CN101999349B - D-limonene-containing mixed oil agent for killing solenopsis invicta buren and method for killing the solenopsis invicta buren - Google Patents
D-limonene-containing mixed oil agent for killing solenopsis invicta buren and method for killing the solenopsis invicta buren Download PDFInfo
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Abstract
The invention provides a d-limonene-containing mixed oil agent for killing solenopsis invicta buren and a method for killing the solenopsis invicta buren. The d-limonene-containing mixed oil agent consists of 80 to 90 percent of d-limonene and 10 to 20 percent of edible vegetable oil in percentage by volume. The method for killing the solenopsis invicta buren comprises the step of placing a carrier adsorbing the d-limonene-containing mixed oil agent into solenopsis invicta buren nests, wherein the using amount of the d-limonene-containing mixed oil agent in each nest is 10 to 50 ml. In the d-limonene-containing mixed oil agent and the method for killing the solenopsis invicta buren, the high volatility of the d-limonene can permeate the nests and wax protective layers of all the individual body surfaces of the solenopsis invicta buren in the nests can be damaged through high permeability of the d-limonene, so the blockage of the spiracles of the solenopsis invicta buren can cause asphyxiation and death of the solenopsis invicta buren; the edible vegetable oil has unique oil odor, so the number of solenopsis invicta buren escaping from the nests caused by the repelling reaction to the d-limonene can be reduced; the d-limonene-containing mixed oil agent enters the nests quickly by a cave administration method, so that all the individuals including the queen ant in each nest can be killed quickly and the aim of killing the solenopsis invicta buren nests is fulfilled.
Description
Technical field:
The invention belongs to the insect control field, be specifically related to the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene of a kind of extremely red fire ant and use the method that this contains the miscible oil killing red ant of (R)-4-isopropenyl-1-methyl-1-cyclohexene.
Background technology:
Red fire ant is a kind of very harmful and be listed in the world one of tool invasion property and destructive 100 kinds of pests to human and livestock health, agricultural production, ecotope and communal facility.Red fire ant stings when stinging human body, rapidly repeatedly injects the venom that contains the high concentration toxin in skin, causes pain as the violent calcination, causes red swelling of the skin and produces the purulence bubble, and allergy sufferers high fever can occur, feels sick, chest pain, shock even death.Red fire ant originates in South America Parana basin, and the '20s invasion in last century U.S. harm is diffused into a plurality of countries such as West Indian Ocean Isle, New Zealand and Puerto Rico subsequently.Although external tag or with the many kinds of measures prevention and control such as period poison bait of insect growth regulator, IGR preparation, red fire ant still spreads in many countries at present through adopting decades with chemical agent.US Experts prediction, the wide geographic area in middle Mexico, Central America, close on surrounding area, Mediterranean, the Caspian Sea and Black Sea in the neighbourhood, many countries and regions such as most area, Africa, India, the southeast, Asia, Middle East, South Japan, Korea S south all are that the potential invasion of red fire ant is regional.Red fire ant is by the anthropochory that may bring in naturally diffusion and the world economy and trade, worldwide extensively invasion, the serious threat that the facing mankind red fire ant endangers.
Found red fire ant in 2003 in China Taiwan, subsequently in Hong Kong, the Electric Field At Ground In Partial Region of the provinces and regions such as Macao, Guangdong, Guangxi, Hunan and Fujian occurs in succession, and is diffusion and spreads situation, the national Ministry of Agriculture classifies it as quarantine pest.Xue Dayong etc. (2005) adopt the parameter of U.S.'s fitting of distribution, utilize respectively CLIMEX and GARP2 kind methods analyst result to show, China south China, East China, Central China and southwest totally 25 provinces and cities and North China some areas, the north in addition can to arrive Hebei Province will be that the potential invasion of red fire ant is regional.The greenhouse culture of global warming and crop provides suitable existence and procreation condition for red fire ant, and therefore, red fire ant is also spread the area to the north of prediction distribution circle.China's scholarly forecast is not eradicated if do not adopt an effective measure, and can cause 1280.4 hundred million yuans economic loss at following 35 years.Red fire ant can't be calculated especially to the loss that environmental disruption causes.To this, the Ministry of Agriculture had worked out " national red fire ant epidemic situation is eradicated plan " (farming is done farming [2005] No. 51) in 2005.The characteristics that, diffusion fast according to the red fire ant reproduction speed spread rapidly, be difficult to eradicate after invade successfully are very difficult processes in the target of China realization elimination red fire ant.
