CN101463216B - Foaming pigment and its production method - Google Patents
Foaming pigment and its production method Download PDFInfo
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- CN101463216B CN101463216B CN2008102181167A CN200810218116A CN101463216B CN 101463216 B CN101463216 B CN 101463216B CN 2008102181167 A CN2008102181167 A CN 2008102181167A CN 200810218116 A CN200810218116 A CN 200810218116A CN 101463216 B CN101463216 B CN 101463216B
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- Prior art keywords
- pigment
- aminomethyl
- foaming
- toner
- propenoate
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- 238000005187 foaming Methods 0.000 title claims abstract description 25
- 239000000049 pigment Substances 0.000 title claims description 50
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000000463 material Substances 0.000 claims abstract description 35
- 239000000839 emulsion Substances 0.000 claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 13
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims abstract description 9
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims abstract description 9
- ZRUPXAZUXDFLTG-UHFFFAOYSA-N 1-aminopentan-2-ol Chemical compound CCCC(O)CN ZRUPXAZUXDFLTG-UHFFFAOYSA-N 0.000 claims abstract description 8
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims abstract description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 239000004005 microsphere Substances 0.000 claims description 21
- 230000008719 thickening Effects 0.000 claims description 16
- 239000012752 auxiliary agent Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- -1 polyoxyethylene octyl phenyl ether Polymers 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000004160 Ammonium persulphate Substances 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 2
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 229920002114 octoxynol-9 Polymers 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- VWSUVZVPDQDVRT-UHFFFAOYSA-N phenylperoxybenzene Chemical compound C=1C=CC=CC=1OOC1=CC=CC=C1 VWSUVZVPDQDVRT-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 2
- 239000003973 paint Substances 0.000 abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002562 thickening agent Substances 0.000 abstract description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 2
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 229920000103 Expandable microsphere Polymers 0.000 abstract 4
- RINWGRJHXCCLOV-UHFFFAOYSA-N BPO Chemical compound BPO RINWGRJHXCCLOV-UHFFFAOYSA-N 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000005033 polyvinylidene chloride Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 13
- 239000006260 foam Substances 0.000 description 9
- 238000010422 painting Methods 0.000 description 9
- 238000007639 printing Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 230000035807 sensation Effects 0.000 description 4
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 240000001592 Amaranthus caudatus Species 0.000 description 2
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 235000012735 amaranth Nutrition 0.000 description 2
- 239000004178 amaranth Substances 0.000 description 2
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- JYNBEDVXQNFTOX-FMQUCBEESA-N lithol rubine Chemical compound OS(=O)(=O)C1=CC(C)=CC=C1\N=N\C1=C(O)C(C(O)=O)=CC2=CC=CC=C12 JYNBEDVXQNFTOX-FMQUCBEESA-N 0.000 description 2
- 235000010187 litholrubine BK Nutrition 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OALHHIHQOFIMEF-UHFFFAOYSA-N 3',6'-dihydroxy-2',4',5',7'-tetraiodo-3h-spiro[2-benzofuran-1,9'-xanthene]-3-one Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC(I)=C(O)C(I)=C1OC1=C(I)C(O)=C(I)C=C21 OALHHIHQOFIMEF-UHFFFAOYSA-N 0.000 description 1
- CGLVZFOCZLHKOH-UHFFFAOYSA-N 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo(3,2-b:3',2'-m)triphenodioxazine Chemical compound CCN1C2=CC=CC=C2C2=C1C=C1OC3=C(Cl)C4=NC(C=C5C6=CC=CC=C6N(C5=C5)CC)=C5OC4=C(Cl)C3=NC1=C2 CGLVZFOCZLHKOH-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical group ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000019219 chocolate Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000010428 oil painting Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- GMMAPXRGRVJYJY-UHFFFAOYSA-J tetrasodium 4-acetamido-5-hydroxy-6-[[7-sulfonato-4-[(4-sulfonatophenyl)diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].OC1=C2C(NC(=O)C)=CC=C(S([O-])(=O)=O)C2=CC(S([O-])(=O)=O)=C1N=NC(C1=CC(=CC=C11)S([O-])(=O)=O)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 GMMAPXRGRVJYJY-UHFFFAOYSA-J 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Developing Agents For Electrophotography (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a foaming paint for manual drawing, mainly comprising paint bottom material, expandable microspheres and toner. The paint bottom material comprises acrylic emulsion, acrylate thickener and auxiliary. The expandable microspheres are polymerized by polyvinylidene chloride, polyurethane, vinylidene chloride and acrylonitrile, or the vinylidene chloride, acrylonitrile and BPO. The diameter of the expandable microspheres is within 5-150micron. The mass part of the expandable microspheres is 2-10 parts of the foaming paint for manual drawing. The auxiliary includes: aminomethyl ethanol, aminomethyl propanol or aminomethyl butanol. After patterns are drawn on paper or canvas by the foaming paint, the drawn patterns are blown by a hair dryer or heated by an iron so that the patterns can be expanded after being heated, thereby obtaining stereoscopic patterns.
