CN101263829A - Medicament for fast preventing and controlling malignant aquatic weed and algae and uses thereof - Google Patents
Medicament for fast preventing and controlling malignant aquatic weed and algae and uses thereof Download PDFInfo
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- CN101263829A CN101263829A CNA2008100610863A CN200810061086A CN101263829A CN 101263829 A CN101263829 A CN 101263829A CN A2008100610863 A CNA2008100610863 A CN A2008100610863A CN 200810061086 A CN200810061086 A CN 200810061086A CN 101263829 A CN101263829 A CN 101263829A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000000052 vinegar Substances 0.000 claims abstract description 28
- 235000021419 vinegar Nutrition 0.000 claims abstract description 28
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Abstract
The invention relates to a medicament for fast preventing the malignant float grasses and the water algae and the application thereof, belonging to the pesticide formulation technical field, which is characterized in that the medicament comprises from 40% to 90% of a plant vinegar fluid, from 5% to 35% of an organic acid, and from 1% to 20% of pesticide addition agent, the plant vinegar fluid is either a bamboo vinegar fluid, a wooden vinegar fluid, and (or) grass vinegar fluid, the organic acid is one of or a mixture of more than one of a formic acid, an acetic acid, a propionic acid, a 2-methyl propionic acid, an ethyl acetic acid, a 4-hydroxy ethyl acetic acid, a pentanoic acid, a benzoic acid, a 2,6-hydroxy benzoic acid, a 3-hydroxy-4-methoxy benzoic acid or a 3-methoxy-4-hydroxy benzoic acid. The medicament has the advantages of fast destroying the chlorophyll, stopping the plant to do the photosynthesis, commonly killing the water algae in a half hour and the float grass in three hours by spraying, having low production cost, strong killing capability, wide adaptable temperature range and pH value range. The active component of the invention has the advantages of being the natural-occurring substance, no corrosion, nonirritant, safe use, and reliability, easy biodegradation, and no secondary pollution.
Description
Technical field
The invention belongs to technical field of pesticide preparations, be specially medicament of a kind of quick control malignant aquatic weed and algae and uses thereof.
Background technology
" wawter bloom " (water blooms) is a kind of natural, ecological phenomenon in the fresh water, caused by algae such as blue-green algae, green alga, diatoms." wawter bloom " phenomenon is just on the books on Ancient Times in China history, and when " wawter bloom " took place, it is blue or green that water generally is, and in their very fast disappearances of occurring in nature, do not bring harm to aquatic products animal and human class.After the eutrophication, " wawter bloom " is frequent to be occurred in the fresh water, and area spreads year by year, and the duration prolongs year by year.Taihu Lake, Dian Chi, Chaohu, Hongchehu Lake have " wawter bloom ", even the river that flows, as maximum tributary, the Changjiang river---" wawter bloom " also appears in the section of river, Hankow, downstream, Han River.The maximum harm that " wawter bloom " causes in the fresh water is: the drinking water source is on the hazard, the algae toxin influences human beings'health by food chain, the secondary metabolite MCRST of blue-green algae " wawter bloom " can damage liver, has short cancer effect, directly threatens human beings'health and existence.In addition, the filter of waterworks is by algae " wawter bloom " filling, and " wawter bloom " that swim on the water surface influences view, and unpleasant stink is arranged.When the algae raised growth, these algae can discharge toxin---water bloom, and fish are had toxic action.After the algae mortality, in corrupt, the process that is decomposed, also want dissolved oxygens a large amount of in the consume water, make the serious stench of water body.The main cause that causes the wawter bloom phenomenon still is that the waters is used chemical fertilizer, resident living sewage and industrial wastewater along the line in a large number and entered rivers and lakes in a large number, causes nitrogen in the rivers and lakes, phosphorus, potassium equal size to rise.The freshwater resources of China are just very shortage originally, and the algal tufa of wreaking havoc (wawter bloom) breaks out, and this shortage phenomenon is made the matter worse.How controlling breaking out of algal tufa effectively, allow people enjoy safe freshwater resources and healthy ecotope, is great demand both domestic and external.
