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CN102319196A - Disposable sleep facial mask composition and preparation method thereof - Google Patents

Disposable sleep facial mask composition and preparation method thereof Download PDF

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Publication number
CN102319196A
CN102319196A CN201110305618A CN201110305618A CN102319196A CN 102319196 A CN102319196 A CN 102319196A CN 201110305618 A CN201110305618 A CN 201110305618A CN 201110305618 A CN201110305618 A CN 201110305618A CN 102319196 A CN102319196 A CN 102319196A
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China
Prior art keywords
skin
surface film
sleep surface
extract
disposable sleep
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CN201110305618A
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CN102319196B (en
Inventor
沈伟良
张丽华
何丹
姚国英
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Ou Shi Overflows Biological Co Ltd
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沈志荣
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Abstract

The invention belongs to a disposable sleep facial mask composition for moisturizing at night and a preparation method thereof. The facial mask composition comprises the following components in percentage by weight: (a) 0.01 to 30 percent of skin moistening grease, (b) 0.01 to 20 percent of humectant, (c) 0.01 to 10 percent of thickening polymer, (d) 0.01 to 10 percent of skin conditioner and (e) 10 to 90 percent of deionized water. The facial mask composition can moisturize skin fully at night, open a deep penetration channel for the skin, replenish amino acid and strengthen the updating capacity of the skin, so that the skin breathes smoothly.

Description

A kind of disposable sleep surface film composition and preparation method thereof
Technical field
The invention belongs to disposable sleep surface film composition of a kind of moisturizing in night and preparation method thereof.
Background technology
In order to let skin also can absorb competent moisture, keep the tender state of water at night.Chinese invention patent application (application number: 201010519548.9 applyings date: 2010-10-26) disclose a kind of modification Margarita Fructus Pruni pseudocerasi dimension C sleep facial film and preparation method thereof; This patent is through with reacting with surfactant after the nanometer Margarita powder heat-activated; Make modified nanometer Margarita powder, disperse the modification Margarita powder through turbine stirring at water again, hyaluronate sodium, glycerin polyether, butanediol is soluble in water; Fully stir and heating; Afterwards formula components such as polysorbas20, isononyl isononanoate, cetearyl alcohol are added oil cauldron, after stirring homogenizing, be chilled to about 45 ℃; Add additive and essence, antiseptic etc. one by one, process modification Margarita Fructus Pruni pseudocerasi dimension C sleep facial film.This patent can fully be infiltrated skin at sleep period chien shih moisture and nutritional labeling, concentrates and improves the skin state.
Summary of the invention
In order to let skin also can absorb competent moisture, keep the tender state of water at night.An object of the present invention is to provide a kind of disposable sleep surface film composition, this mask composition can let skin in abundant moisturizing at night, for skin is opened the percdation passage, replenishes aminoacid, strengthen the skin updating ability, breathe smooth and easy.Another object of the present invention provides the method for preparing that a kind of above-mentioned disposable sleep facial film makes up.
In order to realize above-mentioned first purpose, the technical scheme below the present invention has adopted:
A kind of disposable sleep surface film composition, said mask composition comprises following component by weight percentage:
(a) 0.01% to 30% skin moistening oils and fats;
(b) 0.01% to 20% wetting agent;
(c) 0.01% to 10% thickening polymer;
(d) 0.01% to 10% skin conditioning agent;
(e) 10% to 90% deionized water.
As preferably, said mask composition comprises following component by weight percentage:
(a) 1% to 20% skin moistening oils and fats;
(b) 1% to 20% wetting agent;
(c) 0.01% to 8% thickening polymer;
(d) 0.01% to 8% skin conditioning agent;
(e) 10% to 90% deionized water.
Preferred as again, said mask composition comprises following component by weight percentage:
(a) 5% to 15% skin moistening oils and fats;
(b) 5% to 20% wetting agent;
(c) 0.01% to 6% thickening polymer;
(d) 0.01% to 6% skin conditioning agent;
(e) 10% to 90% deionized water.
