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CN101627783B - Transportation type preservative paper for red grapes - Google Patents

Transportation type preservative paper for red grapes Download PDF

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Publication number
CN101627783B
CN101627783B CN 200710186888 CN200710186888A CN101627783B CN 101627783 B CN101627783 B CN 101627783B CN 200710186888 CN200710186888 CN 200710186888 CN 200710186888 A CN200710186888 A CN 200710186888A CN 101627783 B CN101627783 B CN 101627783B
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red grapes
wax
preservative paper
red
organic acid
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CN101627783A (en
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吴斌
钟梅
王吉德
尹勇前
司志伟
王頔
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URUMQI GREEN DOCTOR PRESERVATIVE TECHNOLOGY Co Ltd
Xinjiang University
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URUMQI GREEN DOCTOR PRESERVATIVE TECHNOLOGY Co Ltd
Xinjiang University
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Abstract

The invention relates to transportation type preservative paper for red grapes, which is characterized in that ceraceous materials are used as hydrophobic materials, and a mixture of pyrosulfite and organic acid is diffused in the ceraceous materials (the weight proportion of pyrosulfite and organic acid to the ceraceous materials is 10:90 to 90:10) to form an active material layer capable of slowly releasing SO2. Hot pressing is carried out on the active material layer by non-woven fabrics and breathable film to form the preservative paper. The release period of the preservative paper in the low and damp transportation process of red grapes can reach four or five days, and the residue amount of SO2 in the preserved red grapes is smaller than 10 ppm.

Description

Transportation type preservative paper for red grapes
Technical field
The present invention relates to cold chain storage, the long-distance transport preservation method of red grape, particularly to discharging SO in the present red grape preservation process continuously 2The SO that fresh-keeping pattern causes 2Excess accumulation makes red grape produce poisoning, bleaching, causes red grape pericarp after transportation to fade and loses original local flavor and a kind of novel transportation type preservative paper for red grapes invented.
Background technology
Xinjiang red grape essential species is implanted in areas such as Xinjiang Yi Li, Aksu, Kuerle, because the climatic conditions arid in Xinjiang is short of rain, and the photo-thermal aboundresources, the temperature difference is big.Here the red grape that grows out flavor is sweet, tasty and refreshing, sugar content is high, does not have difference with U.S. import grape, and sugar content is also a little more than American red globe grape.And the grape fringe is big, beautiful in colour, quality is crisp firmly, sugar content is high, and single fruit weight maximum can reach gram more than 20, and Dan Suike reaches about 1 kilogram.Medicinal, nutrition, the health-care effect of red grape are fairly obvious, can alleviate about edible 50 grams during hypoglycemia, can remove hypoglycemic symptom immediately.Nutrition is very abundant, and it contains glucose and fructose more than 17%, the malic acid of 0.5%-1.5%, tartaric acid, citric acid etc.The protein and human body trace elements necessary and multivitamin and amino acid such as the potassium that enriches, calcium, sodium, manganese that contain 0.15%-0.9%.Annual full boundary has eating red proposition mouthful Central Asia raw and being transported to each big city, interior ground about 300,000 tons to sell.
At present, the tin foil that Xinjiang red grape transport point is used mainly is to adopt craft paper to process with moulding paper disposable encapsulation pyrosulfurous acid salt, though this tin foil has reduced SO than previous antistaling paper for grapes 2Release rate and burst size, but since red grape to SO 2Gas concentration is sensivity relatively, so still there is SO 2Excessive and the shortcomings such as injury red grape pericarp color and luster and mouthfeel of concentration in early stage, and, the SO in red grape pulp 2Residual quantity is higher than the standard allowance in the world, has had a strong impact on the outlet sales volume of Xinjiang red grape.
The invention provides a kind of simple, efficient, controlled SO 2Method for generation, and developed transportation type preservative paper for red grapes, can control SO 2Release rate and burst size, release period reached about 45 days, made SO in the red grape of fresh-keeping mistake 2Residual quantity less than 10ppm.
Summary of the invention
The present invention adopts wax material to make lyophobic dust, pyrosulfurous acid salt and organic acid compound is distributed in the wax material (mass ratio: pyrosulfurous acid salt+organic acid: wax material=10: 90~90: 10) form and can slowly discharge SO 2The active material layer of gas, and with nonwoven fabrics and breathable films active material layer is carried out hot pressing and form tin foil, its composition is seen (Fig. 1,2).In the present invention, the compound of sulfites or sulfites and organic acid thing and wax material also can be the compound with several kinds of acidic materials and several kinds of wax materials.Its reaction occurring mode is following:
Figure GSB00000807436400011
Owing to the existence of wax material is arranged in reaction, thereby weakens pyrosulfurous acid salt and the infiltration rate that water in air is divided, and reduced the speed of response of pyrosulfurous acid salt and acidic materials, make active material layer can slowly discharge SO uniformly 2Gas.Simultaneously, the existence of acidic materials can make second SO in the pyrosulfite class 2Discharge, prolonged the deenergized period of tin foil, and improved the degree of utilization of product.The present invention has placed organic acid substance and wax material extends to about 45 days tin foil deenergized period; The red grape of handling through the present invention still keeps good quality in transportation and short-term storage; The mouthfeel of red grape remains unchanged with the fruit look, through measuring the SO in the pulp 2Residual quantity is less than 10ppm.
Organic acid substance among the present invention can be weak organic acid classes such as citric acid, tartaric acid;
Wax material among the present invention can be following material: paraffin, polypropylene wax, Tissuemat E or ceresine wax.Breathable films can be following material: polyester, polypropylene, poly-vinyl, the film that polyvinylchloride or their compound are processed etc.
Simultaneously, nonwoven fabrics that the present invention adopts and breathable films material all have hydrophobic, have reduced the rate of moisture absorption of tin foil in the red grape transportation like this, reduction by a relatively large margin SO 2Red grape is injured.Utilize the control SO that above material can be successful 2The burst size of gas and release rate have reduced red grape poisoning effect, thereby make red grape after transportation, still keep original local flavor and mouthfeel.The economic value added and the market competitive power of Xinjiang red grape have been improved.
Description of drawings
For the architectural feature of transportation type preservative paper for red grapes better is described, carry out the following description with regard to its architectural feature.
Fig. 1 is that figure is cut on the plane of transportation type preservative paper for red grapes;
The planar view of Fig. 2 transportation type preservative paper for red grapes;
1,1 among Fig. 1 and Fig. 2 is nonwoven cloth material;
2,2 among Fig. 1 and Fig. 2 is the plastic films gas permeable material of permeability to air;
3,3 among Fig. 1 and Fig. 2 is for containing the active coating of pyrosulfurous acid salt and organic acid and wax material;
The specific embodiment
Embodiment 1
Weight ratio does, sodium pyrosulfite 70%, and citric acid 10%, paraffin are 20%, relative humidity is more than 90%, with nonwoven fabrics and polypropylene film heat seal encapsulation.Low temperature transportation red grape release period is about 40 days.
Embodiment 2
Weight ratio does, sodium pyrosulfite 75%, and citric acid 5%, paraffin are 20%, relative humidity is more than 90%, with nonwoven fabrics and polypropylene film heat seal encapsulation.Low temperature transportation red grape release period is about 45 days.
Embodiment 3
Weight ratio does, sodium pyrosulfite 70%, and tartaric acid 10%, paraffin are 20%, relative humidity is more than 90%, with nonwoven fabrics and polypropylene film heat seal encapsulation.Low temperature transportation red grape release period is about 40 days.
Embodiment 4
Weight ratio does, sodium pyrosulfite 75%, and tartaric acid 5%, ceresine wax are 20%, relative humidity is more than 90%, with nonwoven fabrics and mylar heat seal encapsulation.Low temperature transportation red grape release period is about 45 days.
Embodiment 5
Weight ratio does, sodium pyrosulfite 70%, and tartaric acid+citric acid 10%, ceresine wax are 20%, relative humidity is more than 90%, with nonwoven fabrics and mylar heat seal encapsulation.Low temperature transportation red grape release period is about 38 days.
Embodiment 6
Weight ratio does, sodium pyrosulfite 75%, and tartaric acid+citric acid 10%, ceresine wax are 15%, relative humidity is more than 90%, with nonwoven fabrics and mylar encapsulation.Low temperature transportation red grape release period is about 45 days.

