CN101406189B - Aqueous emulsion containing chlorfenapyr and preparation method thereof - Google Patents
Aqueous emulsion containing chlorfenapyr and preparation method thereof Download PDFInfo
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- CN101406189B CN101406189B CN2008100738462A CN200810073846A CN101406189B CN 101406189 B CN101406189 B CN 101406189B CN 2008100738462 A CN2008100738462 A CN 2008100738462A CN 200810073846 A CN200810073846 A CN 200810073846A CN 101406189 B CN101406189 B CN 101406189B
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Abstract
The invention relates to a water emulsion containing chlorfenapyr and a method for preparing the same. The pesticidal active ingredients of the water emulsion are formed by compounding chlorfenapyr or the chlorfenapyr and one of the pesticidal active ingredients such as bifenthrin, chlorpyrifos, nitenpyram and the like; and other components of the water emulsion comprise a solvent, an emulsifier, a penetrating agent, a synergist, an antifreeze, a defoamer, water and the like. The water emulsion uses a large amount of water to substitute organic solvents, and has low cost and good environmental compatibility.
Description
Technical field
The present invention relates to a kind of agricultural chemicals, particularly a kind of aqueous emulsion that contains capillary and preparation method thereof.
Background technology
Capillary, English name chlorfenapyr, molecular formula C
15H
11BrClF
3N
2O, chemical name 4-bromo-2-(4-chlorphenyl)-1-(ethoxyl methyl)-5-(trifluoromethyl) pyrroles-3-nitrile has another name called and eliminates, and being American Cyanamid Company found and the fragrant pyroles insecticidal/acaricidal agent of exploitation in the later stage eighties.This agricultural chemicals is to be able to successfully develop through the chemical constitution transformation to natural antibiotics.
This compound is a kind of preinsecticide; Itself insect there is not the poisoning effect; After its mechanism of action is insect's food-taking or contact capillary; In insect bodies, change the tool insecticidal active compound into, act on target polypide intracellular plastochondria then, destroy the physiology course that oxidative phosphorylation ADP is transformed into ATP through mixed-functional oxidase.ATP is the chemical energy that cell earns a bare living, and can not produce ATP, and cell just stops vital functions, finally causes insect dead.Used most of pesticide species on this mechanism of action and the market, all different like organic phosphor, pyrethroid, AVM etc.Therefore, this agricultural chemicals can be prevented and treated the insect that these agricultural chemicals is produced resistance, perhaps delays the generation of pest resistance to insecticide with these agriculture chemical compoundings.Through the developmental research in more than 20 years, capillary many countries and regions worldwide were able to successfully develop and come into the market.Its high-efficiency broad spectrum, characteristic of wide insecticidal spectrum, especially the excellent preventive effect to difficult pest controls such as diamond-back moth, beet armyworms receives the market favor.
The formulation that capillary is registered in the market mainly contains three kinds of missible oil, microemulsion, suspending agent, and not seeing has the aqueous emulsion registration, does not also see the report of capillary and the composite aqueous emulsion of other former medicine components.
Summary of the invention
The objective of the invention is to provide in order to overcome the defective that above-mentioned prior art exists a kind of safe in utilization, the feature of environmental protection good, improve drug effect, enlarges insecticidal spectrum, the lower-cost capillary aqueous emulsion and preparation method thereof that contains.
In order to solve the problems of the technologies described above; The present invention realizes through following technical scheme: the insecticidal active ingredient of this aqueous emulsion is by a kind of composite the forming among capillary or capillary and the X; Wherein X is Biphenthrin, chlopyrifos or Nitenpyram etc.; Mass ratio is in capillary and the composite aqueous emulsion of other several kinds of components: capillary/X=0.1-99.9/99.9-0.1, and wherein, the capillary mass percent is 1%～30%; Also add solvent, emulsifier, bleeding agent, synergist, thickener, antifreezing agent or antifoaming agent and water in the aqueous emulsion.
Its constituent content (in the aqueous emulsion weight portion): 1～30 part of capillary, 0～30 part of Biphenthrin, 0～40 part of chlopyrifos, 0～30 part of Nitenpyram, 3～30 parts of solvents, 3～15 parts of emulsifier, 0～5 part of thickener, 0～10 part of bleeding agent, 0～20 part of synergist, 0～5 part of stabilizing agent, 0～5 part of antifreezing agent, 0～1 part of antifoaming agent, water is supplied 100 parts.
Capillary and Biphenthrin mass ratio are 30:1-0.03:1.
