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CN101170076A - Method for manufacturing organic electroluminescent device and image display system - Google Patents

Method for manufacturing organic electroluminescent device and image display system Download PDF

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Publication number
CN101170076A
CN101170076A CNA2006101377373A CN200610137737A CN101170076A CN 101170076 A CN101170076 A CN 101170076A CN A2006101377373 A CNA2006101377373 A CN A2006101377373A CN 200610137737 A CN200610137737 A CN 200610137737A CN 101170076 A CN101170076 A CN 101170076A
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organic electroluminescent
polysilicon layer
layer
manufacture method
electroluminescent element
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CN101170076B (en
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詹川逸
刘俊彦
曾章和
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Chi Mei Optoelectronics Corp
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Toppoly Optoelectronics Corp
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Abstract

A method for manufacturing an organic electroluminescent device comprises: providing a substrate, wherein the substrate comprises a first element area and a second element area; forming an amorphous silicon layer over the substrate; forming a protective film over a portion of the amorphous silicon layer in the second device region; performing excimer laser annealing process on the amorphous silicon layer to convert the amorphous silicon layer into a polycrystalline silicon layer; removing the protective film; and patterning the polysilicon layer to form a first patterned polysilicon layer in the first device region and a second patterned polysilicon layer in the second device region, wherein the grain size of the first patterned polysilicon layer is larger than that of the second patterned polysilicon layer, thereby forming the organic electroluminescent device.

Description

有机电激发光元件的制造方法及影像显示系统 Manufacturing method of organic electroluminescent element and image display system

技术领域 technical field

本发明涉及一种电激发光元件的制造方法和采用该电激发光元件的影像显示系统,且特别是涉及一种薄膜晶体管的制造方法和采用该薄膜晶体管的影像显示系统。The invention relates to a manufacturing method of an electroluminescent element and an image display system using the electroluminescent element, and in particular to a manufacturing method of a thin film transistor and an image display system using the thin film transistor.

背景技术 Background technique

一般而言,薄膜晶体管主要包括非晶硅薄膜晶体管与多晶硅薄膜晶体管。现有电激发光元件显示器(electroluminescent device display)的阵列基板可以区分为发光区与电路区,而阵列基板的制造方法主要包括:形成薄膜晶体管(thin film transistor;TFT)、形成像素电极、以及形成有机发光二极管。其中,薄膜晶体管的制造工艺通常包括下列步骤:在基板的整个表面上形成缓冲层、多晶硅层、栅极绝缘层、栅极、层间介电层。在薄膜晶体管完成之后,接着形成像素电极,且此像素电极与薄膜晶体管呈电连接。之后,再于发光区上形成透明阳极、有机发光层、以及反射式阴极,而完成电激发光元件的制作。通常,多晶硅薄膜晶体管制造工艺中包含准分子激光退火(excimerlaser anneal;ELA)步骤,以将缓冲层上的非晶硅层转化为多晶硅层,而形成多晶硅薄膜晶体管。Generally speaking, thin film transistors mainly include amorphous silicon thin film transistors and polysilicon thin film transistors. The array substrate of an existing electroluminescent device display (electroluminescent device display) can be divided into a light-emitting area and a circuit area, and the manufacturing method of the array substrate mainly includes: forming a thin film transistor (thin film transistor; TFT), forming a pixel electrode, and forming Organic Light Emitting Diodes. Wherein, the manufacturing process of the thin film transistor generally includes the following steps: forming a buffer layer, a polysilicon layer, a gate insulating layer, a gate, and an interlayer dielectric layer on the entire surface of the substrate. After the thin film transistor is completed, the pixel electrode is then formed, and the pixel electrode is electrically connected to the thin film transistor. Afterwards, a transparent anode, an organic light-emitting layer, and a reflective cathode are formed on the light-emitting area to complete the fabrication of the electroluminescent element. Usually, the polysilicon thin film transistor manufacturing process includes an excimer laser anneal (excimerlaser anneal; ELA) step to convert the amorphous silicon layer on the buffer layer into a polysilicon layer to form a polysilicon thin film transistor.

