
s, twist factor is 466 yarn; On the warp-wise of this woven fabric and broadwise, all every 6～8mm, being embedded with a specific insulation is 1.32 * 10
-316 plying ultra-high count yarns in Europe centimetre; Warp-wise density is 1050/10cm, and latitudinal density is 997/10cm, weight per square meter 65 grams;
intermediate layer is double-deck warp-knitted fabric, and one deck of this bilayer warp-knitted fabric adopts eight line braidings, knitting needle odd numbers to classify a high position as and even number is classified room as separately, and cloth cover produces two every two ultra-thin tissue, another layer adopts 18 line braidings, knitting needle to classify a high position as and even number is classified low level as separately at odd number, and cloth cover produces ultra-thin mesh tissue, and raw yarn is 1.26 * 10 by specific insulation
-4Europe centimetre, fineness are that carbon fiber and the specific insulation of 12D is 1.26 * 10
-6Europe centimetre, fineness are that the stainless steel fibre of 8D is that the 3.5:5 blending forms according to weight ratio respectively, skin is adhesive-bonded fabric, by polyester, polypropylene, benzimidazole, the polyarylene hydrocarbon, pi copolyesters separately jointly mixes and spins hollow fibre filament with graphite powder, this doughnut filament diameter is 0.4mm, aperture is 4um, then by hollow fibre filament and calcium ion weight ratio, be the alginate short fiber mixing of 44:56, the gained composite fibre is carried out combing through carding machine and is formed the mat net, by lapping machine, mat stratum reticulare layer laying reached to the feltwork that thickness is 0.11mm ~ 0.12mm, by needing machine, feltwork is carried out to acupuncture, making filament carry out 3～5 times connects fully mutually, by the hollow fibre filament felt heat hot phase-splitting after acupuncture, send into again leaching in the strong acid groove, then with the hollow fibre filament felt after 6～8 cleaning leachings of pure water, by neutralization solution, process again, dry, dried hollow fibre filament felt was carried out to sintering by heat-treatment furnace in 15～18 minutes 1150～1200 ℃ of heat treated,
Wherein bottom, intermediate layer and skin all will be interweaved and be connected by viscose fibre, before the connection that interweaves, bottom, intermediate layer and outer field fabric be applied by following step respectively successively:
One, by 6.0 grams 4,4 '-diaminodiphenyl ether and the full and uniform mixing of 14.48 gram DADPS, maintain the temperature at 65 ℃ and carried out uniform stirring 20 minutes, adds 18.0 gram magnesium hydrate powders, adopting rotating speed is the high-speed emulsifying machine high speed shear dispersion 45min of 150000r/min, add 4.18 gram pyromellitic acid anhydride powder, at 65 ℃ of temperature, stirring reaction is 35 minutes, cooling 5 minutes, standing 4 hours, filter, drying, obtain fire-retardant powder;
Two, the fire-retardant powder in step 1 is passed through to high-pressure spraying machine, evenly spray three layers of fire-retardant powder on bottom, intermediate layer and outer field fabric.
2. a kind of hierarchical coating ultraviolet-resistant composite fabric according to claim 1, it is characterized in that: on the warp-wise of bottom woven fabric and broadwise, all every 6.5mm, being embedded with a specific insulation is 1.32 * 10
-316 plying ultra-high count yarns in Europe centimetre.
3. a kind of hierarchical coating ultraviolet-resistant composite fabric according to claim 1, it is characterized in that: on the warp-wise of bottom woven fabric and broadwise, all every 7mm, being embedded with a specific insulation is 1.32 * 10
-316 plying ultra-high count yarns in Europe centimetre.