As preferably, said skin moistening oils and fats is selected one or more in Cyclomethicone, caprylic/capric triglyceride, the Radix Oenotherae erythrosepalae oil for use.
As preferably, said wetting agent is selected betanin, propylene glycol, sorbitol, butanediol, 1 for use, in 2-hexanediol, caprylyl glycol, dipropylene glycol, glycerol, diglycerol, pentanediol and the Polyethylene Glycol one or more; What be preferred for this compositions again is betanin, glycerol or propylene glycol.
As preferably, said thickening polymer is selected in polysaccharide, acrylic copolymer and the cellulosic polymer one or more for use; Be preferred for this compositions again be in CTFA called after 2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate copolymers, xanthan gum and the hydroxyethyl-cellulose one or more.
As preferably, said skin conditioning agent is selected in allantoin, Margarita powder, Herba Violae Hortensis flower extract, America Ramulus Sambuci Williamsii extract, Fructus psidii guajavae immaturus extract and the hyaluronate sodium one or more for use.
As preferably, said composition also comprises antiinflammatory, and described antiinflammatory is selected glycyrrhizic acid dipotassium for use.
As preferably, said said composition also comprises one or more in chelating agen, antiseptic and the essence.
The present composition also can comprise various other compositions.The function of the concrete composition of compositions of the present invention and effect will be described in more detail below.
The skin moistening oils and fats
Skin moistening oils and fats in the present composition can pin moisture, prevents excessive volatilization, makes skin keep the tender gloss of water.
Soothing oil alicyclic ring polydimethylsiloxane in the present composition, its weight by said compositions is about 0.01% to 20%, preferably is about 0.01% to 15%, and more preferably from about 0.01% to 10%.It is nontoxic, to skin and mucosa nonirritant, It is generally accepted it is safe.Have excellent chemical stability, antistatic behaviour and breathability can freely be breathed skin, and the skin sense that silk is sliding reduces sticky sense.
Skin moistening oils and fats caprylic/capric triglyceride in the present composition, its weight by said compositions is about 0.01% to 20%, preferably is about 0.01% to 15%, and more preferably from about 0.01% to 10%.It is the low viscosity oils and fats, and fabulous skin isostearyl glyceryl pentaerythrityl ether is absorbed easily, gives the skin silk sliding gloss.
Skin moistening oils and fats Radix Oenotherae erythrosepalae oil in the present composition, its weight by said compositions is about 0.01% to 20%, preferably is about 0.01% to 15%, and more preferably from about 0.01% to 10%.Extracted form natural plant contains multiple fatty acid, mainly comprises linoleic acid (linoleicacid), gamma-Linolenic acid (γ-linolenic acid), oleic acid (oleic acid); Palmic acid (palmitic acid), stearic acid (stearic acid), suitable-6,9; 12-28 carbon-trienic acid (cis-6,9,12-octadecatrienoic acid), suitable-9; 12,15-28 carbon-trienic acid (cis-9,12,15-octadecatrienoic acid).Contained gamma-Linolenic acid is that human body can not synthetic essential fatty acid, can improve xerosis cutis, itch or even the effect of inflammation.Radix Oenotherae erythrosepalae oil also has antioxidation, moistens and softening skin, and be good emollient.
Wetting agent
About by weight wetting agent of 0.01% to 20% among the present invention is a polyhydric alcohol; Compositions described herein preferably comprises by the weight of said compositions about 1% to 20%; The wetting agent of 2%-20% more preferably, instance comprises propylene glycol, sorbitol, butanediol, 1,2-hexanediol, caprylyl glycol, dipropylene glycol, glycerol, diglycerol, pentanediol, Polyethylene Glycol; And their mixture, what be preferred for this compositions is glycerol, propylene glycol.
Another kind of wetting agent betanin among the present invention, formal name used at school N-trimethyl glycine is natural NMF, absorbs fast, active high new moisturizer, can improve the moisture holding capacity of skin rapidly, the activated cell vigor keeps skin moist, smooth.