然而,由于准分子激光退火(excimer laser anneal;ELA)步骤所制作出的薄膜晶体管(例如,用于驱动的薄膜晶体管(driving TFT))具有很大的电子移动率(mobility)变异性,因此会导致每一个子像素的发光亮度皆不一致,而产生颜色不均(Mura)的缺陷。However, since thin film transistors (for example, driving TFTs) produced by the excimer laser annealing (excimer laser anneal; ELA) step have large electron mobility (mobility) variability, there will be As a result, the luminance of each sub-pixel is inconsistent, resulting in the defect of uneven color (Mura).

因此业界亟需一种可以解决上述问题的电激发光元件。Therefore, the industry urgently needs an electroluminescent element that can solve the above-mentioned problems.

发明内容 Contents of the invention

鉴于上述问题,本发明几个优选实施例通过增加保护膜(protection film)的方式,以改善薄膜晶体管间电性差异过大的问题。而且,通过增加保护膜的方式,可以使用较小的通道长度(channel length)而提高开口率。In view of the above problems, several preferred embodiments of the present invention improve the problem of excessive electrical differences between thin film transistors by adding a protection film. Moreover, by increasing the protective film, the aperture ratio can be increased by using a smaller channel length.

本发明优选实施例提供一种有机电激发光元件的制造方法,包括:提供基板,该基板包括第一元件区域与第二元件区域;形成非晶硅层于该基板上方;形成保护膜于该第二元件区域内的部分该非晶硅层上方;对该非晶硅层进行准分子激光退火工艺,以将该非晶硅层转化为多晶硅层;移除该保护膜;以及图案该多晶硅层,以在该第一元件区域形成第一图案化多晶硅层,及在该第二元件区域形成第二图案化多晶硅层,其中该第一图案化多晶硅层的晶粒尺寸大于该第二图案化多晶硅层,藉此形成有机电激发光元件。A preferred embodiment of the present invention provides a method for manufacturing an organic electroluminescent element, comprising: providing a substrate, the substrate including a first element region and a second element region; forming an amorphous silicon layer on the substrate; forming a protective film on the substrate above the portion of the amorphous silicon layer in the second element region; performing an excimer laser annealing process on the amorphous silicon layer to convert the amorphous silicon layer into a polysilicon layer; removing the protective film; and patterning the polysilicon layer , to form a first patterned polysilicon layer in the first element region, and form a second patterned polysilicon layer in the second element region, wherein the grain size of the first patterned polysilicon layer is larger than the second patterned polysilicon layer layer, thereby forming an organic electroluminescence element.

本发明另一优选实施例提供一种有机电激发光元件的制造方法,包括:提供基板,该基板包括第一元件区域与第二元件区域;形成第一、第二图案化非晶硅层于该第一、第二元件区域上方;形成保护膜于该第二图案化非晶硅层上方;以及对该第一、第二图案化非晶硅层进行准分子激光退火工艺,以将该第一、第二图案化非晶硅层转化为第一、第二图案化多晶硅层,其中该第一图案化多晶硅层的晶粒尺寸大于该第二图案化多晶硅层,藉此形成有机电激发光元件。Another preferred embodiment of the present invention provides a method for manufacturing an organic electroluminescent element, comprising: providing a substrate, the substrate including a first element region and a second element region; forming a first and second patterned amorphous silicon layer on above the first and second element regions; forming a protective film above the second patterned amorphous silicon layer; and performing an excimer laser annealing process on the first and second patterned amorphous silicon layers, so that the first 1. The second patterned amorphous silicon layer is converted into the first and second patterned polysilicon layers, wherein the grain size of the first patterned polysilicon layer is larger than that of the second patterned polysilicon layer, thereby forming organic electroluminescence element.

本发明又一优选实施例提供一种有机电激发光元件的制造方法,包括:提供基板,该基板包括第一元件区域与第二元件区域;形成图案化保护膜于该第二元件区域上方;形成非晶硅层于该基板与该图案化保护膜上方;对该非晶硅层进行准分子激光退火工艺,以将该非晶硅层转化为多晶硅层;以及该多晶硅层图案化,以在该第一元件区域形成第一图案化多晶硅层,及在该第二元件区域形成第二图案化多晶硅层,其中该第一图案化多晶硅层的晶粒尺寸大于该第二图案化多晶硅层,藉此形成有机电激发光元件。Another preferred embodiment of the present invention provides a method for manufacturing an organic electroluminescent element, including: providing a substrate, the substrate including a first element region and a second element region; forming a patterned protective film on the second element region; forming an amorphous silicon layer over the substrate and the patterned protective film; performing an excimer laser annealing process on the amorphous silicon layer to convert the amorphous silicon layer into a polysilicon layer; and patterning the polysilicon layer to A first patterned polysilicon layer is formed in the first element region, and a second patterned polysilicon layer is formed in the second element region, wherein the grain size of the first patterned polysilicon layer is larger than that of the second patterned polysilicon layer, by This forms an organic electroluminescence element.