The mass ratio of capillary and chlopyrifos is 4:1-0.025:1.
The mass ratio of capillary and Nitenpyram is 30:1-0.03:1.
Described solvent is selected from one or more mixture of methyl alcohol, xylol, cyclohexanone, ethyl acetate, carbon 9 aromatic hydrocarbons or methyl naphthalene.
Described emulsifier is selected from one or more the mixture in AEO, APES, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, APES phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, the calcium dodecyl benzene sulfonate.
Said bleeding agent is selected from azone, thiophene ketone, organosilicon, oozes among T or the JFC one or both soon; Synergist is selected from one or both in Butacide or the synergy phosphorus.
Said thickener is selected in xanthans, gelatin, cyclodextrin, polyvinyl alcohol, cellulose and derivative thereof or the modified starch water-soluble high-molecular substance one or both for use; Described antifreezing agent is selected from one or both the mixture in ethylene glycol, the glycerine; Antifoaming agent is an organosilicon.
The preparation method who contains the capillary aqueous emulsion comprises following processing step: (annotate: the consumption of following each component is all counted by weight)
(1) makes oil phase
1～30 part of capillary or add for 3～30 parts with solvent with 0～40 part of 0～30 part of Biphenthrin, chlopyrifos is in the same place, and stirs it is dissolved fully; Add 3～15 parts of emulsifier, 0～10 part of bleeding agent, 0～20 part of synergist again, stir into even oil phase.
(2) make water
0～30 part of Nitenpyram, 0～5 part of thickener, 0～5 part of stabilizing agent, 0～5 part of antifreezing agent, 0～1 part of antifoaming agent and water are complemented to 100 parts be added in and be mixed together, stir into the homogeneous water.
(3) emulsification pretreatment
Under high-speed stirred, oil phase is added aqueous phase, form finely disseminated emulsion liquid, promptly get aqueous emulsion.Speed of agitator is 1000～5000 rev/mins, and mixing time is 30～60 minutes.
Aqueous emulsion of the present invention is owing to contain or only contain a small amount of organic solvent, thus can avoid producing with transporting procedures in inflammable and explosive phenomenon.This formulation does not have unpleasant poisonous smell, and is little to eye irritation, reduced the pollution to environment, improved the safety to production, storing and user greatly.In addition, aqueous emulsion is a matrix with the water of a large amount of cheapnesss, substitutes organic solvent; The emulsifier consumption is 3%～15%, and cost is low, and Environmental compatibility is good; Though increased auxiliary agents such as some antifreezing agents, stabilizing agent; But along with the raising of International Crude Oil, the solvent price climbs up and up, and makes aqueous emulsion on cost, than corresponding missible oil bigger advantage arranged.Because with an organic solvent minimizing, the pressure of environment is diminished, the toxicity of warm blooded animal is reduced, make that the toxicity to non-target organism reduces.Capillary is processed into aqueous emulsion and is re-dubbed aqueous emulsion with organic phosphates, chrysanthemum ester class, nicotinoids, can improve drug effect, enlarge insecticidal spectrum, delay the development of pest resistance to insecticide, reduce cost, reduce environmental pollution, therefore have the wide development application prospect.
Description of drawings
Fig. 1 is the process chart of aqueous emulsion of the present invention.
Embodiment
Embodiment 1:
With the finished product aqueous emulsion is that weight 100kg calculates.10kg capillary (folding hundred) is used the 10kg cyclohexanone solvent; After stirring dissolving in 10 minutes at normal temperatures; Add emulsifier 5kg APES phosphate, 1kg calcium dodecyl benzene sulfonate, 3kg ethylene glycol antifreeze, 0.05kg antifoaming agent, water complements to 100kg, after mixing; Become the milky opaque liquid after 0.5 hour with the high-shear emulsion machine shearing again, promptly get 10% capillary aqueous emulsion.
The preparation method:
A. in container with electronic stirring, add in the former medicine of capillary and the organic solvent cyclohexanone, start and be stirred to till the capillary dissolving, by above-mentioned prescription adding emulsifier, stir into even oil phase again.Subsequent use as oil phase.
B. in the mixing kettle of band high speed shear, antifreezing agent, antifoaming agent under agitation are added to the water successively, till being dissolved into uniform liquid fully, subsequent use as water.
C. start high-speed shearing machine, oil phase add aqueous phase, be controlled at 1000～5000 rev/mins, stirred 30 minutes at rotating speed, White-opalescent shape liquid, be 10% capillary aqueous emulsion.
