CN101767953A - Novel thermal insulation mortar foaming agent and preparation method thereof - Google Patents
Novel thermal insulation mortar foaming agent and preparation method thereof Download PDFInfo
- Publication number
- CN101767953A CN101767953A CN 201010123876 CN201010123876A CN101767953A CN 101767953 A CN101767953 A CN 101767953A CN 201010123876 CN201010123876 CN 201010123876 CN 201010123876 A CN201010123876 A CN 201010123876A CN 101767953 A CN101767953 A CN 101767953A
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- foaming agent
- thermal insulation
- insulation mortar
- water
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- 239000004570 mortar (masonry) Substances 0.000 title claims abstract description 32
- 238000009413 insulation Methods 0.000 title claims abstract description 29
- 239000004088 foaming agent Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 24
- 239000003292 glue Substances 0.000 claims abstract description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920000159 gelatin Polymers 0.000 claims abstract description 13
- 235000019322 gelatine Nutrition 0.000 claims abstract description 13
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000839 emulsion Substances 0.000 claims abstract description 11
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims abstract description 11
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims abstract description 11
- 229920000570 polyether Polymers 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 11
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 8
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 8
- 239000010703 silicon Substances 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 8
- 235000011121 sodium hydroxide Nutrition 0.000 claims abstract description 8
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000001828 Gelatine Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 12
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 10
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 10
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 108010010803 Gelatin Proteins 0.000 claims description 8
- 239000008273 gelatin Substances 0.000 claims description 8
- 235000011852 gelatine desserts Nutrition 0.000 claims description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 7
- -1 olefin sulfonate Chemical class 0.000 claims description 7
- 229920002050 silicone resin Polymers 0.000 claims description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000006260 foam Substances 0.000 abstract description 17
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 235000021120 animal protein Nutrition 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
- 238000005187 foaming Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000011381 foam concrete Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Degasification And Air Bubble Elimination (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
The invention provides a novel thermal insulation mortar foaming agent and a preparation method thereof, belongs to the technical field of foaming agent and provides the novel thermal insulation mortar foaming agent, which is characterized by small generated foams, independent enclosing, high intensity, good stability and excellent uniformity and dispersity, and the preparation method thereof. The novel thermal insulation mortar foaming agent is prepared by the following components in part by weight: 4 to 20 parts of lauryl sodium sulfate, 5 to 15 parts of sodium dodecyl benzene sulfonate, 1 to 10 parts of alpha-olefin sulfonate, 0.01 to 3 parts of HPMC, 0.01 to 3 parts of gelatine powder, 1 to 10 parts of glue, 0.02 to 3 parts of polyether emulsion, 1 to 10 parts of animal protein, 50 to 70 parts of water, 5 to 10 parts of sodium alcohol ether sulphate, 10 to 15 parts of rosin, 0.01 to 2 parts of ninol, 1 to 10 parts of siliceous dust, 0.02 to 3 parts of silicon resin, 0.1 to 3 parts of water reducer, 1 to 5 parts of caustic soda and 0.1 to 2 parts of hydrochloric acid. The novel thermal insulation mortar foaming agent is applied to the technical field of foaming agent.
Description
Technical field
Novel thermal insulation mortar foaming agent of the present invention and preparation method thereof belongs to the whipping agent technical field.
Background technology
Current, the status of building energy conservation in energy-saving and emission-reduction is more and more important.The proportion of thermal insulation mortar class material constantly increases in field of thermal insulation, but the high shortcoming of such material ubiquity thermal conductivity, and this does not meet the development trend of building energy conservation.Along with the maturation of foamed concrete technology, be subjected to extensive approval thereby in material of construction, add bubble reduction thermal conductivity.Foaming technique can be applied to the thermal insulation mortar field, is the once great breakthrough of building energy saving field.
Tradition whipping agent function is few, poor with mortar bonding, the froth stability, homogeneity, dispersiveness, the foam independence that generate are all undesirable, and thermal insulation mortar is subjected to the restriction of aspects such as intensity, material, only use traditional whipping agent can't satisfy construction and require with insulation.