Thickening agent
In some embodiments, compositions of the present invention can also comprise one or more thickening agents, and said compositions comprises by the weight of said compositions about 0.01% to 10%, preferably is about 0.01% to 8%, more preferably from about 0.01% to 6% thickening agent.
The non-limiting kind of thickening agent comprises and is selected from following material: carboxylic acid polyalcohol (like Carbopol 980), cross-linked polyacrylate polymer, synthetic high molecular polymer (like cellulose ethers), natural high molecular polymer (like natural gum).
Acrylate copolymer in the present composition is pressed the material of CTFA called after 2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate copolymers, and it has remarkable emulsifying thickening capabilities, gives product softish quality.
Xanthan gum in the present composition is claimed HUANGJIAO, HANSHENGJIAO again, and yellow unit cell polysaccharide is a kind of monospore polysaccharide that is produced by false xanthomonas fermentation, and natural carbohydrate is fabulous thickening agent and stabilizing agent.
Hydroxyethyl-cellulose in the present composition; The water-soluble cellulose ether of nonionic; Be a kind of white or faint yellow, tasteless, nontoxic pulverulent solids has good thickening, suspension, dispersion, emulsifying, bonding, film forming, protection moisture and characteristics such as protecting colloid is provided.
Antiinflammatory
The glycyrrhizic acid dipotassium of the present composition is made antiinflammatory, molecular formula: C 42H 60K 2O 16Radix Glycyrrhizae just has detoxifcation, antiinflammatory anti-allergic effects as medicine since ancient times.Its curative effect is widely known by the people.Effective ingredient further investigation to Radix Glycyrrhizae extract shows: glycyrrhizic acid and potassium salt thereof have the effect of good anti-allergic effects, Detoxication and similar adrenal gland's sebum hormone, even life-time service also has no side effect.Glycyrrhizic acid dipotassium such as is used for cosmetics and has antiinflammatory, antiallergic, preserve moisture at effect.
Skin conditioning agent
The various skin conditioner that the present composition added is allantoin, Margarita powder, Herba Violae Hortensis flower extract, America Ramulus Sambuci Williamsii extract, Fructus psidii guajavae immaturus extract and hyaluronate sodium.
The allantoin of the present composition is a kind of amphoteric compound, can combine multiple material to form double salt.The content of the allantoin that the present composition adds is preferably about 0.01% to 20% by the weight of said compositions, and more preferably from about 0.01% to 10%.
Above-mentioned allantoin has shading, sterilization and anticorrosion, pain relieving, antioxidation, can make skin keep moisture content, moistens and soft, is the additive of cosmetics such as cosmetology.The cosmetics that add allantoin have protective tissue, hydrophilic, absorb water and effect such as prevent that moisture from distributing; Make skin softness and high resilience, and beautiful gloss is arranged.Allantoin can also promote tissue growth, cell metabolism, soften cuticle albumen.The content of natural allantoin is very low because traditional handicraft is extracted from natural animal-plant, complex process, cost are too high; Can't use on a large scale; Therefore the existing main chemical synthesis that adopts is extracted synthetic allantoin, like the direct condensation method of carbamide glyoxalic acid, acetic acid acid calcium salt acid-soluble method, carbamide dichloroacetic acid heating, oxalic acid electrolysis oxidation of glyoxal, Chloral synthetic method etc.
The Margarita powder of the present composition, its content is about 0.01% to 10% by the weight of the present composition, preferably is about 0.01% to 8%, is more preferably 0.01% to 6%.
The Margarita powder of the present composition is nano level Margarita powder, and pure physical pulverization makes; Contain and be rich in various trace elements such as 18 seed amino acids, large number of biological activated calcium, abundant vitamin B complex and zinc-iron selenium; Can regulate human endocrine, effectively suppress pigmentation, strengthen the skin metabolism ability; Promote reepithelialization, the whitening effect skin.
The content of the Herba Violae Hortensis flower extract that the present composition adds is preferably about 0.01% to 8% by the weight of said compositions; More preferably from about 0.01% to 6%; The active quantities of the Herba Violae Hortensis flower extract of the present composition is preferred about 0.001% to 8% by the weight of said compositions, and more preferably from about 0.001% to 6%.
