CN102183532B - Method for improving CT measurement fluid saturation accuracy - Google Patents

Abstract

The invention relates to a method for improving the accuracy of CT measurement of fluid saturation; a. respectively carrying out CT scanning on dry core samples inside and outside the core holder to obtain CT values; b. respectively carrying out CT scanning on a rock core of 100% saturated saline water in and out of the rock core holder to obtain CT values; c. the method comprises the following steps of creating bound water in a holder by a rock core, and measuring the CT value of the rock core in a bound water state; after the bound water is produced, calculating the saturation of the bound water according to the volume of the discharged water and the volume of the discharged water; d. respectively carrying out CT scanning on saturated saline water, experimental oil and peripheral air to obtain CT values; wherein the CT value of the air is a constant value in any medium; e. calculating the CT value of the saline water and the CT value of the oil in the rock core holder by using formulas III and V; f. c, utilizing a formula V to drive according to the CT value of the corrected saline water and oil obtained in the step eCalculating the oil-water saturation in the replacement process; the relative error of saturation is within 1%.

Description

A kind of method that improves CT measurement fluid saturation precision

Technical field

The present invention relates to a kind of method of testing rock core fluid saturation, be specifically related to the method that a kind of CT accurately measures fluid saturation.

Background technology

The CT technology is as measuring technology conventional in the core analysis, is widely used in nonuniformity mensurations, core sample selection, crack quantitative test of core description, rock core, the online aspects such as measurement, flowing experiment research of saturation degree.And utilize CT that the saturation degree of fluid in the rock is measured, become that the CT technology is the most general in petroleum industry, one of the most effective experimental technique.

The ultimate principle of CT scan rock is: the X-ray beam that CT machine internal X-ray pipe produces from a plurality of directions along object certain selected tomography aspect shine, the X ray amount that sees through by mensuration, organize the absorption coefficient of constituent parts volume after the digitizing through calculating this aspect, these absorption coefficients can consist of different character matrixs; Carry out digital-to-analog conversion by high-speed computer in the machine, can show or take photos at screen, the image of reconstruction can also provide each pixel X ray attenuation coefficient, usually uses the CT value representation.

For a fault surface of rock, the CT value that image provides is the mean value of each volume element, that is:

CT _dry＝(1-Φ)CT _grain+ΦCT _air (1)

CT _DryThe CT value of-dried rock fault surface

CT _GrainThe CT value of-rock skeleton

CT _AirThe CT value of-air

The factor of porosity of Φ-rock, %

Want the saturation degree of fluid in the computing rock, must be first with rock 100% saturated a kind of fluid.Such as elder generation's 100% saturation water, then obtain:

CT _waterwet＝(1-Φ)CT _grain+ΦCT _water (2)

CT _WaterwetThe CT value of fault surface behind-rock 100% saturation water

CT _GrainThe CT value of-rock skeleton

CT _WaterThe CT value of-water

The factor of porosity of Φ-rock, %

And the factor of porosity of rock also can calculate by (1) (2) two formulas:

$\mathrm{\Φ}=\frac{{\mathrm{CT}}_{\mathrm{waterwet}}-{\mathrm{CT}}_{\mathrm{dry}}}{{\mathrm{CT}}_{\mathrm{water}}-{\mathrm{CT}}_{\mathrm{air}}}---\left(3\right)$

The CT value of a certain moment rock fault surface is in the displacement process:

CT _x＝(1-Φ)CT _grain+Φ(S _wCT _water+S _oCT _oil) (4)

CT _xThe CT value of-a certain moment rock fault surface

CT _GrainThe CT value of-rock skeleton

CT _WaterThe CT value of-water

CT _OilThe CT value of-oil

The factor of porosity of Φ-rock, %

S _w-water saturation, %

S _o-oil saturation, %

According to S _w+ S _o=1 reaches (1) (2) (4) formula can calculate moisture, oil saturation:

$S_o=\frac{{\mathrm{CT}}_{\mathrm{waterwet}}-{\mathrm{CT}}_x}{{\mathrm{CT}}_{\mathrm{waterwet}}-{\mathrm{CT}}_{\mathrm{dry}}}\·\frac{{\mathrm{CT}}_{\mathrm{water}}-{\mathrm{CT}}_{\mathrm{air}}}{{\mathrm{CT}}_{\mathrm{water}}-{\mathrm{CT}}_{\mathrm{oil}}}$

