CN102229847A - Nano-silver-containing pure water base plate strip steel rolling fluid - Google Patents
Nano-silver-containing pure water base plate strip steel rolling fluid Download PDFInfo
- Publication number
- CN102229847A CN102229847A CN2011101356791A CN201110135679A CN102229847A CN 102229847 A CN102229847 A CN 102229847A CN 2011101356791 A CN2011101356791 A CN 2011101356791A CN 201110135679 A CN201110135679 A CN 201110135679A CN 102229847 A CN102229847 A CN 102229847A
- Authority
- CN
- China
- Prior art keywords
- water
- strip steel
- silver
- plate strip
- steel rolling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005096 rolling process Methods 0.000 title claims abstract description 42
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 30
- 239000010959 steel Substances 0.000 title claims abstract description 30
- 239000012530 fluid Substances 0.000 title abstract 8
- 239000007788 liquid Substances 0.000 claims abstract description 25
- 239000007866 anti-wear additive Substances 0.000 claims abstract description 15
- 229910052709 silver Inorganic materials 0.000 claims description 20
- 239000004332 silver Substances 0.000 claims description 20
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 10
- -1 ammonium phosphate ester Chemical class 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229960004418 trolamine Drugs 0.000 claims description 4
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 239000004254 Ammonium phosphate Substances 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- ABBQHOQBGMUPJH-UHFFFAOYSA-M Sodium salicylate Chemical compound [Na+].OC1=CC=CC=C1C([O-])=O ABBQHOQBGMUPJH-UHFFFAOYSA-M 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 2
- 239000002518 antifoaming agent Substances 0.000 claims description 2
- 239000013530 defoamer Substances 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229940096992 potassium oleate Drugs 0.000 claims description 2
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 claims description 2
- 229960004025 sodium salicylate Drugs 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 13
- 238000001816 cooling Methods 0.000 abstract description 5
- 238000011109 contamination Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 239000003995 emulsifying agent Substances 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000001050 lubricating effect Effects 0.000 abstract description 3
- 230000000813 microbial effect Effects 0.000 abstract description 3
- 239000010731 rolling oil Substances 0.000 abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 230000006866 deterioration Effects 0.000 abstract 1
- 238000005553 drilling Methods 0.000 abstract 1
- 239000002075 main ingredient Substances 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 12
- 230000000845 anti-microbial effect Effects 0.000 description 8
- 238000010186 staining Methods 0.000 description 8
- 239000000314 lubricant Substances 0.000 description 7
- 238000005461 lubrication Methods 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011882 ultra-fine particle Substances 0.000 description 2
- 241000143060 Americamysis bahia Species 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910017770 Cu—Ag Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241000863032 Trieres Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention provides a nano-silver-containing pure water base plate strip steel rolling fluid. The nano-silver-containing pure water base plate strip steel rolling fluid takes water as a carrier and contains 0.2-7wt% of water soluble extreme pressure antiwear additive and 0.005-3wt% of water soluble nano silver hydrosol. In the invention, the water soluble extreme pressure antiwear additive and the water soluble nano silver hydrosol are adopted as the main ingredients of the water soluble plate strip steel rolling fluid, and the problems that consumption of rolling oil is high, oil spray pollution is serious and the environment is polluted by microbial contamination, deterioration, decomposition and discharge of an emulsified liquid in a plate strip steel rolling process can be solved. The nano-silver-containing pure water base plate strip steel rolling fluid provided by the invention contains no oil or emulsifier, water is used for substituting oil, cost is reduced, and excellent antibacterial property is realized; and the performance of the nano-silver-containing pure water base plate strip steel rolling fluid can reach the operating requirement of plate strip steel rolling, and the nano-silver-containing pure water base plate strip steel rolling fluid has a practical effect of environmental protection, thus industrialization is convenient to realize. The nano-silver-containing pure water base plate strip steel rolling fluid provided by the invention also can be applied to a drilling machine, a grinding machine and other industries requiring for high cooling and lubricating properties.
Description
Technical field
The present invention relates to a kind of soluble oil that is used for the strip steel rolling.
