CN101831126A - Fully anti-ultraviolet, anti-fatigue, and anti-malignant melanoma optical protective material - Google Patents
Fully anti-ultraviolet, anti-fatigue, and anti-malignant melanoma optical protective material Download PDFInfo
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- CN101831126A CN101831126A CN 201010169715 CN201010169715A CN101831126A CN 101831126 A CN101831126 A CN 101831126A CN 201010169715 CN201010169715 CN 201010169715 CN 201010169715 A CN201010169715 A CN 201010169715A CN 101831126 A CN101831126 A CN 101831126A
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- malignant melanoma
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- 239000000463 material Substances 0.000 title claims abstract description 55
- 230000001681 protective effect Effects 0.000 title claims abstract description 28
- 230000003287 optical effect Effects 0.000 title claims abstract description 26
- 208000035250 cutaneous malignant susceptibility to 1 melanoma Diseases 0.000 title claims abstract description 21
- 201000001441 melanoma Diseases 0.000 title claims abstract description 21
- 230000002929 anti-fatigue Effects 0.000 title claims abstract description 18
- 230000009876 antimalignant effect Effects 0.000 title claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 34
- 239000000654 additive Substances 0.000 claims abstract description 17
- 230000000996 additive effect Effects 0.000 claims abstract description 17
- 239000000975 dye Substances 0.000 claims description 12
- 239000006096 absorbing agent Substances 0.000 claims description 10
- 230000000694 effects Effects 0.000 abstract description 6
- 230000004224 protection Effects 0.000 abstract description 3
- 230000006750 UV protection Effects 0.000 abstract description 2
- 230000032683 aging Effects 0.000 abstract 1
- 230000003667 anti-reflective effect Effects 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 239000006081 fluorescent whitening agent Substances 0.000 abstract 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract 1
- -1 5-tertiary butyl-2-benzoxazolyl Chemical group 0.000 description 8
- 206010070834 Sensitisation Diseases 0.000 description 8
- 238000002845 discoloration Methods 0.000 description 8
- 230000008313 sensitization Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 239000011521 glass Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 210000003491 skin Anatomy 0.000 description 5
- FRQPHGSNRQEKOX-UHFFFAOYSA-N 6h-benzo[c][1,2]benzoxazine Chemical class C1=CC=C2NOC3=CC=CC=C3C2=C1 FRQPHGSNRQEKOX-UHFFFAOYSA-N 0.000 description 4
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
- 239000012964 benzotriazole Substances 0.000 description 4
- 150000001565 benzotriazoles Chemical class 0.000 description 4
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 4
- 208000027418 Wounds and injury Diseases 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 208000014674 injury Diseases 0.000 description 3
- ZMLPKJYZRQZLDA-UHFFFAOYSA-N 1-(2-phenylethenyl)-4-[4-(2-phenylethenyl)phenyl]benzene Chemical group C=1C=CC=CC=1C=CC(C=C1)=CC=C1C(C=C1)=CC=C1C=CC1=CC=CC=C1 ZMLPKJYZRQZLDA-UHFFFAOYSA-N 0.000 description 2
- VQMHSKWEJGIXGA-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-6-dodecyl-4-methylphenol Chemical compound CCCCCCCCCCCCC1=CC(C)=CC(N2N=C3C=CC=CC3=N2)=C1O VQMHSKWEJGIXGA-UHFFFAOYSA-N 0.000 description 2
- RYAIMSPHUVXLQI-UHFFFAOYSA-N 4-(aminomethyl)-2-(benzotriazol-2-yl)phenol Chemical compound NCC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 RYAIMSPHUVXLQI-UHFFFAOYSA-N 0.000 description 2
- 206010042496 Sunburn Diseases 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000002313 adhesive film Substances 0.000 description 2
- 150000001555 benzenes Chemical class 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 210000004379 membrane Anatomy 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229950002083 octabenzone Drugs 0.000 description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 229930192474 thiophene Natural products 0.000 description 2
- 206010039424 Salivary hypersecretion Diseases 0.000 description 1
- 210000001744 T-lymphocyte Anatomy 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 208000009621 actinic keratosis Diseases 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000002925 chemical effect Effects 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 230000002650 habitual effect Effects 0.000 description 1
- 230000001900 immune effect Effects 0.000 description 1
- 210000000987 immune system Anatomy 0.000 description 1
- 210000001821 langerhans cell Anatomy 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 208000026451 salivation Diseases 0.000 description 1
- 210000004927 skin cell Anatomy 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to a fully anti-ultraviolet, anti-fatigue, and anti-malignant melanoma optical protective material. The optical protective material is characterized by comprising the following materials in percentage by weight: 0.010 to 30.000 weight percent of additive and the balance of base stock, wherein the additive is a fluorescent whitening agent and/or an ultraviolet absorber, and also No.beta-1 decomposition antireflective agent, color-changing agent and/or toner can be added into the additive and the base stock. The optical protective material has the effect of full ultraviolet protection, namely 100 percent of ultraviolet UV400 protection, can prevent harmful light from causing human body to generate malignant melanoma, avoid human fatigue, furniture color change and embrittlement caused by the harmful light, particularly has better advanced protective effect on infants, students and young ladies, and can protect tender skin and slow down the aging process.
