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CN102173716A - Analogous ceramic high-temperature resistant friction material and preparation method thereof - Google Patents

Analogous ceramic high-temperature resistant friction material and preparation method thereof Download PDF

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Publication number
CN102173716A
CN102173716A CN 201110045089 CN201110045089A CN102173716A CN 102173716 A CN102173716 A CN 102173716A CN 201110045089 CN201110045089 CN 201110045089 CN 201110045089 A CN201110045089 A CN 201110045089A CN 102173716 A CN102173716 A CN 102173716A
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friction material
weight percent
temperature resistant
friction
analogous
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CN102173716B (en
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付业伟
施俭亮
李贺军
齐乐华
朱文婷
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Xi'an Boxin New Materials Technology Co ltd
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Northwestern Polytechnical University
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/30Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
    • C04B26/32Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Braking Arrangements (AREA)

Abstract

The invention discloses an analogous ceramic high-temperature resistant friction material and a preparation method thereof, which are used for solving the technical problem of poor heat resistance of the traditional friction material. The analogous ceramic high-temperature resistant friction material is prepared by replacing a phenolic resin adhesive in an organically synthesized friction material with an inorganic liquid water-soluble aluminum silicate adhesive, and the heat resistance of the friction material is enhanced because the analogous ceramic high-temperature resistant friction material does not contain organic components. The analogous ceramic high-temperature resistant friction material is not reduced in friction coefficient after being ablated at the high temperature of 600 DEG C; and in addition, the friction material with ceramic characteristics is prepared by discarding a high-temperature sintering process of the traditional ceramic friction material on the aspect of a preparation process and adopting a preparation process of the organically synthesized friction material, thereby the cost is greatly lowered.