Embodiment 2:
With the finished product aqueous emulsion is that weight 100kg calculates.5kg capillary (folding hundred), 10kg Biphenthrin (folding hundred) are used the 15kg xylene solvent; After stirring dissolving in 0.5 hour at normal temperatures; Add emulsifier 4kg APES phosphate, 2kg aliphatic alcohol polyoxyvinethene phosphate, 3kg ethylene glycol antifreeze, 0.1kg antifoaming agent and water and complement to 100kg; Stir after 0.5 hour, become the milky opaque liquid after 0.5 hour, promptly get 15% capillary Biphenthrin emulsion in water through the high-shear emulsion machine shearing.
The preparation method:
A. former medicine of capillary and the former medicine of Biphenthrin are joined in the organic solvent xylol; Constantly stir, till dissolving fully, add emulsifier APES phosphate, aliphatic alcohol polyoxyvinethene phosphate again; Be stirred to and mix, subsequent use as oil phase.
B. in the mixing kettle of band high speed shear, antifreezing agent, antifoaming agent under agitation are added to the water successively, till being dissolved into uniform liquid fully, subsequent use as water.
C. start high-speed shearing machine, oil phase added aqueous phase, be controlled at 1000～5000 rev/mins, stirred 30 minutes at rotating speed, White-opalescent shape liquid, be 15% capillary Biphenthrin emulsion in water.
Embodiment 3:
With the finished product aqueous emulsion is that weight 100kg calculates.With 5kg capillary (folding hundred), 20kg chlopyrifos (folding hundred) with 10kg xylol and 6kg cyclohexanone solvent; After stirring dissolving in 0.5 hour at normal temperatures; Add emulsifier 4kg APES phosphate, 3kg alkylaryl polyoxyethylene polyoxypropylene ether, 1kg calcium dodecyl benzene sulfonate, 3kg ethylene glycol antifreeze, 0.05kg antifoaming agent, water again and complement to 100kg; After mixing; Become the milky opaque liquid after 1 hour through the high-shear emulsion machine shearing, promptly get the disinsection aqueous emulsion of 25% capillary chlopyrifos.
The preparation method:
A. former medicine of capillary and the former medicine of chlopyrifos are joined in the organic solvent xylol; Constantly stir; Till capillary, chlopyrifos dissolving; Add emulsifier APES phosphate, alkylaryl polyoxyethylene polyoxypropylene ether, calcium dodecyl benzene sulfonate again, be stirred to and mix, subsequent use as oil phase.
B. by above-mentioned prescription antifreezing agent, antifoaming agent under agitation are added to the water successively, constantly stir, till being dissolved into uniform liquid fully, subsequent use as water.
C. start high-speed shearing machine earlier, oil phase added aqueous phase, be controlled at 1000～5000 rev/mins, stirred 60 minutes at rotating speed, White-opalescent shape liquid, be 25% capillary chlorpyrifos aqueous emulsion.
Embodiment 4:
With the finished product aqueous emulsion is that weight 100kg calculates.10kg capillary (folding hundred) is used the 10kg xylene solvent; After normal stirring and dissolving down; Add emulsifier 5kg APES phosphate, 2kg aliphatic alcohol polyoxyvinethene phosphate, 10kg Nitenpyram (folding hundred), 3kg glycerine antifreezing agent, 0.05kg antifoaming agent and water again and complement to 100kg; After mixing, become the milky opaque liquid after 0.5 hour, promptly get the disinsection aqueous emulsion of 20% capillary Nitenpyram through the high-shear emulsion machine shearing.
The preparation method:
A. the former medicine of the former medicine of capillary is joined in the organic solvent xylol, constantly stirring till the capillary dissolving, adds emulsifier APES phosphate, aliphatic alcohol polyoxyvinethene phosphate again, is stirred to mix, and is subsequent use as oil phase.
B. by above-mentioned prescription Nitenpyram, antifreezing agent, antifoaming agent under agitation are added to the water successively, constantly stir, till being dissolved into uniform liquid fully, subsequent use as water.
C. start high-speed shearing machine earlier, oil phase added aqueous phase, be controlled at 1000～5000 rev/mins, stirred 30 minutes at rotating speed, White-opalescent shape liquid, be 20% capillary Nitenpyram aqueous emulsion.