Although brought into play strong effect with chemical insecticide prevention and control red fire ant both at home and abroad, long-term a large amount of chemical insecticides that use certainly will pollute soil and water resource, then the mankind are caused potential very big harm after pollutant enters food chain.Along with the improvement of the progress of society, expanding economy and people's life, human food hygiene and Environmental security consciousness improve gradually, and people urgently wish with nuisanceless, of low pollution and the effective traditional pest control with insecticide medicament of the anti-control products replacement of insect.
At present become the (R)-4-isopropenyl-1-methyl-1-cyclohexene that is applied to food industry and chemical engineering industry low toxic pesticide in extensive use aspect sanitary insect pest and the agricultural insect pests control with pesticide preparation as pesticide synergistic agent both at home and abroad, and quick-acting with it, toxicity is low, the residual characteristics such as low and chemical pesticide match in excellence or beauty.In recent years China has reported chemical agent for preventing and curing lepidopterous, coleoptera, Hymenoptera, Homoptera and the Diptera pest research of doing synergist preparation with (R)-4-isopropenyl-1-methyl-1-cyclohexene, and Yuan Zhenguo (on 03 10th, 2004) has invented the insects such as Lepidoptera cabbage caterpillar, prodenia litura, diamond-back moth, aphid that are used for the control crops with the (R)-4-isopropenyl-1-methyl-1-cyclohexene bio-synergistic insecticide of (R)-4-isopropenyl-1-methyl-1-cyclohexene, pyrethroid, emulsifier and solvent preparation; Li Jianlin (on 02 13rd, 2008) has invented a kind of highly effective environment-friendly type biological insecticide that combines with (R)-4-isopropenyl-1-methyl-1-cyclohexene, nimbin, emulsifier and solvent, can close and the fruit and vegetable food of immediate access uses at any environment field; Mention in He Cuijuan, song letter (2008) " application and the DEVELOPMENT PROSPECT of d one citrene bio-synergistic insecticide in the agricultural production " literary composition, with the product " 37% feels happy missible oil " of (R)-4-isopropenyl-1-methyl-1-cyclohexene bio-synergistic insecticide exploitation the indoor and outdoor of Cruciferous Vegetable Pests aphid in Lepidoptera, the Homoptera (Lipaphis erysimi), cabbage caterpillar (Pieris rapae), diamond-back moth (Plutella xylostella), beet armyworm (Laphygma exigua) larva and camphor tree camphor tree nest snout moth's larva is tested the control efficiency that all reaches more than 85%; Etc..
The external method that once adopted suds to make surfactant and (R)-4-isopropenyl-1-methyl-1-cyclohexene and water mixed liquid perfusion ant nest is processed single anthill, or with (R)-4-isopropenyl-1-methyl-1-cyclohexene, turpentine oil, pyrethroid etc. and water mixed perfusion anthill, fill with nest no matter adopt which kind of intermixture, all emphasize to fill with whole ant nest, guarantee that whole ant nest is fully saturated by liquid.Above method weak point be dosage large, waste time and energy, high in cost of production, particularly place far away is more inconvenient in dried up source.
