CN101962521B - Opening time adjustable wallpaper adhesive and preparation method thereof - Google Patents
Opening time adjustable wallpaper adhesive and preparation method thereof Download PDFInfo
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- CN101962521B CN101962521B CN2010101383192A CN201010138319A CN101962521B CN 101962521 B CN101962521 B CN 101962521B CN 2010101383192 A CN2010101383192 A CN 2010101383192A CN 201010138319 A CN201010138319 A CN 201010138319A CN 101962521 B CN101962521 B CN 101962521B
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Abstract
The invention relates to an opening time adjustable wallpaper adhesive and a preparation method thereof. The wallpaper adhesive consists of the following raw materials in percentage by weight: 5 to 95 percent of emulsion, 0.5 to 25 percent of cellulose ether, 0.5 to 35 percent of starch ether and the balance of water. The preparation method comprises the following steps of: mixing the following raw materials: 5 to 95 percent of emulsion, 0.5 to 25 percent of cellulose ether, 0.5 to 35 percent of starch ether and the balance of water; adding the cellulose ether into water for dissolution, and fully stirring uniformly; adding the starch ether into aqueous solution of cellulose ether, and fully stirring uniformly; and mixing the cellulose ether and starch ether mixed solution and the emulsion according to a ratio, and fully stirring uniformly. The invention has the advantages that: the starch ether and the cellulose ether are compounded into the emulsion through mechanical blending, and the two materials are coordinated to fulfill the aims of thickening, retaining water and improving construction performance.
Description
Technical field
The present invention relates to a kind of wallpaper tackiness agent, relate in particular to the component and the method for manufacture thereof of this wallpaper tackiness agent.
Background technology
The wallpaper tackiness agent adopts modified-cellulose as staple usually, cooperates the metope treatment agent all to have bond effect preferably to the wallpaper of differing texture.Yet because the cold water-soluble of ether of cellulose is relatively poor, construction has brought a lot of inconvenience to house ornamentation.
The report of at present relevant wallpaper tackiness agent is all less both at home and abroad, mainly concentrates on the research to the polyvinyl alcohol tackiness agent, and adjustable wallpaper tackiness agent of open hour is not still had report.
So-called adjustable wallpaper tackiness agent of open hour is meant: a kind ofly regulate this wallpaper tackiness agent film forming surface drying time to satisfy the wallpaper tackiness agent of different construction requirements through changing in the prescription each component concentration.
Summary of the invention
The technical issues that need to address of the present invention have provided adjustable wallpaper tackiness agent of a kind of open hour, are intended to solve the above problems;
The present invention also provides the method for making said product.
In order to solve the problems of the technologies described above, the present invention realizes through following technical scheme:
The present invention is that water is formed by emulsion, ether of cellulose, starch ethers, surplus; Each raw material accounts for weight percent: emulsion 5-95%, ether of cellulose 0.5-25%, and starch ethers 0.5-35%, surplus is a water; Described ether of cellulose is a molecular weight 1,000~200, the hydroxyethylmethyl-cellulose ether of 000 hydroxypropyl methyl cellulose ether or molecular weight 1,000~200,000; Starch ethers is yam starch ether or W-Gum ether or wheat starch ether or tapioca(flour) ether; Emulsion adopts VAE emulsion or benzene emulsion or pure-acrylic emulsion.
Preparing method of the present invention realizes through following steps:
Batching: take by weighing ether of cellulose, starch ethers, emulsion and water by above-mentioned prescription;
With the ether of cellulose dissolving that is added to the water, stir;
Again starch ethers is joined in the cellulose ether aqueous solution, stir;
With the mixing solutions and the emulsion proportional mixing of ether of cellulose and starch ethers, stir promptly and get.
Compared with prior art, the invention has the beneficial effects as follows: advance in the emulsion starch ethers, ether of cellulose are compound through mechanical blending, reach two kinds of material thickenings, water conservation, improve the coordinative role of workability.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail:
The present invention realizes through following technical scheme:
The present invention is that water is formed by emulsion, ether of cellulose, starch ethers, surplus; Each raw material accounts for weight percent: emulsion 5-95%, ether of cellulose 0.5-25%, and starch ethers 0.5-35%, surplus is a water; Described ether of cellulose is a molecular weight 1,000~200, the hydroxyethylmethyl-cellulose ether of 000 hydroxypropyl methyl cellulose ether or molecular weight 1,000~200,000; Starch ethers is yam starch ether or W-Gum ether or wheat starch ether or tapioca(flour) ether; Emulsion adopts VAE emulsion or benzene emulsion or pure-acrylic emulsion.