$S_w=1-\frac{{\mathrm{CT}}_{\mathrm{waterwet}}-{\mathrm{CT}}_x}{{\mathrm{CT}}_{\mathrm{waterwet}}-{\mathrm{CT}}_{\mathrm{dry}}}\·\frac{{\mathrm{CT}}_{\mathrm{water}}-{\mathrm{CT}}_{\mathrm{air}}}{{\mathrm{CT}}_{\mathrm{water}}-{\mathrm{CT}}_{\mathrm{oil}}}---\left(5\right)$

As can be seen from the above equation, calculate the CT value that the two-phase fluid saturation degree need to be known air, water and oil.But under normal conditions, rock core all is to test in core holding unit, and because ray hardened impact, it is different that water is directly exposed to airborne CT value with oil in the core holding unit neutralization; Oil and the CT value of water in core holding unit are difficult to again obtain, and all application are exposed to the CT value of airborne water and oil and calculate, and can bring certain error to the result of calculation of saturation degree.

Adopt another kind of method in some research work, be about to rock 100% saturation water post-drying, 100% saturated oil again obtains:

CT _oilwet＝(1-Φ)CT _grain+ΦCT _oil (6)

CT _OilwetThe CT value of fault surface behind-rock 100% saturated oil

CT _GrainThe CT value of-rock skeleton

CT _OilThe CT value of-oil

The factor of porosity of Φ-rock, %

Again moisture, oil saturation are calculated:

$S_o=\frac{{\mathrm{CT}}_{\mathrm{waterwet}}-{\mathrm{CT}}_x}{{\mathrm{CT}}_{\mathrm{waterwet}}-{\mathrm{CT}}_{\mathrm{oilwet}}}$

$S_w=\frac{{\mathrm{CT}}_x-{\mathrm{CT}}_{\mathrm{oilwet}}}{{\mathrm{CT}}_{\mathrm{waterwet}}-{\mathrm{CT}}_{\mathrm{oilwet}}}---\left(7\right)$

Avoid oil, water CT value to change the error of bringing with the method, also improved the degree of accuracy of measuring.But common rock core displacement test all needs to make irreducible water, and the method carries out needing twice also oven dry of saturated liquid before the displacement test so that corresponding experimentation is too loaded down with trivial details, and the core sample more intense to susceptibility also can cause certain injury.

Summary of the invention

The objective of the invention is to propose a kind of easy experiment test method that can improve CT measurement fluid saturation precision.

A kind of method that CT measures the fluid saturation precision that improves of the present invention, it comprises the steps:

A. after the core sample oven dry, carry out CT scan, obtain the CT value CT of this dried rock core fault surface _{Outside the dry}Again this rock core is packed in the core holding unit, and under the same condition of displacement process and under the same CT condition rock core is scanned, obtain the CT value CT of dried rock core fault surface _{Dry In}

B. with behind this rock core 100% saturated brine, in the inside and outside CT scan of carrying out of core holding unit, experiment condition and step a are in full accord respectively, the outer CT value CT of core holding unit behind acquisition rock core 100% saturated brine _{Outside the waterwet}With the CT value CT in the core holding unit _{In the waterwet}

C. rock core utilizes oily expelling water to make irreducible water in clamper, measures the CT value of core sample under the irreducible water state; And in endpiece metering water outlet, oil pump capacity, made behind the irreducible water according to water outlet, fluid volume irreducible water saturation S _wCalculate;

D. carry out CT scan with oil and peripheral air and obtain CT value CT with salt solution, experiment saturated respectively _{Outside the water}, CT _{Outside the oil}And CT _AirWherein, the CT value of air all is definite value in any medium;

E. utilize formula III that the CT value of salt solution in the core holding unit is calculated CT _{Water In}

F. pass through the CT of dried core sample in the core holding unit _{In the dry}, 100% saturated brine the CT of core sample _{In the waterwet}, the CT of core sample under the irreducible water state _{In the x}, the irreducible water saturation S that obtains of step c _w, and the CT of salt solution in core holding unit that obtain of step e _{In the water}, utilize formula V that the CT value of oil in the core holding unit is calculated CT _{In the oil}

$S_w=1-\frac{{\mathrm{CT}}_{\mathrm{waterwet}}-{\mathrm{CT}}_x}{{\mathrm{CT}}_{\mathrm{waterwet}}-{\mathrm{CT}}_{\mathrm{dry}}}\·\frac{{\mathrm{CT}}_{\mathrm{water}}-{\mathrm{CT}}_{\mathrm{air}}}{{\mathrm{CT}}_{\mathrm{water}}-{\mathrm{CT}}_{\mathrm{oil}}}---\left(V\right)$

G. the corrected salt solution and the oily CT value that obtain according to step e, step f utilize formula V that the profit saturation degree in the displacement process is calculated.