The Herba Violae Hortensis flower extract of the present composition is rich in globulariacitrin, Saponin and vitamin C, tocopherol etc.The equilibrated health status of conditioning skin to water oil has antibacterial action, the pox that significantly disappears effect comprehensively.
The content of the America Ramulus Sambuci Williamsii extract that the present composition adds is preferably about 0.01% to 8% by the weight of said compositions; More preferably from about 0.01% to 6%; The active quantities of the America Ramulus Sambuci Williamsii extract of the present composition is preferred about 0.001% to 8% by the weight of said compositions, and more preferably from about 0.001% to 6%.
The America Ramulus Sambuci Williamsii extract that the present composition adds contains the Ramulus Sambuci Williamsii anthocyanin, anthocyanidin glycoside, morroniside etc.Have superpower moisturizing effect, and can make the eye skin in time absorb nutritional labeling; Promote the cutaneous circulation flow velocity simultaneously, reduce the eye edema, very effective to dispeling the eye black eye, let two pupils look eagle-eyed.
The content of the Fructus psidii guajavae immaturus extract that the present composition adds is preferably about 0.01% to 8% by the weight of said compositions; More preferably from about 0.01% to 6%; The active quantities of the Fructus psidii guajavae immaturus extract of the present composition is preferred about 0.001% to 8% by the weight of said compositions, and more preferably from about 0.001% to 6%.
The Fructus psidii guajavae immaturus extract of the present composition; Be rich in trace element such as vitamin C, protein, fat, vitamin A, category-B vitamin, calcium, phosphorus, ferrum, can be effectively in and free radical, enhance metabolism; Help skin to discharge " toxin ", bring into play the whitening skin and preserving moisture effect immediately.
The hyaluronate sodium of the present composition is the glutinous sugar of a kind of bionical thing, and molecular weight is greater than 1,000,000, and the hyaluronic acid sodium content of the present composition is about 0.01% to 10% by the invention composition weight meter, and is preferred about 0.01% to 5%, is more preferably 0.01% to 3%.
Contain 10% to 20% moisture in the normal human skin horny layer, it prevents skin aging, prevents that the various stimulations of external environment from all having significant role skin care.With advancing age or the variation of environment, moisture can drop to below 10%, and skin can be dry, produces wrinkle.The hyaluronate sodium of the present composition can be alleviated this problem, and its theoretical water retention value reaches 1000ml/g, is the key component of water conservation in the human body skin, and not only moistening effect is good, and do not have greasy feeling with stop up pore etc. shortcoming.Can also eliminate oxygen-derived free radicals, repair the skin that shines the back damage.
Preferred as again, said composition is made up of following component by mass percentage:
Composition Weight %
Cyclomethicone 1.0~8.0
Caprylic/capric triglyceride 0.8~5.0
Radix Oenotherae erythrosepalae oil 1.0~6.0
Essence 0~0.5
Deionized water 40~80
Glycerol 10~30
Butanediol 0~8.0
2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate copolymers 0~6.0
Methyl hydroxybenzoate 0~0.5
Allantoin 0.3~3.0
Xanthan gum 0~1.0
Hydroxyethyl-cellulose 0~0.5
The EDTA disodium 0~0.5
Hyaluronate sodium 0~3
Glycyrrhizic acid dipotassium 0~3
The Herba Violae Hortensis flower extract 0~5
Guava extract 0~5
The America Ramulus Sambuci Williamsii extract 0~5
Betanin 1.0~8.0
Margarita powder 0~2
DMDM Hydantoin/iodine propilolic alcohol butyl mephenesin Carbamate 0~0.8
It is not 0 that above-mentioned Herba Violae Hortensis flower extract, guava extract, America Ramulus Sambuci Williamsii extract, Margarita powder have at least a kind of.
In order to realize second above-mentioned purpose, the technical scheme below the present invention has adopted:
A kind of method of above-mentioned disposable sleep surface film composition is characterized in that this method comprises the steps:
1) with the oil phase substance mix homogeneously;
2) water and aqueous substance are mixed, be heated to 70 ℃~90 ℃, to dissolving;
3) heat to 55 ℃~65 ℃, oil phase adds water, and homogenizing stirs; To 50 ℃, add other components, stir discharging.