In addition, in recent years along with the malignant aquatic weed ecological invasion, in many developing countries, the calamity of malignant aquatic weed has been not only an ecological problem, and becomes serious economic problems.Some countries in Africa and South Asia, the course line that blocks up after weter hyacinth breaks out, obstruction water channel, threat fishery even invasion power station or the like directly cause serious economic loss.In China, only salvage one every year and just spend more than one hundred million units, yet this still can not stop spreading of weter hyacinth and loss that it causes.The ethologist is verified, the invasion of weter hyacinth causes omnibearing, three-dimensional destruction will for the aquatic ecosystem: on the water surface, the layer upon layer of plant of weter hyacinth can exceed the water surface more than 1.5 meters, their block sunlight enter water body, oxygen in a large amount of consume water causes illumination under water and oxygen to lack; And under the water surface, when the rotten plant of dead back enrichment pollutant sinks under water, simultaneously a large amount of pollutants are brought into the bottom, make the end give birth to the ecosystem and suffer extinction.
In the bitter Shanghai that enjoys the weter hyacinth invasion, the numeral of appearance of the city environmental sanitation administrative department shows, ton weter hyacinth surplus Shanghai City had salvaged 260,000 altogether in 2006, cost be set out 3889 person-times and 1092 ship/time ship.Yet everything can not stop in July, 2007 weter hyacinth to stage a comeback former years in advance.Machinery is salvaged and is seemed simple and fast, is but generally acknowledged it is the most expensive improvement method.In Shanghai, about 100 yuans of the cost of one ton of weter hyacinth of every salvaging does not also count shipping charges and landfill expense here, and of paramount importancely is, the speed that machinery is salvaged is unable to catch up with the speed of weter hyacinth growth at all.Every year all will be manually salvaged weter hyacinth on ground such as China Guangdong, Yunnan, Zhejiang, Fujian, and only Wenzhou, Zhejiang and Putian, Fujian artificial salvage expenses in 1999 just is respectively 1,000 ten thousand and 5,000,000 yuan.How many artificial weter hyacinth total costs of salvaging in the whole nation has, and present do not have accurately statistics, but surpass 100,000,000 yuan at least, but also must persevere year after year.
Because the weter hyacinth overgrowing, the Dian Chi has become smelly pool, and the desirable water tourism circuit that builds up the 1970s and 1980s is forced to cancellation; Dian Chi Cao Hai also has 16 kinds of higher plants the sixties, and to only remaining 3 kinds of the nineties in 20th century, the edible seaweed flower waits because of living space forfeiture death; In some areas, weter hyacinth even " involving " social security also, dense plant in blocks provides the natural field of concealing for criminal.Weter hyacinth is not only wreaked havoc China, is also endangering many countries in North America, Asia, Oceania and Africa, allows world's headache for it, becomes the typical case's " representative " for the war of people and biology.The numeral of World Conservation Union shows that in the poorest Africa, the world, seven annual " costs " of paying for the control weter hyacinth of country are 20,000,000 to 50,000,000 dollars.And the effect of weter hyacinth? because the fast development of feed industry since the eighties in 20th century, by basic " discard ", other purposes arouse doubts laden with anxiety especially, are difficult to conviction as the main application of feed for it.The insider points out no matter still calculate from social perspective from economical, ecological, loses more than gain.
Summary of the invention
At the above-mentioned problems in the prior art, the objective of the invention is to design the technical scheme of medicament that a kind of quick control malignant aquatic weed and algae are provided and uses thereof, the production cost cheapness, the power of killing livestock is strong, it is fast to kill algae speed, and Applicable temperature, pH value are in extensive range.
The medicament of described a kind of quick control malignant aquatic weed and algae, it is characterized in that containing plant vinegar liquid 40-90%, organic acid 5-35%, insecticides adjuvant 1-20%, described plant vinegar liquid is a Bamboo vinegar solution, pyroligneous liquor and/or careless vinegar liquid, described organic acid is a formic acid, acetate, propionic acid, 2 Methylpropionic acid, n-butyric acie, 4 hydroxybutyric acid, valeric acid, benzoic acid, 2, the 6-dihydroxy-benzoic acid, one or more mixtures of 3-hydroxyl-4-methoxy benzoic acid or 3-methoxyl group-4-hydroxybenzoic acid, described insecticides adjuvant are DBSA, dodecyl phenyl-hydrogen-sulfate or lignin sulfonic acid.
The medicament of described a kind of quick control malignant aquatic weed and algae is characterized in that described plant vinegar liquid content is 45-85%, is preferably 60-80%.