Description
Technical field
The present invention relates to a kind of improvement of optical protective material, specifically refer to a kind of whole anti-UV antifatigue and anti-malignant melanoma optical protective material.
Background technology
Ultraviolet ray is the short invisible light of a kind of wavelength ratio visible light, and wavelength region: 280nm-400nm has significant chemical effect.Ultraviolet ray is not merely from sunlight, and various artificial lights also can produce certain ultraviolet ray as UV-lamp, computer, TV etc.Excessive uviolizing has certain injury to people's skin and eyes, and ultraviolet ray can destroy the human skin cell, causes wrinkle, color spot, make skin prematurely senile, produce sunburn and sunburn when serious, or the solar keratosis of skin and mucous membrane, canceration caused.Ultraviolet irradiation also can hurt the Langerhans cell in the epidermis simultaneously, and the main effect of L cell is to unite the external attack of antagonism with the T cell, so just can destroy the human immune system, and immunological competence is descended.The harmful light that ultraviolet ray is produced can cause human-body fatigue, furniture variable color and embrittlement, and is especially even more serious to child, student and Ms's injury, and the harmful light irradiation causes human body to produce malignant melanoma the most at last for a long time.
In order to prevent the injury of ultraviolet ray to human body, people research and develop and have made multiple antiultraviolet technology and product.For example: notification number is the Chinese invention patent application of CN1594646 disclosed " a kind of hydrophobic and ultraviolet radiation preventing transparent film and preparation thereof ", and it is to adopt magnetron sputtering method to prepare the hydrophobic and ultraviolet radiation preventing transparent film of nitrogen-doped titanium dioxide.Notification number is that the Chinese invention patent application of CN1951850 disclosed " ultraviolet ray screening film-plating glass and manufacture method thereof " is to adopt the high temperature pyrolysis spraying method to make ultraviolet ray screening film-plating glass, but this coated glass has reduced the transmitance of visible light, and does not reach the effect of fully anti-ultraviolet.At present also do not have a kind of material or film under the situation that does not influence light transmission, transparency and sharpness, can reach the effect of real fully anti-ultraviolet.
Summary of the invention
Technical problem to be solved by this invention be the present situation at prior art provide a kind of can whole anti-UV antifatigue and anti-malignant melanoma optical protective material.
Another technical problem to be solved by this invention is whole anti-UV antifatigue and the anti-malignant melanoma optical protective material that the variable color of a kind of energy is provided at the present situation of prior art.
The present invention adds the additive that accounts for base-material total amount 0.010-30.000wt% on the raw material basis that makes habitual optical protective material, better, can add β-1# and decompose transparent agent and improve the phase solubility of additive in base-material, thereby under the prerequisite of the not original light transmission of loss material, sharpness, give performances such as its fully anti-ultraviolet, antifatigue, variable color.