The present invention is owing to adopted above-mentioned technical scheme, and after use, this sleep surface film composition is that skin is opened infiltration lane, deep layer moisturizing, osmotrophy material.Can let skin in abundant moisturizing at night,, replenish aminoacid for skin is opened the percdation passage, strengthen the skin updating ability, breathe smooth and easy.
The specific embodiment
Preparation process of the present invention is the state that each composition is mixed to the comparison homogeneous, and step is:
1. oil phase mix homogeneously;
2. water, glycerol, 2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate copolymers, methyl hydroxybenzoate, allantoin, xanthan gum, hydroxyethyl-cellulose, EDTA disodium mix, and are heated to 80 ℃ and are uniformly dispersed;
3. heat to 60 ℃, oil phase adds water, and homogenizing stirs;
4. during to 50 ℃, add all the other components, stir discharging;
5. storage → the inspection of semifinished product → fill → product inspection → warehouse-in.
Specific embodiment:
Figure 2011103056185100002DEST_PATH_IMAGE001
Phase 1 is put into container and is mixed; Mutually 2 put into another vessel in heating to 80 ℃; To 60 ℃ of phases, 1 adding phase 2, emulsifying, homogenizing stirs, and is cooled to 50 ℃, adds phase 3, after stirring, discharging.
Method of testing:
In order to test moisturizing of the present invention, conditioning effect, carried out investigation experiment on probation:
1, respondent: each department ordinary consumer 50 people, 46 parts of the trial state feedback forms of regaining at last;
2, control time: December in 2008 on February 10th, 1 2009 on the 10th;
3, use product: No. 1 product is the product according to formulation of the present invention; No. 2 products are the rival factory similar products;
4, method of testing: after the tester face cleaning, about respectively No. 1 product and No. 2 products being coated on two cheek, observe and experience result of use;
5, the test form is following:
The use of No. 1 product of table 1 (60 days) feedback conclusive table
Figure 2011103056185100002DEST_PATH_IMAGE002
No. 2 products of table 2 use (60 days) feedback conclusive table
Figure 2011103056185100002DEST_PATH_IMAGE003
The conditioning effect contrast statistical table of No. 1 product of table 3 and No. 2 products
Figure 2011103056185100002DEST_PATH_IMAGE004
The statistical table of table 4 tester recommended products model
Proposed model No. 1 No. 2
The recommendation number 39 7
Percentage ratio 84.78% 15.22%
6, feedback conclusion:
The tester representes that all No. 1 product again can be too not thick and heavy in moisturizing, lets skin experience the water profit and can freely breathe again, and after often using, the colour of skin is obviously ruddy glossy, and wrinkle obviously reduces, and is delicate penetrating, and do not have the people that allergic phenomena is arranged in the questionnaire that reclaims.
Can know that by table 5 84.78% people recommends to use product No. 1, have only 15.22% people to recommend to use product No. 2.

Claims (10)

1. disposable sleep surface film composition is characterized in that said mask composition comprises following component by weight percentage:
(a) 0.01% to 30% skin moistening oils and fats;
(b) 0.01% to 20% wetting agent;
(c) 0.01% to 10% thickening polymer;
(d) 0.01% to 10% skin conditioning agent;
(e) 10% to 90% deionized water.
2. a kind of disposable sleep surface film composition according to claim 1 is characterized in that said mask composition comprises following component by weight percentage:
(a) 1% to 20% skin moistening oils and fats;
(b) 1% to 20% wetting agent;
(c) 0.01% to 8% thickening polymer;
(d) 0.01% to 8% skin conditioning agent;
(e) 10% to 90% deionized water.
3. a kind of disposable sleep surface film composition according to claim 1 is characterized in that said mask composition comprises following component by weight percentage:
(a) 5% to 15% skin moistening oils and fats;
(b) 5% to 20% wetting agent;
(c) 0.01% to 6% thickening polymer;
(d) 0.01% to 6% skin conditioning agent;
(e) 10% to 90% deionized water.