Summary of the invention
For overcoming the deficiencies in the prior art, the invention provides the small and independent sealing of a kind of generation foam, intensity height, good stability, novel thermal insulation mortar foaming agent of homogeneity and excellent dispersion and preparation method thereof.
For solving the problems of the technologies described above, the technical solution used in the present invention is: novel thermal insulation mortar foaming agent is equipped with by following weight part:
Sodium lauryl sulphate: 4～20 parts, Sodium dodecylbenzene sulfonate: 5～15 parts, α-sodium olefin sulfonate: 1～10 part, HPMC:0.01～3 part, rubber powder: 0.01～3 part, glue class: 1～10 part, polyethers emulsion: 0.02～3 part, animal proteinum: 1～10 part, water: 50～70 parts; Described glue class is a gelatine or for gelatin or for gelatin.
Described novel thermal insulation mortar foaming agent also comprises: polyoxyethylenated alcohol sodium sulfate: 5～10 parts, rosin: 10～15 parts, Buddhist nun are received: 0.01～2 part, silicon ash: 1～10 part, silicone resin: 0.02～3 part, water reducer: 0.1～3 part, caustic soda: 1～5 part, hydrochloric acid: 0.1～2 part.
A kind of method for preparing above-mentioned novel thermal insulation mortar foaming agent is prepared raw material by above-mentioned weight part proportioning, and prepares by following step:
The first step: glue class and animal proteinum are prepared into powdery and mixing, place in the heating container, under 70～80 ℃ of temperature condition, water-bath 5～7 hours is with products therefrom cooling, filtration;
Second step: sodium lauryl sulphate, Sodium dodecylbenzene sulfonate and polyethers emulsion is all soluble in water, be heated to 100 ℃ and be incubated 2.5 hours then;
The 3rd step: above two kinds of mixtures are put into heating container mix, surplus water is added, stirred this secondary mixture 2 hours;
The 4th step: required component rubber powder, HPMC are added in the above-mentioned secondary mixture, and stirred 1～2 hour, what draw promptly is this whipping agent.
The method of the above-mentioned novel thermal insulation mortar foaming agent of another kind of preparation is prepared raw material by above-mentioned weight part proportioning, and presses following step preparation:
The first step: glue class, rosin, animal proteinum and caustic soda are prepared into powdery and mix, then add hydrochloric acid and place in the heating container, under 70～80 ℃ of temperature condition, water-bath 5～7 hours is with the products therefrom cooling, filter;
Second step: with sodium lauryl sulphate, Sodium dodecylbenzene sulfonate, polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, Buddhist nun receive, silicon ash, silicone resin, polyethers emulsion and water reducer be all soluble in water, is heated to 100 ℃ and be incubated 2.5 hours then;
The 3rd step: above two kinds of mixtures are put into heating container mix, surplus water is added, stirred this secondary mixture 2 hours;
The 4th step: required component rubber powder, HPMC are added in the above-mentioned secondary mixture, and stirred 1～2 hour, what draw promptly is this whipping agent.
The present invention compares the beneficial effect that has with prior art:
1, adopted organic and inorganic technologies composite foamed, the foam of generation is small and amount is big, has improved the effect of foaming greatly.
2, by adding animal proteinoid material, glue class material, chemical additive etc., the foam of generation is had " skeleton ", certain intensity is promptly arranged, at room temperature, this foam can be preserved more than 24 hours.
3, the foam that sends of this whipping agent can be on the foam wall after the foaming film forming, each foam is independently sealed, different foam amounts with can reduce thermal conductivity 0.02～0.04w/mk after mortar mixes, improve heat-insulating property.
4, with thermal insulation mortar mechanically spraying foaming technique seamless combination, can make the bubble amount reach optimization, the foamed heat insulating mortar of ejection is even, high-strength, thermal conductivity is low, and reduces cost.
5, this whipping agent preparation method is simple, and cost is low, and than traditional whipping agent foaming efficient height, adding can reach the requirement of bubble amount on a small quantity.
