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CN101560350B - Water-base adhesion force enhancing primer for ultraviolet light curing and production method thereof - Google Patents

Water-base adhesion force enhancing primer for ultraviolet light curing and production method thereof Download PDF

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Publication number
CN101560350B
CN101560350B CN 200810036305 CN200810036305A CN101560350B CN 101560350 B CN101560350 B CN 101560350B CN 200810036305 CN200810036305 CN 200810036305 CN 200810036305 A CN200810036305 A CN 200810036305A CN 101560350 B CN101560350 B CN 101560350B
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China
Prior art keywords
water
ultraviolet light
base resin
light polymerization
sticking power
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CN 200810036305
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Chinese (zh)
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CN101560350A (en
Inventor
伍忠岳
叶荣森
肖志军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Zhanchen Intelligent Property Management Co ltd
China Zhanchen New Materials Group Co.,Ltd.
Shanghai Zhanchen Paint Co ltd
Zhuhai Zhanchen New Material Co ltd
Original Assignee
Shanghai Fuchen Chemical Co Ltd
Beijing Zhanchen Chemical Co Ltd
Zhanchen Paint Group Co Ltd
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Priority to CN 200810036305 priority Critical patent/CN101560350B/en
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Abstract

The invention provides a water-base adhesion force enhancing primer for ultraviolet light polymerization and a production method thereof. The primer comprises the following components by the weight percent: 55-56 of water-base resin A, 35-40 of water-base resin B, 2-5 of alcoholic solvent, 1-2 of water and 0.1-0.3 of thickening agent, wherein the water-base resin A is a copolymer of styrene and acrylic ester; and the water-base resin B is a polyurethane latex or a dispersoid of polyester acrylic ester and aliphatic isocyanate. The water-base adhesion force enhancing primer for ultraviolet light polymerization has the advantages of environmental protection and less smell, can be directly diluted by water, can greatly improve the adhesion force of an ultraviolet light polymerization coating and a base material and has lower cost.