Description
Technical field
The present invention relates to a kind of pigment, particularly a kind of foaming pigment and working method thereof that is used for relief painting.
Background technology
Pigment is a kind of tinting material, is a kind of coloring matter with decoration and provide protection, except drawing, and also widespread use in industry such as printing ink, plastics, coating, rubber, pottery, papermaking.The pigment of drawing a picture usually also divides a variety of, and poster paint, watercolor, pigment, oil colour etc. are arranged, and various sole pigments all have some particular performances, to meet the requirement of application.Divide from chemistry definition, pigment generally is divided into mineral dye and pigment dyestuff again, all will add auxiliary agent when people use pigment, gives the physical and chemical performances such as tack, dispersiveness, flowability, solidified nature or froth breaking, foaming of pigment.
For the pigment of drawing, people are general, and what pursue is that the solubility property of pigment is good, and has bright-colouredly, fine and smooth, and drawing is smooth, and water resisting property is strong, draw characteristics such as dry back is colour-fast.But the diversification of Along with people's life; The picture of demand has been not limited to traditional drawings such as oil painting, watercolor, ink and wash, gouache, and people have also created some relief paintings in recent years, particularly fasten with glue on painting canvas with some fibre, plastics, stalk, stone even some metals; Received liking of the public; But, also also has certain limitation, in recent years because such painting making technology is complicated; The appearance of foam ink has had the works of relief painting in the drawing of printing.The characteristics of foam ink are that the ink marks after the printing can foam after heat treated, make the printing ink of figure line, the protruding certain altitude of trace.Contain foam material in this printing ink.The printed document heat treated, promptly the foaming protuberance becomes the relief printed matter that has that protrudes certain altitude.Foam ink has two kinds: a kind of is the microballoon foam ink, be with the high molecular polymer monomer through being processed into the hollow microsphere that is filled with low boiling point solvent, solvent gasification during heating makes microsphere diameter increase 5～30 times and protruding; Another kind is the bottom of trench foam ink, is that chloroethylene polymerization is become paste resin, whipping agent is dissolved in wherein processes printing ink, can decomposite gas after this printing ink is heated, the embossing of expanding, the seal face of formation relief.Because the foam ink stereoscopic sensation is strong, is widely used in packing and decorating, books and periodicals decoration, braille book, construction process material etc.
But in the pigment that being seen Freehandhand-drawing is drawn, for example poster paint, watercolor, pigment, oil colour are not also reported the content that adopts foaming pigment to draw a picture at present.
Summary of the invention
The purpose of this invention is to provide a kind of foaming pigment and working method thereof of handwritten drawings, have after the handwritten drawings, through heat treated, the protuberance that also can foam becomes the protrusion certain altitude, the effect that stereoscopic sensation is strong.