Description

High temperature resistant friction materials of class pottery and preparation method thereof
Technical field
The present invention relates to a kind of high temperature resistant friction materials, is the high temperature resistant friction materials of kind pottery specifically.Also relate to the high temperature resistant method for preparing friction of this kind pottery.
Background technology
Along with vehicle develops to environmental protection, high speed and heavily loaded direction, people are to the demands for higher performance of automobile brake material, and particularly when high-temperature brake, the stability and the security of material are most important.Brake system of car mainly uses semimetal friction material, no asbestos organic friction material (NAO), powder metallurgy friction material, ceramic frication material etc. at present.Semimetal friction material, no asbestos organic friction material have preparation technology's characteristic of simple, but thermotolerance is relatively poor, and powder metallurgy friction material, ceramic frication material thermotolerance are better, but complicated process of preparation, the cost height.
Document 1 " patent publication No. is the Chinese patent of CN02119505.6 " discloses a kind of asbestos-free friction material and manufacture method.The composition proportioning of this friction materials: resin 10~20%, powdered iron ore 5~25%, reburned magnesia 1~10%, ferrophosphorus breeze 1~5%, aluminum oxide 1~10%, silica 1~7%, barite 1~20%, wollastonite 1~15%, carbon black 1~8%, lime carbonate 1~15%, graphite 1~10%, tyre talc 1~10%, vegetable fibre 1~20%, sepiolite 1~20%, steel fiber 1~5%, Zinic stearas 0.1~4%.Producing and manufacturing technique: raw material is mixed back 110~130 ℃ of following preheatings 30 minutes, weighing certain material, to put into mould hot-forming under 165~170 ℃ temperature and 25MPa, 5~20 minutes dwell times, earlier 140 ℃ of sulfurations 1.5~2 hours, vulcanized 4~8 hours at 165 ℃ again after the pressure release.The characteristics of this class friction materials are that the frictional behaviour adjustability is good, and preparation technology is simple; But because the restriction of resin glue, thermotolerance is relatively poor, when temperature is higher than 300 ℃ heat fading will take place, and wear rate increases, and maximum operation (service) temperature is not higher than 400 ℃.
Document 2 " patent publication No. is the Chinese patent of CN01115331.8 " discloses a kind of ceramic friction material and manufacture method that contains steel fiber, the composition of material is: copper powder and glass putty 53~69%, the short steel fiber 10~40% of cutting, iron powder 0~10%, inorganic oxide or mineral 3~8%, graphite 5~12%, molybdenumdisulphide 0~4%.Manufacturing process is: coldmoulding under 150~300MPa pressure, under the reducing gas protection, carry out sintering, 700~920 ℃ of sintering temperatures, pressure 1~2MPa, 3~8 hours time.The resistance toheat of this metalloid ceramic frication material is good, heat fading can not take place under 500 ℃ of working conditions; But preparation process processing condition more complicated, the cost height.
Summary of the invention
In order to overcome the deficiency of existing friction materials poor heat resistance, the invention provides the high temperature resistant friction materials of kind pottery.By replace resol or the modified phenolic resin adhesive in organic synthetic friction material with mineral binder bond, the high temperature resistant friction materials of preparation class pottery owing to do not have organic composition in the high temperature resistant friction materials of class pottery, can improve the thermotolerance of friction materials.
The invention still further relates to the high temperature resistant method for preparing friction of this kind pottery.
The technical solution adopted for the present invention to solve the technical problems: the high temperature resistant friction materials of kind pottery is that 15~30% fortifying fibre, weight percent are that 40~59% the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent, weight percent are that 15~23% friction modifiers and weight percent are that 10~14% filler is prepared from by weight percent;
Described fortifying fibre is several mixtures of appointing of PAN-based carbon fiber, asphalt base carbon fiber, copper fiber, ceramic fiber, glass fibre, non-asbestos deposit fibres or steel fiber;
Described friction modifiers is several mixtures of appointing of graphite, molybdenumdisulphide, aluminium sesquioxide, silicon-dioxide, silicon carbide, silicon nitride or boron nitride;
Described filler is several mixtures of appointing of zinc oxide, barium sulfate, kaolin, lime carbonate, fluorite powder, breeze, chromite, magnesium oxide or diatomite in powder.
The high temperature resistant method for preparing friction of a kind of above-mentioned class pottery, be characterized in may further comprise the steps: with weight percent is that 10~14% filler and weight percent are that 15~23% friction modifiers is added in the blender and mixes, add weight percent then and be 15~30% fortifying fibre and mix, to the fortifying fibre homodisperse; Adding weight percent and be 40~59% the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent stirs; Stir simultaneously and utilize the heating jacket heating in the stirrer bottom, the top takes gas blower blowing hot-air forced convection mode to promote moisture evaporation in the compound to obtain the powder material at last; At room temperature the powder material is put into the mould extrusion forming, forming pressure 20~50MPa, pressurize 10~30 minutes; Blank after the moulding is put into the temperature programmed control air dry oven, open gas blower, heat-treat.