Background technology
In Iron And Steel Industry and non-ferrous metal processing, rolling is to utilize roll metal stock to be rolled into the processing mode of the sheet material of all size.Can be processed into difform material to steel, copper, aluminium etc. by rolling processing.Need use a large amount of rolling lubricants when rolling and cool off and lubricate, improve the quality of products and protect roll.
The effect of rolling lubricant is: reduce frictional coefficient and frictional force on the distorted area contacting surface, reduce the wearing and tearing of roll, to the wetting action of rolled piece, prevent that on the rolled piece surface intermetallic from sticking together, thereby improve calendering efficient; Cooling effect is to take away the fricative a large amount of heat in metallic surface in the operation of rolling, makes the mechanical property of metal and surface shape unaffected.
At present, rolling lubricant has types such as oil type ROLLING OIL and emulsion aq. type lubricant.The oil type lubricant has good lubricating effect, but cooling performance is poor slightly, also exists inflammable and shortcoming contaminate environment.The solubility liquid (claiming emulsion again) that the emulsion aq. type is commonly used is made up of mineral oil (or vegetables oil), water, emulsifying agent, additive.It had both had the good advantage of oil type lubricant oilness, had the well behaved advantage of water cooling again, also reduced the danger of catching fire in the lubricant use simultaneously.Weak point be gone bad by microbial contamination easily, corrupt, influence its work-ing life.
Summary of the invention
The purpose of this invention is to provide a kind of pure water base plate strip steel rolling liquid that contains nanometer silver, to overcome the above-mentioned defective that prior art exists.
The pure water base plate strip steel rolling liquid that contains nanometer silver of the present invention is carrier with water, contains weight percent and be 0.2～7% the water-soluble extreme pressure anti-wear additives and 0.005%～3% the water-soluble nano silver water-sol;
Preferably, be carrier with water, contain weight percent and be 0.5～3.5% the water-soluble extreme pressure anti-wear additives and 0.5%～2% the water-soluble nano silver water-sol;
Described water-soluble extreme pressure anti-wear additives is more than one in the water-soluble extreme pressure anti-wear additives of EPW, trolamine, water-soluble phosphate, sodium salicylate or the potassium oleate;
Described water-soluble extreme pressure anti-wear additives is that EPW is that the Vanderbilt company trade mark is the water-soluble extreme pressure anti-wear additives of EPW, is the composition of trolamine and ammonium phosphate ester;
Water-soluble phosphate can adopt the product of the quick oil product chemical industry of think of company limited;
In the described water-soluble nano silver water-sol, the median size of silver particles is 10～50 nanometers, and the weight content of silver particles is 0.5～1.0%, preferably 1.0%;
The described water-soluble nano silver water-sol, the method that can provide with reference to following document is prepared:
(1) Zhao Bin, Yao Ming be virtuous etc. " control of the particle diameter of silver particles in the silver-colored ultrafine particle dispersed liquid ", " petrochemical complex " 1996,25 (3), 159;
(2) " preparation of the copper ultrafine particle dispersed liquid of polymer protection " " petrochemical complex " 1993,22 (3), 159 of Zhao Bin, Gao Zongming etc.;
(3) ZL00111402.2, bimetal Cu-Ag colloid as antibacterial agent and preparation method thereof.
The water-soluble anti-rust inhibiter is phenylpropyl alcohol triazole, tetrahydroglyoxaline or is 15～40% the 2-amino-2-methyl-1-propanol aqueous solution for containing weight percent, or contain the aqueous solution that weight percent is the polycarboxylic acid of 20-50%, as above the dried shrimps woods chemistry company limited trade mark is the product of CP-35;
Dispersion agent is selected from more than one in Polyvinylpyrolidone (PVP) (PVP), polyvinyl alcohol, methylcellulose gum, Natvosol or the gelatin;
Defoamer is three-dimensional siloxanes or polyether antifoam agent, and it is the product of 3529B that three-dimensional siloxanes can adopt the quick oil product chemistry of the think of company limited trade mark;
Preferably, the described pure water base plate strip steel rolling liquid that contains nanometer silver, form by following components in weight percentage:
Further preferred, the described pure water base plate strip steel rolling liquid that contains nanometer silver, water-soluble steel plate rolling liquid is made up of following components in weight percentage:
The preparation that contains the pure water base plate strip steel rolling liquid of nanometer silver of the present invention is the method for the physical mixed of routine, each component is mixed to stir getting final product.