Summary of the invention:
The purpose of this invention is to provide the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene of a kind of extremely red fire ant and use the method that this contains the miscible oil killing red ant of (R)-4-isopropenyl-1-methyl-1-cyclohexene, utilize this miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene according to method killing red ant of the present invention, have simple to operation, dosage is few, the advantage that cost is low, and to ecological environment security, be the method for the killing red ant of a kind of environmental protection, highly effective and safe.
The miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene that kills red fire ant of the present invention is characterized in that, by total volume fraction 100%, is comprised of (R)-4-isopropenyl-1-methyl-1-cyclohexene 80%～90% and edible vegetable oil 10%～20%.
The described miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene by total volume fraction 100%, is preferably: described (R)-4-isopropenyl-1-methyl-1-cyclohexene is 90%, and edible vegetable oil is 10%.
Described edible vegetable oil is preferably peanut oil, rapeseed oil, sesame oil, sunflower seed oil or soybean oil.
Application of the present invention contains the method for the miscible oil killing red ant of (R)-4-isopropenyl-1-methyl-1-cyclohexene, it is characterized in that, may further comprise the steps: the absorption requirement 1 described carrier that contains the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene of having the right is put into the red fire ant ant nest, and the every nest consumption that contains the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene is 10～50ml.
Described carrier is preferably sponge.
Preferably, the method of described killing red ant is: in red fire ant anthill center, get into the cave vertically downward at the bottom of nest, then absorption is had the sponge block of the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene to drop in the cave, the sealing hole, the every nest consumption that contains the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene is 10～50ml.By this mode dispenser, than being easier to operation, less to the red fire ant disturbance in the ant nest, control efficiency is good.
Described in red fire ant anthill center, be inserted to nest under the iron staff with Φ 3～6cm of getting into the cave vertically downward at the bottom of the nest preferably is vertical in the anthill center at the bottom of, produce the cave.
The miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene that kills red fire ant of the present invention is like this preparation, content by the each component of the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene, measure respectively (R)-4-isopropenyl-1-methyl-1-cyclohexene and edible vegetable oil, then with both mixing and stirring, namely obtain the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene that kills red fire ant of the present invention.
The inventor finds through experiment, if use in the input cave of only adsorbing the sponge block that (R)-4-isopropenyl-1-methyl-1-cyclohexene is arranged, then seal the hole, (R)-4-isopropenyl-1-methyl-1-cyclohexene also can volatilize, in nest, fully fill the air, but the effect of control is not fine, can not reach the purpose of killing red ant ant nest, in the 2m of some ant nest scope, new ant nest is arranged again.Find by experiment, this is that when (R)-4-isopropenyl-1-methyl-1-cyclohexene volatilized, some red fire ant may be fled from rapidly ant nest, sets up new ant nest, thereby has affected control efficiency because (R)-4-isopropenyl-1-methyl-1-cyclohexene has repellent action to red fire ant.The inventor forms the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene by (R)-4-isopropenyl-1-methyl-1-cyclohexene and edible vegetable oil are matched, reduce red fire ant to the repellent reaction of (R)-4-isopropenyl-1-methyl-1-cyclohexene by the unique salted cake fried in sesame oil smell of edible vegetable oil, thereby improve (R)-4-isopropenyl-1-methyl-1-cyclohexene to the insect killing effect of red fire ant.
The present invention puts into the red fire ant ant nest with the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene of 10～50ml by absorption carrier; the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene fully fills the air in nest with its good volatile performance; and destroy the wax protective layer of all individual body surfaces of red fire ant in nest with its powerful permeance property; causing red fire ant ventilation hole obstruction to cause to be choked to death dies; thereby kill fast all individualities that comprise queen in the nest, reach the purpose of killing red ant ant nest.Compare with the method for the water mixed liquid perfusion ant nest of other materials with (R)-4-isopropenyl-1-methyl-1-cyclohexene of the prior art, the present invention need not to fill whole ant nest, but utilize the volatility of killing the red fire ant miscible oil to fill the air whole ant nest, killing red ants, therefore the present invention have simple to operation, time saving and energy saving, drug dose is few, cost is low, the significant advantage of nest effect of all can using and go out throughout the year, the method is the innovation of adopting on the (R)-4-isopropenyl-1-methyl-1-cyclohexene killing red ant method.