本发明还提供一种影像显示系统,包括:有机电激发光元件,包括:上方具有像素区的基板,其中该像素区包括多个次像素,且每一个次像素包括:开关区及驱动区;开关薄膜晶体管,置于该开关区;以及驱动薄膜晶体管,置于该驱动区,且至少包括栅极、位于该栅极下方的多晶硅层及位于该多晶硅层下方的图案化保护膜,其中该图案化保护膜为金属层且介于该多晶硅层与该基板之间。The present invention also provides an image display system, comprising: an organic electroluminescent element, including: a substrate with a pixel area above, wherein the pixel area includes a plurality of sub-pixels, and each sub-pixel includes: a switch area and a drive area; a switch thin film transistor placed in the switch area; and a drive thin film transistor placed in the drive area and at least including a gate, a polysilicon layer under the gate, and a patterned protective film under the polysilicon layer, wherein the pattern The protective film is a metal layer and is between the polysilicon layer and the substrate.

综上所述,本发明优选实施例的方法可以改善薄膜晶体管间电性差异过大的问题、提高开口率,并且不会增加工艺的复杂度。To sum up, the method of the preferred embodiment of the present invention can solve the problem of excessive electrical difference between thin film transistors, increase the aperture ratio, and will not increase the complexity of the process.

附图说明 Description of drawings

图1为绘示有源矩阵式有机电激发光元件中一个像素的等效电路图。FIG. 1 is an equivalent circuit diagram of a pixel in an active matrix organic electroluminescence device.

图2a~2f为绘示本发明优选实施例中有机电激发光元件的制造方法的剖面图。2a-2f are cross-sectional views illustrating a method for manufacturing an organic electroluminescence device in a preferred embodiment of the present invention.

图3a~3f为绘示本发明另一优选实施例中有机电激发光元件的制造方法的剖面图。3a-3f are cross-sectional views illustrating a method for manufacturing an organic electroluminescent device in another preferred embodiment of the present invention.

图4a~4g为绘示本发明又一优选实施例中有机电激发光元件的制造方法的剖面图。4a-4g are cross-sectional views illustrating a manufacturing method of an organic electroluminescence device in another preferred embodiment of the present invention.

图5a~5g为绘示本发明又一优选实施例中有机电激发光元件的制造方法的剖面图。5a-5g are cross-sectional views illustrating a method for manufacturing an organic electroluminescence device in another preferred embodiment of the present invention.

图6为绘示本发明优选实施例中用于显示影像的系统。FIG. 6 is a diagram illustrating a system for displaying images in a preferred embodiment of the present invention.