The foaming pigment of handwritten drawings of the present invention: it mainly comprises: pigment bed material, expended microsphere and toner are formed, and the composition and the mass fraction of described bed material are:
ACRYLIC EMULSION: 80-97 part;
Propenoate thickening material: 1-3 part;
Auxiliary agent: 0.2-1.0 part;
Described expended microsphere is with polyvinylidene dichloride, urethane, vinylidene chloride and vinyl cyanide; Or vinylidene chloride, vinyl cyanide and the polymerization of diphenyl peroxide first phthalein are formed; Said expended microsphere diameter is between the 5-150 micron; The mass fraction of expended microsphere in the foaming pigment of handwritten drawings is 2-10 part, and described auxiliary agent comprises aminomethyl ethanol, aminomethyl propanol or aminomethyl butanols.
Described toner comprises that the fine arts are red, lithol rubine, permanent bordeaux FGR, permanent yellow 5GX, Fast Yellow 10G, forever solid orange, phthalocyanine blue, phthalocyanine green, permanent violet, fluorescein, fluorescent yellow, fluorescent blue, fluorescence green, fluorescence is pink or fluorescence is purple; Or lemon yellow, Sunset yellow, famille rose, light blue, amaranth, tetraiodofluorescein, greyish purple, brilliant black, chocolate brown, light green, antholeucin, amaranth, carbon black, titanium oxide (titanium white), phthalein viridescent, phthalocyanine blue, medium chrome yellow medium yellow, red iron oxide, can also be inorganic or pigment dyestuffs such as ability production metallic color, pearly-lustre look, luminous color.Toner approximately is 0.5-5 part at the mass fraction of the foaming pigment of handwritten drawings, but in fact general according to the depth of required color, deep or light decision.
Above-described ACRYLIC EMULSION is water miscible chemical substance, and it has good physics-chem characteristic, can most of organic volatile solvent be replaced water, reduces topsoil significantly thereby reach.And ACRYLIC EMULSION to be added to pigment postadhesion power strong, have the light of guarantor, protect excellent properties such as look, have ornamental preferably.What at present, be used for the water-borne coatings film forming matter has aqueous alkide resin, aminoresin, resol, vibrin, epoxy resin, a vinyl resin etc.Stability is high, glossiness is good because water-borne acrylic resin has, rheological property and the good advantage of surface adsorption performance; Therefore with ACRYLIC EMULSION as pigment bed material of the present invention; Can improve the water-soluble and mobile of pigment; It is even to adhere to painting canvas at the process water colour of drawing a picture, and the distribution of expended microsphere is also very even.
Above-described propenoate thickening material is to adopt ethyl propenoate and methylacrylic acid to make initiator at ammonium persulphate; Sodium lauryl sulphate is made emulsifying agent; Phthalic acid two propylene esters or polyoxyethylene octyl phenyl ether are done to process under the condition of linking agent; Preparing method's existing introduction in document (seen " the journal .2007 of Shenyang Univ. of Science and Engineering, 26 (3) .-73-76 " " synthetic and performance study of polyacrylate-type thickeners ", Xu Shujiao; Mu Rui; Deng Aimin); This type thickening material has that oneself viscosity is low, thickening capabilities is strong, good stability, be difficult for characteristics such as mildew; Be widely used in water-based paint at present abroad, but do not seen that the bed material that is used for pigment, the present invention add Acrylate Emulsion Thickener and can guarantee that expended microsphere is stable in the bed material of foaming pigment; After finishing, rough sketch can not trickle by pigment, and not mouldy.
The effect of above-described aminomethyl ethanol (trade(brand)name APM 95), aminomethyl propanol or aminomethyl butanols auxiliary agent is: 1, reduce dispersant dosage, and reduce foam, improve dispersion efficiency; 2, optimize the colo(u)rant dispersion effect, improve the stability that contains reactive pigment (like ZnO) system, 3, effectively control pH value; Reduce formulation cost, 4, promote the thickening material performance, reduce the thickening material consumption; Reduce the pigment smell, improve mill base color developing 5, help improving the not xanthochromia property of pigment, improve washable wiping property and water tolerance; Help improving gloss, 6, make the anti-storage of pigment, the time with iron flask dress pigment; Corrosion be can reduce in the jar and the increase of the volatile organic component (VOC) that do not cause system of getting rusty, its performance and cost advantage in the low cost prescription, more shown.