The medicament of described a kind of quick control malignant aquatic weed and algae is characterized in that described organic acid content is 10-30%, is preferably 15-25%.
The medicament of described a kind of quick control malignant aquatic weed and algae is characterized in that described insecticides adjuvant content is 2-8%, is preferably 3-6%.
The medicament of described a kind of quick control malignant aquatic weed and algae is characterized in that the application of this medicament in the preparation of preparation control malignant aquatic weed and algae.
The medicament of described a kind of quick control malignant aquatic weed and algae is characterized in that the application of this medicament in the preparation of preparation control Eichhornia crassipes, hornwort, water peanut, metasequoia seedling, weter hyacinth, Monochoria vaginalis or straw grass.
The medicament of described a kind of quick control malignant aquatic weed and algae is characterized in that the application of this medicament in preparation control industrial circulating water or the agent of cooling water bactericidal/algicidal.
Above-mentioned medicament can also be used for the algae that kills of swimming pool, landscape water and indoor and outdoor fountain.
Described plant vinegar liquid is the aqueous material of brown that is condensed at normal temperatures by the gas that collection after vegetable material and the industrial wood waste pyrolysis thereof obtains, existing plant vinegar liquid mainly contains Bamboo vinegar solution, pyroligneous liquor and careless vinegar liquid, Bamboo vinegar solution is the accessory substance that bamboo surplus material of processing obtains through high temperature pyrolysis, pyroligneous liquor is the accessory substance that wood machining residues and shell obtain through high temperature pyrolysis, and careless vinegar liquid is meant the accessory substance that herbaceous plant, crop stalk and crops husk obtain through high temperature pyrolysis.
The medicament of above-mentioned a kind of quick control malignant aquatic weed and algae, the chlorophyll of energy rapid damage algae and floating pasture and water, stop photosynthesis of plants and kill plants, generally in spraying to algae half an hour, just it can be killed in 3 hours to pasture and water, its production cost cheapness, the power of killing livestock is strong, and algae speed is fast extremely, Applicable temperature, pH value are in extensive range, efficient, long-acting, wide spectrum, low toxicity.Proportion can produce foam more again under the spraying situation, enter and to float in the water body on the top layer, directly kill the top layer algae, be particularly suitable for fixing a point to throw in the zone of assembling in algae, both guaranteed that local higher concentration killed algae and ensures that also the cultivated animals normal life is unaffected, also reduce the whole medication of system, thereby reduce use cost.And active component is a natural materials, non-corrosiveness, and nonirritant, safe and reliable; Easily biological-degradable can not cause secondary pollution, and no emission limit set meets environmental protection standard.
The percentage composition that relates in the present specification unless otherwise indicated is weight percentage.
Embodiment
Now, further specify beneficial effect of the present invention in conjunction with the embodiments of the invention and the test of pesticide effectiveness.
Embodiment 1: input 380kg Bamboo vinegar solution, 100kg formic acid, 20kg DBSA are stirred into final products in the 500L reactor.
Embodiment 2: drop into the 350kg pyroligneous liquor in the 500L reactor, add 80kg acetate, 2kg benzoic acid, 2kg 2,6-dihydroxy-benzoic acid, 2kg 3-hydroxyl-4-methoxy benzoic acid and 2kg 3-methoxyl group-4-hydroxybenzoic acid add the 20kg DBSA again and are stirred into final products after the stirring and dissolving.
Embodiment 3:
In the 500L reactor, drop into 320kg grass vinegar liquid, add 60kg acetate, add the 20kg DBSA after the stirring and dissolving again and be stirred into final products.
Embodiment 4: drop into 200kg Bamboo vinegar solution, 220kg pyroligneous liquor in the 500L reactor, add 10kg benzoic acid, 2,10kg 6-dihydroxy-benzoic acid, 10kg 3-hydroxyl-4-methoxy benzoic acid and 10kg 3-methoxyl group-4-hydroxybenzoic acid, add 40kg dodecyl phenyl-hydrogen-sulfate after the stirring and dissolving again, be stirred into final products.
Embodiment 5: drop into 200kg Bamboo vinegar solution, 120kg pyroligneous liquor, 120kg grass vinegar liquid in the 500L reactor, add 10kg benzoic acid, 2,10kg 6-dihydroxy-benzoic acid, 10kg 3-hydroxyl-4-methoxy benzoic acid and 10kg 3-methoxyl group-4-hydroxybenzoic acid, add the 20kg lignin sulfonic acid after the stirring and dissolving again, be stirred into final products.