Embodiment
Novel thermal insulation mortar foaming agent is equipped with by following weight part:
Sodium lauryl sulphate: 4～20 parts, Sodium dodecylbenzene sulfonate: 5～15 parts, α-sodium olefin sulfonate: 1～10 part, HPMC:0.01～3 part, rubber powder: 0.01～3 part, glue class: 1～10 part, polyethers emulsion: 0.02～3 part, animal proteinum: 1～10 part, water: 50～70 parts; Described glue class is a gelatine or for gelatin or for gelatin.
Described novel thermal insulation mortar foaming agent also comprises: polyoxyethylenated alcohol sodium sulfate: 5～10 parts, rosin: 10～15 parts, Buddhist nun are received: 0.01～2 part, silicon ash: 1～10 part, silicone resin: 0.02～3 part, water reducer: 0.1～3 part, caustic soda: 1～5 part, hydrochloric acid: 0.1～2 part.
A kind of more excellent proportioning of novel thermal insulation mortar foaming agent of the present invention is:
Sodium lauryl sulphate: 15 parts, Sodium dodecylbenzene sulfonate: 10 parts, polyoxyethylenated alcohol sodium sulfate: 8 parts, α-sodium olefin sulfonate: 5 parts, rosin: 12 parts, HPMC:1 part, rubber powder: 1 part, glue class: 5 parts, Buddhist nun are received: 1 part, silicon ash: 5 parts, silicone resin: 1 part, polyethers emulsion: 1 part, animal proteinum: 5 parts, water reducer: 1 part, caustic soda: 2 parts, hydrochloric acid: 1 part, water: 60 parts;
The present invention has adopted organic composite foamed with inorganic technologies, the foam that produces is small and amount is big, improved the effect of foaming greatly, by adding animal proteinoid material, glue class material, chemical additive etc., the foam of generation is had " skeleton ", certain intensity is promptly arranged, and at room temperature, this foam can be preserved more than 24 hours.Described glue class is a gelatine or for gelatin or for gelatin; The foam that this whipping agent sends can be on the foam wall after the foaming film forming, each foam is independently sealed, different foam amounts with can reduce thermal conductivity 0.02～0.04w/mk after mortar mixes, improve heat-insulating property; The present invention and thermal insulation mortar mechanically spraying foaming technique seamless combination can make the bubble amount reach optimization, and the foamed heat insulating mortar of ejection is even, high-strength, thermal conductivity is low, and reduces cost.
A kind of method for preparing above-mentioned novel thermal insulation mortar foaming agent is prepared raw material by above-mentioned weight part proportioning, and prepares by following step:
The first step: glue class and animal proteinum are prepared into powdery and mixing, place in the heating container, under 70～80 ℃ of temperature condition, water-bath 5～7 hours is with products therefrom cooling, filtration;
Second step: sodium lauryl sulphate, Sodium dodecylbenzene sulfonate and polyethers emulsion is all soluble in water, be heated to 100 ℃ and be incubated 2.5 hours then;
The 3rd step: above two kinds of mixtures are put into heating container mix, surplus water is added, stirred this secondary mixture 2 hours;
The 4th step: required component rubber powder, HPMC are added in the above-mentioned secondary mixture, and stirred 1～2 hour, what draw promptly is this whipping agent.
The method of the above-mentioned novel thermal insulation mortar foaming agent of another kind of preparation is prepared raw material by above-mentioned weight part proportioning, and presses following step preparation:
The first step: glue class, rosin, animal proteinum and caustic soda are prepared into powdery and mix, then add hydrochloric acid and place in the heating container, under 70～80 ℃ of temperature condition, water-bath 5～7 hours is with the products therefrom cooling, filter;
Second step: with sodium lauryl sulphate, Sodium dodecylbenzene sulfonate, polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, Buddhist nun receive, silicon ash, silicone resin, polyethers emulsion and water reducer be all soluble in water, is heated to 100 ℃ and be incubated 2.5 hours then;
The 3rd step: above two kinds of mixtures are put into heating container mix, surplus water is added, stirred this secondary mixture 2 hours;
The 4th step: required component rubber powder, HPMC are added in the above-mentioned secondary mixture, and stirred 1～2 hour, what draw promptly is this whipping agent.
This whipping agent preparation method is simple, and cost is low, and than traditional whipping agent foaming efficient height, adding can reach the requirement of bubble amount on a small quantity.