The invention has the beneficial effects as follows: the present invention adopts the water-soluble extreme pressure anti-wear additives and the water-soluble nano silver water-sol, main component as water-soluble strip steel rolling liquid, the contriver finds, the water-soluble nano silver water-sol, be a kind of extreme pressure anti-wear additives, have anti-microbial property again, therefore, the technology that solved is in strip steel rolling process, and that ROLLING OIL consumes is high, contaminated with oil mist is serious, the microbial contamination of emulsion, rotten, corruption and exhaust emission environmental problem.The present invention is oil-containing and emulsifying agent not, and with water for oil, cost reduces, and has good germ resistance again, the performance that contains the pure water base plate strip steel rolling liquid of nanometer silver of the present invention reaches the service requirements of strip steel rolling, and the practical function of environmental protection is arranged; Be convenient to industrialization.The pure water base plate strip steel rolling liquid that contains nanometer silver of the present invention also can be applied to rig bed, grinding machine and the high industry of other cooling and lubricating performance requriementss.
Embodiment
Among the embodiment, extreme pressure and antiwear behavior PB value adopts GB/T3142-82 (90) four-ball wear test machine (MIS-10P, Jinan trier factory) to test the extreme pressure and antiwear behavior of each sample: last non seizure load PB (N) value.
Rustless property adopts the antirust experimental technique of JB-T 9189-1999 water material, and the cast iron powder method is measured the rustless property of this kind rolling mill compound.With iron filings filter paper rust staining experiment test, filter paper does not have rust staining behind the 24h, shows that it has rustless property preferably.
Anti-microbial property adopts GB-15979-2002 appendix C 5 vibration flask method to carry out bacteriostasis rate (or sterilizing rate) test of germ resistance.
Among the embodiment, in the water-soluble nano silver water-sol, the weight content of nanometer silver is 1%, and the median size of silver particles is 20 nanometers.
Embodiment 1
Prescription: (100g)
Each component is mixed, can obtain product.
Record the extreme pressure and antiwear behavior PB value 804N of this rolling lubrication liquid.
Rustless property is as follows: filter paper does not have rust staining rustless property is preferably arranged behind the 24h, and the anti-microbial property bacteriostasis rate reaches 100%.
Embodiment 2
Prescription: (100g)
The weight concentration of the 2-amino-2-methyl-1-propanol aqueous solution is 25%.
Each component is mixed, can obtain product.
Record the extreme pressure and antiwear behavior PB value 804N of this rolling lubrication liquid.
Rustless property is as follows: filter paper does not have rust staining rustless property is preferably arranged behind the 24h, and the anti-microbial property bacteriostasis rate reaches 100%.
Embodiment 3
Prescription: (100g)
Each component is mixed, can obtain product.
Record the extreme pressure and antiwear behavior P of this rolling lubrication liquid
BValue 862N.
Rustless property is as follows: filter paper does not have rust staining behind the 24h, and rustless property is preferably arranged.The anti-microbial property bacteriostasis rate reaches 100%.
Embodiment 4
Prescription: (100g)
Each component is mixed, can obtain product.
Record the extreme pressure and antiwear behavior P of this rolling lubrication liquid
BValue 921N.
Rustless property is as follows: filter paper does not have rust staining behind the 24h, and rustless property is preferably arranged.The anti-microbial property bacteriostasis rate reaches 100%.
Embodiment 5
Prescription: (100g)
Each component is mixed, can obtain product.
Record the extreme pressure and antiwear behavior P of this rolling lubrication liquid
BValue 804N.
Rustless property is as follows: filter paper does not have rust staining behind the 24h, and rustless property is preferably arranged.The anti-microbial property bacteriostasis rate reaches 100%.
Embodiment 6
Prescription: (100g)
Each component is mixed, can obtain product.
Record the extreme pressure and antiwear behavior P of this rolling lubrication liquid
BValue 696N.
Rustless property is as follows: filter paper does not have rust staining behind the 24h, and rustless property is preferably arranged.The anti-microbial property bacteriostasis rate reaches 100%.