Active ingredient (R)-4-isopropenyl-1-methyl-1-cyclohexene in the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene that the present invention adopts be a kind of can be by the degradable degreasing solvent of biology, be the nontoxic fully natural green environment-friendly products of food-grade, regarded as the solvent of GRAS (safety) level and be widely used in pharmaceutical industry by Food and Drug Administration (FDA), and batching edible vegetable oil is the daily edible oil and fat of people, unique salted cake fried in sesame oil smell can reduce red fire ant to the repellent reaction of (R)-4-isopropenyl-1-methyl-1-cyclohexene, thereby improves (R)-4-isopropenyl-1-methyl-1-cyclohexene to the insect killing effect of red fire ant.The miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene that the present invention adopts is the medicament of the killing red ant ant nest of a kind of environmental protection to ecological environment security, highly effective and safe.Therefore the present invention can be applicable in the strategic objective of eradicating red fire ant.
Embodiment:
Below be to further specify of the present invention, rather than limitation of the present invention.
One, preparation contains the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene
Content by the miscible oil each component that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene measures respectively (R)-4-isopropenyl-1-methyl-1-cyclohexene and edible vegetable oil, then both is mixed, and stirs.
Wherein, by total volume fraction 100%, contain the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene, formed by (R)-4-isopropenyl-1-methyl-1-cyclohexene 80% and peanut oil 20% for I number; Contain the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene II number, formed by (R)-4-isopropenyl-1-methyl-1-cyclohexene 85% and peanut oil 15%; Contain the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene III number, formed by (R)-4-isopropenyl-1-methyl-1-cyclohexene 90% and peanut oil 10%.
Experiment place: residential quarter 1
1. sponge being cut into specification is 3 * 3 * 3cm fritter, and each sponge block splashes into I, the II of 10ml or the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene III number.Compare with same method with pure (R)-4-isopropenyl-1-methyl-1-cyclohexene and edible vegetable oil.
2. to the ripe active mound of the red fire ant of anthill Φ 20～40cm, at the bottom of being inserted to nest under vertical in the anthill center with the iron staff of Φ 3cm, fill in from extracting in the cave that stays behind the iron staff with 1～5 in the sponge that tweezers will adsorb 10ml I, II or contain the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene for III number, the quantity of sponge block is determined according to the size of ant nest, then seal the hole with earth, 15 repetitions are established in each test.The ant nest of contrast vertically bores until a hole is bored in the bottom of nest down in nest in the anthill center with iron staff equally, after extracting iron staff out, throw in the sponge block that contains edible vegetable oil or contain pure (R)-4-isopropenyl-1-methyl-1-cyclohexene of experimental group equivalent respectively in contrast, then with the earth sealing, 15 repetitions are established in each contrast.
3. excavated with spud in the 7th day after the dispensing and throw in absorption and I, II are arranged or contain the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene for III number and the ant nest inspection of the sponge block of pure (R)-4-isopropenyl-1-methyl-1-cyclohexene, the method for digging nest: at first dig the edge of anthill, check whether also have dead worker ant; Excavate again the ant nest center, dig the ant nest bottom always, carefully search dead ant corpse (comprising queen) while digging; Check at last whether whether anthill has new ant nest in the 2m on every side, cause the red fire ant transfer to judge (R)-4-isopropenyl-1-methyl-1-cyclohexene.
Throw in the contrast nest that adsorbs the sponge block that edible vegetable oil is arranged with the iron wire insertion, check red fire ant survival condition in the nest.