Description

The water-based sticking power that is used for ultraviolet light polymerization strengthens priming paint and working method thereof
Technical field
The present invention relates to a kind of water-based sticking power and strengthen priming paint, refer in particular to a kind of aqueous priming paint and working method thereof of improving sticking power between harder sheet material of quality and ultraviolet curable coating when being used for ultraviolet light polymerization (UV) application.
Background technology
Ultraviolet light polymerization (UV) is coated with to be contained in and has obtained development faster in recent years, especially in dull and stereotyped furniture and timber floor production, because its hardness is high, repainting hours is short, the development of production efficiency advantages of higher is rapid.But in UV application production process; The sticking power problem becomes its fast-developing resistance; Particularly when the roller coating of timber floor is produced; Owing to timber floor with the general quality of timber is very hard, the timber kapillary is less, some timber has reasons such as grease, make its sticking power when the UV application relatively poor, as draw 2 * 2mm lattice with blade; But white spotted finiss when scraping resitant coatings with blade big area release coating or with coin then (coating disengaging timber), this problem hamper the widespread use of UV lacquer in the application of floor for a long time always.Do more existing reports in aspect such as hide finishes at employing aqueous photo-curing resin; The patent No. of announcing like on February 25th, 2004 is the photo curable aqueous coating agent of CN1477168A; A kind of exactly oil polish finish that is used for timber, leather, paper, its during to woodwork coating sticking power do not have remarkable improvement.
Summary of the invention
The purpose of this invention is to provide a kind of water-based sticking power that is used for ultraviolet light polymerization and strengthen priming paint and working method thereof, to overcome the above-mentioned defective that prior art exists.
The said water-based sticking power that is used for ultraviolet light polymerization of the present invention strengthens priming paint, comprises following components in weight percentage:
Water-base resin A 55%~60%;
Water-base resin B 35%~40%
Alcoholic solvent 2%~5%;
Water 1%~2%
Thickening material 0.1%~0.3%
Said water-base resin A is a copolymer in cinnamic acrylic ester, and technical requirements is: weight contains 30~32% admittedly, pH value 7~9, and particle diameter≤0.5um can adopt the UCAR of U.S. UCAR company TMR-64;
Emulsion or dispersion-s that said water-base resin B is the water-based radiation curing; It mainly acts on is the sticking power that improves between workability and aqueous coating and solvent-borne type ultraviolet curable coating; Its staple is the polyaminoester emulsion or the dispersion-s of polyester type propenoate and aliphatic isocyanates, can adopt the UV LS2348 like BAYER company;
Said alcoholic solvent is the monohydroxy-alcohol of C2~C3, more than one in preferred alcohol, Virahol or the isopropylcarbinol;
Said thickening material is one or both in the association type polyurethane thickener, and its chemical composition is roughly association type urethane, can adopt the PUR40 of German bright icepro company;
Preferably, also comprise the skimmer of gross weight 0.1%~0.2%, the preferred polysiloxane-polyether copolymer of skimmer, the trade mark that can adopt TEGO company is the product of TEGO810;
Preferably, also comprise the base material wetting agent of gross weight 0.1%~0.2%, the preferred polysiloxane-polyether copolymerization of base material wetting agent, the trade mark that can adopt TEGO company is the product of TEGO270;
Said skimmer and base material wetting agent are polysiloxane-polyether copolymer, and still, difference wherein is that the former wetting ability is poor, and latter's wetting ability will be got well.
Preferred according to the present invention, also comprise the pH value regulator of gross weight 0.1%~0.2%, pH value regulator is a 2-amino-2-methyl-1-propanol, the trade mark of preferred U.S. Mykrolis Corp is the product of AMP-95.
Preferred according to the present invention, also comprise the fungicidal preservative of gross weight 0.1%~0.2%, major ingredient is the octyl group RH-893, like the PARMETOL N20 of German Shu Mei company.
Making method of the present invention comprises the steps:
(1) at first water-base resin A and water-base resin B are mixed, under agitation add skimmer and alcoholic solvent, dispersed with stirring then;
(2) add thickening material, base material wetting agent, fungicidal preservative, pH value regulator and water then, dispersed with stirring adds the thickening material adjustment and promptly obtains product for viscosity to 75~85KU/25 ℃.
Method of use of the present invention can be wiping, also can be roller coating.
Use when of the present invention, note following item:
1. must select for use suitable sand paper to the sheet material sanded before the construction, to obtain fine and smooth surface.
2. this aqueous priming paint must be fully dry, just can carry out the next procedure construction, otherwise the not good problem of sticking power also can occur.When adopting the construction of wiping method, generally under 25 ℃, 75% humidity, can carry out the construction of next procedure in 3 hours, low temperature below 10 ℃ with high humidity such as the condition of relative humidity more than 75% under, but proper extension time of drying; During the ultraviolet light polymerization roller coating, can suitably adjust temperature of oven and storing time.
The water-based sticking power that is used for ultraviolet light polymerization of the present invention strengthens priming paint, and following advantage is arranged: environmental protection, and very little flavor, direct dilute with water can improve the sticking power of ultraviolet curable coating and base material greatly, and cost is lower.
Embodiment
Embodiment 1
Raw-material weight per-cent is following:
Water-base resin A 60%
Water-base resin B 35%
Ethanol 3.0%
Water 1.2%
Thickening material PUR40 0.3%
Base material wetting agent TEGO270 0.2%
Skimmer TEGO810 0.1%
PH value regulator AMP-95 0.1%
Fungicidal preservative K-20 0.1%
100%
Water-base resin A is a copolymer in cinnamic acrylic ester, and weight contains 30% admittedly, pH value 7, particle diameter≤0.5um;
Water-base resin B is the polyaminoester emulsion of polyester type propenoate and aliphatic isocyanates;
Concrete making processes is: (1) adds in the cylinder dispersed with stirring with water-base resin A and water-base resin B; (2) with adding behind skimmer TEGO810 and the ethanol mixing, dispersed with stirring, and adding PUR40 were disperseed 5 minutes; (3) adding successively, TEGO270, AMP-95 and K-20 then, dispersed with stirring 5 minutes adds PUR40 adjustment viscosity and gets final product to 75KU/ ℃.
Detected result is following:
Solid content: 32% GB/T 1725-79 (second method)
Outward appearance: oyster white semi-fluid GB 1727-79
The sticking power of UV coating and base material behind this priming paint of roller coating :≤1 grade.
Embodiment 2
Raw-material weight per-cent is following:
Water-base resin A 55%
Water-base resin B 39%
The mixture of Virahol and isopropylcarbinol (1: 1, weight ratio) 4.2%
Water 1.0%
Thickening material PUR40 0.1%
Base material wetting agent TEGO270 0.1%
Skimmer TEGO810 0.2%
PH value regulator AMP-95 0.2%
Fungicidal preservative K-20 0.2%
100%。
Water-base resin A is a copolymer in cinnamic acrylic ester, and weight contains 31% admittedly, pH value 9, particle diameter≤0.5um.
The preparation method is with embodiment 1, and the adjustment viscosity gets final product to 85KU/ ℃.
Detected result is following:
Solid content: 33% GB/T 1725-79 (second method)
Outward appearance: oyster white semi-fluid GB 1727-79
The sticking power of UV coating and base material behind this priming paint of roller coating :≤1 grade.