Beneficial effect of the present invention is, final irreducible water saturation was easy to by the volumetric method accurate measurement when irreducible water was made in the method utilization, by this irreducible water saturation, and core sample scans the rock porosity value that obtains outside clamper, the CT value of water and oil is proofreaied and correct rear recycling formula convection cell saturation degree to be calculated, can greatly improve the degree of accuracy of measurement, so that the relative error of saturation degree is in 1%.On the other hand, the method only needs a saturated liquid, has reduced compared with the prior art operation steps.

Description of drawings

Fig. 1 is that oil-water is to permeability curve figure.

Embodiment

Embodiment 1 utilizes the CT scan technology accurately to measure profit two phase saturations and to make profit relative

Permeability curve

(1) sample: the I4D of Daqing oil field Portugal well Sandstone Cores sample 32#.

(2) instrument: GE LightSpeed 8 helical layer Medical CT scanners; The carbon fiber core holding unit; Quzix SP-5000 high-pressure metering pump.

(3) CT scan condition: scanning voltage: 100kV, sweep current: 100mA, scan mode: axial scan, scanning bed thickness: 1.25mm, each scan slice width of cloth number: 49 width of cloth.

(4) experimentation:

1. after core sample oven dry is weighed and measured factor of porosity and air permeability, be placed on core holding unit and scan outward, and the CT value of writing scan direction, position and each scan slice;

2. during core sample is packed core holding unit into, add confined pressure to 5MPa with distilled water, under the direction of scanning with step 1 rock core is scanned, and the CT value of writing scan position and each scan slice;

3. the NaI aqueous solution 24 hours of rock core vacuum saturated 5% is taken out and is claimed weight in wet base and buoyant weight, calculates volume of voids and degree of saturation.Degree of saturation is being carried out next step experiment again more than 99%;

Core sample respectively outside core holding unit and in the core holding unit (adding the 5MPa confined pressure) scan, direction of scanning, position respectively with step 1,2 in full accord, record the CT value of each scan slice;

5. rock core utilizes oily expelling water to make irreducible water in clamper, and in endpiece metering water outlet, oil pump capacity, according to water outlet, fluid volume irreducible water saturation is calculated after having made irreducible water;

6. the core sample (in clamper) of having made irreducible water is scanned, direction of scanning, position and step 2 are in full accord, record the CT value of each scan slice;

7. 5%NaI solution, the experiment of saturated usefulness are carried out CT scan with oil and peripheral air and obtain the CT value;

8. oil and 5%NaI solution are injected rock sample in the ratio of setting, after stablizing wait flowing, core sample (in clamper) is scanned, direction of scanning, position and step 2 are in full accord, record the CT value of each scan slice; Record simultaneously two ends pressure reduction;

9. change profit and inject ratio, repeating step 8 finishes experiment until last profit injects ratio;

10. utilize formula (III) and (V) each profit is injected profit two-phase saturation computation than lower each section, and average and be this profit and inject saturation degree than profit two-phase in the lower rock core; Utilize Darcy formula that the relative permeability of profit two-phase is calculated, and draw permeability-ratio curve as shown in Figure 1.

Experimental data and result are as shown in table 1.

Table 1

Reference examples 1 utilizes volumetric method, conventional CT method and the inventive method to measure profit two phase saturations

(1) sample: two in the I4D of Daqing oil field Portugal well Sandstone Cores sample.2# sample length 6.31cm wherein, diameter 2.541cm, factor of porosity 19.8%, air permeability 154mD; 34# sample length 5.717cm, diameter 2.538cm, factor of porosity 22.5%, air permeability 642mD.

(2) instrument: GE LightSpeed 8 helical layer Medical CT scanners; The carbon fiber core holding unit; Quzix SP-5000 high-pressure metering pump.

(3) CT scan condition: scanning voltage: 100kV, sweep current: 100mA, scan mode: axial scan, scanning bed thickness: 1.25mm.