The present invention is widely used in chemical industry, building material field, has great application value.
Claims (4)
1. novel thermal insulation mortar foaming agent is characterized in that being equipped with by following weight part:
Sodium lauryl sulphate: 4～20 parts, Sodium dodecylbenzene sulfonate: 5～15 parts, α-sodium olefin sulfonate: 1～10 part, HPMC:0.01～3 part, rubber powder: 0.01～3 part, glue class: 1～10 part, polyethers emulsion: 0.02～3 part, animal proteinum: 1～10 part, water: 50～70 parts; Described glue class is a gelatine or for gelatin or for gelatin.
2. novel thermal insulation mortar foaming agent according to claim 1 is characterized in that: described novel thermal insulation mortar foaming agent also comprises: polyoxyethylenated alcohol sodium sulfate: 5～10 parts, rosin: 10～15 parts, Buddhist nun are received: 0.01～2 part, silicon ash: 1～10 part, silicone resin: 0.02～3 part, water reducer: 0.1～3 part, caustic soda: 1～5 part, hydrochloric acid: 0.1～2 part.
3. one kind prepares the method for novel thermal insulation mortar foaming agent according to claim 1, it is characterized in that preparing raw material by above-mentioned weight part proportioning, and prepares by following step:
The first step: glue class and animal proteinum are prepared into powdery and mixing, place in the heating container, under 70～80 ℃ of temperature condition, water-bath 5～7 hours is with products therefrom cooling, filtration;
Second step: sodium lauryl sulphate, Sodium dodecylbenzene sulfonate and polyethers emulsion is all soluble in water, be heated to 100 ℃ and be incubated 2.5 hours then;
The 3rd step: above two kinds of mixtures are put into heating container mix, surplus water is added, stirred this secondary mixture 2 hours;
The 4th step: required component rubber powder, HPMC are added in the above-mentioned secondary mixture, and stirred 1～2 hour, what draw promptly is this whipping agent.
4. method for preparing as novel thermal insulation mortar foaming agent as described in the claim 2 is characterized in that: prepare raw material by above-mentioned weight part proportioning, and by following step preparation:
The first step: glue class, rosin, animal proteinum and caustic soda are prepared into powdery and mix, then add hydrochloric acid and place in the heating container, under 70～80 ℃ of temperature condition, water-bath 5～7 hours is with the products therefrom cooling, filter;
Second step: with sodium lauryl sulphate, Sodium dodecylbenzene sulfonate, polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, Buddhist nun receive, silicon ash, silicone resin, polyethers emulsion and water reducer be all soluble in water, is heated to 100 ℃ and be incubated 2.5 hours then;
The 3rd step: above two kinds of mixtures are put into heating container mix, surplus water is added, stirred this secondary mixture 2 hours;
The 4th step: required component rubber powder, HPMC are added in the above-mentioned secondary mixture, and stirred 1～2 hour, what draw promptly is this whipping agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101238767A CN101767953B (en) | 2010-03-11 | 2010-03-11 | Novel thermal insulation mortar foaming agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101238767A CN101767953B (en) | 2010-03-11 | 2010-03-11 | Novel thermal insulation mortar foaming agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101767953A true CN101767953A (en) | 2010-07-07 |
| CN101767953B CN101767953B (en) | 2012-07-25 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2010101238767A Expired - Fee Related CN101767953B (en) | 2010-03-11 | 2010-03-11 | Novel thermal insulation mortar foaming agent and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102212356A (en) * | 2011-04-08 | 2011-10-12 | 西安石油大学 | High temperature foaming agent |