Claims (6)

1. the water-based sticking power that is used for ultraviolet light polymerization strengthens priming paint, it is characterized in that, comprises following components in weight percentage:
Water-base resin A 55%~60%;
Water-base resin B 35%~40%
Alcoholic solvent 2%~5%;
Water 1%~2%
Thickening material 0.1%~0.3%;
Described water-base resin A is a copolymer in cinnamic acrylic ester;
Polyaminoester emulsion or dispersion-s that described water-base resin B is polyester type propenoate and aliphatic isocyanates, described alcoholic solvent are the monohydroxy-alcohol of C2~C3, and described thickening material is one or both in the association type polyurethane thickener.
2. the water-based sticking power that is used for ultraviolet light polymerization according to claim 1 strengthens priming paint, it is characterized in that also comprise the skimmer of gross weight 0.1%~0.2%, skimmer is that the trade mark is the polysiloxane-polyether copolymer of TEGO810.
3. strengthen priming paint according to each described water-based sticking power that is used for ultraviolet light polymerization of claim 1~2; It is characterized in that; The base material wetting agent that also comprises gross weight 0.1%~0.2%, base material wetting agent are that the trade mark is the polysiloxane-polyether copolymer of TEGO270.
4. strengthen priming paint according to each described water-based sticking power that is used for ultraviolet light polymerization of claim 1~2, it is characterized in that also comprise the pH value regulator of gross weight 0.1%~0.2%, pH value regulator is a 2-amino-2-methyl-1-propanol.
5. strengthen priming paint according to each described water-based sticking power that is used for ultraviolet light polymerization of claim 1~2, it is characterized in that, also comprise the fungicidal preservative of gross weight 0.1%~0.2%.
6. strengthen the preparation method of priming paint according to each described water-based sticking power that is used for ultraviolet light polymerization of claim 1~5, it is characterized in that, comprise the steps:
(1) at first water-base resin A and water-base resin B are mixed, under agitation add skimmer and alcoholic solvent, dispersed with stirring then;
(2) add thickening material, base material wetting agent, fungicidal preservative, pH value regulator and water then, dispersed with stirring adds the thickening material adjustment and promptly obtains product for viscosity to 75~85KU/25 ℃.
CN 200810036305 2008-04-18 2008-04-18 Water-base adhesion force enhancing primer for ultraviolet light curing and production method thereof Active CN101560350B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN101560350B true CN101560350B (en) 2012-09-05

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102888161B (en) * 2012-10-23 2016-08-03 上海维凯光电新材料有限公司 Environment-friendly water-based high adhesion force PET precoated shet coating composition and preparation, purposes
EP3296672A4 (en) * 2015-05-11 2018-06-20 Panasonic Intellectual Property Management Co., Ltd. Domestic electric appliance
CN109278368A (en) * 2018-07-20 2019-01-29 无锡和烁丰新材料有限公司 A kind of structure and its production technology of the blank synthetic paper of two-sided writing

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4268580A (en) * 1978-09-13 1981-05-19 Unisearch Limited Radiation cured coating for leather
CN1396220A (en) * 2001-07-13 2003-02-12 大连路明发光科技股份有限公司 Luminous water paint and its preparing process
CN1796478A (en) * 2004-12-20 2006-07-05 比亚迪股份有限公司 Coating material solidified by ultraviolet light and prepartion method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4268580A (en) * 1978-09-13 1981-05-19 Unisearch Limited Radiation cured coating for leather
CN1396220A (en) * 2001-07-13 2003-02-12 大连路明发光科技股份有限公司 Luminous water paint and its preparing process
CN1796478A (en) * 2004-12-20 2006-07-05 比亚迪股份有限公司 Coating material solidified by ultraviolet light and prepartion method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
F.Masson et al..UV-radiation curing of waterbased urethane-acrylate coatings.《PROGRESS IN ORGANIC COATINGS》.2000,第39卷115-126. *

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