CN101338081B - Dispersed deep blue dye composition - Google Patents
Dispersed deep blue dye composition Download PDFInfo
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- CN101338081B CN101338081B CN 200810063113 CN200810063113A CN101338081B CN 101338081 B CN101338081 B CN 101338081B CN 200810063113 CN200810063113 CN 200810063113 CN 200810063113 A CN200810063113 A CN 200810063113A CN 101338081 B CN101338081 B CN 101338081B
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- blue dye
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- 239000001045 blue dye Substances 0.000 title claims abstract description 26
- 239000000203 mixture Substances 0.000 title claims description 88
- 150000001875 compounds Chemical class 0.000 claims abstract description 82
- 239000012752 auxiliary agent Substances 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 239000000975 dye Substances 0.000 abstract description 32
- 239000004744 fabric Substances 0.000 abstract description 17
- 238000000034 method Methods 0.000 abstract description 9
- 238000005406 washing Methods 0.000 abstract description 6
- 239000000835 fiber Substances 0.000 abstract description 5
- 230000002209 hydrophobic effect Effects 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract description 3
- 229920000728 polyester Polymers 0.000 abstract description 3
- 238000001694 spray drying Methods 0.000 abstract description 3
- 239000011859 microparticle Substances 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 210000004243 sweat Anatomy 0.000 abstract 1
- 238000004043 dyeing Methods 0.000 description 20
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229920002334 Spandex Polymers 0.000 description 8
- 239000004759 spandex Substances 0.000 description 8
- 239000002270 dispersing agent Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000000986 disperse dye Substances 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- 0 COc(cc(c(*)c1)N=Nc(c(Br)cc([N+]([O-])=O)c2)c2[N+]([O-])=O)c1N(*)* Chemical compound COc(cc(c(*)c1)N=Nc(c(Br)cc([N+]([O-])=O)c2)c2[N+]([O-])=O)c1N(*)* 0.000 description 4
- 229920004933 Terylene® Polymers 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920005552 sodium lignosulfonate Polymers 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- -1 alkyl naphthalene sulfonic acid formaldehyde Chemical compound 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 235000019357 lignosulphonate Nutrition 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- 229920004935 Trevira® Polymers 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
- C09B67/0082—Preparations of disperse dyes or solvent dyes in liquid form
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Abstract
The invention provides a dispersive dark blue dye compound which essentially comprises the following components: one or more than one type of component A with the structure as seen in formula (I), one or more than one type of component B with the structure as seen in formula (II), one or more than one type of component C with the structure as seen in formula (III) and one or more than one type ofcomponent D with the structure as seen in formula (IV); the dispersive dark blue dye compound of the invention can dye with liquid and emulsifiable paste which become micro particles and power and particles which are dried through a spray drying method. The dispersive dye compound of the invention can dye with liquid and emulsifiable paste which become micro particles and power and particles which are dried through a spray drying method. When the dispersive dark blue dye compound of the invention is used to dye polyester fiber and other hydrophobic materials, dark blue dye fabric with excellent performance, such as bright color, good dispersibility, light resistance, washing resistance, sweat resistance, etc. can be obtained by adjusting the ratio of different components.
Description
(1) technical field
The present invention relates to a kind of dispersed deep blue dye composition, especially a kind of dispersed deep blue dye composition of suitable printing and dyeing hydrophobic fiber material.
(2) background technology
More and more higher to the requirement of terylene and spandex material dyeing aspect in recent years, particularly along with the development of polyester fibre/spandex mixed fibre, need in a hurry on the market a kind of be applied to above fiber the time, every dyeing behavior performance unanimity such as its washing fastness, perspiration fastness, dye uptake, lifting force or the less dyestuff of difference.When dying dark heavy colour pool especially, as widely used blue-black dye species, people then have the requirement of more increasing to its dyeing behavior and every fastness, and general dispersed dye differ greatly in last fastness when dying ordinary polyester and spandex lining, particularly aspect washing fastness, it is differential reach one-level or more than.