简单符号说明simple notation

I~开关薄膜晶体管区域;II~驱动薄膜晶体管区域;100~像素;102~开关薄膜晶体管;104~驱动薄膜晶体管;106~有机发光二极管;108~数据线;110~扫描线;112~储存电容;200~基板;202~缓冲层;204~非晶硅层;204a~多晶硅层;204b~多晶硅层;204c~通道区;204d~源/漏极;204’b~第一有源层;204’c~通道区;204’d~轻掺杂漏极;204’e~源/漏极;206~保护膜;208~准分子激光退火工艺;210~栅极介电层;212~栅极;214~栅极;216~层间介电层;218~导线;220~保护层;224~透明电极;300~基板;302~缓冲层;304~非晶硅层;304a~图案化非晶硅层;304b~图案化非晶硅层;304c~多晶硅层;304d~多晶硅层;304’a~通道区;304’b~轻掺杂漏极;304’c~源/漏极;304’d~通道区;304’e~源/漏极;306~保护膜;308~准分子激光退火工艺;309~栅极介电层;310~栅极;312~栅极;314~层间介电层;316~导线;318~保护层;322~透明电极;400~基板;402~图案化保护膜;404~缓冲层;406~非晶硅层;406a~多晶硅层;406c~通道区;406’a~图案化多晶硅层;406’b~轻掺杂漏极;406’c~源/漏极;406’d~通道区;406b~图案化多晶硅层;406d~源/漏极;408~准分子激光退火工艺;410~栅极介电层;412~栅极;414~栅极;416~层间介电层;418~导线;420~保护层;424~透明电极;500~基板;502~图案化保护膜;504~缓冲层;506~非晶硅层;506a~多晶硅层;506c~通道区;506’a、506b~图案化多晶硅层;506’b~轻掺杂漏极;506’c~源/漏极;506’d~通道区;506b~图案化多晶硅层;506d~源/漏极;508~准分子激光退火工艺;510~栅极介电层;512~栅极;514~栅极;516~层间介电层;518~导线;520~保护层;524~透明电极;600~电子元件;610~有机电激发光元件;620~显示面板;630~控制器;640~平面面板元件;650~输入元件;2000~有机电激发光元件;3000~有机电激发光元件;4000~有机电激发光元件。I~switching thin film transistor area; II~driving thin film transistor area; 100~pixel; 102~switching thin film transistor; 104~driving thin film transistor; 106~organic light emitting diode; 108~data line; 110~scanning line; 112~storage capacitor 200~substrate; 202~buffer layer; 204~amorphous silicon layer; 204a~polysilicon layer; 204b~polysilicon layer; 204c~channel region; 204d~source/drain; 'c~channel region; 204'd~lightly doped drain; 204'e~source/drain; 206~protective film; 208~excimer laser annealing process; 210~gate dielectric layer; 212~gate ; 214~gate; 216~interlayer dielectric layer; 218~wire; 220~protective layer; 224~transparent electrode; 300~substrate; 302~buffer layer; 304~amorphous silicon layer; 304a~patterned amorphous Silicon layer; 304b ~ patterned amorphous silicon layer; 304c ~ polysilicon layer; 304d ~ polysilicon layer; 304'a ~ channel region; 304'b ~ lightly doped drain; 304'c ~ source/drain; 304' d~channel area; 304'e~source/drain; 306~protective film; 308~excimer laser annealing process; 309~gate dielectric layer; 310~gate; 312~gate; 314~interlayer dielectric Electric layer; 316~wire; 318~protective layer; 322~transparent electrode; 400~substrate; 402~patterned protective film; 404~buffer layer; 406~amorphous silicon layer; 406a~polysilicon layer; 406c~channel area; 406'a~patterned polysilicon layer; 406'b~lightly doped drain; 406'c~source/drain; 406'd~channel region; 406b~patterned polysilicon layer; 406d~source/drain; 408 ~excimer laser annealing process; 410~gate dielectric layer; 412~gate; 414~gate; 416~interlayer dielectric layer; 418~wire; 420~protective layer; 424~transparent electrode; 500~substrate ; 502~patterned protective film; 504~buffer layer; 506~amorphous silicon layer; 506a~polysilicon layer; 506c~channel region; 506'a, 506b~patterned polysilicon layer; ; 506'c~source/drain; 506'd~channel area; 506b~patterned polysilicon layer; 506d~source/drain; 508~excimer laser annealing process; 510~gate dielectric layer; 512~gate 514~grid; 516~interlayer dielectric layer; 518~wire; 520~protective layer; 524~transparent electrode; 600~electronic component; 610~organic electroluminescence component; 620~display panel; 630~control device; 640~plane panel components; 650~input components; 2000~organic electroluminescent components; 3000~organic electroluminescent components; 4000~organic electroluminescent components.

具体实施方式 Detailed ways

图1为绘示有源矩阵式有机电激发光元件中一个像素的等效电路图。值得注意的是,在说明书内所指的每一个“像素”包括一个开关薄膜晶体管(switching thin film transistor)与驱动薄膜晶体管(driving thin film transistor)FIG. 1 is an equivalent circuit diagram of a pixel in an active matrix organic electroluminescence device. It is worth noting that each "pixel" referred to in the specification includes a switching thin film transistor (switching thin film transistor) and a driving thin film transistor (driving thin film transistor)

