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CN101705491A - High-temperature zinc alloy sacrificial anode - Google Patents

High-temperature zinc alloy sacrificial anode Download PDF

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Publication number
CN101705491A
CN101705491A CN200910230198A CN200910230198A CN101705491A CN 101705491 A CN101705491 A CN 101705491A CN 200910230198 A CN200910230198 A CN 200910230198A CN 200910230198 A CN200910230198 A CN 200910230198A CN 101705491 A CN101705491 A CN 101705491A
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percent
sacrificial anode
zinc alloy
zinc
equal
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CN200910230198A
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Inventor
刘光洲
孙明先
付洪田
王海涛
郝少丽
郭宇
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QINGDAO SUNRUI CORROSION AND FOULING CONTROL Co
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QINGDAO SUNRUI CORROSION AND FOULING CONTROL Co
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Priority to CN200910230198A priority Critical patent/CN101705491A/en
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Abstract

The invention belongs to the technical field of corrosion and protection, and relates to a high-temperature zinc alloy sacrificial anode used for cathode protection, wherein alloy elements are added in a zinc substrate, a sacrificial anode material with high electrochemistry performance is obtained by controlling the proportion of AI and Mn elements, the electric capacity of the anode is larger than 790A h/kg, surface dissolving is uniform, and corrosion products are easy to fall off so as to be used for the cathode protection in high-temperature seawater; the formula of the zinc alloy sacrificial anode is as follows: 0.2 to 1.0 percent of AI, 0.05 to 0.2 percent of Mn, impurity content thereof is as follows: less than or equal to 0.03 percent of Pb, less than or equal to 0.002 percent of Cd, less than or equal to 0.001 percent of Cu, less than or equal to 0.001 percent of Fe, and the balance of Zn; carbon crucible is used for smelting zinc ingot in a heating furnace, AI and Mn are added into a molten zinc solution according to proportion, a graphite rod is used for stirring, deslagging is conducted, and the product is taken out of the furnace for casting; and the preparation technology is mature, the operation is simple and convenient, the proportion is reasonable, the service life is long, and the effect is good, thus being widely applied to the cathode protection in the seawater field in high temperature environment.