(3) summary of the invention
The present invention seeks to for a kind of dark blue disperse dye composition is provided, when being applied to hydrophobic fiber material dyeing, fabric can be dyed the mazarine color and luster, and every fastness excellent property, during to terylene and these two kinds of material dyeing of spandex, water-fastly wash, perspiration resistance, sun-resistant fastness differ very little, washing fastness basically identical especially.In addition, this dispersed deep blue dye also is applicable to superfine Denier fibre dyeing, and enhancing rate is good, has good colorant match consistency and dyeing circulation ratio.
The technical solution used in the present invention is:
A kind of dispersed deep blue dye composition, mainly comprise following component: one or more structures suc as formula the component A shown in (I), one or more structures suc as formula the B component shown in (II), one or more structures suc as formula the component C shown in (III) and one or more structures suc as formula the component D shown in (IV), based on described component A, B component, component C and component D, component A quality percentage composition is 45～95%, B component quality percentage composition is 0.1～10%, component C quality percentage composition is 0～5%, and component D quality percentage composition is 1～50%;
In the formula (I): X
1Be cyano group or halogen; R
1, R
2Independent separately is C
1～C
4Alkyl ,-CH
2COOR
12,-C
2H
4COOR
13Or C
2H
4OCOR
14, wherein, R
12, R
13, R
14Independent separately is C
1～C
4Alkyl; In the formula, R
3, R
4Independent separately is C
1～C
4Alkyl.
In the formula (II): R
5For-OH, C
1～C
4Alkyl or C
1～C
4Alkoxyl group; R
6, R
7Independent separately is C
1～C
4Alkyl, cyanoethyl or-R
10COOR
11, wherein, R
10, R
11Independent separately is C
1～C
4Alkyl.
In the formula (III): X
2Be hydrogen, C
1～C
4Alkoxyl group or-COOC
2H
4OC
2H
4OCH
3X
3For hydrogen, nitro or-OSO
2-Ph (Ph is a benzene); X
4Be hydrogen or nitro; R
8Be C
1～C
4Alkyl.
In the formula (IV): Y is-O or-NH; R
9For by cyano group, hydroxyl, C
1～C
4The C that alkoxyl group or phenyl replace
1～C
4Alkyl.
Preferably, based on described component A, B component, component C and component D, the quality percentage composition of component A is 50～90%, and the quality percentage composition of B component is 0.1～5%, the quality percentage composition of component C is 0～3%, and the quality percentage composition of component D is 5～45%.
Perhaps, described dispersed deep blue dye composition is made up of component A, B component, component C, component D and auxiliary agent, based on described component A, B component, component C and component D, the quality percentage composition of component A is 50～90%, the quality percentage composition of B component is 0.1～5%, the quality percentage composition of component C is 0～3%, and the quality percentage composition of component D is 5～45%; The auxiliary agent quality is component A, B component, component C and component D quality sum 0.8～5 times.
Described component A is preferably one of following formula or two or more mixture wherein:
Described B component is preferably one of following formula or two or more mixture wherein:
Described component C is preferably one of following formula or two or more mixture wherein:
Described component C is preferably one of following formula or two or more mixture wherein:
Preferably, described dispersed deep blue dye composition is made up of compound (I-1), compound (II-1), compound (III-1) and compound (IV-1), based on described compound (I-1), compound (II-1), compound (III-1) and compound (IV-1), compound (I-1) quality percentage composition is 45～95%, compound (II-1) quality percentage composition is 0.1～10%, compound (III-1) quality percentage composition is 0～5%, and compound (IV-1) quality percentage composition is 1～50%;
Preferably, based on described compound (I-1), compound (II-1), compound (III-1) and compound (IV-1), compound (I-1) quality percentage composition is 50～90%, compound (II-1) quality percentage composition is 0.1～5%, compound (III-1) quality percentage composition is 0～3%, and compound (IV-1) quality percentage composition is 5～45%.