如图1所示,在包括多个像素的像素区域(未显示)内,像素100包含开关薄膜晶体管102、驱动薄膜晶体管104、有机发光二极管106、数据线108、扫描线110以及储存电容112。有机发光二极管106还包括阳极、电激发光层与阴极(未显示)。值得注意的是,开关薄膜晶体管102与驱动薄膜晶体管104形成于同一像素内。As shown in FIG. 1 , in a pixel region (not shown) including a plurality of pixels, a pixel 100 includes a switching TFT 102 , a driving TFT 104 , an OLED 106 , a data line 108 , a scanning line 110 and a storage capacitor 112 . The OLED 106 further includes an anode, an electroluminescent layer and a cathode (not shown). It should be noted that the switching thin film transistor 102 and the driving thin film transistor 104 are formed in the same pixel.

第1实施例first embodiment

图2a~2f为绘示本发明优选实施例中有机电激发光元件的制造方法的剖面图。2a-2f are cross-sectional views illustrating a method for manufacturing an organic electroluminescence device in a preferred embodiment of the present invention.

如图2a所示,在包括第一元件区域(例如,开关薄膜晶体管(switchingthin film transistor)区域I)与第二元件区域(例如,驱动薄膜晶体管(drivingthin film transistor)区域II)的基板200上依次形成缓冲层202、非晶硅层204与保护膜206。其中,保护膜206形成于第二元件区域II内的部分非晶硅层204上方;且保护膜206包括以硅为基材的材料,例如是氧化硅(SiOx)、氮化硅(SiNx)、氮氧化硅(SiOxNy)、或氧化硅与氮化硅的叠层结构。As shown in FIG. 2a, on a substrate 200 including a first element region (for example, a switching thin film transistor (switchingthin film transistor) region I) and a second element region (for example, a driving thin film transistor (drivingthin film transistor) region II) in sequence A buffer layer 202 , an amorphous silicon layer 204 and a protective film 206 are formed. Wherein, the protection film 206 is formed on the part of the amorphous silicon layer 204 in the second element region II; and the protection film 206 includes a material based on silicon, such as silicon oxide (SiOx), silicon nitride (SiNx), Silicon oxynitride (SiOxNy), or a stacked structure of silicon oxide and silicon nitride.

如图2b所示,对非晶硅层204进行准分子激光退火工艺208,以将该非晶硅层转化为多晶硅层(204a,204b);但是,在准分子激光退火工艺208中,因为保护膜206可以反射部分激光能量的缘故,所以导致部分多晶硅层204a与部分多晶硅层204b具有不同结晶效果。也就是说,由于未被保护膜206覆盖的部分多晶硅层204b直接受到完整的准分子激光能量照射的缘故,所以具有较大尺寸的晶粒(grain),而其电子迁移率大约为100cm2/V-s。另一方面,由于保护膜206反射部分激光能量的缘故,因而下方的多晶硅层204a的晶粒尺寸较小,但是晶粒均一性(uniformity)却增加,而其电子迁移率大约小于100cm2/V-s。As shown in Figure 2b, an excimer laser annealing process 208 is performed on the amorphous silicon layer 204 to convert the amorphous silicon layer into a polysilicon layer (204a, 204b); however, in the excimer laser annealing process 208, because the protection Part of the polysilicon layer 204 a and part of the polysilicon layer 204 b have different crystallization effects because the film 206 can reflect part of the laser energy. That is to say, since the part of the polysilicon layer 204b not covered by the protective film 206 is directly irradiated by the complete excimer laser energy, it has a larger grain size, and its electron mobility is about 100 cm 2 / Vs. On the other hand, due to the part of the laser energy reflected by the protective film 206, the grain size of the underlying polysilicon layer 204a is smaller, but the grain uniformity (uniformity) is increased, and its electron mobility is approximately less than 100 cm 2 /Vs .

如图2c所示,移除保护膜206。接着,如图2d所示,图案多晶硅层(204a,204b),而形成位于开关薄膜晶体管区域I内的第一有源层204’b与位于驱动薄膜晶体管区域II内的第二有源层204a。As shown in FIG. 2c, the protection film 206 is removed. Next, as shown in FIG. 2d, the polysilicon layer (204a, 204b) is patterned to form the first active layer 204'b located in the switching thin film transistor region I and the second active layer 204a located in the driving thin film transistor region II. .