The present invention solves the problems of the technologies described above the technical scheme that is adopted: this whole anti-UV antifatigue and anti-malignant melanoma optical protective material is characterized in that comprising:
Additive 0.010-30.000wt%
The base-material surplus
The each component sum is 100wt%; Wherein, described additive is selected from white dyes and/or UV light absorber, and both mix when using, and white dyes and UV light absorber can be mixed by arbitrary proportion.
In order to improve the intermiscibility of additive and base-material, improve the product sharpness, the β-1# that can also add 0.001-0.150wt% in the such scheme decomposes transparent agent.
Described base-material can be selected all material that can make optical protective material in the prior art for use, preferably, can be selected from acrylic polymer, PET, PVC, PVB, PC, PVP, PS, PU or glass.
Described white dyes can be selected white dyess such as dibenzoxazine class, diphenylethyllene benzene class and distyryl biphenyl class for use.Preferably, can select 2 for use, two (the 5-tertiary butyl-2-benzoxazolyl) thiophene or 2,2 of 5-'-(4,4 '-diphenylethyllene) dibenzoxazine.
Described UV light absorber also claims the UV absorption agent, can be selected from 2-(2 '-hydroxyl-3 '-tertiary butyl-5 '-aminomethyl phenyl)-the 5-chlorinated benzotriazole, 2-(2 '-hydroxyl-3 ', 5 '-the diamyl phenyl) benzotriazole, 2-(2 '-hydroxyl-5 '-the Te octyl phenyl) benzotriazole, 2-(2 '-hydroxyl-3 '-tertiary butyl-5 '-aminomethyl phenyl)-the 5-chlorinated benzotriazole, 2-(2H-benzotriazole-2-yl)-6-(dodecyl)-4-methylphenol, Octabenzone, 2-hydroxyl-4-methoxy benzophenone, 2-(2 '-hydroxyl-5 '-aminomethyl phenyl) benzotriazole or ether aldehyde.
Described additive can also comprise colour-changing agent, the consumption of colour-changing agent can decide according to the thickness of prepared material and the amount of base-material, its consumption can be 0.010-20.000wt%, and amount ranges is 0.100-10.000wt% preferably, preferred 0.200-4.000wt%.
Described colour-changing agent can be selected from photosensitive colour-changing agent and/or temperature sensing color changing agent.Can select sensitization discoloration MC powder, sensitization discoloration PS powder, sensitization discoloration OP powder, sensitization discoloration aqueous emulsion etc. preferably for use.
Practical situation with base-material can also selectivity add toner as required, be pigment, the addition of toner also is that the thickness according to the amount of base-material and prepared material decides, and the addition of toner is generally 0.001-2.000wt%, and amount ranges is 0.005-1.500wt% preferably.
In the such scheme, preferably, the consumption of described additive can be 0.100-15.000wt%, preferred 0.200-8.000wt%; Described β-1# decomposes the preferred 0.005-0.010wt% of consumption of transparent agent.
Utilize the prepared material of prescription of the present invention can thoroughly isolate ultraviolet ray, avoid light fatigue, can reach the effect of uvioresistant UV400, have the fully anti-ultraviolet function, and, further improved the transparency and the sharpness of material because β-1# decomposes the interpolation of transparent agent.
Compared with prior art; prescription provided by the present invention can reach the effect of 100% uvioresistant UV400; particularly creatively adopted β-1# to decompose the intermiscibility that transparent agent improves additive and base-material; thereby improved the usage quantity of additive widely; the optical protective material that obtains can prevent effectively that harmful light from causing that human body produces malignant melanoma; avoid the caused human-body fatigue of harmful light, furniture variable color and embrittlement; especially child, student and Ms there is preferably protective effect in advance; can protect tender and lovely skin, delaying senility.Whole anti-UV antifatigue provided by the present invention and anti-malignant melanoma optical protective material are made optical protection layer, electron membrane, building film, automobile adhesive film, aircraft rupture disk or the like, and rete is clear, can thoroughly isolate ultraviolet ray.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail.