Claims (2)

1. transportation type preservative paper for red grapes; It is characterized by; Pyrosulfurous acid salt and organic acid compound are distributed in the wax material, by quality ratio: pyrosulfurous acid salt+organic acid: wax material=10: 90~90: 10 can slowly discharge SO to form 2The active material layer of gas, this active material layer that contains the pyrosulfurous acid salt carries out the hot pressing encapsulation with nonwoven fabrics and breathable films with active material layer,
Wherein, said wax material is: paraffin, polypropylene wax, Tissuemat E or ceresine wax; Said breathable films is: polyester, polypropylene, poly-vinyl, the film that polyvinylchloride or their compound are processed.
2. by the described transportation type preservative paper for red grapes of claim 1, wherein: organic acid is a tartaric acid, citric acid.
CN 200710186888 2007-11-23 2007-11-23 Transportation type preservative paper for red grapes Active CN101627783B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN 200710186888 CN101627783B (en) 2007-11-23 2007-11-23 Transportation type preservative paper for red grapes

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CN101627783B true CN101627783B (en) 2012-09-05

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101926387B (en) * 2010-09-17 2012-11-28 天津农科食品生物科技有限公司 Pollution-free grape fresh-keeping mat and preparation method thereof
CN104322659A (en) * 2014-09-24 2015-02-04 陈辉 Storage and preservation method for grapes
CN104686647B (en) * 2015-02-06 2018-04-03 盐城工学院 A kind of grape fresh-keeping controlled atmosphere paper

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1279021A (en) * 1999-06-30 2001-01-10 中国科学院新疆物理研究所 Quick-acting antistaling paper for grapes
CN1279022A (en) * 1999-06-30 2001-01-10 中国科学院新疆物理研究所 Long-acting antistaling tablet for grapes
CN1413475A (en) * 2001-10-22 2003-04-30 新疆大学 Long-acting antistaling agent for grape
CN1435532A (en) * 2002-02-01 2003-08-13 珠海真绿色技术有限公司 Sulfur dioxide slowly releasing fruit preserving composite paper and producing method thereof
CN1760446A (en) * 2004-10-11 2006-04-19 新疆大学 Method and equipment for producing preserving paper for grape
JP4117240B2 (en) * 2003-10-07 2008-07-16 三菱電機株式会社 Wireless mobile communication system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1279021A (en) * 1999-06-30 2001-01-10 中国科学院新疆物理研究所 Quick-acting antistaling paper for grapes
CN1279022A (en) * 1999-06-30 2001-01-10 中国科学院新疆物理研究所 Long-acting antistaling tablet for grapes
CN1413475A (en) * 2001-10-22 2003-04-30 新疆大学 Long-acting antistaling agent for grape
CN1435532A (en) * 2002-02-01 2003-08-13 珠海真绿色技术有限公司 Sulfur dioxide slowly releasing fruit preserving composite paper and producing method thereof
JP4117240B2 (en) * 2003-10-07 2008-07-16 三菱電機株式会社 Wireless mobile communication system
CN1760446A (en) * 2004-10-11 2006-04-19 新疆大学 Method and equipment for producing preserving paper for grape

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