Description

A kind of high-temperature zinc alloy sacrificial anode
Technical field:
The invention belongs to the corrosion and protection technical field, relate to the high-temperature zinc alloy sacrificial anode that a kind of galvanic protection is used.
Background technology:
In recent years, along with the development of offshore oil production and refining of petroleum industry, the mileage of oil pipeline increases sharply, and residing environment is numerous and complicated also, as seabed, soil etc.Oil pipeline will be corroded in these environment inevitably, the corrosion damage of oil pipeline not only can cause financial loss, and can since crude oil leakage cause environmental disaster or endanger public security, therefore, must take anti-corrosion measure to oil pipeline.For pipeline under the ocean, it is anticorrosion that main anti-corrosion measure is exactly coating and sacrificial protection associating.But, the corrosive environment of pipeline under the ocean has singularity: for improving the flowability of crude oil, often will heat, make that the envrionment temperature around the pipeline is everlasting between 50~70 ℃, therefore, existing sacrificial anode performance under this work condition environment all sharply descends.When at high temperature using as common ternary zinc anode, intergranular corrosion can take place, current efficiency significantly reduces, and current potential is shuffled, even current potential than iron and steel also just becomes, and not only can not protect the iron and steel facility, quickens its corrosion on the contrary.Traditional sacrificial aluminium alloy anode is surface passivation easily in high temperature seawater, forms one deck corrosion product duricrust, the magnitude of current takes place sharply descend, and does not have due provide protection.Therefore, need a kind of sacrificial anode material that is adapted at using in the high temperature seawater of development.The high-temperature zinc alloy anode has a tame manufacturer can make this product abroad, and its anodic actual capacitance only is 780Ah/kg, and integrated performance index also is difficult to satisfy the requirement for anticorrosion of respective environment.
Summary of the invention:
The objective of the invention is to overcome the shortcoming of prior art; seek to prepare a kind of novel sacrificial anode material; make it in high temperature seawater, have excellent electrochemical properties; anode capacity is greater than 780Ah/kg; surface dissolution is even; operating potential meets the requirement of GB/T 4950-2002, can be used for the galvanic protection of pipeline under the ocean.
To achieve these goals, the new type high temperature sacrificial zinc alloy anode material of the present invention's design adds alloying element by weight percentage in the zinc-base body, ratio by control Al, Mn element, obtain the sacrificial anode material of high electrochemical performance, the anodic electrical capacity is greater than 790Ah/kg, surface dissolution is even, and corrosion product comes off easily, is used for the galvanic protection of high temperature seawater; The weight percent prescription of its sacrificial zinc alloy anode is Al:0.2-1.0%; Mn:0.05-0.2%; Foreign matter content: Pb≤0.03%; Cd≤0.002%; Cu≤0.001%; Fe≤0.001%; Surplus is Zn.
The high-temperature zinc alloy sacrificial anode that the present invention relates to adopts conventional fusion casting processing and manufacturing, contains zinc ingot metal with the special graphite crucible, in process furnace zinc ingot metal is melted, according to certain proportioning, in fused zinc liquid, add Al and Mn, stir with graphite rod, slagging-off, tapping casting; Process furnace is selected coke stove, electric furnace, oil oven, steam stove etc. for use.Its chemical property sees Table 1.
The chemical property of table 1 high-temperature zinc alloy sacrificial anode (in 50 ℃ the natural sea-water)
Open circuit potential, V (SCE) Operating potential, V (SCE) Actual capacitance, Ah/kg Current efficiency, % The dissolving situation
??-1.09~-??1.05 ??-1.05~-??1.00 ??≥790 ??≥97 Product comes off easily, and surface dissolution is even
The present invention compared with prior art, its preparation technology's method maturation, easy and simple to handle, reasonable ratio, long service life is protected effectively, can be widely used in the galvanic protection in the seawater field under the hot environment.
Embodiment:
Below by embodiment the present invention is further described.
Embodiment 1: the prescription of a kind of sacrificial zinc alloy anode that present embodiment relates to is (weight percent): Al:0.2%; Mn:0.05%; Foreign matter content: Pb≤0.03%; Cd≤0.002%; Cu≤0.001%; Fe≤0.001%; Surplus is Zn; High-temperature zinc alloy sacrificial anode adopts the fusion casting processing and manufacturing, and its chemical property sees Table 2.
Embodiment 2: the prescription that present embodiment relates to another kind of sacrificial zinc alloy anode is (weight percent): Al:1.0%; Mn:0.1%; Foreign matter content: Pb≤0.03%; Cd≤0.002%; Cu≤0.001%; Fe≤0.001%; Surplus is Zn; Sacrificial zinc alloy anode adopts the fusion casting processing and manufacturing, and its chemical property sees Table 2.
Embodiment 3: the prescription that present embodiment relates to another high-temperature zinc alloy sacrificial anode is (weight percent): Al:0.6%; Mn:0.2%; Foreign matter content: Pb≤0.03%; Cd≤0.002%; Cu≤0.001%; Fe≤0.001%; Surplus is Zn; Sacrificial zinc alloy anode adopts the fusion casting processing and manufacturing, and its chemical property sees Table 2.
According to GB/T 17848-1999 specified standards test method the zinc alloy anode chemical property is tested, the chemical property of each embodiment sees Table 2.
The chemical property of three embodiment high-temperature zinc alloy sacrificial anodes of table 2 (in 50 ℃ the natural sea-water)
Figure G2009102301981D0000031

Claims (1)

