A kind of high-strength abrasion-proof cast steel lining board and manufacture method thereof
Technical field
The present invention is a kind of high-strength abrasion-proof cast steel lining board and manufacture method thereof, belongs to technical field of metal wear.
Background technology
Industries such as metallurgical mine, cement building material, electric power, chemical fertilizer, coal, chemical industry are extensive use of the ball mill grinding material, and wherein liner plate is the main expendable part in the ball mill, and its quality had both influenced the grinding machine production operational availability, also ectocrine abrasive lapping cost.Lining board of grinder material commonly used mainly contains two big classes, one class is a Hadfield Steel, its toughness height, original hardness is low, and the work hardening of main dependence austenite improves its hardness in the use, after abundant work hardening, its hardness is brought up to HB400-500 by original HB200, and use obtains good result of use under the high impact loads condition, but uses under medium and small shock load condition, fully work hardening of austenite, it wears no resistance.Another kind of is alloy white cast iron, its hardness height, and toughness is low, and result of use is good under no shock load, but is prone to cracked phenomenon having under the shock load condition to use.In addition, in recent years because the develop rapidly of China's Iron And Steel Industry, cause steel scrap and iron alloy supply day to be becoming tight, price also rises steadily, therefore high mangaenese steel and alloy white cast iron production cost constantly rise, developing low-cost, high performance lining board of grinder material satisfy vast ball mill user's normal service requirements as early as possible, are extremely important undoubtedly.Chinese invention patent CN1080327 discloses a kind of low-alloyed ball mill wearing liner plate and manufacturing process, the content that it is characterized in that each material composition (weight %) is: C0.35~0.5%, Cr0.8~1.5%, Si0.6~1.2%, Mo0.3~0.5%, Mn0.6~1.4%, Cu0.5~1%, 1#RE0.01~0.1%, surplus is Fe.The principal feature of this invention is to adopt the rotten processing of 1#RE simultaneously and improve Cu content, improved the modification effect of 1#RE, played crystal grain thinning, purify crystal boundary, improved the effect of hardening capacity and tissue and performance uniformity, owing to contain expensive molybdenum and copper, therefore, production cost is higher.In addition, only add rare earth, purification and thinning effect are not so good, so this invention lining material toughness is lower, impelling strength α
k>18J/cm
2Chinese invention patent CN1165203 also discloses a kind of multicomponent alloy abrasion-resistant anti-corrosion high-ductility liner plate and manufacture method thereof, the chemical ingredients of liner plate is (% meter by weight) C=0.45-0.65, Si=0.5-1.1, Mn=1.6-3.0, Cr=0.5-1.2, B=0.001-0.0025, Ti=0.1-0.2, P≤0.04, S≤0.04, Re=0.1, surplus is Fe.Cast liner plate by this composition, air carries out residual heat insulation 16-24h to 230-330 ℃ after 780-830 ℃ of annealing reheat is incubated certain hour to 820-860 ℃, 250-270 ℃, 4~6h tempering.This liner plate carbon content is higher, and toughness is low, and fragility is big, and in addition, the boron add-on is very little, and is unfavorable to improving liner plate hardening capacity, in addition, the thermal treatment process complexity, the cycle is long, the energy consumption height.Chinese invention patent CN101054652 also discloses a kind of ball grinding machine lining board chemical ingredients (weight percent): C0.6-0.8%, Si0.3-0.8%, Mn0.3-0.8%, Cr2.0-4.5%, Ni0.2-2.0%, Mo0.1-0.8%, S<0.04%, P<0.04%, surplus are Fe.Its manufacturing process is: ball grinding machine lining board is heated to 860-960 ℃, be incubated 2-3 hour, quench then and cool off in the entry, its temperature is descended fast, when workpiece surface temperature drops to 580-680 ℃, from water, take out, the air hollow in forced convection is chilled to room temperature again, carry out 480-520 ℃ of tempering afterwards, naturally cooling gets product.The ball grinding machine lining board of this invention has very high hardness, intensity, and hardening capacity is better, the wear resistance height, but contain expensive molybdenum and nickel, its cost is 1.5 times of high mangaenese steel.And carbon content is higher, and is easy to crack during shrend.
Summary of the invention
The object of the invention provides a kind of chemical ingredients and manufacture method thereof of high-strength abrasion-proof cast steel lining board.Hardness of the present invention and impelling strength are between high mangaenese steel and alloy white cast iron.By the reasonable component design, under the cold quenching condition, obtain lath martensite and add the minimal residue austenite, this martensitic steel has good impelling strength and higher hardness, and its hardness is 50-55HRC; Impelling strength α
k=60-80J/cm
2, tensile strength sigma
b=1450-1600MPa.Its microstructure is: lath martensite+minimal residue austenite, retained austenite thickness is less than 80nm.The main starting material of the present invention have steel cuttings and a small amount of cheap iron alloy, and cost is lower than high mangaenese steel, and wear resistance is better than high mangaenese steel under medium impact load.