The invention has the beneficial effects as follows: because the water-soluble silicic acid aluminium of employing inorganic, fluid tackiness agent replaces the phenolic resin adhesive in organic synthetic friction material, the high temperature resistant friction materials of preparation class pottery, owing to do not have organic composition in the high temperature resistant friction materials of class pottery, improved the thermotolerance of friction materials.The high temperature resistant friction materials of class pottery of the present invention preparation, frictional coefficient is undamped after through 600 ℃ of high temperature ablations; Discard tradition aspect the preparation technology high-sintering process of ceramic frication material adopts the preparation technology of organic synthesis friction materials, prepares the friction materials with ceramic characteristics, and cost reduces significantly.
Below in conjunction with embodiment the present invention is elaborated.
Embodiment
Embodiment 1: starting material are formed: filler 20g comprises zinc oxide 5g, barium sulfate 5g, kaolin 8g, lime carbonate 2g; Friction modifiers 40g comprises graphite 14g, aluminium sesquioxide 12g, silica 1 4g; Fortifying fibre 60g comprises PAN-based carbon fiber 15g, ceramic fiber 5g, asphalt base carbon fiber 15g, copper fiber 25g, the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 80g.
Preparation technology: at first each filler 20g and friction modifiers 40g are added in the blender and mix, add fortifying fibre 60g then and mix, to the fiber homodisperse.Adding the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 80g stirs.Stir simultaneously and utilize the heating jacket heating in the stirrer bottom, the top takes gas blower blowing hot-air forced convection mode to promote moisture evaporation in the compound, and obtaining granularity at last is that 0.01~1mm and moisture content are 5~10% powder material.At room temperature the powder material is put into the mould extrusion forming, forming pressure 20MPa, pressurize 30 minutes.Blank is put into the temperature programmed control air dry oven, open gas blower, heat-treat.
Embodiment 2: starting material are formed: filler 30g comprises zinc oxide 5g, barium sulfate 8g, kaolin 5g, lime carbonate 7g, fluorite powder 5g; Friction modifiers 50g comprises graphite 16g, aluminium sesquioxide 15g, silica 1 9g, and fortifying fibre 40g comprises PAN-based carbon fiber 15g, glass fibre 10g, steel fiber 15g, the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 100g.
Preparation technology: at first each filler 30g and friction modifiers 50g are added in the blender and mix, add fortifying fibre 40g then and mix, to the fiber homodisperse.Adding the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 100g stirs.Stir simultaneously and utilize the heating jacket heating in the stirrer bottom, the top takes gas blower blowing hot-air forced convection mode to promote moisture evaporation in the compound, and obtaining granularity at last is that 0.01~1mm and moisture content are 5~10% powder material.At room temperature the powder material is put into the mould extrusion forming, forming pressure 45MPa, pressurize 15 minutes.Blank is put into the temperature programmed control air dry oven, open gas blower, heat-treat.
Embodiment 3: starting material are formed: filler 25g comprises zinc oxide 4g, barium sulfate 3g, kaolin 6g, lime carbonate 2g, breeze 4g, chromite 6g; Friction modifiers 30g comprises graphite 9g, aluminium sesquioxide 21g; Fortifying fibre 30g comprises PAN-based carbon fiber 10g, asphalt base carbon fiber 10g, copper fiber 10g; The water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 120g.
Preparation technology: at first each filler 20g and friction modifiers 40g are added in the blender and mix, add fortifying fibre 60g then and mix, to the fiber homodisperse.Adding the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 80g stirs.Stir simultaneously and utilize the heating jacket heating in the stirrer bottom, the top takes gas blower blowing hot-air forced convection mode to promote moisture evaporation in the compound, and obtaining granularity at last is that 0.01~1mm and moisture content are 5~10% powder material.At room temperature the powder material is put into the mould extrusion forming, forming pressure 50MPa, pressurize 120 minutes.Blank is put into the temperature programmed control air dry oven, open gas blower, heat-treat.
Embodiment 4: starting material are formed: filler 25g comprises zinc oxide 4g, magnesium oxide 3g, kaolin 6g, fluorite powder 2g, diatomite in powder 4g, chromite 6g; Friction modifiers 30g comprises molybdenumdisulphide 9g, silicon carbide 7g, silicon nitride 7g, boron nitride 7g; Fortifying fibre 40g comprises PAN-based carbon fiber 10g, non-asbestos deposit fibres 10g, asphalt base carbon fiber 10g, copper fiber 5g, steel fiber 5g; The water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 110g.
Preparation technology: at first each filler 20g and friction modifiers 30g are added in the blender and mix, add fortifying fibre 40g then and mix, to the fiber homodisperse.Adding the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent 110g stirs.Stir simultaneously and utilize the heating jacket heating in the stirrer bottom, the top takes gas blower blowing hot-air forced convection mode to promote moisture evaporation in the compound, and obtaining granularity at last is that 0.01~1mm and moisture content are 5~10% powder material.At room temperature the powder material is put into the mould extrusion forming, forming pressure 50MPa, pressurize 10 minutes.Blank is put into the temperature programmed control air dry oven, open gas blower, heat-treat.
The high temperature resistant friction materials frictional behaviour test of the class pottery of the present invention's preparation: the high temperature resistant friction materials of class pottery of preparation is put into retort furnace ablated 600 ℃ of ablation temperatures 2 hours.Utilize QDM type adjustable speed pressure regulation dry type friction material test machine that the frictional coefficient of material before and after ablating is measured, test is carried out with brake facing according to the GB5763-1998 automobile, and test-results sees the following form.
Figure BSA00000439486500041
The contriver is in the disclosed process parameters range of technical scheme, and different parameter collocation are all tested, and have all obtained good effect.