Embodiment 5:
With finished product aqueous emulsion weight is that 100kg calculates; After 5kg capillary (folding hundred), 20kg chlopyrifos (folding hundred) dissolved with 10kg xylol and 6kg cyclohexanone solvent; Add emulsifier 4kg APES phosphate, 3kg alkylaryl polyoxyethylene polyoxypropylene ether, 1kg calcium dodecyl benzene sulfonate, 3kg ethylene glycol antifreeze, 0.05kg antifoaming agent, water again and complement to 100kg; After mixing; Become the milky opaque liquid after 1 hour through the high-shear emulsion machine shearing, promptly get 25% capillary chlorpyrifos aqueous emulsion.
The preparation method:
A. former medicine of capillary and the former medicine of chlopyrifos are joined in organic solvent xylol and the cyclohexanone; Constantly stir; Dissolve fully until capillary, chlopyrifos; Add emulsifier APES phosphate, alkylaryl polyoxyethylene polyoxypropylene ether, calcium dodecyl benzene sulfonate again, be stirred to and mix, subsequent use as oil phase.
B. by above-mentioned prescription antifreezing agent, antifoaming agent under agitation are added to the water successively, constantly stir, till being dissolved into uniform liquid fully, subsequent use as water.
C. start high-speed shearing machine, oil phase is added aqueous phase, rotating speed is controlled at 1000～5000 rev/mins, stirs 60 minutes, gets the opaque shape liquid of milky, is 25% capillary chlorpyrifos aqueous emulsion.
Embodiment 6:
With finished product aqueous emulsion weight is that 100kg calculates; With 10kg capillary (folding hundred) with after the 10kg xylene soluble; Add emulsifier 5kg APES phosphate, 2kg aliphatic alcohol polyoxyvinethene phosphate, 10kg Nitenpyram (folding hundred), 3kg glycerine antifreezing agent, 0.05kg antifoaming agent and water again and complement to 100kg; After mixing, become the milky opaque liquid after 0.5 hour, promptly get 20% capillary Nitenpyram aqueous emulsion through the high-shear emulsion machine shearing.
The preparation method:
A. the former medicine of capillary is joined in the organic solvent xylol, constantly stirring till the capillary dissolving, adds emulsifier APES phosphate, aliphatic alcohol polyoxyvinethene phosphate again, is stirred to mix, and is subsequent use as oil phase.
B. by above-mentioned prescription Nitenpyram, antifreezing agent, antifoaming agent under agitation are added to the water successively, constantly stir, till being dissolved into uniform liquid fully, subsequent use as water.
C. start high-speed shearing machine, oil phase is added aqueous phase, rotating speed is controlled at 1000～5000 rev/mins, stirs 30 minutes, gets the opaque shape liquid of milky, is 20% capillary Nitenpyram aqueous emulsion.
Embodiment 7:
10% capillary aqueous emulsion and 10% capillary missible oil are to the comparison of diamond-back moth control efficiency.
For clear and definite 10% capillary aqueous emulsion and the 10% capillary missible oil control efficiency to diamond-back moth, the applicant had carried out drug effect test of field zone in 2007.District's group arrangement is at random adopted in the field efficacy experiment, adopts the knapsack sprayer spraying, and every processing triplicate is respectively at handling back 1 day, 3 days, 7 days investigation experimental results.According to the computes control efficiency.
Control efficiency (%)=[1-(T
a* C
b)/(T
b* C
a)] * 100
T
a: insect population quantity after the treatment region dispenser
T
b: insect population quantity before the treatment region dispenser
C
a: insect population quantity after the dispenser of check plot
C
b: insect population quantity before the dispenser of check plot
Supply the reagent agent:
Handle 1000 times of dilutions of 1:10% capillary aqueous emulsion
Handle 1000 times of dilutions of 2:10% capillary missible oil
Handle 3: blank
Experimental result is seen table 1
The effect of table 1 different disposal control diamond-back moth
Can know that by table 1 10% capillary aqueous emulsion is suitable to the control efficiency of diamond-back moth with 1000 times of dilutions of 10% capillary missible oil.Behind the medicine 72 hours, 10% capillary aqueous emulsion and 1000 times of dilution preventive effects of 10% capillary missible oil were respectively 82.92% and 83.24%.Because aqueous emulsion replaces the organic solvent in the missible oil with a large amount of water, the pressure to environment when practicing thrift cost also will reduce greatly.
Embodiment 8:
10% capillary aqueous emulsion and 10% capillary missible oil are to the comparison of beet armyworm control efficiency.