The working method of foaming pigment product of the present invention is: with ACRYLIC EMULSION, propenoate thickening material, auxiliary agent aminomethyl ethanol, aminomethyl propanol or the aminomethyl butanols of above-mentioned mass fraction, add the proper amount of clear water dissolving earlier, toner is water or alcohol dissolving separately also; According to the mixed of bed material and toner, add expended microsphere more then, mix and adding enough water; The amount that adds water is generally according to the moist colours concentration on the market; Water cut is about 50-80%, and last tinning obtains product.
Outstanding substantive distinguishing features of the present invention and obvious improvement are:
1, the foaming pigment product has after the handwritten drawings, and through heat treated, also foaming is swelled; Become the protrusion certain altitude, effect that stereoscopic sensation is strong, its uses extremely simple and convenient; Can pigment directly be drawn a picture after opening jar, also can dilute and draw a picture with suitable quantity of water, when we with foaming pigment after paper or painting canvas are painted out pattern; With the pattern that air duct blows or the flatiron heating is painted, promptly inflatable after the pattern heating, obtain the spatial pattern; Heating can be foamed, and becomes 3D effect.
2, the foaming pigment product is a kind of in the pigment, has increased gorgeous brilliance to life, and it is specially adapted to children and makes use by hand, is a kind of security pigment product.The artist can enough the foaming pigment abundant colors world that landscape painting, cartoon, figure painting wait to express them of drawing, suitably heating finishing after, expended microsphere shows out stereoscopic sensation intensive 3D effect picture especially.
Embodiment
Embodiment 1
With 80 kilograms ACRYLIC EMULSION, 2 kilograms propenoate thickening material, 0.3 kilogram auxiliary agent aminomethyl ethanol; Add 30 kilograms of clear water dissolvings earlier, toner permanent bordeaux FGR dissolves with 1 liter of 70% (volume) alcohol separately for 2 kilograms, then bed material and toner is mixed; Add 3 kilograms of expended microspheres again; Mix and add 50 kg of water, last tinning obtains product.
Embodiment 2
With 95 kilograms ACRYLIC EMULSION, 2.5 kilograms propenoate thickening material, 0.3 kilogram auxiliary agent aminomethyl propanol; Add the proper amount of clear water dissolving earlier, the toner fluorescent blue is dissolved with 2 liter of 70% (volume) alcohol separately for 4 kilograms, then bed material and toner is mixed; Add 10 kilograms of expended microspheres again; Mix and add 80 kg of water, last tinning obtains product.
Embodiment 3
With 90 kilograms ACRYLIC EMULSION, 2.5 kilograms propenoate thickening material, 0.5 kilogram auxiliary agent aminomethyl butanols; Add the proper amount of clear water dissolving earlier, the toner phthalein also dissolves with 10 kg of water separately for dark green 8 kilograms, then bed material and toner is mixed; Add 5 kilograms of expended microspheres again; Mix and add 40 kg of water, last tinning obtains product.
Embodiment 4
With 85 kilograms ACRYLIC EMULSION, 2.5 kilograms propenoate thickening material, 0.8 kilogram auxiliary agent aminomethyl propanol or aminomethyl butanols; Add the proper amount of clear water dissolving earlier, toner permanent yellow 5GX also dissolves with 10 kg of water separately for 6 kilograms, then bed material and toner is mixed; Add 4 kilograms of expended microspheres again; Mix and add 60 kg of water, last tinning obtains product.