Claims (2)

1. the high temperature resistant friction materials of kind pottery is that 15~30% fortifying fibre, weight percent are that 40~59% the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent, weight percent are that 15~23% friction modifiers and weight percent are that 10~14% filler is prepared from by weight percent;
Described fortifying fibre is several mixtures of appointing of PAN-based carbon fiber, asphalt base carbon fiber, copper fiber, ceramic fiber, glass fibre, non-asbestos deposit fibres or steel fiber;
Described friction modifiers is several mixtures of appointing of graphite, molybdenumdisulphide, aluminium sesquioxide, silicon-dioxide, silicon carbide, silicon nitride or boron nitride;
Described filler is several mixtures of appointing of zinc oxide, barium sulfate, kaolin, lime carbonate, fluorite powder, breeze, chromite, magnesium oxide or diatomite in powder.
2. the high temperature resistant method for preparing friction of the described class pottery of a claim 1, it is characterized in that may further comprise the steps: with weight percent is that 10~14% filler and weight percent are that 15~23% friction modifiers is added in the blender and mixes, add weight percent then and be 15~30% fortifying fibre and mix, to the fortifying fibre homodisperse; Adding weight percent and be 40~59% the water-soluble silicic acid aluminium of inorganic, fluid tackiness agent stirs; Stir simultaneously and utilize the heating jacket heating in the stirrer bottom, the top takes gas blower blowing hot-air forced convection mode to promote moisture evaporation in the compound to obtain the powder material at last; At room temperature the powder material is put into the mould extrusion forming, forming pressure 20~50MPa, pressurize 10~30 minutes; Blank after the moulding is put into the temperature programmed control air dry oven, open gas blower, heat-treat.
CN 201110045089 2011-02-24 2011-02-24 Analogous ceramic high-temperature resistant friction material and preparation method thereof Active CN102173716B (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102618216A (en) * 2012-02-27 2012-08-01 西北工业大学 Ceramic-like friction material and preparation method thereof
CN104087245A (en) * 2014-07-01 2014-10-08 北京瑞斯福高新科技股份有限公司 Friction material for brake-shoe of heavy axle-load wagon and preparation method of friction material
CN104817819A (en) * 2015-04-23 2015-08-05 中国地质大学(武汉) Spherical silicon oxide filled composite friction material preparation method
CN105299112A (en) * 2015-11-12 2016-02-03 东营睿智友亮石油设备有限公司 Environment-friendly coconut charcoal fiber composite friction material and manufacturing method for brake pad
CN105819861A (en) * 2016-03-17 2016-08-03 杭州富阳飞博科技有限公司 High strength corrosion resistant ceramic plate and preparation technology thereof
CN107573897A (en) * 2017-09-27 2018-01-12 武汉元丰摩擦材料有限公司 A kind of high-temperature resistant friction material additive and preparation method thereof
CN108003836A (en) * 2017-11-29 2018-05-08 北京天仁道和新材料有限公司 It is used to prepare the composite fibre and preparation method and ceramic frication material and preparation method and Ceramic Disc Brakes of ceramic frication material
CN108331860A (en) * 2018-04-04 2018-07-27 成都工业学院 A kind of brake block
CN109336615B (en) * 2018-12-03 2021-06-22 中国科学院兰州化学物理研究所 High-toughness, wear-resistant and friction-reducing sialon-tin composite material
CN113929352A (en) * 2020-06-29 2022-01-14 比亚迪股份有限公司 Imitation ceramic material and preparation method and application thereof

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US6062569A (en) * 1997-12-12 2000-05-16 Northrop Grumman Corporation Fiber reinforced ceramic matrix composite piston ring
CN101592203A (en) * 2009-07-06 2009-12-02 中南大学 A kind of semimetal ceramic base automobile brake pad and preparation method thereof
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JP2010249313A (en) * 2009-03-24 2010-11-04 Mitsuboshi Belting Ltd Belt type transmission
CN101592203A (en) * 2009-07-06 2009-12-02 中南大学 A kind of semimetal ceramic base automobile brake pad and preparation method thereof
CN101664979A (en) * 2009-10-09 2010-03-10 山东双连制动材料有限公司 Preparation method of friction material

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102618216A (en) * 2012-02-27 2012-08-01 西北工业大学 Ceramic-like friction material and preparation method thereof
CN104087245A (en) * 2014-07-01 2014-10-08 北京瑞斯福高新科技股份有限公司 Friction material for brake-shoe of heavy axle-load wagon and preparation method of friction material
CN104817819A (en) * 2015-04-23 2015-08-05 中国地质大学(武汉) Spherical silicon oxide filled composite friction material preparation method
CN105299112A (en) * 2015-11-12 2016-02-03 东营睿智友亮石油设备有限公司 Environment-friendly coconut charcoal fiber composite friction material and manufacturing method for brake pad
CN105819861A (en) * 2016-03-17 2016-08-03 杭州富阳飞博科技有限公司 High strength corrosion resistant ceramic plate and preparation technology thereof
CN105819861B (en) * 2016-03-17 2018-07-27 佛山市禅城区优胜陶瓷有限公司 A kind of high-strength corrosion-resisting ceramic wafer and its preparation process
CN107573897A (en) * 2017-09-27 2018-01-12 武汉元丰摩擦材料有限公司 A kind of high-temperature resistant friction material additive and preparation method thereof
CN108003836A (en) * 2017-11-29 2018-05-08 北京天仁道和新材料有限公司 It is used to prepare the composite fibre and preparation method and ceramic frication material and preparation method and Ceramic Disc Brakes of ceramic frication material
CN108331860A (en) * 2018-04-04 2018-07-27 成都工业学院 A kind of brake block
CN109336615B (en) * 2018-12-03 2021-06-22 中国科学院兰州化学物理研究所 High-toughness, wear-resistant and friction-reducing sialon-tin composite material
CN113929352A (en) * 2020-06-29 2022-01-14 比亚迪股份有限公司 Imitation ceramic material and preparation method and application thereof

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