如图2e所示,形成栅极介电层210,以覆盖第一有源层204’b与第二有源层204a等图案化多晶硅层以及缓冲层202。As shown in FIG. 2e , a gate dielectric layer 210 is formed to cover the patterned polysilicon layer and the buffer layer 202 such as the first active layer 204'b and the second active layer 204a.

接着,如图2f所示,依次进行后续工艺,以形成栅极(212,214)、层间介电层216、导线218、覆盖层220、及透明电极(像素电极)224,由于此部分并非本发明重点,在此省略说明。最后,完成有机电激发光元件2000,包括开关薄膜晶体管与驱动薄膜晶体管。上述开关薄膜晶体管包括栅极212、栅极介电层210与第一有源层204’b;另外,上述驱动薄膜晶体管包括栅极214、栅极介电层210与第二有源层204a。其中,第一有源层204’b包括通道区204’c、轻掺杂漏极(lightly doped drain)204’d、源/漏极204’e;第二有源层204a包括通道区204c与源/漏极204d。Then, as shown in FIG. 2f, follow-up processes are performed sequentially to form gates (212, 214), interlayer dielectric layer 216, wire 218, cover layer 220, and transparent electrode (pixel electrode) 224, because this part is not The key points of the present invention are omitted here. Finally, the organic electroluminescent device 2000 is completed, including the switching thin film transistor and the driving thin film transistor. The switching thin film transistor includes a gate 212, a gate dielectric layer 210, and a first active layer 204'b; in addition, the driving thin film transistor includes a gate 214, a gate dielectric layer 210, and a second active layer 204a. Wherein, the first active layer 204'b includes a channel region 204'c, a lightly doped drain (lightly doped drain) 204'd, and a source/drain 204'e; the second active layer 204a includes a channel region 204c and source/drain 204d.

第2实施例2nd embodiment

图3a~3f为绘示本发明另一优选实施例中有机电激发光元件的制造方法的剖面图。3a-3f are cross-sectional views illustrating a method for manufacturing an organic electroluminescent device in another preferred embodiment of the present invention.

如图3a所示,在包括开关薄膜晶体管(switching thin film transistor)区域I与驱动薄膜晶体管(driving thin film transistor)区域II的基板300上依次形成缓冲层302与非晶硅层304。As shown in FIG. 3a, a buffer layer 302 and an amorphous silicon layer 304 are sequentially formed on a substrate 300 including a switching thin film transistor region I and a driving thin film transistor region II.

如图3b所示,将非晶硅层304图案化,以形成位于开关薄膜晶体管区域I的图案化非晶硅层304b以及位于驱动薄膜晶体管区域II的图案化非晶硅层304a。As shown in FIG. 3 b , the amorphous silicon layer 304 is patterned to form a patterned amorphous silicon layer 304 b located in the switching TFT region I and a patterned amorphous silicon layer 304 a located in the driving TFT region II.

如图3c所示,形成覆盖图案化非晶硅层304a以及部分缓冲层302表面的保护膜306。上述保护膜306包括以硅为基材的材料,例如是氧化硅(SiOx)、氮化硅(SiNx)、氮氧化硅(SiOxNy)、或氧化硅与氮化硅的叠层结构。As shown in FIG. 3 c , a protective film 306 covering the surface of the patterned amorphous silicon layer 304 a and part of the buffer layer 302 is formed. The protective film 306 includes a silicon-based material, such as silicon oxide (SiOx), silicon nitride (SiNx), silicon oxynitride (SiOxNy), or a stacked structure of silicon oxide and silicon nitride.