Claims (5)
1. the pure water base plate strip steel rolling liquid that contains nanometer silver, it is characterized in that, with water is carrier, contain weight percent and be 0.2～7% the water-soluble extreme pressure anti-wear additives and 0.005%～3% the water-soluble nano silver water-sol, described water-soluble extreme pressure anti-wear additives is more than one in the water-soluble extreme pressure anti-wear additives of EPW, trolamine, water-soluble phosphate, sodium salicylate or the potassium oleate; In the described water-soluble nano silver water-sol, the median size of silver particles is 10～50 nanometers, and the weight content of silver particles is 0.5～1.0%, the composition that described water-soluble extreme pressure anti-wear additives EPW is trolamine and ammonium phosphate ester.
2. the pure water base plate strip steel rolling liquid that contains nanometer silver according to claim 1 is characterized in that, is carrier with water, contains weight percent and be 0.5～3.5% the water-soluble extreme pressure anti-wear additives and 0.5%～3% the water-soluble nano silver water-sol.
3. the pure water base plate strip steel rolling liquid that contains nanometer silver according to claim 1 is characterized in that, is made up of following components in weight percentage:
4. the pure water base plate strip steel rolling liquid that contains nanometer silver according to claim 1 is characterized in that, is made up of following components in weight percentage:
5. according to claim 3 or the 4 described pure water base plate strip steel rolling liquid that contain nanometer silver, it is characterized in that, the water-soluble anti-rust inhibiter is phenylpropyl alcohol triazole, tetrahydroglyoxaline or is 15～40% the 2-amino-2-methyl-1-propanol aqueous solution for containing weight percent, or contains the aqueous solution that weight percent is the polycarboxylic acid of 20-50%;
Dispersion agent is selected from more than one in Polyvinylpyrolidone (PVP), polyvinyl alcohol, methylcellulose gum, Natvosol or the gelatin;
Defoamer is three-dimensional siloxanes or polyether antifoam agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110135679 CN102229847B (en) | 2011-05-24 | 2011-05-24 | Nano-silver-containing pure water base plate strip steel rolling fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110135679 CN102229847B (en) | 2011-05-24 | 2011-05-24 | Nano-silver-containing pure water base plate strip steel rolling fluid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102229847A true CN102229847A (en) | 2011-11-02 |
| CN102229847B CN102229847B (en) | 2013-06-05 |
Family
ID=44842453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110135679 Active CN102229847B (en) | 2011-05-24 | 2011-05-24 | Nano-silver-containing pure water base plate strip steel rolling fluid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102229847B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102807913A (en) * | 2012-07-17 | 2012-12-05 | 上海金兆节能科技有限公司 | Trace lubricating oil for machining steel hub and preparation method thereof |
| CN105368564A (en) * | 2015-11-17 | 2016-03-02 | 东莞市安美润滑科技有限公司 | Aqueous cutting fluid containing nano silver and preparation method and application method thereof |
| CN109337738A (en) * | 2018-09-06 | 2019-02-15 | 安美科技股份有限公司 | A kind of aqueous rolling mill compound containing nano silver and preparation method thereof and application method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999061567A1 (en) * | 1998-05-29 | 1999-12-02 | Unilever N.V. | Lubricant compositions |
| CN1552833A (en) * | 2003-05-31 | 2004-12-08 | 中国科学院兰州化学物理研究所 | Water-based lubricating nanometer metal antifriction and wear resistant intensifying agent |
| CN1970707A (en) * | 2006-11-09 | 2007-05-30 | 上海大学 | High-performance high water-based lubricant composition |
| CN101130711A (en) * | 2006-08-23 | 2008-02-27 | 冯为民 | Method of producing water-based cutting fluid |
| CN102010778A (en) * | 2010-12-16 | 2011-04-13 | 东莞市垠星科技发展有限公司 | Non-ferrous metal semisynthesis machining liquid |
-
2011
- 2011-05-24 CN CN 201110135679 patent/CN102229847B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999061567A1 (en) * | 1998-05-29 | 1999-12-02 | Unilever N.V. | Lubricant compositions |