4. digging the nest check result on the 7th day after the test is:
Every nest is thrown in 15 nests that absorption has 1～5 of the miscible oil sponge block that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene for 10ml I number, have a small amount of movable worker ant is arranged in the 2 nest nests, there is the worker ant more than 200 movable around the table of mound, in 13 nests and anthill edge has no movable red fire ant, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest decline rate is 86.6%.
Every nest is thrown in 15 nests that absorption has 1～5 of the miscible oil sponge block that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene for 10ml II number, have a small amount of movable worker ant is arranged in the 1 nest nest, there is the worker ant more than 200 movable around the table of mound, in 14 nests and anthill edge has no movable red fire ant, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest decline rate is 93.3%.
Every nest is thrown in 15 nests that absorption has 1～5 of the miscible oil sponge block that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene for 10mlIII number, in 15 nests and anthill edge has no movable red fire ant, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest decline rate is 100%.
Above-mentioned input absorption has I, II and contains for III number in the peripheral 2m of anthill of test ant nest of miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene and is showed no new red fire ant ant nest.
Every nest is thrown in 15 nests of 1～5 of sponge block that absorption has the pure (R)-4-isopropenyl-1-methyl-1-cyclohexene of 10ml, have no movable red fire ant inside and outside 12 ant nests, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, the anthill edge of all the other 3 ant nests has than the multi-activity worker ant, in the peripheral 2m of anthill 1～2 tiny anthill is arranged.
The red fire ant that every nest is thrown in 15 nests of 1～5 of sponge block that absorption has 10ml peanut oil is movable normal.
Embodiment 2:
Experiment place: residential quarter 2
This identical with embodiment 1, as just to test place difference of the present embodiment subbase is tested in the place of the present embodiment according to the method for embodiment 1.Test was dug the nest check result in rear the 7th day:
Every nest is thrown in 15 nests of 1～5 of sponge block that absorption has the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene for 10ml I number, have a small amount of movable worker ant is arranged in the 1 nest nest, there is the worker ant more than 200 movable around the table of mound, in 14 nests and anthill edge has no movable red fire ant, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest decline rate is 93.3%.
Every nest is thrown in 15 nests of 1～5 of sponge block that absorption has the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene for 10ml II number, have a small amount of movable worker ant is arranged in the 1 nest nest, there is the worker ant more than 200 movable around the table of mound, in 14 nests and anthill edge has no movable red fire ant, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest decline rate is 93.3%.
Every nest is thrown in 15 nests of 1～5 of sponge block that absorption has the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene for 10ml III number, have a small amount of movable worker ant is arranged in the 1 nest nest, there is the worker ant more than 200 movable around the table of mound, in 14 nests and anthill edge has no movable red fire ant, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest decline rate is 93.3%.
Above-mentioned input absorption has I, II and contains for III number in the peripheral 2m of anthill of test ant nest of miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene and is showed no new red fire ant ant nest.
Every nest is thrown in 15 nests of 1～5 of sponge block that absorption has the pure (R)-4-isopropenyl-1-methyl-1-cyclohexene of 10ml, have no movable red fire ant inside and outside 13 ant nests, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, the anthill edge of all the other 2 ant nests has than the multi-activity worker ant, in the peripheral 2m of anthill 1 tiny anthill is arranged respectively.
The red fire ant that every nest is thrown in 15 nests of 1～5 of sponge block that absorption has 10ml peanut oil is movable normal.
Embodiment 3:
Experiment place: residential quarter 3
This identical with embodiment 1, as just to test place difference of the present embodiment subbase is tested in the place of the present embodiment according to the method for embodiment 1.Test was dug the nest check result in rear the 7th day:
Every nest is thrown in 15 nests of 1～5 of sponge block that absorption has the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene for I number of 10ml, have a small amount of movable worker ant is arranged in the 1 nest nest, there is the worker ant more than 200 movable around the table of mound, in 14 nests and anthill edge has no movable red fire ant, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest decline rate is 93.3%.