(4) experimentation:

1. after the core sample oven dry, be placed on core holding unit and scan outward, and the CT value of writing scan direction, position and each scan slice;

2. during core sample is packed core holding unit into, add confined pressure to 5MPa with distilled water, under the direction of scanning with step 1 rock core is scanned, and the CT value of writing scan position and each scan slice;

3. the NaI aqueous solution 24 hours of rock core vacuum saturated 5% is taken out and is claimed weight in wet base and buoyant weight, calculates volume of voids and degree of saturation.Degree of saturation is being carried out next step experiment again more than 99%;

Core sample respectively outside core holding unit and in the core holding unit (adding the 5MPa confined pressure) scan, direction of scanning, position respectively with step 1,2 in full accord, record the CT value of each scan slice;

5. rock core utilizes oily expelling water to make irreducible water in clamper, and in endpiece metering water outlet, oil pump capacity, according to water outlet, fluid volume irreducible water saturation is calculated after having made irreducible water;

6. the core sample (in clamper) of having made irreducible water is scanned, direction of scanning, position and step 2 are in full accord, record the CT value of each scan slice;

7. 5%NaI solution, the experiment of saturated usefulness are carried out CT scan with oil and peripheral air and obtain the CT value;

8. with the flow velocity injection rock sample of 5%NaI solution with 0.5ml/min, 0.5min rear termination of pumping, the volume of oil and water scans core sample (in clamper) simultaneously in the recorded stream fluid, direction of scanning, position and step 2 are in full accord, record the CT value of each scan slice.

9. turn on pump again, every 0.5min stops pump No. one time, and repeating step 8 is until no longer fuel-displaced end experiment.

10. utilize formula (III) and (V) to the profit two-phase saturation computation of each section after the each time termination of pumping, and average and be the saturation degree of profit two-phase in this moment rock core; Calculate profit two phase saturations according to volumetric method simultaneously, computing formula is as follows:

$S_w=\frac{\mathrm{vt}+S_{\mathrm{wi}}{V}_p-\mathrm{\Δ}{V}_w}{V_p}\×100\%$

S _w-water saturation, %

The v-injection rate, ml/min

The t-injection length, min

S _Wi-irreducible water saturation, %

V _p-volume of voids, ml

Δ V _w-accumulative total water outlet volume, ml

Utilize volumetric method, conventional CT method (referring to the background technology part) and the inventive method to measure profit two phase saturation results as shown in table 2, take the volumetric method measurement result as standard, conventional CT method measuring error is 0.5～3.6%, and the measuring error of the inventive method only is 0～1.5%, as seen, method measuring accuracy of the present invention is higher.

Table 2

Claims (1)

1. one kind is improved the method that CT measures the fluid saturation precision, it is characterized in that, it comprises the steps:

A. after the core sample oven dry, carry out CT scan, obtain the CT value CT of dried rock core fault surface _{Outside the dry}Again this rock core is packed in the core holding unit, and under the same condition of displacement process and under the same CT condition rock core is scanned, obtain the CT value CT of dried rock core fault surface _{Dry In}

B. with behind this rock core 100% saturated brine, in the inside and outside CT scan of carrying out of core holding unit, experiment condition and step a are in full accord respectively, the outer CT value CT of core holding unit behind acquisition rock core 100% saturated brine _{Outside the waterwet}With the CT value CT in the core holding unit _{In the waterwet}

C. rock core utilizes oily expelling water to make irreducible water in clamper, measures the CT value CT of core sample under the irreducible water state _{In the x}And in endpiece metering water outlet, oil pump capacity, made behind the irreducible water according to water outlet, fluid volume irreducible water saturation S _wCalculate;

D. carry out CT scan with oil and peripheral air and obtain CT value CT with salt solution, experiment saturated respectively _{Outside the water}, CT _{Outside the oil}And CT _AirWherein, the CT value of air all is definite value in any medium;

E. utilize formula III that the CT value of salt solution in the core holding unit is calculated CT _WaterIn;

F. pass through the CT of dried core sample in the core holding unit _{In the dry}, 100% saturated brine the CT of core sample _{In the waterwet}, the CT of core sample under the irreducible water state _{In the x}, the irreducible water saturation S that obtains of step c _w, and the CT of salt solution in core holding unit that obtain of step e _{In the water}, utilize formula V that the CT value of oil in the core holding unit is calculated CT _{In the oil}

G. the corrected salt solution and the oily CT value CT that obtain according to step e, step f _{Water In}And CT _{In the oil}, utilize formula V that the irreducible water saturation in the displacement process is calculated.

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