When described disperse black dye composition is made finished product, can exist with the dye powder form separately, also can comprise auxiliary agent, preferably, described dispersed deep blue dye composition is by compound (I-1), compound (II-1), compound (III-1), compound (IV-1) is formed and auxiliary agent is formed, based on described compound (I-1), compound (II-1), compound (III-1) and compound (IV-1), compound (I-1) quality percentage composition is 50～90%, compound (II-1) quality percentage composition is 0.1～5%, compound (III-1) quality percentage composition is 0～3%, and compound (IV-1) quality percentage composition is 5～45%; The auxiliary agent quality is compound (I-1), compound (II-1), compound (III-1) and compound (IV-1) quality sum 0.8～5 times.
Dye composite of the present invention with aforementioned specific blending ratio preparation, can obtain the mazarine tone, dyes by ways customary in the industry, can obtain the dyeing and weaving thing of colour fastness excellences such as form and aspect are full, light fastness, washing fastness, perspiration fastness.
Disperse dye composition of the present invention also can comprise other dispersed dye component.
Because the singularity of dye industry is difficult to also there is no need to make pure product, can have the impurity in some preparation process usually, also allows to contain the physics impurity of a spot of moisture content and trace when dispersed dye of the present invention are made finished product.
When preparing mazarine disperse dye composition of the present invention, employed component A, B component, component C and component D can be synthetic by mode well known to those skilled in the art easily, wherein component A can be with reference to the method preparation of introducing among the patent CN98116047.6, also can adopt the commercial goods, B component can prepare with reference to the method among the CN101100560A, component C can be with reference to JP11158402, method preparation among the JP10077583, component D can be with reference to patent JP39/14992, method preparation described in the JP30/3384 also can be adopted commercial goods dye monomer A, dye monomer B, dye monomer C and dye monomer D.
Disperse dye composition of the present invention generally needs to add auxiliary agent and disperses in the commercialization process.After for example structural formula (I), (II), (III), (IV) represented dye monomer compound being mixed by above-mentioned proportioning, in the presence of auxiliary agent, water or other wetting agent, carry out corpusculed with pulverizers such as sand mill or shredders; Also structural formula (I), (II), (III), (IV) represented dye monomer compound can be carried out mixing with aforementioned proportion after corpusculed is handled with pulverizers such as sand mill or shredders respectively in the presence of auxiliary agent, water or other wetting agent in addition.Usually, the auxiliary agent quality is 0.8～5: 1 with the ratio of dye monomer compound total mass.
Described auxiliary agent is dispersed dye dispersion agent commonly used, diffusants etc. when composite, one of preferred following or its several mixture arbitrarily: anionic dispersing agents such as naphthalene sulfonic acidformaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic formaldehyde condensation compound, sulfonated lignin.Particularly, naphthalene sulfonic acidformaldehyde condensation product such as dispersing agent NNO, alkyl naphthalene sulfonic acid formaldehyde condensation products such as Dispersant MF (condensation compound of methyl naphthalene sulfonic acid and formaldehyde), benzyl naphthalene sulfonic formaldehyde condensation compound such as dispersing agent CNF etc., sulfonated lignin such as sodium lignosulfonate (as commercial dispersants Reax 83A, Reax 85A) etc.
Disperse dye composition of the present invention, can with the liquid state behind the corpusculed, emulsifiable paste attitude or with spray-drying process carry out dried powdery, graininess is supplied with dyeing.When dying hydrophobic material such as trevira with the disperse dye composition of the present invention preparation, can obtain to have by adjusting proportion among different that coloured light is gorgeous, the mazarine dyeing and weaving thing of premium propertiess such as good dispersity, sun-proof, washable, perspiration resistance.
(4) embodiment
The present invention is described further below in conjunction with specific embodiment, but protection scope of the present invention is not limited in this:
Embodiment 1:
Component A, the B component of 3 gram formulas (II-1), component C, the component D of 23.5 gram formulas (IV-1) of 1.5 gram formulas (III-1), 135 sodium lignosulfonates that restrain with 72 gram formulas (I-1), add water 500 gram piece together mix after, grind pre-dispersed with shredder, spraying drying, the dyestuff that gets product, this dyestuff can offer the good mazarine of the every fastness ability of fabric.