For clear and definite 10% capillary aqueous emulsion and the 10% capillary missible oil control efficiency to beet armyworm, the applicant had carried out drug effect test of field zone in 2007.District's group arrangement is at random adopted in the field efficacy experiment, adopts the knapsack sprayer spraying, and every processing triplicate is respectively at handling back 1 day, 3 days, 7 days investigation experimental results.According to the computes control efficiency.
Control efficiency (%)=[1-(T
a* C
b)/(T
b* C
a)] * 100
T
a: insect population quantity after the treatment region dispenser
T
b: insect population quantity before the treatment region dispenser
C
a: insect population quantity after the dispenser of check plot
C
b: insect population quantity before the dispenser of check plot
Supply the reagent agent:
Handle 1000 times of dilutions of 1:10% capillary aqueous emulsion
Handle 1000 times of dilutions of 2:10% capillary missible oil
Handle 3: blank
Experimental result is seen table 2
The effect of table 2 different disposal control beet armyworm
Can know that by table 2 10% capillary aqueous emulsion is suitable to the control efficiency of beet armyworm with 1000 times of dilutions of 10% capillary missible oil.Behind the medicine 72 hours, 10% capillary aqueous emulsion and 1000 times of dilution preventive effects of 10% capillary missible oil were respectively 86.10% and 86.00%.
Embodiment 9:
15% capillary Biphenthrin emulsion in water and 15% capillary Biphenthrin missible oil are to the comparison of beet armyworm control efficiency.
For clear and definite 15% capillary Biphenthrin emulsion in water and the 15% capillary Biphenthrin missible oil control efficiency to beet armyworm, the applicant had carried out drug effect test of field zone in 2007.District's group arrangement is at random adopted in the field efficacy experiment, adopts the knapsack sprayer spraying, and every processing triplicate is respectively at handling back 1 day, 3 days, 7 days investigation experimental results.According to the computes control efficiency.
Control efficiency (%)=[1-(T
a* C
b)/(T
b* C
a)] * 100
T
a: insect population quantity after the treatment region dispenser
T
b: insect population quantity before the treatment region dispenser
C
a: insect population quantity after the dispenser of check plot
C
b: insect population quantity before the dispenser of check plot
Supply the reagent agent:
Handle 1000 times of dilutions of 1:15% capillary Biphenthrin emulsion in water
Handle 1000 times of dilutions of 2:15% capillary Biphenthrin missible oil
Handle 3: blank
Experimental result is seen table 3
The effect of table 3 different disposal control beet armyworm
Can know that by table 3 15% capillary Biphenthrin emulsion in water is suitable to the control efficiency of beet armyworm with 1000 times of dilutions of 15% capillary Biphenthrin missible oil.Behind the medicine 72 hours, 15% capillary Biphenthrin emulsion in water and 1000 times of dilution preventive effects of 15% capillary Biphenthrin missible oil were respectively 87.66% and 88.47%.Owing in aqueous emulsion, replace the organic solvent in the missible oil with a large amount of water, the pressure to environment when practicing thrift cost also will reduce greatly.
Embodiment 10:
25% capillary chlorpyrifos aqueous emulsion and 25% capillary chlorpyrifos ec are to the comparison of prodenia litura control efficiency
For clear and definite 25% capillary chlorpyrifos aqueous emulsion and the 25% capillary chlorpyrifos ec control efficiency to prodenia litura, the applicant had carried out drug effect test of field zone in 2007.District's group arrangement is at random adopted in the field efficacy experiment, adopts the knapsack sprayer spraying, and every processing triplicate is respectively at handling back 1 day, 3 days, 7 days investigation experimental results.According to the computes control efficiency.
Control efficiency (%)=[1-(T
a* C
b)/(T
b* C
a)] * 100
T
a: insect population quantity after the treatment region dispenser
T
b: insect population quantity before the treatment region dispenser
C
a: insect population quantity after the dispenser of check plot
C
b: insect population quantity before the dispenser of check plot
Supply the reagent agent:
Handle 1000 times of dilutions of 1:25% capillary chlorpyrifos aqueous emulsion
Handle 1000 times of dilutions of 2:25% capillary chlorpyrifos ec
Handle 3: blank
Experimental result is seen table 4
The effect of table 4 different disposal control prodenia litura
Can know that by table 4 25% capillary chlorpyrifos aqueous emulsion is suitable to the control efficiency of prodenia litura with 1000 times of dilutions of 25% capillary chlorpyrifos ec.Behind the medicine 72 hours, 25% capillary chlorpyrifos aqueous emulsion and 1000 times of dilution preventive effects of 25% capillary chlorpyrifos ec were respectively 85.35% and 86.36%.