| CN1552833A (en) * | 2003-05-31 | 2004-12-08 | 中国科学院兰州化学物理研究所 | Water-based lubricating nanometer metal antifriction and wear resistant intensifying agent |
| CN101130711A (en) * | 2006-08-23 | 2008-02-27 | 冯为民 | Method of producing water-based cutting fluid |
| CN1970707A (en) * | 2006-11-09 | 2007-05-30 | 上海大学 | High-performance high water-based lubricant composition |
| CN102010778A (en) * | 2010-12-16 | 2011-04-13 | 东莞市垠星科技发展有限公司 | Non-ferrous metal semisynthesis machining liquid |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102807913A (en) * | 2012-07-17 | 2012-12-05 | 上海金兆节能科技有限公司 | Trace lubricating oil for machining steel hub and preparation method thereof |
| CN105368564A (en) * | 2015-11-17 | 2016-03-02 | 东莞市安美润滑科技有限公司 | Aqueous cutting fluid containing nano silver and preparation method and application method thereof |
| CN109337738A (en) * | 2018-09-06 | 2019-02-15 | 安美科技股份有限公司 | A kind of aqueous rolling mill compound containing nano silver and preparation method thereof and application method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102229847B (en) | 2013-06-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2018032853A1 (en) | Micro-emulsion cutting fluid and preparation process therefor | |
| CN102796594B (en) | Cold-rolled sheet rolling emulsified oil containing modified nano copper and preparation method thereof | |
| CN109468162B (en) | Water-based rolling liquid containing hexagonal boron nitride nanoparticles and preparation method thereof | |
| CN102757852B (en) | Rolling lubricant composition and usage thereof | |
| CN108315085B (en) | High-temperature-resistant liquid metal extreme pressure lubricant and preparation method thereof | |
| WO2009076151A1 (en) | Formulation of a metalworking fluid | |
| CN102229847B (en) | Nano-silver-containing pure water base plate strip steel rolling fluid | |
| CN104450120A (en) | Semi-synthetic metal wire drawing lubricant liquid and preparation method thereof | |
| CN103184095A (en) | Aqueous solution lubricant for aluminum cold rolling | |
| CN107090328B (en) | Combined emulsifier, hot aluminum rolling oil containing combined emulsifier and application of combined emulsifier | |
| CN101519621A (en) | High-performance high-water base lubricant | |
| CN100457878C (en) | High-performance high water-based lubricant composition | |
| CN106367164B (en) | Graphene lubricating oil additive and preparation method thereof | |
| CN112111318A (en) | Plain carbon steel cold rolling oil composition, preparation method and application thereof | |
| CN113201390A (en) | Antifriction heat-resistant lithium-based grease and preparation method thereof | |
| CN105779092A (en) | Composite oil film bearing lubricating oil | |
| CN110218607A (en) | A kind of nano graphene oxide of composite mixed B-N/artificial schellite/silica stamping die lubricating fluid and preparation method thereof | |
| CN101244458A (en) | Metallic nano-particle surface amendment | |
| CN113278461B (en) | Volatile stamping oil | |
| JP2925449B2 (en) | Hot rolling lubricant and method of supplying hot rolling lubricant | |
| CN108441279B (en) | Bi-component high-lubricity antirust emulsified oil and preparation method and application thereof | |
| Sun et al. | The size effect of typical micro‐and nano‐calcium carbonate additives on the friction properties of calcium sulfonate grease | |
| CN103450985B (en) | Aluminum and aluminum alloy hot-rolled ionic emulsion composition | |
| CN117701325B (en) | Non-sulfur-chlorine system stainless steel cold rolling oil and preparation method and test method thereof | |
| TWI847476B (en) | Metalworking oil additive for improving extreme pressure and emulsibility |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240820 Address after: Room 1005, Building 2, No. 100 Qinzhou Road, Xuhui District, Shanghai, 200235 Patentee after: SHANGHAI HAIDU CHEMICAL TECHNOLOGY Co.,Ltd. Country or region after: China Patentee after: SHANGHAI HIRI LUBRICANTS R & D CENTER Address before: Room 1005, Building 2, No. 100 Qinzhou Road, Xuhui District, Shanghai, 200235 Patentee before: SHANGHAI HAIDU CHEMICAL TECHNOLOGY Co.,Ltd. Country or region before: China |
|
| TR01 | Transfer of patent right |