Purpose of the present invention can realize by following measure:
High-strength abrasion-proof cast steel lining board of the present invention is characterized in that, the chemical composition weight percent of liner plate is: 0.25-0.45C, 1.0-1.8Si, 1.0-2.0Mn, 0.8-1.5Cr, 0.003-0.008B, 0.02-0.08Al, 0.04-0.15Ti, 0.02-0.10La, 0.02-0.10Ce, 0.02-0.08Ba, 0.02-0.10Ca, all the other are Fe and inevitable trace impurity, and 3.5<Si+Mn+Cr<4.5,0.05<La+Ce<0.18.
Liner plate electrosmelting of the present invention, its manufacturing technology steps is:
1. with steel cuttings, carburelant and the fusing of ferrochrome Hybrid Heating, the molten clear back of molten steel adds ferrosilicon and ferromanganese;
2. the stokehold is adjusted to branch and temperature is risen to 1610~1640 ℃ after qualified, adds aluminium deoxidation earlier, then adds the composite deoxidant of siliceous, calcium, barium and aluminium, comes out of the stove subsequently;
3. ferrotianium, ferro-boron and mixed rare earth of lanthanum and cerium are crushed to the fritter of granularity, after oven dry below 200 ℃, place the casting ladle bottom, with the method that pours in the bag molten steel is carried out composite inoculating and handle less than 12mm;
4. use the sand mold casting liner plate, 1500~1540 ℃ of teeming temperatures;
5. pour into a mould the air cooling liner plate of unpacking after 2~6 hours, spruing, cleaning undesirable root, overlap, burr;
6. liner plate quenches at 880~950 ℃, soaking time 3~6 hours, and water-cooled then, tempering ℃ is carried out in reheat to 180~240, soaking time 4~10 hours, stove is chilled to less than air cooling after 150 ℃.
Effect of the present invention:
1. with the liner plate of the present invention's manufacturing, production technique is easy, and its microstructure is: lath martensite+minimal residue austenite, retained austenite thickness is less than 80nm.Liner plate hardness is 50-55HRC; Impelling strength α
k=65-80J/em
2, tensile strength sigma
b=1450-1600MPa has good wear resistance.
2. the main starting material of liner plate of the present invention have steel cuttings and a small amount of cheap iron alloy, do not contain expensive alloying element, and alloy addition is less, has lower production cost, and cost is than the low 8-15% of high mangaenese steel.
3. liner plate of the present invention is after the composite deoxidant processing and titaniferous, boron and the processing of mixed rare earth of lanthanum and cerium composite inoculating of siliceous, calcium, barium and aluminium, and inclusion is few, and fluidity molten steel is good, has good cast form performance.
4. improve more than 2.0 times than Mn13 high manganese steel lining plate the work-ing life of liner plate of the present invention.
Embodiment
The invention will be further described below in conjunction with embodiment:
Embodiment 1:
With 500 kilograms of medium-frequency induction furnace melting molten steel, its manufacturing technology steps is:
1. with steel cuttings, carburelant and the fusing of ferrochrome Hybrid Heating, the molten clear back of molten steel adds ferrosilicon and ferromanganese;
2. the stokehold is adjusted to branch and temperature is risen to 1634 ℃ after qualified, adds aluminium deoxidation earlier, then adds the composite deoxidant of siliceous, calcium, barium and aluminium, comes out of the stove subsequently;
3. ferrotianium, ferro-boron and mixed rare earth of lanthanum and cerium are crushed to the fritter of granularity, after oven dry below 200 ℃, place the casting ladle bottom, with the method that pours in the bag molten steel is carried out composite inoculating and handle less than 12mm;
4. use the sand mold casting liner plate, 1528 ℃ of teeming temperatures;
5. pour into a mould the air cooling liner plate of unpacking after 4 hours, spruing, cleaning undesirable root, overlap, burr;
6. liner plate quenches at 920 ℃, soaking time 4 hours, and water-cooled then, reheat to 210 ℃ carries out tempering, soaking time 8 hours, stove is chilled to less than air cooling after 150 ℃.The chemical ingredients of liner plate of the present invention sees Table 1, and the liner plate mechanical property sees Table 2.