Embodiment 11:
20% capillary Nitenpyram aqueous emulsion and 20% capillary Nitenpyram missible oil are to the comparison of tobacco aphid control efficiency
For clear and definite 20% capillary Nitenpyram aqueous emulsion and the 20% capillary Nitenpyram missible oil control efficiency to tobacco aphid, the applicant had carried out drug effect test of field zone in 2007.District's group arrangement is at random adopted in the field efficacy experiment, adopts the knapsack sprayer spraying, and every processing triplicate is respectively at handling back 1 day, 3 days, 7 days investigation experimental results.According to the computes control efficiency.
Control efficiency (%)=[1-(T
a* C
b)/(T
b* C
a)] * 100
T
a: insect population quantity after the treatment region dispenser
T
b: insect population quantity before the treatment region dispenser
C
a: insect population quantity after the dispenser of check plot
C
b: insect population quantity before the dispenser of check plot
Supply the reagent agent:
Handle 1500 times of dilutions of 1:20% capillary Nitenpyram aqueous emulsion
Handle 1500 times of dilutions of 2:20% capillary Nitenpyram missible oil
Handle 3: blank
Experimental result is seen table 5
The effect of table 5 different disposal control tobacco aphid
Can know that by table 5 20% capillary Nitenpyram aqueous emulsion is suitable to the control efficiency of tobacco aphid with 1500 times of dilutions of 20% capillary Nitenpyram missible oil.Behind the medicine 72 hours, 20% capillary Nitenpyram aqueous emulsion and 1500 times of dilution preventive effects of 20% capillary Nitenpyram missible oil were respectively 94.64% and 93.69%.Owing in aqueous emulsion, replace the organic solvent in the missible oil with a large amount of water, the pressure to environment when practicing thrift cost also will reduce greatly.
Claims (3)
1. aqueous emulsion that contains capillary is characterized in that: the insecticidal active ingredient of this aqueous emulsion is by capillary and Nitenpyram is composite forms, and the mass percent of capillary is 1%～30%; The component content of aqueous emulsion is counted with the aqueous emulsion weight portion: 0～1 part of 1～30 part of capillary, 0～30 part of Nitenpyram, 3～30 parts of solvents, 3～15 parts of emulsifier, 0～5 part of thickener, 0～10 part of bleeding agent, 0～20 part of synergist, 0～5 part of stabilizing agent, 0～5 part of antifreezing agent and antifoaming agent, and water is supplied 100 parts; Wherein the mass ratio of capillary and Nitenpyram is 30: 1～0.03: 1; Wherein said solvent is selected from one or more mixture of methyl alcohol, xylol, cyclohexanone, ethyl acetate, carbon 9 aromatic hydrocarbons or methyl naphthalene; Described emulsifier is selected from one or more the mixture in AEO, APES, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, APES phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, the calcium dodecyl benzene sulfonate.
2. the aqueous emulsion that contains capillary according to claim 1 is characterized in that: said bleeding agent is selected from one or both among azone, thiophene ketone, organosilicon, fast penetrant T or the JFC; Synergist is selected from one or both in Butacide or the synergy phosphorus.
3. the aqueous emulsion that contains capillary according to claim 1 is characterized in that: said thickener is selected in xanthans, gelatin, cyclodextrin, polyvinyl alcohol, cellulose and derivative thereof or the modified starch water-soluble high-molecular substance one or both for use; Described antifreezing agent is selected from one or both the mixture in ethylene glycol, the glycerine; Antifoaming agent is an organosilicon.
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102388907A (en) * | 2011-10-19 | 2012-03-28 | 广东中迅农科股份有限公司 | Pesticide composition containing chlorfenapyr and bifenthrin |
| CN103004857B (en) * | 2012-12-24 | 2016-01-06 | 海利尔药业集团股份有限公司 | A kind of Pesticidal combination containing Biphenthrin and chlorfenapyr |
| CN105076185B (en) * | 2015-08-21 | 2017-04-05 | 山东农业大学 | The Pesticidal combination and its preparation and application of a kind of capillary and anabasine insecticide |
| CN109526969A (en) * | 2018-11-21 | 2019-03-29 | 江苏钟山化工有限公司 | A kind of high-content capillary aqueous emulsion and preparation method thereof |
| CN112715539B (en) * | 2021-01-28 | 2022-06-17 | 菲吉乐科(南京)生物科技有限公司 | Auxiliary penetrating agent suitable for bacteriophage to penetrate into tuber crops and preparation method and application thereof |
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