Preparing method of the present invention realizes through following steps:
Batching: take by weighing ether of cellulose, starch ethers, emulsion and water by above-mentioned prescription;
With the ether of cellulose dissolving that is added to the water, stir;
Again starch ethers is joined in the cellulose ether aqueous solution, stir;
With the mixing solutions and the emulsion proportional mixing of ether of cellulose and starch ethers, stir promptly and get.
In view of starch ethers has very strong thixotropy, can improve workability, ether of cellulose has good water-retentivity and thickening effectiveness; With the aqueous solution of starch ethers and ether of cellulose and emulsion in proportion blend prepare adjustable wallpaper tackiness agent of open hour; Starch ethers is dissolved in the water with colloidal form, and its aqueous solution contains the hydration macromole, the flowability performance non-Newtonian fluid of solution; Thixotropy is stronger, can improve workability; The ether of cellulose water retention capacity is strong, has significant thickening power, advances in the emulsion starch ethers, ether of cellulose are compound through mechanical blending, reaches two kinds of material thickenings, water conservation, improves the coordinative role of workability.
Open hour provided by the invention adjustable wallpaper tackiness agent stable preparation process is easy to realize suitability for industrialized production, and cost is low, technology is simple.And prepared wallpaper adhesives excellent property can not pollute wallpaper, and is environmentally friendly to the human non-toxic evil, and the open hour can be regulated through the change of prescription according to actual needs, have the potentiality of applying, and market outlook are wide.
Embodiment 1
By weight,, after abundant mechanical stirring, in solution, add starch ethers 3%, be uniformly dispersed through mechanical stirring with ether of cellulose 4%, water 42%.Again mixture solution and emulsion 51% are promptly got through the abundant mixing of mechanical stirring.
Embodiment 2
By weight,, after abundant mechanical stirring, in solution, add starch ethers 2.5%, be uniformly dispersed through mechanical stirring with ether of cellulose 0.5%, water 26%.Again mixture solution and emulsion 71% are promptly got through the abundant mixing of mechanical stirring.
Embodiment 3
By weight,, after abundant mechanical stirring, in solution, add starch ethers 8%, be uniformly dispersed through mechanical stirring with ether of cellulose 11%, water 62%.Again mixture solution and emulsion 19% are promptly got through the abundant mixing of mechanical stirring.
Embodiment 4
By weight,, after abundant mechanical stirring, in solution, add starch ethers 0.5%, be uniformly dispersed through mechanical stirring with ether of cellulose 25%, water 69.5%.Again mixture solution and emulsion 5% are promptly got through the abundant mixing of mechanical stirring.
Embodiment 5
By weight,, after abundant mechanical stirring, in solution, add starch ethers 35%, be uniformly dispersed through mechanical stirring with ether of cellulose 6%, water 53%.Again mixture solution and emulsion 6% are promptly got through the abundant mixing of mechanical stirring.
Embodiment 6
By weight,, after abundant mechanical stirring, in solution, add starch ethers 12%, be uniformly dispersed through mechanical stirring with ether of cellulose 18%, water 52%.Again mixture solution and emulsion 18% are promptly got through the abundant mixing of mechanical stirring.
Embodiment 7
By weight,, after abundant mechanical stirring, in solution, add starch ethers 5.5%, be uniformly dispersed through mechanical stirring with ether of cellulose 3.5%, water 43%.Again mixture solution and emulsion 48% are promptly got through the abundant mixing of mechanical stirring.
Embodiment 8
By weight,, after abundant mechanical stirring, in solution, add starch ethers 3%, be uniformly dispersed through mechanical stirring with ether of cellulose 22%, water 64%.Again mixture solution and emulsion 11% are promptly got through the abundant mixing of mechanical stirring.
Embodiment 9
By weight,, after abundant mechanical stirring, in solution, add starch ethers 31%, be uniformly dispersed through mechanical stirring with ether of cellulose 4%, water 44%.Again mixture solution and emulsion 21% are promptly got through the abundant mixing of mechanical stirring.
Embodiment 10
By weight,, after abundant mechanical stirring, in solution, add starch ethers 12%, be uniformly dispersed through mechanical stirring with ether of cellulose 17%, water 58%.Again mixture solution and emulsion 13% are promptly got through the abundant mixing of mechanical stirring.
Embodiment 11
By weight,, after abundant mechanical stirring, in solution, add starch ethers 8%, be uniformly dispersed through mechanical stirring with ether of cellulose 9.5%, water 47.5%.Again mixture solution and emulsion 35% are promptly got through the abundant mixing of mechanical stirring.
All on sale on the raw materials market that the present invention adopts.