Every nest is thrown in 15 nests of 1～5 of sponge block that absorption has the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene for 10ml II number, have a small amount of movable worker ant is arranged in the 1 nest nest, there is the worker ant more than 200 movable around the table of mound, in 14 nests and anthill edge has no movable red fire ant, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest decline rate is 93.3%.
Every nest is thrown in 15 nests of 1～5 of sponge block that absorption has the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene for 10ml III number, in 15 nests and anthill edge has no movable red fire ant, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest decline rate is 100%.
Above-mentioned input absorption has I, II and contains for III number in the peripheral 2m of anthill of test ant nest of miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene and is showed no new red fire ant ant nest.
In 15 nests that the sponge block of the pure (R)-4-isopropenyl-1-methyl-1-cyclohexene of every nest input absorption 10ml is 1～5, have no movable red fire ant inside and outside 13 ant nests, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, the anthill edge of all the other 2 ant nests has than the multi-activity worker ant, in the peripheral 2m of anthill 1 and 2 tiny anthill is arranged respectively.
The red fire ant that every nest is thrown in 15 nests of 1～5 of sponge block that absorption has 10ml peanut oil is movable normal.
The result of three embodiment is as shown in table 1:
Table 1: the effect that contains the miscible oil killing red ant ant nest of (R)-4-isopropenyl-1-methyl-1-cyclohexene
The ripe active mound of the red fire ant of Φ 20～40cm is all selected in above test, at the bottom of being inserted to nest under vertical in anthill centre of surface position with the iron staff of Φ 3cm, I with absorption 10ml, II, 1～5 of the sponge block that contains the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene or (R)-4-isopropenyl-1-methyl-1-cyclohexene or edible vegetable oil for III number is rendered to and is extracted in the cave that stays behind the iron staff, live the hole with grave, throw in absorption I is arranged, II, the test nest number that contains the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene for III number respectively is 45 ant nests, test has obtained containing for I number (R)-4-isopropenyl-1-methyl-1-cyclohexene after 7 days the miscible oil nest effect of going out is 91.1%, the nest effect of going out that contains the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene for II number is 93.3%, the nest effect 97.8% of going out that contains the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene for III number, the nest effect of going out of pure (R)-4-isopropenyl-1-methyl-1-cyclohexene are 84.4% and edible vegetable oil result that red fire ant is had no adverse effects.Throwing in absorption has I, II and contains for III number in the peripheral 2m of anthill of test ant nest of miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene and be showed no new red fire ant ant nest.And throw in the nest that adsorbs the sponge block that pure (R)-4-isopropenyl-1-methyl-1-cyclohexene is arranged, some anthill edge has than the multi-activity worker ant, and in the peripheral 2m of anthill 1～2 tiny anthill is arranged, and does not reach the desirable nest effect of going out.
Above embodiment explanation, utilize the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene that contains of the present invention according to method killing red ant of the present invention, can realize the purpose of killing red ant ant nest, red fire ant is had no adverse effects and the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene confirms than the pure (R)-4-isopropenyl-1-methyl-1-cyclohexene significant result of nest effect of going out from edible vegetable oil, edible vegetable oil has reduced the repellent reaction of red fire ant to (R)-4-isopropenyl-1-methyl-1-cyclohexene.
Utilize the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene that contains of the present invention according to method killing red ant of the present invention, have that dosage is little, application method is easy, time saving and energy saving, the significant advantage of nest effect of all can using and go out throughout the year, therefore, the method is to adopt the technical innovation of (R)-4-isopropenyl-1-methyl-1-cyclohexene killing red ant.
Claims (6)
1. the method for a killing red ant, it is characterized in that, may further comprise the steps: have the carrier of the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene that kills red fire ant to put into the red fire ant ant nest absorption, the every nest consumption that kills the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene of red fire ant is 10 ~ 50ml, the described miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene that kills red fire ant, by total volume fraction 100%, formed by (R)-4-isopropenyl-1-methyl-1-cyclohexene 80% ~ 90% and edible vegetable oil 10% ~ 20%.