Table 1 liner plate chemical ingredients
Element |
C |
Si |
Mn |
Cr |
B |
Al |
Ti |
Composition |
0.41 |
1.38 |
1.70 |
1.09 |
0.004 |
0.052 |
0.114 |
Element |
La |
Ce |
Ba |
Ca |
S |
P |
Fe |
Composition |
0.037 |
0.066 |
0.039 |
0.046 |
0.018 |
0.031 |
Surplus |
Table 2 liner plate mechanical property
Hardness HRC |
Impelling strength J/cm
2 |
Tensile strength MPa |
53.7 |
71.5 |
1553.1 |
Embodiment 2:
With 1000 kilograms of medium-frequency induction furnace melting molten steel, its manufacturing technology steps is:
1. with steel cuttings, carburelant and the fusing of ferrochrome Hybrid Heating, the molten clear back of molten steel adds ferrosilicon and ferromanganese;
2. the stokehold is adjusted to branch and temperature is risen to 1624 ℃ after qualified, adds aluminium deoxidation earlier, then adds the composite deoxidant of siliceous, calcium, barium and aluminium, comes out of the stove subsequently;
3. ferrotianium, ferro-boron and mixed rare earth of lanthanum and cerium are crushed to the fritter of granularity, after oven dry below 200 ℃, place the casting ladle bottom, with the method that pours in the bag molten steel is carried out composite inoculating and handle less than 12mm;
4. use the sand mold casting liner plate, 1517 ℃ of teeming temperatures;
5. pour into a mould the air cooling liner plate of unpacking after 3 hours, spruing, cleaning undesirable root, overlap, burr;
6. liner plate quenches at 895 ℃, soaking time 5 hours, and water-cooled then, reheat to 195 ℃ carries out tempering, soaking time 6 hours, stove is chilled to less than air cooling after 150 ℃.The chemical ingredients of liner plate of the present invention sees Table 3, and the liner plate mechanical property sees Table 4.
Table 3 liner plate chemical ingredients
Element |
C |
Si |
Mn |
Cr |
B |
Al |
Ti |
Composition |
0.31 |
1.64 |
1.39 |
1.20 |
0.005 |
0.039 |
0.088 |
Element |
La |
Ce |
Ba |
Ca |
S |
P |
Fe |
Composition |
0.068 |
0.071 |
0.069 |
0.034 |
0.020 |
0.035 |
Surplus |
Table 4 liner plate mechanical property
Hardness HRC |
Impelling strength J/cm
2 |
Tensile strength MPa |
51.3 |
77.4 |
1494.8 |
Embodiment 3:
With 750 kilograms of medium-frequency induction furnace melting molten steel, its manufacturing technology steps is:
1. with steel cuttings, carburelant and the fusing of ferrochrome Hybrid Heating, the molten clear back of molten steel adds ferrosilicon and ferromanganese;
2. the stokehold is adjusted to branch and temperature is risen to 1638 ℃ after qualified, adds aluminium deoxidation earlier, then adds the composite deoxidant of siliceous, calcium, barium and aluminium, comes out of the stove subsequently;
3. ferrotianium, ferro-boron and mixed rare earth of lanthanum and cerium are crushed to the fritter of granularity, after oven dry below 200 ℃, place the casting ladle bottom, with the method that pours in the bag molten steel is carried out composite inoculating and handle less than 12mm;
4. use the sand mold casting liner plate, 1536 ℃ of teeming temperatures;
5. pour into a mould the air cooling liner plate of unpacking after 6 hours, spruing, cleaning undesirable root, overlap, burr;
6. liner plate quenches at 930 ℃, soaking time 4 hours, and water-cooled then, reheat to 215 ℃ carries out tempering, soaking time 9 hours, stove is chilled to less than air cooling after 150 ℃.The chemical ingredients of liner plate of the present invention sees Table 5, and the liner plate mechanical property sees Table 6.
Table 5 liner plate chemical ingredients
Element |
C |
Si |
Mn |
Cr |
B |
Al |
Ti |
Composition |
0.25 |
1.04 |
1.93 |
0.87 |
0.007 |
0.147 |
0.049 |
Element |
La |
Ce |
Ba |
Ca |
S |
P |
Fe |
Composition |
0.020 |
0.094 |
0.075 |
0.022 |
0.018 |
0.037 |
Surplus |
Table 6 liner plate mechanical property
Hardness HRC |
Impelling strength J/cm
2 |
Tensile strength MPa |
50.8 |
79.1 |
1467.3 |
Get the liner plate of the present invention use of installing, the result is as follows:
Grind iron ore on working conditions φ 2.7m * 3.6m ball mill, mill speed 22.4rpm, iron ore ore pulp pH:4.5~6.5, ore hardness f:14~18, maximum ball radius<120mm goes into ore grinding stone granularity 0~40mm.Test with machine with high manganese steel lining plate, grinding machine work is after 6 months, the abrasion loss of high manganese steel lining plate on average reaches 29.6mm, and the greatest wear amount of liner plate of the present invention only is 9.1mm, wear liner of the present invention is even, do not have in the use peel off, phenomenon of rupture occurs, its wear resistance improves more than 2 times than Mn13 high manganese steel lining plate.In addition, liner plate of the present invention is used to grind cement clinker on φ 3.5m * 8.1m ball mill, and improve 2.5 times or more than high manganese steel lining plate work-ing life.
Liner plate of the present invention is main raw material with the steel cuttings, add an amount of Si, Mn and Cr alloying element in addition, also add elements such as a small amount of B, Al, Ti, La, Ce, Ca and Ba, do not contain alloying elements such as expensive nickel, molybdenum, copper, vanadium, the starting material source is abundant, cheap, liner plate of the present invention has lower production cost, than the low 8-15% of high manganese steel lining plate, and long service life, improve more than 2 times than Mn13 high manganese steel lining plate.Liner plate of the present invention is safe in utilization, reliable, and the market competitiveness is strong, applies to have remarkable economical and social benefit.