| CN102329149A (en) * | 2011-07-12 | 2012-01-25 | 梁材 | Foaming agent for sound absorption foam concrete product and preparation method for foaming agent |
| CN102329150A (en) * | 2011-07-28 | 2012-01-25 | 梁材 | Concrete foaming agent and preparation method thereof |
| CN102344299A (en) * | 2011-07-12 | 2012-02-08 | 梁材 | Foaming agent used in ultra-low density anti-seepage foamed concrete, and preparation method thereof |
| CN102964080A (en) * | 2012-10-26 | 2013-03-13 | 安徽艾柯泡塑股份有限公司 | Composite foaming agent for concrete |
| CN103553421A (en) * | 2013-11-01 | 2014-02-05 | 邹平福海科技发展有限公司 | Environment-friendly compound concrete foaming agent and preparation method thereof |
| CN104098343A (en) * | 2013-04-15 | 2014-10-15 | 北京华德创业环保设备有限公司 | Foaming agent for filling materials |
| CN104176971A (en) * | 2014-08-06 | 2014-12-03 | 广州市永昊建设工程有限公司 | Foaming agent and preparation method thereof |
| CN107236375A (en) * | 2017-06-20 | 2017-10-10 | 合肥尚涵装饰工程有限公司 | It is a kind of effectively to purify emulsion paint of air and preparation method thereof |
| CN108947311A (en) * | 2017-05-26 | 2018-12-07 | 高志明 | A kind of lignin-base foam concrete foamer |
| CN110156370A (en) * | 2019-05-05 | 2019-08-23 | 东南大学 | A kind of compound foaming agent |
| CN110747331A (en) * | 2019-12-12 | 2020-02-04 | 四川高锗再生资源有限公司 | Scour prevention feed liquid, preparation method thereof and application thereof in germanium concentrate leaching distillation |
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| CN1583940A (en) * | 2004-05-28 | 2005-02-23 | 湖北大学 | Use of residual active sludge protein as foam drilling liquid and preparing method thereof |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102212356A (en) * | 2011-04-08 | 2011-10-12 | 西安石油大学 | High temperature foaming agent |
| CN102329149B (en) * | 2011-07-12 | 2013-05-08 | 梁材 | Foaming agent for sound absorption foam concrete product and preparation method for foaming agent |
| CN102329149A (en) * | 2011-07-12 | 2012-01-25 | 梁材 | Foaming agent for sound absorption foam concrete product and preparation method for foaming agent |
| CN102344299A (en) * | 2011-07-12 | 2012-02-08 | 梁材 | Foaming agent used in ultra-low density anti-seepage foamed concrete, and preparation method thereof |
| CN102329150A (en) * | 2011-07-28 | 2012-01-25 | 梁材 | Concrete foaming agent and preparation method thereof |
| CN102329150B (en) * | 2011-07-28 | 2013-05-08 | 梁材 | Concrete foaming agent and preparation method thereof |
| CN102964080B (en) * | 2012-10-26 | 2014-04-23 | 安徽艾柯泡塑股份有限公司 | Composite foaming agent for concrete |
| CN102964080A (en) * | 2012-10-26 | 2013-03-13 | 安徽艾柯泡塑股份有限公司 | Composite foaming agent for concrete |
| CN104098343A (en) * | 2013-04-15 | 2014-10-15 | 北京华德创业环保设备有限公司 | Foaming agent for filling materials |
| CN103553421A (en) * | 2013-11-01 | 2014-02-05 | 邹平福海科技发展有限公司 | Environment-friendly compound concrete foaming agent and preparation method thereof |
| CN103553421B (en) * | 2013-11-01 | 2015-10-14 | 深圳市中天元实业有限公司 | A kind of environmentally friendly compounding coagulation soil whipping agent and preparation method thereof |
| CN104176971A (en) * | 2014-08-06 | 2014-12-03 | 广州市永昊建设工程有限公司 | Foaming agent and preparation method thereof |
| CN104176971B (en) * | 2014-08-06 | 2017-01-18 | 广州市永昊建设工程有限公司 | Foaming agent and preparation method thereof |
| CN108947311A (en) * | 2017-05-26 | 2018-12-07 | 高志明 | A kind of lignin-base foam concrete foamer |
| CN107236375A (en) * | 2017-06-20 | 2017-10-10 | 合肥尚涵装饰工程有限公司 | It is a kind of effectively to purify emulsion paint of air and preparation method thereof |
| CN110156370A (en) * | 2019-05-05 | 2019-08-23 | 东南大学 | A kind of compound foaming agent |
| CN110747331A (en) * | 2019-12-12 | 2020-02-04 | 四川高锗再生资源有限公司 | Scour prevention feed liquid, preparation method thereof and application thereof in germanium concentrate leaching distillation |
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