Embodiment 6: drop into 100kg Bamboo vinegar solution, 110kg pyroligneous liquor, 100kg grass vinegar liquid in the 500L reactor, add formic acid, acetate, propionic acid, 2 Methylpropionic acid, n-butyric acie, 4 hydroxybutyric acid, each 10kg of valeric acid, add the 20kg lignin sulfonic acid after the stirring and dissolving again, be stirred into final products.
The control efficiency of above-mentioned medicament below is described by test.
Table 1. embodiment 1-6 is to the algae killing effect (with organic acid concentration) of microcystic aeruginosa
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝240.4546+59.2918lnC | 0.9826 | 0.0174 | 0.040 |
| Embodiment 2 | Y＝142.6744+29.8120lnC | 0.9953 | 0.0004 | 0.045 |
| Embodiment 3 | Y＝175.1437+38.7707lnC | 0.9459 | 0.0150 | 0.040 |
| Embodiment 4 | Y＝143.8634+25.6412lnC | 0.9765 | 0.0002 | 0.026 |
| Embodiment 5 | Y＝171.2401+24.5297lnC | 0.9214 | 0.0786 | 0.0071 |
| Embodiment 6 | Y＝175.8428+40.8052lnC | 0.9518 | 0.0482 | 0.046 |
Table 2. embodiment 1-6 is to the algae killing effect (with organic acid concentration) of wawter bloom Microcystis aeruginosa
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝112.0709+22.8086lnC | 0.9820 | 0.0005 | 0.066 |
| Embodiment 2 | Y＝122.5054+17.6147lnC | 0.9023 | 0.0054 | 0.016 |
| Embodiment 3 | Y＝119.6202+18.1192lnC | 0.9721 | 0.0001 | 0.021 |
| Embodiment 4 | Y＝108.9595+16.4025lnC | 0.9725 | 0.0054 | 0.028 |
| Embodiment 5 | Y＝168.2690+25.1239lnC | 0.9886 | 0.0114 | 0.0090 |
| Embodiment 6 | Y＝156.9457+21.9519lnC | 0.9013 | 0.0367 | 0.0077 |
Table 3. embodiment 1-6 is to the algae killing effect (with organic acid concentration) of wawter bloom anabena
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝194.0203+35.9195lnC | 0.9856 | 0.0144 | 0.018 |
| Embodiment 2 | Y＝134.5779+32.4152lnC | 0.9778 | 0.0040 | 0.074 |
| Embodiment 3 | Y＝310.0035+65.5633lnC | 0.9391 | 0.0609 | 0.019 |
| Embodiment 4 | Y＝190.5732+35.8029lnC | 0.9564 | 0.0436 | 0.020 |
| Embodiment 5 | Y＝142.7530+23.2602lnC | 0.9737 | 0.0002 | 0.018 |
| Embodiment 6 | Y＝118.4047+22.0486lnC | 0.9873 | 0.0002 | 0.045 |
Table 4. embodiment 1-6 is to the algae killing effect (with organic acid concentration) of chlorella vulgaris
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝130.4102+36.4962lnC | 0.9526 | 0.0033 | 0.11 |
| Embodiment 2 | Y＝81.2889+50.9684lnC | 0.9552 | 0.0113 | 0.54 |
| Embodiment 3 | Y＝100.5905+40.7706lnC | 0.9829 | 0.0004 | 0.29 |
| Embodiment 4 | Y＝62.1245+9.7936lnC | 0.9272 | 0.0728 | 0.29 |
| Embodiment 5 | Y＝94.9832+21.4631lnC | 0.9619 | 0.0001 | 0.12 |
| Embodiment 6 | Y＝93.7971+21.2880lnC | 0.9394 | 0.0178 | 0.13 |
Table 5. embodiment 1-6 is to the algae killing effect (with organic acid concentration) of chlorella pyrenoidosa
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝92.3495+31.9602lnC | 0.9953 | 0.0047 | 0.27 |