Embodiment 5
With 97 kilograms ACRYLIC EMULSION, 2.5 kilograms propenoate thickening material, 0.2 kilogram auxiliary agent aminomethyl ethanol and 0.2 kilogram aminomethyl propanol; Add the proper amount of clear water dissolving earlier, toner fluorescence dissolves with 2 liter of 70% (volume) alcohol separately for purple 3 kilograms, then bed material and toner is mixed; Add 10 kilograms of expended microspheres again, mix and add 100 kg of water, then bed material and toner are mixed; Last tinning obtains product.
Embodiment 6
With 88 kilograms ACRYLIC EMULSION, 2.5 kilograms propenoate thickening material, 1.0 kilograms auxiliary agent aminomethyl ethanol; Add the proper amount of clear water dissolving earlier, the toner lithol rubine is also used 10 kg of water or 2 liter of 70% (volume) alcohol dissolving for 6 kilograms, then bed material and toner is mixed; Add 8 kilograms of expended microspheres again; Mix and adding enough water, last tinning obtains product.
Claims (4)
1. the foaming pigment of handwritten drawings, it is characterized in that: it mainly comprises: pigment bed material, expended microsphere and toner are formed, and the composition and the mass fraction of described bed material are:
ACRYLIC EMULSION: 80-97 part;
Propenoate thickening material: 1-3 part;
Auxiliary agent: 0.2-1.0 part;
Described expended microsphere is with polyvinylidene dichloride, urethane, vinylidene chloride and vinyl cyanide; Or vinylidene chloride, vinyl cyanide and diphenyl peroxide first phthalein are polymerized; Said expended microsphere diameter is between the 5-150 micron, and the mass fraction of expended microsphere in the foaming pigment of handwritten drawings is 2-10 part;
Described auxiliary agent comprises aminomethyl ethanol, aminomethyl propanol or aminomethyl butanols.
2. foaming pigment according to claim 1; It is characterized in that: described propenoate thickening material is to adopt ethyl propenoate and methylacrylic acid to make initiator at ammonium persulphate; Sodium lauryl sulphate is made emulsifying agent, and phthalic acid two propylene esters or polyoxyethylene octyl phenyl ether are done to process under the condition of linking agent.
3. foaming pigment according to claim 1 is characterized in that: described toner comprises mineral dye, pigment dyestuff or high-visibility pigment.
4. the working method of foaming pigment as claimed in claim 1 is characterized in that: with 80-97 mass parts ACRYLIC EMULSION, 1-3 mass parts propenoate thickening material, 0.2-1.0 mass parts auxiliary agent aminomethyl ethanol, aminomethyl propanol or aminomethyl butanols, add the clear water dissolving earlier; Toner is water or alcohol dissolving separately also; According to the mixed of bed material and toner, add 2-10 mass parts expended microsphere more then, mix and adding enough water; Last tinning obtains product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102181167A CN101463216B (en) | 2008-12-05 | 2008-12-05 | Foaming pigment and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102181167A CN101463216B (en) | 2008-12-05 | 2008-12-05 | Foaming pigment and its production method |
Publications (2)
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| CN101962916B (en) * | 2010-09-30 | 2012-07-25 | 深圳云之彩美术工艺用品有限公司 | Cloth color pigment and application thereof |
| CN103835154A (en) * | 2012-11-20 | 2014-06-04 | 江南大学 | Fabric manually painted with multicolor coating foam |
| CN104073053A (en) * | 2014-06-15 | 2014-10-01 | 安徽奥邦新材料有限公司 | Novel orange antirust composite pigment and preparation method thereof |
| CN104073063A (en) * | 2014-06-15 | 2014-10-01 | 安徽奥邦新材料有限公司 | Composite vermilion antirust pigment and preparation method thereof |
| CN108239423A (en) * | 2016-12-26 | 2018-07-03 | 江苏格罗瑞化学有限公司 | A kind of enhanced pigment formula of chemical industry brightness and production method |
| CN109703009A (en) * | 2019-02-28 | 2019-05-03 | 陕西科技大学 | A kind of method of 3D printing braille |
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