CN101328687A - Environment-friendly type terylene low temperature dyeing assistant with alkyl phthalic imide as vector and preparation thereof - Google Patents
Environment-friendly type terylene low temperature dyeing assistant with alkyl phthalic imide as vector and preparation thereof Download PDFInfo
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- CN101328687A CN101328687A CNA2008100637086A CN200810063708A CN101328687A CN 101328687 A CN101328687 A CN 101328687A CN A2008100637086 A CNA2008100637086 A CN A2008100637086A CN 200810063708 A CN200810063708 A CN 200810063708A CN 101328687 A CN101328687 A CN 101328687A
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- 238000004043 dyeing Methods 0.000 title claims abstract description 81
- -1 alkyl phthalic imide Chemical compound 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000005020 polyethylene terephthalate Substances 0.000 title claims description 35
- 229920004933 Terylene® Polymers 0.000 title claims description 34
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 23
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 23
- 239000004359 castor oil Substances 0.000 claims abstract description 19
- 235000019438 castor oil Nutrition 0.000 claims abstract description 19
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 19
- 239000000839 emulsion Substances 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 17
- 238000009313 farming Methods 0.000 claims description 8
- VPLDXHDOGVIETL-UHFFFAOYSA-N 2-propan-2-ylisoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(C(C)C)C(=O)C2=C1 VPLDXHDOGVIETL-UHFFFAOYSA-N 0.000 claims description 7
- 229940078863 isopropylphthalimide Drugs 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 3
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical group CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 claims description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- 210000000481 breast Anatomy 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 239000004744 fabric Substances 0.000 abstract description 7
- 239000012752 auxiliary agent Substances 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000003995 emulsifying agent Substances 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000004753 textile Substances 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 15
- 239000000835 fiber Substances 0.000 description 14
- 239000011734 sodium Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 9
- 239000000986 disperse dye Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 7
- 239000003599 detergent Substances 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical group CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 5
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 5
- 238000005265 energy consumption Methods 0.000 description 3
- 238000009830 intercalation Methods 0.000 description 3
- 230000002687 intercalation Effects 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- AWFYPPSBLUWMFQ-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(1,4,6,7-tetrahydropyrazolo[4,3-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)NN=C2 AWFYPPSBLUWMFQ-UHFFFAOYSA-N 0.000 description 2
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 2
- 229920002334 Spandex Polymers 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000005063 solubilization Methods 0.000 description 2
- 230000007928 solubilization Effects 0.000 description 2
- 239000004759 spandex Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
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- 239000012141 concentrate Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention discloses an environment-friendly terylen low-temperature dyeing auxiliary agent taking alkyl phthalimide as a carrier and a preparation method thereof. The compositions in percentage by weight of the dyeing auxiliary agent are: 70 to 90 percent of alkyl phthalimide compound, 8 to 15 percent of concentrated emulsion 8206, 1 to 7.5 percent of castor oil polyoxyethylene ether sulphonated matter and 1 to 7.5 percent of alkyl phenol polyoxyethylene ether, wherein the alkyl phthalimide is takes as the carrier; and the concentrated emulsion 8206, the castor oil polyoxyethylene ether sulphonated matter and the alkyl phenol polyoxyethylene ether are takes as an emulsifying agent. The environment-friendly terylen low-temperature dyeing auxiliary agent is used in low-temperature dyeing of terylen and terylen-containing textile fabrics; moreover, the dyeing auxiliary agent not only has the characteristics of nontoxicity, tastelessness, environmental protection and low cost, etc., but also has the advantages of high dye uptake, excellent level dyeing property, high dyeing fastness and wide application range, etc., thereby meeting the requirements of low-temperature dyeing production of terylen-containing textile fabrics.
Description
Technical field
The present invention relates to terylene low temperature dyeing assistant and preparation method thereof, more particularly relating to a kind of is the environment-friendly type terylene low temperature dyeing assistant and preparation method thereof of carrier with the alkyl phthalic imide.
Background technology
Polyster fibre degree of crystallinity height, degree of orientation height, structure is tight, under standard state (20 ℃, relative humidity 65%), regain has only 0.4%, and the moisture absorption swellability is little during dyeing, under the boiling dyeing at normal pressure condition, the big molecule of DISPERSE DYES is difficult to be diffused into fibrous inside, and dyeing is difficulty, and dyeability is poor.Three kinds of methods of the general employing of dyeing terylene at present: the first, high-temperature and high pressure dyeing process, this method equipment requires high, and dyeing time is long and energy consumption is big.The second, pad-dry-cure dyeing method, this method energy consumption height, dyeing back product feel is undesirable.Three, carrier low temperature dyeing method, this method can reduce expense and the shortening production cycle of dyeing at aspects such as energy consumption, machineries on the one hand, save cost, reduce consuming; On the other hand can solution and the technical problem of non-refractory fibers such as blend polyester or the spandex that interweaves, wool, real silk, the advantage of various fibers is given full play to, thereby obtained high-quality DYED FABRICS, expand blend polyester or MIXED FABRIC staining technique.
Terylene carrier low temperature dyeing need be added one or more carrier auxiliary agents that polyster fibre is played plasticising, expanded effect.At present, the terylene low temperature dyeing carrier mainly concentrates on ester class, ethers and compound three major types thereof on the domestic and international market, they present the short effect of dying of low temperature, still also have simultaneously following problem: cause easily that in polyster fibre dyeing the dye liquor dispersion stabilization descends, dyestuff is assembled generation and is dyed defect; Dyeing back carrier is removed difficulty, causes the stimulation to human body of color fastness decreased and fabric; The carrier that has, poisonous or difficult degradation, harmful to human body and environment; These factors have caused the terylene low temperature dyeing method not to be used widely just.
Along with constantly riseing of oil price, the ratio that the dyeing energy cost accounts for production cost improves constantly, and dyeing industry presses for the terylene low temperature dyeing technology, presses for the environment-friendly highly efficient terylene low temperature dyeing assistant.
In sum, constantly surging and people are to the strong pursuit of dress-goods personalization, variation and functionalization in view of the international energy price, the present invention has developed terylene low temperature dyeing assistant of a kind of efficient, environmental protection and preparation method thereof, satisfies the terylene low temperature dyeing demand of practical production.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, providing a kind of is the environment-friendly type terylene low temperature dyeing assistant and preparation method thereof of carrier with the alkyl phthalic imide.
The environment-friendly type terylene low temperature dyeing assistant that with the alkyl phthalic imide is carrier consists of by weight percentage:
Alkyl phthalic imide compounds: 70%～90%;
Farming emulsion 8206:8%～15%;
Castor oil polyoxyethylene ether sulfonated bodies: 1%～7.5%;
Alkylphenol polyoxyethylene: 1%～7.5%.
The preparation method who with the alkyl phthalic imide is the environment-friendly type terylene low temperature dyeing assistant of carrier is to be that 8%～15% agricultural emulsion 8206, percentage by weight are that 1%～7.5% castor oil polyoxyethylene ether sulfonated bodies, percentage by weight are that 1%～7.5% alkylphenol polyoxyethylene mixes with percentage by weight, add percentage by weight again and be 70%～90% alkyl phthalic imide compounds and mix, mixing temperature is 40～60 ℃.
Described alkyl phthalic imide compounds is a kind of in normal-butyl phthalimide or the isopropyl phthalimide or two kinds.Farming breast 8206 is non-ionic surface active agent and anion surfactant compound.The castor oil polyoxyethylene ether sulfonated bodies is EL-60 sulfonated bodies, EL-80 sulfonated bodies or EL-90 sulfonated bodies.Alkylphenol polyoxyethylene is isooctylphenol polyoxyethylene ether or polyoxyethylene nonylphenol ether, and wherein the EO number can be selected TX-30, TX-40, TX-50, NP-30, NP-40 or NP-50 greater than 30.
The beneficial effect that the present invention compared with prior art has:
(1) efficient, nontoxic, tasteless, environmental protection, low cost.
(2) aqueous, have the self-emulsifying function, need not to add again any emulsifying agent during use, easily evenly mix with dye liquor, can not cause dyeing defect and cause pipeline blockage, easy to operate.
(3) dye bath pH value stabilization, migration property can be good, and even dyeing is bright in colour and bright.
(4) be applicable to polyester conventional, superfine fibre fabric normal temperature (98 ℃-105 ℃) dyeing, dyeing K/S value high (105 ℃ of K/S values that dye are suitable with 130 ℃ of dyeing of conventional High Temperature High Pressure K/S values) can shorten dyeing time, improves dyeing efficient, and is energy-conservation obvious.
(5) applied widely.This auxiliary agent is not only applicable to the dyeing of polyester fibers such as PET, PTT and PBT, and is applicable to non-refractory fiber blend (or interweaving) coloration of textile materials such as terylene and spandex, wool.
Description of drawings
Fig. 1 is the terylene low temperature dyeing artwork.
Fig. 2 is polyester fibre at high temp and pressure dyeing figure.
The specific embodiment
The carrier of alkyl phthalic imide compounds during as terylene low temperature dyeing.Its introducing causes the fibrous glass temperature to reduce on the one hand, fiber is plasticized, and fiber macromolecular chain segment mobility increases, and it is movable that the molecule segment of amorphous region is more prone to, the polyster fibre free volume increases and causes that dyeing rate accelerates thus, on dyestuff increase.Carrier---the alkyl phthalic imide compounds has stronger affinity to DISPERSE DYES on the other hand, play solubilization, it is adsorbed on fiber surface and forms one deck high concentration dye liquor layer when dyeing, improved the inside and outside dye concentration gradient of fiber, accelerate the dyestuff dyeing speed, add the dye-uptake of big dye.
Farming emulsion 8206, castor oil polyoxyethylene ether sulfonated bodies and alkylphenol polyoxyethylene are emulsifying agent.Because alkyl phthalic imide compounds and water objectionable intermingling are difficult to direct application in the reality printing and dyeing are produced.The use of emulsifying agent can make the alkyl phthalic imide compounds be scattered in the dye liquor uniformly with the form of emulsion on the one hand.Can also play good solubilization to DISPERSE DYES on the other hand, improve the dispersion stabilization of dyestuff, guarantee sufficiently high dye-uptake and dyefastness.
Below in conjunction with example the present invention is described in further detail:
Environment-friendly type terylene low temperature dyeing assistant component and weight percent meter are heavy:
Alkyl phthalic imide compounds: 70%～90%wt%;
Farming emulsion 8206:8%～15%wt%;
Castor oil polyoxyethylene ether sulfonated bodies: 1%～7.5%wt%;
Alkylphenol polyoxyethylene: 1%～7.5%wt%.
The preparation method: with percentage by weight is that 8%～15% agricultural emulsion 8206, percentage by weight are that 1%～7.5% castor oil polyoxyethylene ether sulfonated bodies, percentage by weight are that 1%～7.5% alkylphenol polyoxyethylene mixes, add percentage by weight again and be 70%～90% alkyl phthalic imide compounds and mix, mixing temperature is 40～60 ℃.
Example 1-5:
Select the beautiful H-2GFL of the intercalation reddle of high temperature modification DISPERSE DYES, concentration 2% (o.w.f), dispersant NNO consumption is 1g/L, and the terylene low temperature dyeing assistant consumption is 2g/L, and the sodium hydrosulfite consumption is 2g/L, Na
2CO
3Consumption is 4g/L, and 209 detergent consumptions are 2g/L, and dyeing pH value is 4-5, and bath raio is 1: 30, and the dyeing curve is seen Fig. 1, and terylene low temperature dyeing assistant composition and corresponding coloration result see Table 1.
Table 1
Annotate: A: alkyl phthalic imide compounds (N-butane group phthalimide: isopropyl phthalimide=3: 1), B: agricultural emulsion 8206, C: castor oil polyoxyethylene ether sulfonated bodies: EL-60 sodium sulfonate, D: alkylphenol polyoxyethylene: TX-40; The mixing temperature of example 1-3 is 40 ℃, and the mixing temperature of routine 4-5 is 60 ℃.
Example 6-10:
Select high temperature modification DISPERSE DYES disperse yellow S-4GL, concentration 2% (o.w.f), dispersant NNO consumption is 1g/L, and the terylene low temperature dyeing assistant consumption is 2g/L, and the sodium hydrosulfite consumption is 2g/L, Na
2CO
3Consumption is 4g/L, and 209 detergent consumptions are 2g/L, and dyeing pH value is 4-5, and bath raio is 1: 30, and the dyeing curve is seen Fig. 1, and terylene low temperature dyeing assistant composition and corresponding coloration result see Table 2.
Table 2
Annotate: A: alkyl phthalic imide compounds (N-butane group phthalimide: isopropyl phthalimide=3: 1), B: agricultural emulsion 8206, C: castor oil polyoxyethylene ether sulfonated bodies: EL-60 sodium sulfonate, D: alkylphenol polyoxyethylene: TX-40; The mixing temperature of example 6-10 is 50 ℃.
Example 11-15:
Select high temperature modification DISPERSE DYES disperse dark blue S-RE, concentration 2% (o.w.f), dispersant NNO consumption is 1g/L, and the terylene low temperature dyeing assistant consumption is 2g/L, and the sodium hydrosulfite consumption is 2g/L, Na
2CO
3Consumption is 4g/L, and 209 detergent consumptions are 2g/L, and dyeing pH value is 4-5, and bath raio is 1: 30, and the dyeing curve is seen Fig. 1, and terylene low temperature dyeing assistant composition and corresponding coloration result see Table 3.
Table 3
Annotate: A: alkyl phthalic imide compounds (N-butane group phthalimide: isopropyl phthalimide=3: 1), B: agricultural emulsion 8206, C: castor oil polyoxyethylene ether sulfonated bodies: EL-60 sodium sulfonate, D: alkylphenol polyoxyethylene: TX-40; The mixing temperature of example 11-15 is 50 ℃.
Example 16-39:
Select the beautiful H-2GFL of the intercalation reddle of high temperature modification DISPERSE DYES, concentration 2% (o.w.f), dispersant NNO consumption is 1g/L, and the terylene low temperature dyeing assistant consumption is 2g/L, and the sodium hydrosulfite consumption is 2g/L, Na
2CO
3Consumption is 4g/L, and 209 detergent consumptions are 2g/L, and dyeing pH value is 4-5, and bath raio is 1: 30, and the dyeing curve is seen Fig. 1, and terylene low temperature dyeing assistant composition and corresponding coloration result see Table 4.
Table 4
Annotate: among the routine 16-18: A is a N-butane group phthalimide, and B is agricultural emulsion 8206, C: castor oil polyoxyethylene ether sulfonated bodies: EL-60 sodium sulfonate, D: alkylphenol polyoxyethylene: TX-40; Among the example 19-24: A is the isopropyl phthalimide, and B is agricultural emulsion 8206, and C is castor oil polyoxyethylene ether sulfonated bodies (for the EL-80 sodium sulfonate, being the EL-90 sodium sulfonate among the routine 22-24 among the routine 19-21), and D is alkylphenol polyoxyethylene: TX-40; Among the example 25-39: A is an alkyl phthalic imide compounds (N-butane group phthalimide: isopropyl phthalimide=3: 1), B is agricultural emulsion 8206, C is castor oil polyoxyethylene ether sulfonated bodies (an EL-60 sodium sulfonate), D is that alkylphenol polyoxyethylene (is to be TX-50 among TX-30, the routine 28-30 among the routine 25-27, among the example 31-33 is NP-30, among the example 34-36 is NP-40, is NP-50 among the routine 37-39); The mixing temperature of example 16-39 is 50 ℃.
By table 1, table 2, table 3, table 4 as can be known, no matter for which kind of dyestuff, when alkyl phthalic imide compounds consumption is 70%～90%wt%, farming emulsion 8206 consumptions are 8%～15%wt%, castor oil polyoxyethylene ether sulfonated bodies consumption is 1%～7.5%wt%, when alkylphenol polyoxyethylene is 1%～7.5%wt%, all can obtain good Color.DYED FABRICS has bigger dye level.Compare with high-temperature pressure dyeing (seeing appendix table 5), dyeing K/S value and dyefastness are comparatively approaching.
Thus, we to draw with the alkyl phthalic imide be the environment-friendly type terylene low temperature dyeing assistant outward appearance, composed as follows of carrier:
Outward appearance: light yellow transparent liquid
Form: alkyl phthalic imide compounds: 70%～90%wt%;
Farming emulsion 8206:8%～15%wt%;
Castor oil polyoxyethylene ether sulfonated bodies: 1%～7.5%wt%;
Alkylphenol polyoxyethylene: 1%～7.5%wt%.