| Embodiment 2 | Y＝103.6900+30.0124lnC | 0.9592 | 0.0098 | 0.167 |
| Embodiment 3 | Y＝115.3032+32.4528lnC | 0.9787 | 0.0037 | 0.13 |
| Embodiment 4 | Y＝76.0510+3.4518lnC | 0.9803 | 0.0033 | 0.45 |
| Embodiment 5 | Y＝135.4071+53.2803lnC | 0.9910 | 0.0090 | 0.20 |
| Embodiment 6 | Y＝119.9289+55.8119lnC | 0.9355 | 0.0195 | 0.29 |
Table 6. embodiment 1-6 is to the algae killing effect (with organic acid concentration) of scenedesmus obliquus
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝573.9711+33.8673lnC | 0.9732 | 0.0053 | 0.21 |
| Embodiment 2 | Y＝388.9893+20.3329lnC | 0.983898 | 0.0000 | 0.0574 |
| Embodiment 3 | Y＝383.1540+19.8497lnC | 0.976077 | 0.0000 | 0.0514 |
| Embodiment 4 | Y＝418.0351+23.9411lnC | 0.963361 | 0.0001 | 0.2108 |
| Embodiment 5 | Y＝398.5677+21.8769lnC | 0.969771 | 0.0001 | 0.1203 |
| Embodiment 6 | Y＝344.5758+18.0554lnC | 0.995072 | 0.0000 | 0.0821 |
Table 7. embodiment 1-6 is to the algae killing effect (with organic acid concentration) of four tail grid algaes
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝310.4316+16.6759lnC | 0.950402 | 0.0003 | 0.1650 |
| Embodiment 2 | Y＝314.4908+15.9762lnC | 0.979331 | 0.0000 | 0.0645 |
| Embodiment 3 | Y＝350.2116+18.5845lnC | 0.941866 | 0.0005 | 0.0965 |
| Embodiment 4 | Y＝292.6050+15.5421lnC | 0.916063 | 0.0037 | 0.166 |
| Embodiment 5 | Y＝343.1139+18.1878lnC | 0.961209 | 0.0001 | 0.1002 |
| Embodiment 6 | Y＝265.3255+16.5852lnC | 0.957274 | 0.0002 | 0.2991 |
Table 8. embodiment 1-6 is to the algae killing effect (with organic acid concentration) of goat's horn crescent moon algae
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝349.0293+18.9374lnC | 0.993019 | 0.0000 | 0.1388 |
| Embodiment 2 | Y＝356.1705+18.9716lnC | 0.968840 | 0.0001 | 0.0980 |
| Embodiment 3 | Y＝406.6861+22.5699lnC | 0.946898 | 0.0004 | 0.1370 |
| Embodiment 4 | Y＝312.8848+7.3793lnC | 0.970032 | 0.0001 | 0.038 |
| Embodiment 5 | Y＝295.9284+16.2547lnC | 0.985494 | 0.0000 | 0.2687 |
| Embodiment 6 | Y＝381.6456+20.1356lnC | 0.957584 | 0.0002 | 0.0703 |
Show the 1-8 data as seen: embodiment 1-6 mainly comprises microcystic aeruginosa to blue-green algae, the wawter bloom Microcystis aeruginosa, wawter bloom anabena and green alga mainly comprise chlorella vulgaris, chlorella pyrenoidosa, scenedesmus obliquus, four tail grid algaes and goat's horn crescent moon algae all have higher killing effect, wherein the activity to blue-green algae is higher than the activity of green alga more than 10 times, like this, when water body environment uses, the effect of preferentially killing blue-green algae earlier will be produced, can not only solve or alleviate algae and water " wawter bloom " fast, more can effectively preventing blue-green algae " wawter bloom ", make the water body clear that becomes at short notice, enhance the transparency and improve the appreciative value of water body.