1. high-temperature zinc alloy sacrificial anode, it is characterized in that in the zinc-base body, adding by weight percentage alloying element, the ratio of control Al, Mn element obtains sacrificial anode material, the anodic electrical capacity is greater than 790Ah/kg, surface dissolution is even, corrosion product comes off easily, is used for the galvanic protection of high temperature seawater; The weight percent prescription of its sacrificial zinc alloy anode is Al:0.2-1.0%; Mn:0.05-0.2%; Foreign matter content: Pb≤0.03%; Cd≤0.002%; Cu≤0.001%; Fe≤0.001%; Surplus is Zn.
CN200910230198A 2009-11-20 2009-11-20 High-temperature zinc alloy sacrificial anode Pending CN101705491A (en)

Priority Applications (1)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102418101A (en) * 2011-11-29 2012-04-18 青岛双瑞海洋环境工程有限公司 Composite sacrificial anode for repairing reinforced concrete structure
CN103103537A (en) * 2013-02-28 2013-05-15 青岛双瑞海洋环境工程股份有限公司 Novel zinc alloy sacrificial anode in hot seawater environment
WO2015084691A1 (en) * 2013-12-06 2015-06-11 Saudi Arabian Company Cathodic protection automated current and potential measuring device for anodes protecting vessel internals
CN104862530A (en) * 2015-06-09 2015-08-26 青岛双瑞海洋环境工程股份有限公司 Zinc alloy sacrificial anode applicable to hot seabed mud environment
CN104862710A (en) * 2015-06-09 2015-08-26 青岛双瑞海洋环境工程股份有限公司 Environment-friendly sacrificial zinc alloy anode
CN110106509A (en) * 2019-06-19 2019-08-09 青岛双瑞海洋环境工程股份有限公司 Efficient sacrificial zinc alloy anode for high temperature crude oil sedimentary water environment
CN113046755A (en) * 2021-03-10 2021-06-29 青岛双瑞海洋环境工程股份有限公司 High-temperature-resistant zinc alloy sacrificial anode and preparation method thereof

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102418101A (en) * 2011-11-29 2012-04-18 青岛双瑞海洋环境工程有限公司 Composite sacrificial anode for repairing reinforced concrete structure
CN102418101B (en) * 2011-11-29 2013-07-24 青岛双瑞海洋环境工程股份有限公司 Composite type sacrificial anode for repairing reinforced concrete structures
CN103103537A (en) * 2013-02-28 2013-05-15 青岛双瑞海洋环境工程股份有限公司 Novel zinc alloy sacrificial anode in hot seawater environment
CN103103537B (en) * 2013-02-28 2014-12-17 青岛双瑞海洋环境工程股份有限公司 Novel zinc alloy sacrificial anode in hot seawater environment
WO2015084691A1 (en) * 2013-12-06 2015-06-11 Saudi Arabian Company Cathodic protection automated current and potential measuring device for anodes protecting vessel internals
US9441307B2 (en) 2013-12-06 2016-09-13 Saudi Arabian Oil Company Cathodic protection automated current and potential measuring device for anodes protecting vessel internals
CN104862530A (en) * 2015-06-09 2015-08-26 青岛双瑞海洋环境工程股份有限公司 Zinc alloy sacrificial anode applicable to hot seabed mud environment
CN104862710A (en) * 2015-06-09 2015-08-26 青岛双瑞海洋环境工程股份有限公司 Environment-friendly sacrificial zinc alloy anode
CN104862530B (en) * 2015-06-09 2016-12-07 青岛双瑞海洋环境工程股份有限公司 A kind of sacrificial zinc alloy anode being applicable to hot sea mud environment
CN104862710B (en) * 2015-06-09 2017-07-28 青岛双瑞海洋环境工程股份有限公司 A kind of environmentally friendly sacrificial zinc alloy anode
CN110106509A (en) * 2019-06-19 2019-08-09 青岛双瑞海洋环境工程股份有限公司 Efficient sacrificial zinc alloy anode for high temperature crude oil sedimentary water environment
CN113046755A (en) * 2021-03-10 2021-06-29 青岛双瑞海洋环境工程股份有限公司 High-temperature-resistant zinc alloy sacrificial anode and preparation method thereof

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Open date: 20100512