Base-material among the following embodiment can be chosen all material that can make optical protective material in the prior art wantonly, for example acrylic polymer, PET, PVC, PVB, PC, PVP, PS, PU or glass;
White dyes is selected from the white dyes of classes such as dibenzoxazine class of the prior art, diphenylethyllene benzene class and distyryl biphenyl class.For example: 2, two (the 5-tertiary butyl-2-benzoxazolyl) thiophene or 2,2 of 5-'-(4,4 '-diphenylethyllene) dibenzoxazine;
Described UV light absorber be selected from 2-(2 '-hydroxyl-3 '-tertiary butyl-5 '-aminomethyl phenyl)-the 5-chlorinated benzotriazole, 2-(2 '-hydroxyl-3 ', 5 '-the diamyl phenyl) benzotriazole, 2-(2 '-hydroxyl-5 '-the Te octyl phenyl) benzotriazole, 2-(2 '-hydroxyl-3 '-tertiary butyl-5 '-aminomethyl phenyl)-the 5-chlorinated benzotriazole, 2-(2H-benzotriazole-2-yl)-6-(dodecyl)-4-methylphenol, Octabenzone, 2-hydroxyl-4-methoxy benzophenone, 2-(2 '-hydroxyl-5 '-aminomethyl phenyl) benzotriazole or ether aldehyde;
Colour-changing agent is selected from photosensitive colour-changing agent of the prior art and/or temperature sensing color changing agent.For example can select sensitization discoloration MC powder, sensitization discoloration PS powder, sensitization discoloration OP powder, sensitization discoloration aqueous emulsion etc. for use.
Toner can be selected red agent, blue light agent or the like various toners of the prior art for use.
It is that company limited of permanent Shi Li group (Hong Kong) produces that used β-1# decomposes transparent agent.
Embodiment 1:
Composition consumption (wt%)
White dyes 0.800
UV light absorber 0.500
β-1# decomposes transparent agent 0.008
The base-material surplus
The each component sum is 100wt%.
Above-mentioned materials is made into optical protection layer, and its manufacture craft process is:
Above-mentioned each component is mixed, and melt pelletization adopts rolling process then, extrudes the blown film method, to become thickness be the film of 50 μ m for extruding hydrostomia method or solvent salivation method.
Test the ultraviolet resistance of this film:
Renminbi is lain on the horizontal table top, face up, be radiated on the Renminbi with UV-lamp, the distance between UV-lamp and the bank note a tangible watermark can occur under " people " word about 5cm.At this moment, put into above-mentioned film between Renminbi and UV-lamp, watermark moment disappears fully, and this explanation ultraviolet ray fails to penetrate film, all is blocked in this film outside, has really reached uvioresistant UV400.Adopt this film can be prepared into the protective film of various articles for use; for example adhering film to glass, eyeglass pad pasting, electron membrane, building film, automobile adhesive film, aircraft rupture disk etc.; can prevent effectively that harmful light from causing that human body produces malignant melanoma; avoid the caused human-body fatigue of harmful light, furniture variable color and embrittlement; especially child, student and Ms there is preferably protective effect in advance; can protect tender and lovely skin, delaying senility.
Embodiment 2
Component content (wt%)
UV light absorber 0.400
White dyes 0.600
Toner 0.015
The base-material surplus
Embodiment 3
Component content (wt%)
White dyes 3.000
Colour-changing agent 15.000
β-1# decomposes transparent agent 0.050
The base-material surplus
Embodiment 4
Component content (wt%)
White dyes 10.000
UV light absorber 10.000
Colour-changing agent 3.200
β-1# decomposes transparent agent 0.090
Blue light agent 0.005
The base-material surplus
Embodiment 5
Component content (wt%)
UV light absorber 0.200
White dyes 2.000
Colour-changing agent 1.000
β-1# decomposes transparent agent 0.020
The base-material surplus
Embodiment 6
Component content (wt%)
UV light absorber 6.000
White dyes 5.000
Colour-changing agent 8.000
β-1# decomposes transparent agent 0.055
Coffee toner 1.500
The base-material surplus
Adopt prior art that the material of embodiment 2 to embodiment 6 is made the film that sheet material, sheet material or thickness do not wait respectively, adopt the method identical to test each end properties with embodiment 1.These materials all have the fully anti-ultraviolet function, and sharpness is good.