Embodiment 2～20:
According to data shown in the table 1, with component A, B component, component C, component D and 150 gram auxiliary agent Reax85A, add 500 gram water piece together mix after, grind dispersion with shredder, spraying drying makes finished product then, can offer fabric evenly and the good mazarine of fastness ability.
Table 1
Embodiment 21:
Component A, the B component of 3 gram formulas (II-1), component C, the component D of 23 gram formulas (IV-1) of 2 gram formulas (III-1), 2 gram C.I. Disperse Blue-79s, 150 sodium lignosulfonates that restrain with 70 gram formulas (I-1), after adding 500 gram water and piece together mixing, grind dispersion with shredder, spraying drying, get product, this dyestuff can offer fabric evenly and the good mazarine of fastness ability.
Embodiment 22:
Component A, the B component of 3 gram formulas (II-1), the component C of 2 gram formulas (III-1), the component D, 2 of 23 gram formulas (IV-1) of 70 gram formulas (I-1) are restrained the sodium lignosulfonate of C.I. EX-SF DISPERSE BLUE EX-SF 300 284,150 grams, after adding 500 gram water and piece together mixing, grind dispersion with shredder, spraying drying, get product, this dyestuff can offer fabric evenly and the good mazarine of fastness ability.
Dyeing embodiment:
Dyeing of PET fabric:
Taking by weighing 2 dispersed dye that make of gram embodiment 1 is dispersed in 500 ml waters, adding 1 gram dispersing agent NNO stirs, mix with 180 milliliters water after drawing 20 milliliters, transferring dye bath PH with acetic acid is 5, when being warming up to 50 ℃, put into the pure cloth of washing of 2 grams, begin dyeing, about 1 ℃/min speed is warming up to 130 ℃, insulation dyeing 30 minutes.Be cooled to then about 70 ℃, take out fabric, soap and reduction clearing, oven dry through hot water (60～80 ℃).Observe sample cloth coloured light, adopt that GB GB/T3921, GB/T3922, GB/T8427 test respectively that it is washable, perspiration resistance, colour fastness to light, can offer fabric evenly and the good black of fastness ability the results are shown in Table 2.
The dyeing of spandex fabric:
Taking by weighing 2 dispersed dye that make of gram embodiment 1 is dispersed in 500 ml waters, add 1 gram dispersing agent NNO and 0.5 gram paregal O, stir, mix with 180 milliliters water after drawing 20 milliliters, transferring dye bath PH with acetic acid is 5.5, when being warming up to 20 ℃, put into 2 gram spandex cloth, begin dyeing, slowly be warming up to 95 ℃, insulation dyeing 45 minutes.Be cooled to then about 50 ℃, take out fabric, through soaping and reduction clearing oven dry.Observe sample cloth coloured light, adopt that GB GB/T3921, GB/T3922, GB/T8427 test respectively that it is washable, perspiration resistance, colour fastness to light, can offer fabric evenly and the good black of fastness ability the results are shown in Table 2.
Table 2
According to the method described in the above-mentioned dyeing embodiment, adopt the dyestuff of preparation among the embodiment 2～22 respectively terylene and spandex to be dyeed, can obtain the mazarine fabric of dyeing behavior excellence, and last when dying terylene and spandex, the dyefastness basically identical, difference is less.
Claims (10)
1. dispersed deep blue dye composition, mainly comprise following component: one or more structures suc as formula the component A shown in (I), one or more structures suc as formula the B component shown in (II), one or more structures suc as formula the component C shown in (III) and one or more structures suc as formula the component D shown in (IV), based on described component A, B component, component C and component D, component A quality percentage composition is 45～95%, B component quality percentage composition is 0.1～10%, component C quality percentage composition is 0～5%, and component D quality percentage composition is 1～50%;
In the formula (I): X
1Be cyano group or halogen; R
1, R
2Independently be-CH separately
2COOR
12,-C
2H
4COOR
13Or C
2H
4OCOR
14, wherein, R
12, R
13, R
14Independent separately is C
1～C
4Alkyl; R
3, R
4Independent separately is C
1～C
4Alkyl;
In the formula (II): R
5For-OH, C
1～C
4Alkyl or C
1～C
4Alkoxyl group; R
6, R
7Independent separately is C
1～C
4Alkyl, cyanoethyl or-R
10COOR
11, wherein, R
10, R
11Independent separately is C
1～C
4Alkyl;
In the formula (III): X
2Be hydrogen, C
1～C
4Alkoxyl group or-COOC
2H
4OC
2H
4OCH
3X
3For hydrogen, nitro or-OSO
2-Ph; X
4Be hydrogen or nitro; R
8Be C
1～C
4Alkyl;
In the formula (IV): Y is-O or-NH; R
9For by cyano group, hydroxyl, C
1～C
4The C that alkoxyl group or phenyl replace
1～C
4Alkyl.