4. a kind of hierarchical coating ultraviolet-resistant composite fabric according to claim 1, it is characterized in that: on the warp-wise of bottom woven fabric and broadwise, all every 7.5mm, being embedded with a specific insulation is 1.32 * 10
-316 plying ultra-high count yarns in Europe centimetre.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102610484A CN102416735B (en) | 2011-09-02 | 2011-09-02 | Hierarchical coating ultraviolet-resistant composite fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102610484A CN102416735B (en) | 2011-09-02 | 2011-09-02 | Hierarchical coating ultraviolet-resistant composite fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102416735A CN102416735A (en) | 2012-04-18 |
| CN102416735B true CN102416735B (en) | 2013-11-20 |
Family
ID=45941499
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102610484A Active CN102416735B (en) | 2011-09-02 | 2011-09-02 | Hierarchical coating ultraviolet-resistant composite fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102416735B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102719970A (en) * | 2012-06-18 | 2012-10-10 | 绍兴县恒美花式丝有限公司 | Ecological healthcare bedding shell fabric |
| CN104070711B (en) * | 2014-06-18 | 2016-01-27 | 湖州安芝服饰有限公司 | A kind of heat insulation, insulation, radiation-resistant garment material |
| CN104943290B (en) * | 2015-05-18 | 2017-11-03 | 武汉纺织大学 | A kind of high-elastic sound-absorbing and flame-retardant melt-blowing nonwoven of electrostatic spinning formula and its manufacture method |
| CN107687040B (en) * | 2017-09-21 | 2020-07-14 | 阜阳恒泰纺织有限公司 | Antibacterial soft blended yarn |
| CN107696629A (en) * | 2017-09-29 | 2018-02-16 | 安徽东锦服饰有限公司 | A kind of ultraviolet-resistant fabric |
| CN110592932A (en) * | 2019-08-26 | 2019-12-20 | 浙江辰鸿纺织品科技股份有限公司 | Preparation method of flame-retardant coated fabric |
| CN114657765A (en) * | 2022-04-26 | 2022-06-24 | 朱健 | Corrosion-resistant waterproof fabric and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280485A (en) * | 2008-05-28 | 2008-10-08 | 浙江理工大学 | Preparation of multifunctional textile lining |
| CN101331252A (en) * | 2005-12-16 | 2008-12-24 | 纳幕尔杜邦公司 | Thermal performance garments comprising an ultraviolet light tolerant outer shell fabric of polypyridobisimidazole and polybenzobisoxazole fibers |
| CN101498070A (en) * | 2008-09-18 | 2009-08-05 | 重庆新南国时装有限责任公司 | Textile lining with natural anti-ultraviolet function and production method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04289268A (en) * | 1991-03-13 | 1992-10-14 | Kanebo Ltd | Fabric processed to prevent ultraviolettransmission and its production |
| JPH04333661A (en) * | 1991-04-30 | 1992-11-20 | Asahi Chem Ind Co Ltd | Refreshing fabric |
-
2011
- 2011-09-02 CN CN2011102610484A patent/CN102416735B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101331252A (en) * | 2005-12-16 | 2008-12-24 | 纳幕尔杜邦公司 | Thermal performance garments comprising an ultraviolet light tolerant outer shell fabric of polypyridobisimidazole and polybenzobisoxazole fibers |
| CN101280485A (en) * | 2008-05-28 | 2008-10-08 | 浙江理工大学 | Preparation of multifunctional textile lining |
| CN101498070A (en) * | 2008-09-18 | 2009-08-05 | 重庆新南国时装有限责任公司 | Textile lining with natural anti-ultraviolet function and production method thereof |
Non-Patent Citations (2)
| Title |
|---|
| JP特开平4-289268A 1992.10.14 |
| JP特开平4-333661A 1992.11.20 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102416735A (en) | 2012-04-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102416735B (en) | Hierarchical coating ultraviolet-resistant composite fabric | |
| CN202849672U (en) | Uvioresistant elastic fabric | |
| CN208232462U (en) | A kind of wear-resisting anti-wrinkle fabric | |
| CN109514942A (en) | A kind of ultraviolet-resistant fabric | |
| CN104278412B (en) | A kind of coffee carbon Dual-layer warming fancy suiting | |
| CN213919920U (en) | Uvioresistant high-moisture-absorption polyester fabric | |
| CN110468484B (en) | Environment-friendly fabric and processing method thereof | |
| JP5902391B2 (en) | Thermal insulation fabric and textile products | |
| CN104872901A (en) | Ultraviolet prevention compound fabric | |
| CN202071432U (en) | Bamboo carbon fiber knitted fabric | |
| CN201849034U (en) | Multi-layer composite non-woven fabric | |
| CN214083234U (en) | Moisture absorption breathable polyester viscose grey fabric with yarn interlayer fabric structure | |
| CN109423738A (en) | A kind of artificial cotton fabric of antibacterial, ventilating | |
| CN217671546U (en) | High-strength environment-friendly sofa fabric | |
| CN110774679A (en) | Fabric for keeping children warm and preparation method thereof | |
| CN220409851U (en) | Waterproof breathable textile fabric | |
| CN213972937U (en) | Air-permeable non-woven fabric for filtering | |
| CN221315371U (en) | Nonwoven fabric with good air permeability | |
| CN212949609U (en) | Novel high-sun-resistance outdoor polyester fabric | |
| CN214774519U (en) | Environment-friendly breathable regenerated polyester fabric | |
| CN216804747U (en) | Super gentle compound knitting environmental protection surface fabric of high elasticity spandex | |
| CN218535912U (en) | Antistatic fabric | |
| CN213389076U (en) | Multi-component summer anti-static tooling fabric | |
| CN216033001U (en) | Sweat-absorbing breathable textile fabric with radiation protection function | |
| CN215328610U (en) | High-elasticity blended polyester-cotton fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |