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CN101328278B - Insulation plate interface adhesive and preparation thereof - Google Patents

Insulation plate interface adhesive and preparation thereof Download PDF

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Publication number
CN101328278B
CN101328278B CN2007100751439A CN200710075143A CN101328278B CN 101328278 B CN101328278 B CN 101328278B CN 2007100751439 A CN2007100751439 A CN 2007100751439A CN 200710075143 A CN200710075143 A CN 200710075143A CN 101328278 B CN101328278 B CN 101328278B
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Prior art keywords
insulation plate
plate interface
interface adhesive
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ether
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CN101328278A (en
Inventor
丁华明
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SHENZHEN MINGYUAN BUILDING MATERIAL TECHNOLOGY Co Ltd
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Shenzhen Mingyuan Fiuorocarbon Coationgs Co ltd
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Abstract

The invention relates to an interface agent for surface treatment of a thermal insulation material and provides a bonding interface agent for thermal insulation boards and a preparation method thereof. The bonding interface agent comprises the following compositions in weight portion: 100 portions of portland hydraulic cement, 100 to 180 portions of quartz sand, 2 to 3 portions of high-efficiencywater reducer, 1 to 2 portions of high-efficiency water repellent, 0.5 to 2 portions of lignocellulose, 1 to 2 portions of cellulose ether, 0.8 to 1.5 portions of hardening accelerator, and 60 to 100portions of self-crosslinking adhesive. The bonding interface agent solves the problems that a polystyrene thermal insulation board is difficult to be adhered easily and firmly, is simple in construction for the surface of a polystyrene board can be adhered by common extral wall putty after being coated with a layer of the interface agent by a roller and a brush, greatly reduces the cost of boniding by specialbinding mortar, and has better effect than that of using the special bonding mortar alone.

Description

A kind of insulation plate interface adhesive and preparation method thereof
Technical field
The present invention relates to a kind of heat insulation material surface processing interfacial agents, the interfacial agents that particularly a kind of styrofoam surface treatment is used.
Background technology
Building energy conservation is long-range strategy policy and the fundamental state policy that China formulates, it is the ultimate aim that china natural resources obtains Sustainable development, styrofoam is occupied sizable market share with its excellent heat-insulating property and lower price on the building heat preservation body of wall, the constructional method of its external heat insulating wall is fast with its speed of application, advantages such as construction height is unrestricted, the market share will further enlarge, but styrofoam, especially extrusion molding type styrofoam has the stickup of being not easy and glues shortcomings such as not firm, even the binding agent that preparation is special-purpose, also exist cost too high, rate of drying is slow, shortcoming such as be pasted not strongly, so need p-poly-phenyl warming plate surface to carry out the surface treatment interfacial agents of promptly constructing, to strengthen the cohesive strength of polyphenylene heat insulation slab and adhesive mortar or other matrix material.
Summary of the invention
For effectively addressing the above problem, the object of the present invention is to provide a kind of insulation plate interface adhesive.
Another object of the present invention is to provide a kind of preparation method of insulation plate interface adhesive.
For achieving the above object, technical scheme of the present invention is:
A kind of insulation plate interface adhesive, comprise 100 parts of suitable positions, quartz sand 100-180 part, high efficiency water reducing agent 2-3 part, silicane powder hydrophober 1-2 part, lignocellulose 0.5-2 part, ether of cellulose 1-2 part, non-chlorine type cement early strength agent 0.8-1.5 part, self-cross linking type binding agent 80-100 part.
Described suitable positions is silicate 42.5 cement.
Described quartz sand is 60-200 order grating quartz sand.
Described high efficiency water reducing agent is trimeric cyanamide/polycarboxylic acid high efficiency water reducing agent.
The average fiber length of described lignocellulose is 250-500um.
Described ether of cellulose is methyl hydroxyethylcellulose ether or methylhydroxypropylcellulose ether.
Described self-cross linking type binding agent is an acrylate copolymer class self-cross linking type binding agent.
A kind of preparation method of insulation plate interface adhesive may further comprise the steps:
1) gets 100 parts of suitable positions, 100-180 part quartz sand, 2-3 part high efficiency water reducing agent, 1-2 part silicane powder hydrophober, 0.5-2 part lignocellulose, 1-2 part ether of cellulose and 0.8-1.5 part non-chlorine type cement early strength agent, thorough mixing is even, obtains component A;
2) get the above-mentioned component A for preparing and 80-100 part self-cross linking type binding agent, add the interfacial agents that proper amount of clear water is modulated into paste, the addition of clear water is about about 20% of A component.
Suitable positions, high efficiency water reducing agent, the use of silicane powder hydrophober has guaranteed that the interfacial agents early strength forms the water tolerance that can improve interfacial agents, and the cohesive strength of p-poly-phenyl plate has booster action.
Quartz sand is used for interfacial agents, makes the styrofoam of construction after the interfacial agents have certain roughness, makes interfacial agents and matrix material that bigger contact area be arranged, and its cohesive strength is had enhancement.
The self-cross linking type binding agent has fabulous water-fast, and alkaline resistance properties has extremely strong cohesive force simultaneously, has improved the cohesive force of interfacial agents and styrofoam, is difficult for shortcomings such as bonding and bonding be not firm thereby solved styrofoam.
The invention solves the polyphenylene heat insulation slab problem that is not easy to paste and is pasted not strongly etc., and construction is simple, paste with regard to available common exterior wall putty after only needing styrofoam surface roller coating and brushing one deck interfacial agents, reduced greatly with special-purpose adhesive mortar and carried out the cost that sticking mortar is pasted, and effect is than independent better effects if with special-purpose adhesive mortar.
Embodiment
Embodiment 1
A kind of insulation plate interface adhesive, comprise 1000 gram P.I level 42.5# cement, 1000 gram technical grades, 60~200 order grating quartz sands, trimeric cyanamide/polycarboxylic acid high efficiency water reducing agent X404 that the Italian Ma Bei of 20 grams company produces, the silicane powder hydrophober Sea180 that 12 gram national of the United States starch companies produce, the lignocellulose HM300 that the German CFF of 10 grams company produces, average fiber length is 300um, the methylhydroxypropylcellulose ether MM60001P6 that company of the German SHIN-ETSU HANTOTAI of 15 grams produces, the acrylic acid or the like self-cross linking type binding agent viscopol180 that 10 gram non-chlorine type cement early strength agent technical grade calcium formiates and the Australian Niu Peisi of 800 grams company produce.
The preparation method of above-mentioned insulation plate interface adhesive may further comprise the steps:
1) gets 1000 gram P.I level 42.5# cement, 1000 gram technical grades, 60~200 order grating quartz sands, trimeric cyanamide/polycarboxylic acid high efficiency water reducing agent X404 that the Italian Ma Bei of 20 grams company produces, the silicane powder hydrophober Sea180 that 12 gram national of the United States starch companies produce, lignocellulose HM300, average fiber length that the German CFF of 10 grams company produces are 300um, methylhydroxypropylcellulose ether MM60001P6 that company of the German SHIN-ETSU HANTOTAI of 15 grams produces and 10 gram non-chlorine type cement early strength agent technical grade calcium formiates, thorough mixing is even, obtains component A;
2) get the acrylic acid or the like self-cross linking type binding agent viscopol180 that 2067 gram component A and the Australian Niu Peisi of 800 grams company produce, add 400 gram water, be mixed with the insulation plate interface adhesive of paste.
The using method of above-mentioned insulation plate interface adhesive and effect: above-mentioned insulation plate interface adhesive brushed or roller coating on styrofoam (EPS and XPS), back to be dried matrix material (adhesive mortar) paste heat-preserving plate, and contrast the performance comparison of its construction interfacial agents and the interfacial agents of not constructing, result such as following table 1 according to its cohesive strength of relevant portion standard detection of JG149-2003 " expansion polyphenyl plate thinly plastered external insulation system of outer wall " and JG158-2004 " glue powder polyphenyl granule exterior wall outer heat preservation system ":
Table 1
Figure S07175143920070724D000041
As can be seen from Table 1, the XPS plate of use embodiment 1 described insulation plate interface adhesive brushing and warming plate are after the adhesive mortar bonding, and tensile bond strength obviously strengthens.
Embodiment 2
A kind of insulation plate interface adhesive, comprise 1000 gram P.I level 42.5# cement, 1800 gram technical grades, 60~200 order grating quartz sands, trimeric cyanamide/polycarboxylic acid high efficiency water reducing agent X404 that the Italian Ma Bei of 30 grams company produces, the silicane powder hydrophober Sea180 that 20 gram national of the United States starch companies produce, the lignocellulose HM300 that the German CFF of 18 grams company produces, average fiber length is 300um, the methylhydroxypropylcellulose ether MM60001P6 that company of the German SHIN-ETSU HANTOTAI of 20 grams produces, the acrylic acid or the like self-cross linking type binding agent viscopol180 that 15 gram non-chlorine type cement early strength agent technical grade calcium formiates and the Australian Niu Peisi of 800 grams company produce.
The preparation method of above-mentioned insulation plate interface adhesive may further comprise the steps:
1) gets 1000 gram P.I level 42.5# cement, 1800 gram technical grades, 60~200 order grating quartz sands, trimeric cyanamide/polycarboxylic acid high efficiency water reducing agent X404 that the Italian Ma Bei of 30 grams company produces, the silicane powder hydrophober Sea180 that 20 gram national of the United States starch companies produce, lignocellulose HM300, average fiber length that the German CFF of 18 grams company produces are 300um, methylhydroxypropylcellulose ether MM60001P6 that company of the German SHIN-ETSU HANTOTAI of 20 grams produces and 15 gram non-chlorine type cement early strength agent technical grade calcium formiates, thorough mixing is even, obtains component A;
2) get the acrylic acid or the like self-cross linking type binding agent viscopol180 that 2903 gram component A and the Australian Niu Peisi of 1000 grams company produce, add 600 gram water, be mixed with the insulation plate interface adhesive of paste.
The using method of above-mentioned insulation plate interface adhesive and effect: above-mentioned insulation plate interface adhesive brushed or roller coating on styrofoam (EPS and XPS), back to be dried matrix material (adhesive mortar) paste heat-preserving plate, and contrast the performance comparison of its construction interfacial agents and the interfacial agents of not constructing, result such as following table 2 according to its cohesive strength of relevant portion standard detection of JG149-2003 " expansion polyphenyl plate thinly plastered external insulation system of outer wall " and JG158-2004 " glue powder polyphenyl granule exterior wall outer heat preservation system ":
Table 2
Figure S07175143920070724D000061
As can be seen from Table 2, the EPS plate of use embodiment 2 described insulation plate interface adhesive brushings and warming plate are after the adhesive mortar bonding, and tensile bond strength obviously strengthens.
Embodiment 3
A kind of insulation plate interface adhesive, comprise 1000 gram P.I level 42.5# cement, 1600 gram technical grades, 60~200 order grating quartz sands, trimeric cyanamide/polycarboxylic acid high efficiency water reducing agent X404 that the Italian Ma Bei of 20 grams company produces, the silicane powder hydrophober Sea180 that 18 gram national of the United States starch companies produce, the lignocellulose HM300 that the German CFF of 20 grams company produces, average fiber length is 300um, the methylhydroxypropylcellulose ether MM60001P6 that company of the German SHIN-ETSU HANTOTAI of 16 grams produces, the acrylic acid or the like self-cross linking type binding agent viscopol180 that 14 gram non-chlorine type cement early strength agent technical grade calcium formiates and the Australian Niu Peisi of 900 grams company produce.
The preparation method of above-mentioned insulation plate interface adhesive may further comprise the steps:
1) gets 1000 gram P.I level 42.5# cement, 1600 gram technical grades, 60~200 order grating quartz sands, trimeric cyanamide/polycarboxylic acid high efficiency water reducing agent X404 that the Italian Ma Bei of 20 grams company produces, the silicane powder hydrophober Sea180 that 18 gram national of the United States starch companies produce, lignocellulose HM300, average fiber length that the German CFF of 20 grams company produces are 300um, methylhydroxypropylcellulose ether MM60001P6 that company of the German SHIN-ETSU HANTOTAI of 16 grams produces and 14 gram non-chlorine type cement early strength agent technical grade calcium formiates, thorough mixing is even, obtains component A;
2) get the acrylic acid or the like self-cross linking type binding agent viscopol180 that 2688 gram component A and the Australian Niu Peisi of 900 grams company produce, add 550 gram water, be mixed with the insulation plate interface adhesive of paste.
The using method of above-mentioned insulation plate interface adhesive and effect: above-mentioned insulation plate interface adhesive brushed or roller coating on styrofoam (EPS and XPS), back to be dried matrix material (adhesive mortar) paste heat-preserving plate, and contrast the performance comparison of its construction interfacial agents and the interfacial agents of not constructing, result such as following table 3 according to its cohesive strength of relevant portion standard detection of JG149-2003 " expansion polyphenyl plate thinly plastered external insulation system of outer wall " and JG158-2004 " glue powder polyphenyl granule exterior wall outer heat preservation system ":
Table 3
Figure S07175143920070724D000081
As can be seen from Table 3, the EPS plate of use embodiment 3 described insulation plate interface adhesive brushings and warming plate are after the adhesive mortar bonding, and after water-fast experiment in 96 hours and 10 freeze-thawing resistants experiments, tensile bond strength strengthens respectively; The XPS plate that uses embodiment 3 described insulation plate interface adhesive brushings and warming plate after the adhesive mortar bonding, former intensity and respectively after water-fast experiment in 96 hours and 10 freeze-thawing resistants experiments, tensile bond strength is enhancing to some extent all.
Embodiment 4
A kind of insulation plate interface adhesive, comprise 1000 gram P.I level 42.5# cement, 1000 gram technical grades, 60~200 order grating quartz sands, trimeric cyanamide/polycarboxylic acid high efficiency water reducing agent X404 that the Italian Ma Bei of 20 grams company produces, the silicane powder hydrophober Sea180 that 12 gram national of the United States starch companies produce, the lignocellulose HM300 that the German CFF of 10 grams company produces, average fiber length is 300um, the methylhydroxypropylcellulose ether MM60001P6 that company of the German SHIN-ETSU HANTOTAI of 15 grams produces, the acrylic acid or the like self-cross linking type binding agent viscopol180 that 10 gram non-chlorine type cement early strength agent technical grade calcium formiates and the Australian Niu Peisi of 800 grams company produce.
The preparation method of above-mentioned insulation plate interface adhesive may further comprise the steps:
1) gets 1000 gram P.I level 42.5# cement, 1000 gram technical grades, 60~200 order grating quartz sands, trimeric cyanamide/polycarboxylic acid high efficiency water reducing agent X404 that the Italian Ma Bei of 20 grams company produces, the silicane powder hydrophober Sea180 that 12 gram national of the United States starch companies produce, lignocellulose HM300, average fiber length that the German CFF of 10 grams company produces are 300um, methylhydroxypropylcellulose ether MM60001P6 that company of the German SHIN-ETSU HANTOTAI of 15 grams produces and 10 gram non-chlorine type cement early strength agent technical grade calcium formiates, thorough mixing is even, obtains component A;
2) get the acrylic acid or the like self-cross linking type binding agent viscopol180 that 2067 gram component A and the Australian Niu Peisi of 800 grams company produce, add 400 gram water, be mixed with the insulation plate interface adhesive of paste.
The using method of above-mentioned insulation plate interface adhesive and effect: above-mentioned insulation plate interface adhesive brushed or roller coating on styrofoam (EPS and XPS), back to be dried matrix material (adhesive mortar) paste heat-preserving plate, and contrast the performance comparison of its construction interfacial agents and the interfacial agents of not constructing, result such as following table 4 according to its cohesive strength of relevant portion standard detection of JG149-2003 " expansion polyphenyl plate thinly plastered external insulation system of outer wall " and JG158-2004 " glue powder polyphenyl granule exterior wall outer heat preservation system ":
Table 4
Figure S07175143920070724D000101
From above experimental result as can be seen, sticking EPS styrofoam after the construction interfacial agents is as long as paste with common exterior wall is greasy, just can reach relevant standard fully, for difficult XPS styrofoam (all not reaching relevant criterion) of pasting with adhesive mortar, as long as the R type putty stickup of using with exterior wall also can reach relevant standard, this can reduce greatly than pasting cost with adhesive mortar separately, and cohesive strength is higher than the cohesive strength of pasting with adhesive mortar separately.

Claims (8)

1. insulation plate interface adhesive, it is characterized in that comprising 100 parts of suitable positions, quartz sand 100-180 part, high efficiency water reducing agent 2-3 part, silicane powder hydrophober 1-2 part, lignocellulose 0.5-2 part, ether of cellulose 1-2 part, non-chlorine type cement early strength agent 0.8-1.5 part, self-cross linking type binding agent 60-100 part.
2. a kind of insulation plate interface adhesive according to claim 1 is characterized in that described suitable positions is silicate 42.5 cement.
3. a kind of insulation plate interface adhesive according to claim 1 is characterized in that described quartz sand is 60-200 order grating quartz sand.
4. a kind of insulation plate interface adhesive according to claim 1 is characterized in that described high efficiency water reducing agent is trimeric cyanamide/polycarboxylic acid high efficiency water reducing agent.
5. a kind of insulation plate interface adhesive according to claim 1, the average fiber length that it is characterized in that described lignocellulose is 250-500um.
6. a kind of insulation plate interface adhesive according to claim 1 is characterized in that described ether of cellulose is methyl hydroxyethylcellulose ether or methylhydroxypropylcellulose ether.
7. a kind of insulation plate interface adhesive according to claim 1 is characterized in that described self-cross linking type binding agent is an acrylate copolymer class self-cross linking type binding agent.
8. the preparation method of an insulation plate interface adhesive may further comprise the steps:
1) gets 100 parts of suitable positions, 100-180 part quartz sand, 2-3 part high efficiency water reducing agent, 1-2 part silicane powder hydrophober, 0.5-2 part lignocellulose, 1-2 part ether of cellulose and 0.8-1.5 part non-chlorine type cement early strength agent, thorough mixing is even, obtains component A;
2) get the above-mentioned component A for preparing and 80-100 part self-cross linking type binding agent, add suitable quantity of water.
CN2007100751439A 2007-06-20 2007-06-20 Insulation plate interface adhesive and preparation thereof Expired - Fee Related CN101328278B (en)

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN102336554A (en) * 2011-06-25 2012-02-01 南京工业大学 Cement-based lightweight porous thermal insulation material and preparation method thereof

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CN101638563A (en) * 2009-09-08 2010-02-03 安徽省蓝天化工有限公司 Novel polyphenyl plate bond
WO2013063743A1 (en) * 2011-10-31 2013-05-10 Rohm And Haas Company High performance mortar for exterior insulation finish system
CN102603250A (en) * 2012-02-07 2012-07-25 南京红宝丽新材料有限公司 Adhesion agent for treating surface of high inflaming retarding polyurethane insulation board
CN102747785A (en) * 2012-06-27 2012-10-24 深圳市明远建材科技有限公司 Fire-proof thermal insulation sandwich board mounting component for ceiling and mounting method thereof
CN103613312A (en) * 2013-11-08 2014-03-05 安徽省阜南绿原化工有限公司 Low viscosity water reducer for coal water slurry
CN103613339B (en) * 2013-11-21 2016-08-31 湖北鲁邦建材股份有限公司 A kind of cement base mosaic special stickup pointing and preparation, using method
CN105585292A (en) * 2014-11-17 2016-05-18 天津禹神节能保温材料有限公司 Adhesive mortar for external wall heat insulation
CN104496297A (en) * 2014-11-24 2015-04-08 芜湖中民科技建材有限公司 Dry-mixed exterior wall adhesive mortar, and preparation method thereof
CN105271980A (en) * 2015-09-29 2016-01-27 武汉鲁邦建材有限公司 Two-component interface agent and use method thereof
CN107721294A (en) * 2017-09-12 2018-02-23 南丹县住房和城乡建设局 Sandwich benzene board compound wall
CN110183151A (en) * 2019-04-29 2019-08-30 贵州建工安顺建筑工程有限公司 A kind of interfacial agents and its application
CN110256019A (en) * 2019-07-25 2019-09-20 重庆秦恒建筑材料有限公司 A kind of polyphenyl plate bond
CN110713391A (en) * 2019-10-11 2020-01-21 成都新柯力化工科技有限公司 Light cement insulation board for energy-saving building and preparation method

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