2. dispersed deep blue dye composition as claimed in claim 1, it is characterized in that: based on described component A, B component, component C and component D, the quality percentage composition of component A is 50～90%, the quality percentage composition of B component is 0.1～5%, the quality percentage composition of component C is 0～3%, and the quality percentage composition of component D is 5～45%.
3. dispersed deep blue dye composition as claimed in claim 1, it is characterized in that described dispersed deep blue dye composition is made up of component A, B component, component C, component D and auxiliary agent, based on described component A, B component, component C and component D, the quality percentage composition of component A is 50～90%, the quality percentage composition of B component is 0.1～5%, the quality percentage composition of component C is 0～3%, and the quality percentage composition of component D is 5～45%; The auxiliary agent quality is component A, B component, component C and component D quality sum 0.8～5 times.
4. as the described dispersed deep blue dye composition of one of claim 1～3, it is characterized in that described component A is one of following formula or two or more mixture wherein:
5. as the described dispersed deep blue dye composition of one of claim 1～3, it is characterized in that described B component is one of following formula or two or more mixture wherein:
6. as the described dispersed deep blue dye composition of one of claim 1～3, it is characterized in that described component C is one of following formula or two or more mixture wherein:
7. as the described dispersed deep blue dye composition of one of claim 1～3, it is characterized in that described component D is one of following formula or two or more mixture wherein:
8. dispersed deep blue dye group thing as claimed in claim 1, it is characterized in that described dispersed deep blue dye composition is by compound (I-1), compound (II-1), compound (III-1) and compound (IV-1) are formed, based on described compound (I-1), compound (II-1), compound (III-1) and compound (IV-1), compound (I-1) quality percentage composition is 45～95%, compound (II-1) quality percentage composition is 0.1～10%, compound (III-1) quality percentage composition is 0～5%, and compound (IV-1) quality percentage composition is 1～50%;
9. dispersed deep blue dye composition as claimed in claim 8, it is characterized in that: based on described compound (I-1), compound (II-1), compound (III-1) and compound (IV-1), compound (I-1) quality percentage composition is 50～90%, compound (II-1) quality percentage composition is 0.1～5%, compound (III-) quality percentage composition is 0～3%, and compound (IV-1) quality percentage composition is 5～45%.
10. dispersed deep blue dye composition as claimed in claim 3, it is characterized in that: described dispersed deep blue dye composition is by compound (I-1), compound (II-1), compound (III-1), compound (IV-1) is formed and auxiliary agent is formed, based on described compound (I-1), compound (II-1), compound (III-1) and compound (IV-1), compound (I-1) quality percentage composition is 50～90%, compound (II-1) quality percentage composition is 0.1～5%, compound (III-1) quality percentage composition is 0～3%, and compound (IV-1) quality percentage composition is 5～45%; The auxiliary agent quality is compound (I-1), compound (II-1), compound (III-1) and compound (IV-1) quality sum 0.8～5 times;
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| CN110698880B (en) * | 2019-10-29 | 2021-02-05 | 杭州维昂化工有限公司 | Disperse blue dye composition, disperse blue dye, preparation method of disperse blue dye and fabric |
| CN115521636B (en) * | 2022-10-24 | 2023-06-30 | 浙江博澳新材料股份有限公司 | Sun-proof anthraquinone disperse dye containing dicyano and preparation method thereof |
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