In reality printing and dyeing production process, according to the difference of required dye level, auxiliary dosage is preferably 1g/L-3g/L.
Appendix
The high-temperature pressure dyeing experiment:
Select the intercalation reddle of high temperature modification DISPERSE DYES beautiful H-2GFL, disperse yellow S-4GL, disperse dark blue S-RE concentration 2% (o.w.f), dispersant NNO consumption is 1g/L, and the sodium hydrosulfite consumption is 2g/L, Na
2CO
3Consumption is 4g/L, and 209 detergent consumptions are 2g/L, and dyeing pH value is 4-5, and bath raio is 1: 30, and the dyeing curve is seen Fig. 2, and coloration result sees Table 5.
Table 5
Claims (6)
1, a kind of is the environment-friendly type terylene low temperature dyeing assistant of carrier with the alkyl phthalic imide, it is characterized in that: consist of by weight percentage:
Alkyl phthalic imide compounds: 70%～90%;
Farming emulsion 8206:8%～15%;
Castor oil polyoxyethylene ether sulfonated bodies: 1%～7.5%;
Alkylphenol polyoxyethylene: 1%～7.5%.
2, according to claim 1 a kind of be the environment-friendly type terylene low temperature dyeing assistant of carrier with the alkyl phthalic imide, it is characterized in that described alkyl phthalic imide compounds is a kind of in normal-butyl phthalimide or the isopropyl phthalimide or two kinds.
3, according to claim 1 a kind of be the environment-friendly type terylene low temperature dyeing assistant of carrier with the alkyl phthalic imide, it is characterized in that described farming breast 8206 is non-ionic surface active agent and anion surfactant compound.
4, according to claim 1 a kind of be the environment-friendly type terylene low temperature dyeing assistant of carrier with the alkyl phthalic imide, it is characterized in that described castor oil polyoxyethylene ether sulfonated bodies is EL-60 sulfonated bodies, EL-80 sulfonated bodies or EL-90 sulfonated bodies.
5, according to claim 1 a kind of be the environment-friendly type terylene low temperature dyeing assistant of carrier with the alkyl phthalic imide, it is characterized in that described alkylphenol polyoxyethylene is isooctylphenol polyoxyethylene ether or polyoxyethylene nonylphenol ether, wherein the EO number can be selected TX-30, TX-40, TX-50, NP-30, NP-40 or NP-50 greater than 30.
6, a kind of according to claim 1 be the preparation method of the environment-friendly type terylene low temperature dyeing assistant of carrier with the alkyl phthalic imide, it is characterized in that, with percentage by weight is that 8%～15% agricultural emulsion 8206, percentage by weight are that 1%～7.5% castor oil polyoxyethylene ether sulfonated bodies, percentage by weight are that 1%～7.5% alkylphenol polyoxyethylene mixes, add percentage by weight again and be 70%～90% alkyl phthalic imide compounds and mix, mixing temperature is 40～60 ℃.
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| CN102061635A (en) * | 2010-11-01 | 2011-05-18 | 常州市鑫诺纺织有限公司 | Technological process for polyster fibre dyeing |
| CN102218951A (en) * | 2011-04-12 | 2011-10-19 | 新发纺织印染（绍兴）有限公司 | Low energy consumption printing method for continuously performing aging color fixation on terylene fabric at low temperature |
| CN102605651A (en) * | 2012-03-21 | 2012-07-25 | 武汉工程大学 | Preparation method of novel leveling agent |
| CN102808338A (en) * | 2012-08-23 | 2012-12-05 | 苏州联胜化学有限公司 | Polyester fiber dyeing carrier and preparation method thereof |
| CN103103821A (en) * | 2012-12-14 | 2013-05-15 | 常熟市琴达针织印染有限公司 | Printing process of polyester fabric |
| CN103215831A (en) * | 2013-04-19 | 2013-07-24 | 江阴职业技术学院 | Polyester/sorona mixed fabric disperse dye one-bath process dyeing method |
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