4. a kind of disposable sleep surface film composition according to claim 1 is characterized in that the skin moistening oils and fats selects one or more in Cyclomethicone, caprylic/capric triglyceride, the Radix Oenotherae erythrosepalae oil for use.
5. a kind of disposable sleep surface film composition according to claim 1; It is characterized in that wetting agent selects betanin, propylene glycol, sorbitol, butanediol, 1 for use, in 2-hexanediol, caprylyl glycol, dipropylene glycol, glycerol, diglycerol, pentanediol and the Polyethylene Glycol one or more; What be preferred for this compositions is betanin, glycerol or propylene glycol.
6. a kind of disposable sleep surface film composition according to claim 1 is characterized in that thickening polymer selects in polysaccharide, acrylic copolymer and the cellulosic polymer one or more for use; Be preferred for this compositions be in CTFA called after 2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate copolymers, xanthan gum and the hydroxyethyl-cellulose one or more.
7. a kind of disposable sleep surface film composition according to claim 1 is characterized in that skin conditioning agent selects in allantoin, Margarita powder, Herba Violae Hortensis flower extract, America Ramulus Sambuci Williamsii extract, Fructus psidii guajavae immaturus extract and the hyaluronate sodium one or more for use.
8. a kind of disposable sleep surface film composition according to claim 1, it is characterized in that: said composition also comprises one or more in antiinflammatory, chelating agen, antiseptic and the essence; Described antiinflammatory is selected glycyrrhizic acid dipotassium for use.
9. a kind of disposable sleep surface film composition according to claim 1, it is characterized in that: said composition is made up of following component by mass percentage:
Cyclomethicone 1.0~8.0%
Caprylic/capric triglyceride 0.8~5.0%
Radix Oenotherae erythrosepalae oil 1.0~6.0%
Essence 0~0.5%
Deionized water 40~80%
Glycerol 10~30%
Butanediol 0~8.0%
2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate copolymers 0~6.0%
Methyl hydroxybenzoate 0~0.5%
Allantoin 0.3~3.0%
Xanthan gum 0~1.0%
Hydroxyethyl-cellulose 0~0.5%
EDTA disodium 0~0.5%
Hyaluronate sodium 0~3%
Glycyrrhizic acid dipotassium 0~3%
Herba Violae Hortensis flower extract 0~5%
Guava extract 0~5%
America Ramulus Sambuci Williamsii extract 0~5%
Betanin 1.0~8.0%
Margarita powder 0~2%
DMDM Hydantoin/iodine propilolic alcohol butyl mephenesin Carbamate 0~0.8%;
It is not 0 that above-mentioned Herba Violae Hortensis flower extract, guava extract, America Ramulus Sambuci Williamsii extract, Margarita powder have at least a kind of.
10. a method for preparing claim 1 or 2 or 3 described disposable sleep surface film compositions is characterized in that this method comprises the steps:
1) with the oil phase substance mix homogeneously;
2) water and aqueous substance are mixed, be heated to 70 ℃~90 ℃, to dissolving;
3) heat to 55 ℃~65 ℃, oil phase adds water, and homogenizing stirs; To 50 ℃, add other components, stir discharging.