2. the method for killing red ant according to claim 1 is characterized in that, by total volume fraction 100%, described (R)-4-isopropenyl-1-methyl-1-cyclohexene is 90%, and edible vegetable oil is 10%.
3. the method for killing red ant according to claim 1 is characterized in that, described edible vegetable oil is peanut oil, rapeseed oil, sesame oil, sunflower seed oil or soybean oil.
4. the method for killing red ant according to claim 1 is characterized in that, described carrier is sponge.
5. the method for killing red ant according to claim 4, it is characterized in that, it is described that to have extremely the sponge of the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene of red fire ant put into the red fire ant ant nest absorption be in red fire ant anthill center, get into the cave vertically downward at the bottom of the nest, then absorption there is the sponge block of the miscible oil that contains (R)-4-isopropenyl-1-methyl-1-cyclohexene that kills red fire ant to drop in the cave sealing hole.
6. the method for killing red ant according to claim 5 is characterized in that, and is described in red fire ant anthill center, and getting into the cave vertically downward at the bottom of the nest is at the bottom of iron staff with Φ 3 ~ 6cm is inserted to nest under vertical in the anthill center, to produce the cave.
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| CN 201010599201 CN101999349B (en) | 2010-12-21 | 2010-12-21 | D-limonene-containing mixed oil agent for killing solenopsis invicta buren and method for killing the solenopsis invicta buren |
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| CN 201010599201 CN101999349B (en) | 2010-12-21 | 2010-12-21 | D-limonene-containing mixed oil agent for killing solenopsis invicta buren and method for killing the solenopsis invicta buren |
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| CN106614492A (en) * | 2016-12-26 | 2017-05-10 | 宁德市植保植检站 | Preventing and controlling method for red-imported-fire-ant epidemic situation |
| CN106982808B (en) * | 2017-03-02 | 2020-11-17 | 广东省生物资源应用研究所 | Termite bait, termite trapping and killing device and manufacturing method thereof |
| CN108184829A (en) * | 2017-12-15 | 2018-06-22 | 广西壮族自治区农业科学院植物保护研究所 | A kind of red fire ant smoked kill composition |
| CN112825836B (en) * | 2021-02-24 | 2022-07-01 | 金华市恒安生物技术有限公司 | Anti-escape rapid processing technology for solenopsis invicta |
| CN113180044A (en) * | 2021-04-23 | 2021-07-30 | 四川桐稷科技有限公司 | Solenopsis invicta pheromone attractant and killing agent containing the same |
| MX2024004731A (en) | 2021-10-29 | 2024-05-10 | Shinetsu Chemical Co | Ant control agent and ant control method. |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1678191A (en) * | 2002-09-04 | 2005-10-05 | 托尔·迈克帕特兰德 | Ant spray containing D-limonene |
| CN101049106A (en) * | 2006-11-14 | 2007-10-10 | 红河森菊生物有限责任公司 | Oil preparation for trapping and killing cockroach by natural pyrethrum element and preparation method |
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| US8007820B2 (en) * | 2005-09-16 | 2011-08-30 | W. Neudorff Gmbh Kg | Wide spectrum insecticide and miticide composition |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1678191A (en) * | 2002-09-04 | 2005-10-05 | 托尔·迈克帕特兰德 | Ant spray containing D-limonene |
| CN101049106A (en) * | 2006-11-14 | 2007-10-10 | 红河森菊生物有限责任公司 | Oil preparation for trapping and killing cockroach by natural pyrethrum element and preparation method |
Non-Patent Citations (2)
| Title |
|---|
| "安全优良的植物源杀虫剂已投产";孟祥栋;《中国环保产业》;20010830;第11页 * |
| 孟祥栋."安全优良的植物源杀虫剂已投产".《中国环保产业》.2001,第11页. |
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