The content that does not relate in the foregoing description is same as the prior art.
Claims (9)
1. a whole anti-UV antifatigue reaches anti-malignant melanoma optical protective material, it is characterized in that comprising:
Additive 0.010-30.000wt%
The base-material surplus
The each component sum is 100wt%; Wherein, described additive is selected from white dyes and/or UV light absorber.
2. whole anti-UV antifatigue according to claim 1 and anti-malignant melanoma optical protective material, it is characterized in that also comprising: the β of 0.001-0.150wt%-1# decomposes transparent agent.
3. whole anti-UV antifatigue according to claim 2 and anti-malignant melanoma optical protective material is characterized in that described additive also comprises colour-changing agent, and the consumption of described colour-changing agent is 0.010-20.000wt%.
4. whole anti-UV antifatigue according to claim 3 and anti-malignant melanoma optical protective material, the consumption that it is characterized in that described colour-changing agent is 0.100-10.000wt%.
5. whole anti-UV antifatigue according to claim 4 and anti-malignant melanoma optical protective material, the consumption that it is characterized in that described colour-changing agent is 0.200-4.000wt%.
6. whole anti-UV antifatigue according to claim 1 and anti-malignant melanoma optical protective material is characterized in that also comprising toner, and the addition of described toner is 0.001-2.000wt%.
7. whole anti-UV antifatigue according to claim 6 and anti-malignant melanoma optical protective material, the addition that it is characterized in that described toner is 0.005-1.500wt%.
8. according to described whole anti-UV antifatigue of the arbitrary claim of claim 1 to 7 and anti-malignant melanoma optical protective material, the amount that it is characterized in that described additive is 0.100-15.000wt%.
9. whole anti-UV antifatigue according to claim 8 and anti-malignant melanoma optical protective material, the consumption that it is characterized in that described additive is 0.200-8.000wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101697151A CN101831126B (en) | 2010-03-22 | 2010-03-22 | Fully anti-ultraviolet, anti-fatigue, and anti-malignant melanoma optical protective material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101697151A CN101831126B (en) | 2010-03-22 | 2010-03-22 | Fully anti-ultraviolet, anti-fatigue, and anti-malignant melanoma optical protective material |
Publications (2)
| Publication Number | Publication Date |
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| CN101831126A true CN101831126A (en) | 2010-09-15 |
| CN101831126B CN101831126B (en) | 2012-03-21 |
Family
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|---|---|---|---|
| CN2010101697151A Active CN101831126B (en) | 2010-03-22 | 2010-03-22 | Fully anti-ultraviolet, anti-fatigue, and anti-malignant melanoma optical protective material |
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| CN (1) | CN101831126B (en) |
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| CN103287013A (en) * | 2013-06-19 | 2013-09-11 | 江西科为薄膜新型材料有限公司 | High thermal insulation ultraviolet-proof solar film |
| CN103467936A (en) * | 2013-09-12 | 2013-12-25 | 苏州金海薄膜科技发展有限公司 | PET (polyethylene terephthalate) film capable of absorbing and converting ultraviolet light and shortwave blue light and preparation method thereof |
| CN105295279A (en) * | 2015-10-22 | 2016-02-03 | 袁敏华 | Optical protecting material preventing ultraviolet light and blue light |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104130553A (en) * | 2014-08-01 | 2014-11-05 | 苏州袭麟光电科技产业有限公司 | Anti-ultraviolet solar film and preparation method thereof |
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| WO2017067091A1 (en) * | 2015-10-22 | 2017-04-27 | 袁敏华 | Optical protective material anti ultraviolet light and blue light |
| CN107418114A (en) * | 2015-10-22 | 2017-12-01 | 袁敏华 | The optical protective material of antiultraviolet and blue light |
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| Publication number | Publication date |
|---|---|
| CN101831126B (en) | 2012-03-21 |
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