CN 201110305618 2011-10-11 2011-10-11 Washing-free sleep facial mask composition and preparation method thereof Active CN102319196B (en)

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Related Child Applications (4)

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CN201310082369.7A Division CN103142446B (en) 2011-10-11 2011-10-11 Washing-free sleeping mask composition containing American erberry extracts, pansy flower extracts and pearl powder
CN201310081915.5A Division CN103169643B (en) 2011-10-11 2011-10-11 Washing-free sleeping mask composition containing natural plant extractives
CN201310082367.8A Division CN103156802B (en) 2011-10-11 2011-10-11 Wash-free sleep mask composition containing guava, sambucus canadensis extract and pearl powders
CN201310082709.6A Division CN103211739B (en) 2011-10-11 2011-10-11 Washing-free sleep mask composition containing guava extractive, pansy flower extractive and pearl powder

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CN108295026A (en) * 2018-03-09 2018-07-20 广州市白云采妮化妆品厂 A kind of comprehensive sleep mask and preparation method thereof for improving facial skin quality
CN108420740A (en) * 2018-06-04 2018-08-21 上海应用技术大学 A kind of disposable moisture saver mask and its preparation method and application
CN108434044A (en) * 2018-06-13 2018-08-24 云南精慈生物科技有限公司 A kind of Radix Notoginseng powder facial mask and preparation method thereof
CN112089678A (en) * 2020-10-28 2020-12-18 北海市海真珠化妆品有限公司 Preservative-free moisturizing pearl facial mask and preparation method thereof

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CN102920639A (en) * 2012-11-22 2013-02-13 广西森呼吸科技工程有限公司 Whitening and firming face mask containing plant extractives and preparation method of whitening and firming face mask
CN102988261A (en) * 2012-12-14 2013-03-27 北海黑珍珠海洋生物科技有限公司 Facial mask solution and preparation method thereof
CN104000750A (en) * 2013-02-21 2014-08-27 杭州黛纳生物科技有限公司 Matcha green clay facial mask and manufacturing technology thereof
CN104095777A (en) * 2013-04-03 2014-10-15 上海珍馨化工科技有限公司 Emulsion for viola tricolor nutritive mask, viola tricolor nutritive mask and preparation method of viola tricolor nutritive mask
CN103690456A (en) * 2013-12-04 2014-04-02 青岛海芬海洋生物科技有限公司 Sleeping mask containing sweet pea extract solution and preparation method thereof
CN103893072A (en) * 2014-04-04 2014-07-02 广州丹奇日用化工厂有限公司 Pig skin mask and preparation method thereof
CN104116650B (en) * 2014-08-11 2016-09-28 上海贝泰妮生物科技有限公司 A kind of cream preparation of high oil phase content and emulsifier-free and preparation method thereof
CN104116650A (en) * 2014-08-11 2014-10-29 上海贝泰妮生物科技有限公司 Cream preparation with high oil phase content and no emulsifier and preparation method of cream preparation
CN104644521A (en) * 2014-12-19 2015-05-27 王大明 Oil controlling sleeping mask and preparation method thereof
CN104644518A (en) * 2014-12-19 2015-05-27 王大明 Whitening rose sleeping mask and preparation method thereof
CN104873447A (en) * 2015-06-09 2015-09-02 夏放军 Peach-blossom sleep facial mask and preparation method therefor
CN106265288A (en) * 2016-08-31 2017-01-04 苏州菲博特环保科技有限公司 Hyaluronic acid silk mask and preparation method thereof
CN106399437B (en) * 2016-09-07 2020-02-14 深圳凯联龟业有限公司 Preparation method of small water turtle polypeptide and small water turtle polypeptide mask
CN106399437A (en) * 2016-09-07 2017-02-15 深圳凯联龟业有限公司 Preparation method of mauremys mutica polypeptide and mauremys mutica polypeptide facial mask
CN106511247A (en) * 2016-12-21 2017-03-22 谢桂斌 Moisturizing red wine serum
CN107412098A (en) * 2017-05-24 2017-12-01 佛山市汇汾化妆品科技有限公司 A kind of nti-freckle repairs facial mask
CN108295026A (en) * 2018-03-09 2018-07-20 广州市白云采妮化妆品厂 A kind of comprehensive sleep mask and preparation method thereof for improving facial skin quality
CN108420740A (en) * 2018-06-04 2018-08-21 上海应用技术大学 A kind of disposable moisture saver mask and its preparation method and application
CN108434044A (en) * 2018-06-13 2018-08-24 云南精慈生物科技有限公司 A kind of Radix Notoginseng powder facial mask and preparation method thereof
CN112089678A (en) * 2020-10-28 2020-12-18 北海市海真珠化妆品有限公司 Preservative-free moisturizing pearl facial mask and preparation method thereof

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