Table 9. embodiment 1-6 is to the killing effect (with organic acid concentration) of Eichhornia crassipes
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝260.0843+16.7853lnC | 0.986181 | 0.0000 | 3.6676 |
| Embodiment 2 | Y＝277.7312+16.7859lnC | 0.984982 | 0.0000 | 1.2824 |
| Embodiment 3 | Y＝298.3055+20.2028lnC | 0.940383 | 0.0005 | 4.5945 |
| Embodiment 4 | Y＝270.7499+17.2207lnC | 0.982230 | 0.0001 | 2.7092 |
| Embodiment 5 | Y＝285.0791+17.2241lnC | 0.987153 | 0.0000 | 1.1820 |
| Embodiment 6 | Y＝301.5527+18.7988lnC | 0.976195 | 0.0001 | 1.5437 |
Table 10. embodiment 1-6 is to the killing effect (with organic acid concentration) of hornwort
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝262.9326+15.4626lnC | 0.963158 | 0.0001 | 1.0457 |
| Embodiment 2 | Y＝263.0202+17.5680lnC | 0.961324 | 0.0001 | 5.4197 |
| Embodiment 3 | Y＝273.8510+18.8207lnC | 0.949798 | 0.0003 | 6.8321 |
| Embodiment 4 | Y＝298.4128+18.7910lnC | 0.966273 | 0.0001 | 1.8143 |
| Embodiment 5 | Y＝246.4072+15.4382lnC | 0.944927 | 0.0004 | 2.9842 |
| Embodiment 6 | Y＝235.4362+14.8351lnC | 0.981772 | 0.0000 | 3.7273 |
Table 11. embodiment 1-6 is to the killing effect (with organic acid concentration) of water peanut
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝250.0541+15.6086lnC | 0.938220 | 0.0006 | 2.7145 |
| Embodiment 2 | Y＝261.6705+16.4259lnC | 0.994827 | 0.0001 | 2.5323 |
| Embodiment 3 | Y＝322.0717+21.2218lnC | 0.929187 | 0.0008 | 2.7051 |
| Embodiment 4 | Y＝235.7486+14.5651lnC | 0.984526 | 0.0000 | 2.8936 |
| Embodiment 5 | Y＝286.3759+19.4915lnC | 0.987547 | 0.0000 | 5.4107 |
| Embodiment 6 | Y＝319.8110+19.8768lnC | 0.995338 | 0.0000 | 1.2729 |
Table 12. embodiment 1-6 is to the killing effect (with organic acid concentration) of metasequoia seedling
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝395.9729+25.4546lnC | 0.985289 | 0.0000 | 1.2508 |
| Embodiment 2 | Y＝203.1894+12.9205lnC | 0.950049 | 0.0003 | 7.0936 |
| Embodiment 3 | Y＝330.7576+22.4051lnC | 0.993761 | 0.0000 | 3.6130 |
| Embodiment 4 | Y＝333.5051+21.4950lnC | 0.992666 | 0.0000 | 1.8704 |
| Embodiment 5 | Y＝327.0668+20.6656lnC | 0.985956 | 0.0000 | 1.5043 |
| Embodiment 6 | Y＝249.8208+16.7098lnC | 0.956330 | 0.0002 | 6.4058 |
Table 13. embodiment 1-6 is to the killing effect (with organic acid concentration) of Monochoria vaginalis
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝237.9144+14.5812lnC | 0.964718 | 0.0001 | 2.5296 |
| Embodiment 2 | Y＝322.8403+20.1697lnC | 0.992857 | 0.0000 | 1.3341 |
| Embodiment 3 | Y＝218.0114+14.0412lnC | 0.979348 | 0.0000 | 6.3592 |
| Embodiment 4 | Y＝251.4146+15.3988lnC | 0.957075 | 0.0002 | 2.0868 |
| Embodiment 5 | Y＝186.3047+10.9387lnC | 0.940965 | 0.0005 | 3.8757 |
| Embodiment 6 | Y＝263.7313+16.6717lnC | 0.920345 | 0.0033 | 2.7061 |
Table 14. embodiment 1-6 is to the killing effect (with organic acid concentration) of straw grass
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝216.6119+13.6233lnC | 0.898764 | 0.0059 | 4.8822 |
| Embodiment 2 | Y＝212.7739+13.4085lnC | 0.931239 | 0.0023 | 5.3436 |
| Embodiment 3 | Y＝316.5819+19.8142lnC | 0.991376 | 0.0000 | 1.4354 |
| Embodiment 4 | Y＝279.0912+19.0496lnC | 0.946517 | 0.0004 | 5.9863 |
| Embodiment 5 | Y＝348.3796+22.0997lnC | 0.979800 | 0.0000 | 1.3689 |
| Embodiment 6 | Y＝220.7264+13.8266lnC | 0.968565 | 0.0001 | 4.3398 |
Table 15. embodiment 1-6 is to the killing effect (with organic acid concentration) of rice grass
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝243.3601+15.8584lnC | 0.967512 | 0.0001 | 5.0662 |
| Embodiment 2 | Y＝234.7994+14.2789lnC | 0.975497 | 0.0001 | 2.3949 |
| Embodiment 3 | Y＝254.7208+15.5312lnC | 0.917526 | 0.0013 | 1.89 |
| Embodiment 4 | Y＝250.7244+15.3633lnC | 0.966227 | 0.0001 | 2.1176 |