Claims (9)
1. an adjustable wallpaper tackiness agent of open hour is that water is formed by emulsion, ether of cellulose, starch ethers, surplus; Each raw material accounts for weight percent: emulsion 5-95%, ether of cellulose 0.5-25%, and starch ethers 0.5-35%, surplus is a water; Wherein: described ether of cellulose is a molecular weight 1,000~200, the hydroxyethylmethyl-cellulose ether of 000 hydroxypropyl methyl cellulose ether or molecular weight 1,000~200,000; Starch ethers is yam starch ether or W-Gum ether or wheat starch ether or tapioca(flour) ether; Emulsion adopts VAE emulsion or benzene emulsion or pure-acrylic emulsion.
2. the preparation method of an adjustable wallpaper tackiness agent of open hour, realize through following steps:
Batching: each raw material accounts for weight percent and is: emulsion 5-95%, ether of cellulose 0.5-25%, and starch ethers 0.5-35%, surplus is a water; Wherein: described ether of cellulose is a molecular weight 1,000~200, the hydroxyethylmethyl-cellulose ether of 000 hydroxypropyl methyl cellulose ether or molecular weight 1,000~200,000; Starch ethers is yam starch ether or W-Gum ether or wheat starch ether or tapioca(flour) ether; Emulsion adopts VAE emulsion or benzene emulsion or pure-acrylic emulsion;
With the ether of cellulose dissolving that is added to the water, stir;
Again starch ethers is joined in the cellulose ether aqueous solution, stir;
With the mixing solutions and the emulsion proportional mixing of ether of cellulose and starch ethers, stir promptly and get.
3. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 2, wherein: by weight,, after abundant mechanical stirring, in solution, add starch ethers 3%, be uniformly dispersed through mechanical stirring with ether of cellulose 4%, water 42%; Again mixture solution and emulsion 51% are promptly got through the abundant mixing of mechanical stirring.
4. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 2; Wherein: by weight, with ether of cellulose 0.5%, water 26%, after abundant mechanical stirring; In solution, add starch ethers 2.5%, be uniformly dispersed through mechanical stirring; Again mixture solution and emulsion 71% are promptly got through the abundant mixing of mechanical stirring.
5. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 2, wherein: by weight,, after abundant mechanical stirring, in solution, add starch ethers 8%, be uniformly dispersed through mechanical stirring with ether of cellulose 11%, water 62%; Again mixture solution and emulsion 19% are promptly got through the abundant mixing of mechanical stirring.
6. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 2; Wherein: by weight, with ether of cellulose 25%, water 69.5%, after abundant mechanical stirring; In solution, add starch ethers 0.5%, be uniformly dispersed through mechanical stirring; Again mixture solution and emulsion 5% are promptly got through the abundant mixing of mechanical stirring.
7. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 2, wherein: by weight,, after abundant mechanical stirring, in solution, add starch ethers 35%, be uniformly dispersed through mechanical stirring with ether of cellulose 6%, water 53%; Again mixture solution and emulsion 6% are promptly got through the abundant mixing of mechanical stirring.
8. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 2, wherein: by weight,, after abundant mechanical stirring, in solution, add starch ethers 12%, be uniformly dispersed through mechanical stirring with ether of cellulose 18%, water 52%; Again mixture solution and emulsion 18% are promptly got through the abundant mixing of mechanical stirring.
9. the preparation method of adjustable wallpaper tackiness agent of open hour according to claim 2; Wherein: by weight, with ether of cellulose 3.5%, water 43%, after abundant mechanical stirring; In solution, add starch ethers 5.5%, be uniformly dispersed through mechanical stirring; Again mixture solution and emulsion 48% are promptly got through the abundant mixing of mechanical stirring.
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CN102732184A (en) * | 2012-07-18 | 2012-10-17 | 郭曲玲 | Elastic waterproof binder additive and preparation method thereof |
CN106753076A (en) * | 2015-11-25 | 2017-05-31 | 铂恩塞尔新材料(上海)股份有限公司 | A kind of Environment-friendlywallpaper wallpaper glue material for sticking wallpaper and preparation method thereof |
CN105542678A (en) * | 2016-02-14 | 2016-05-04 | 佛山市恒学科技服务有限公司 | Long-acting antimicrobial mildewproof wallpaper adhesive |
CN106634685B (en) * | 2017-01-03 | 2018-12-28 | 黄淇浩 | A kind of Environmental-friendantistatic antistatic wallpaper glue and preparation method thereof |
CN108658495A (en) * | 2017-08-08 | 2018-10-16 | 苏州金螳螂建筑装饰股份有限公司 | Bond reinforcing agent and preparation method thereof and binding material and its construction method |
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CN1958702A (en) * | 2006-09-06 | 2007-05-09 | 江都中远装饰工程设计研究所 | Hydrosol powder of glue for building |
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