| Embodiment 5 | Y＝235.8025+15.4689lnC | 0.939113 | 0.0005 | 6.0748 |
| Embodiment 6 | Y＝303.9603+19.3065lnC | 0.969571 | 0.0001 | 1.9374 |
Table 16. embodiment 1-6 is to trefoil killing effect (with organic acid concentration)
| Embodiment | Regression equation | Correlation coefficient (r) | Significance level (p) | EC 50(mg/L) |
| Embodiment 1 | Y＝247.6181+15.7961lnC | 0.927774 | 0.0009 | 3.6875 |
| Embodiment 2 | Y＝271.6165+17.7062lnC | 0.996273 | 0.0000 | 3.6663 |
| Embodiment 3 | Y＝251.5796+16.8035lnC | 0.978822 | 0.0000 | 6.1670 |
| Embodiment 4 | Y＝272.4998+17.4732lnC | 0.985743 | 0.0000 | 2.9450 |
| Embodiment 5 | Y＝258.4959+16.4162lnC | 0.991447 | 0.0000 | 3.0492 |
| Embodiment 6 | Y＝276.4001+17.9810lnC | 0.995414 | 0.0000 | 3.4022 |
Show the 9-16 data as seen: embodiment 1-6 comprises mainly that to harmful pasture and water Eichhornia crassipes, hornwort, water peanut, metasequoia seedling, Monochoria vaginalis, straw grass, rice grass and clover all have killing effect preferably, has good preventive and therapeutic effect for the overgrowing that prevents and treats above-mentioned harmful pasture and water.
Claims (7)
1, the medicament of a kind of quick control malignant aquatic weed and algae, it is characterized in that containing plant vinegar liquid 40-90%, organic acid 5-35%, insecticides adjuvant 1-20%, described plant vinegar liquid is a Bamboo vinegar solution, pyroligneous liquor and/or careless vinegar liquid, described organic acid is a formic acid, acetate, propionic acid, 2 Methylpropionic acid, n-butyric acie, 4 hydroxybutyric acid, valeric acid, benzoic acid, 2, the 6-dihydroxy-benzoic acid, one or more mixtures of 3-hydroxyl-4-methoxy benzoic acid or 3-methoxyl group-4-hydroxybenzoic acid, described insecticides adjuvant are DBSA, dodecyl phenyl-hydrogen-sulfate or lignin sulfonic acid.
2, the medicament of a kind of quick control malignant aquatic weed as claimed in claim 1 and algae is characterized in that described plant vinegar liquid content is 45-85%, is preferably 60-80%.
3, the medicament of a kind of quick control malignant aquatic weed as claimed in claim 1 and algae is characterized in that described organic acid content is 10-30%, is preferably 15-25%.
4, the medicament of a kind of quick control malignant aquatic weed as claimed in claim 1 and algae is characterized in that described insecticides adjuvant content is 2-8%, is preferably 3-6%.
5, the medicament of a kind of quick control malignant aquatic weed as claimed in claim 1 and algae is characterized in that the application of this medicament in the preparation of preparation control malignant aquatic weed and algae.
6, the medicament of a kind of quick control malignant aquatic weed as claimed in claim 1 and algae is characterized in that the application of this medicament in the preparation of preparation control Eichhornia crassipes, hornwort, water peanut, metasequoia seedling, weter hyacinth, Monochoria vaginalis or straw grass.
7, the medicament of a kind of quick control malignant aquatic weed as claimed in claim 1 and algae is characterized in that the application of this medicament in preparation control industrial circulating water or the agent of cooling water bactericidal/algicidal.
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Application publication date: 20080917 Assignee: Hangzhou Zhengwei Kunling Ecological Technology Co.,Ltd. Assignor: ZHEJIANG A & F University Contract record no.: X2024980007504 Denomination of invention: A rapid control agent for malignant aquatic plants and algae and its application Granted publication date: 20100922 License type: Common License Record date: 20240619 |
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