如图3d所示,进行准分子激光退火工艺308,以将图案化非晶硅层304a与304b转化为多晶硅层304c与304d。其中,位于开关薄膜晶体管区域I内的多晶硅层304d作为后续形成的开关薄膜晶体管的第一有源层,而位于驱动薄膜晶体管区域II内的多晶硅层304c则作为后续形成的驱动薄膜晶体管的第二有源层。但是,在准分子激光退火工艺308中,因为保护膜306可以反射部分激光能量的缘故,所以导致多晶硅层304c与多晶硅层304d具有不同结晶效果。换句话说,由于未被保护膜306覆盖的多晶硅层304b直接受到完整的准分子激光能量照射的缘故,所以具有较大尺寸的晶粒(grain),而其电子迁移率大约为100cm2/V-s。另一方面,由于保护膜306反射部分激光能量的缘故,因而下方的多晶硅层304c的晶粒尺寸较小,但是晶粒均一性(uniformity)却增加,而其电子迁移率大约小于100cm2/V-s。As shown in FIG. 3d, an excimer laser annealing process 308 is performed to convert the patterned amorphous silicon layers 304a and 304b into polysilicon layers 304c and 304d. Among them, the polysilicon layer 304d located in the switching thin film transistor region I is used as the first active layer of the subsequently formed switching thin film transistor, and the polysilicon layer 304c located in the driving thin film transistor region II is used as the second active layer of the subsequently formed driving thin film transistor. active layer. However, in the excimer laser annealing process 308 , because the protective film 306 can reflect part of the laser energy, the polysilicon layer 304 c and the polysilicon layer 304 d have different crystallization effects. In other words, since the polysilicon layer 304b not covered by the protective film 306 is directly irradiated with the full excimer laser energy, it has larger grains, and its electron mobility is about 100 cm 2 /Vs . On the other hand, due to the part of the laser energy reflected by the protective film 306, the grain size of the underlying polysilicon layer 304c is smaller, but the grain uniformity (uniformity) is increased, and its electron mobility is approximately less than 100 cm 2 /Vs .

如图3e所示,形成栅极介电层309,以覆盖第一有源层与第二有源层等图案化多晶硅层以及缓冲层302。As shown in FIG. 3 e , a gate dielectric layer 309 is formed to cover the patterned polysilicon layer such as the first active layer and the second active layer and the buffer layer 302 .

接着,如图3f所示,依次进行后续工艺,以形成栅极(310,312)、层间介电层314、导线316、覆盖层318、及透明电极(像素电极)322,由于此部分并非本发明重点,在此省略说明。最后,完成有机电激发光元件3000,包括开关薄膜晶体管与驱动薄膜晶体管。上述开关薄膜晶体管包括栅极310、栅极介电层309与第一有源层;另外,上述驱动薄膜晶体管包括栅极312、栅极介电层309与第二有源层。其中,第一有源层包括通道区304’a、轻掺杂漏极(lightly doped drain)304’b、源/漏极304’c;第二有源层包括通道区304’d与源/漏极304’e。Next, as shown in FIG. 3f, subsequent processes are performed sequentially to form gates (310, 312), interlayer dielectric layers 314, wires 316, covering layers 318, and transparent electrodes (pixel electrodes) 322. Since this part is not The key points of the present invention are omitted here. Finally, the organic electroluminescent device 3000 is completed, including the switching thin film transistor and the driving thin film transistor. The switching thin film transistor includes a gate 310 , a gate dielectric layer 309 and a first active layer; in addition, the driving thin film transistor includes a gate 312 , a gate dielectric layer 309 and a second active layer. Wherein, the first active layer includes channel region 304'a, lightly doped drain (lightly doped drain) 304'b, source/drain 304'c; the second active layer includes channel region 304'd and source/drain Drain 304'e.

第3实施例3rd embodiment

图4a~4g为绘示本发明又一优选实施例中有机电激发光元件的制造方法的剖面图。4a-4g are cross-sectional views illustrating a manufacturing method of an organic electroluminescence device in another preferred embodiment of the present invention.

如图4a所示,在包括开关薄膜晶体管(switching thin film transistor)区域I与驱动薄膜晶体管(driving thin film transistor)区域II的基板400上形成图案化保护膜402。上述图案化保护膜位于驱动薄膜晶体管区域II内。上述图案化保护膜402的材料包括氧化硅(SiOx)、氮化硅(SiNx)、氮氧化硅(SiOxNy)、或其叠层结构。As shown in FIG. 4a, a patterned protection film 402 is formed on a substrate 400 including a switching thin film transistor region I and a driving thin film transistor region II. The above-mentioned patterned protective film is located in the region II of the driving thin film transistor. The material of the patterned protection film 402 includes silicon oxide (SiOx), silicon nitride (SiNx), silicon oxynitride (SiOxNy), or a stacked structure thereof.

如图4b所示,形成缓冲层404于图案化保护膜402与基板400上方。接着,形成非晶硅层406于缓冲层404上方,如图4c所示。As shown in FIG. 4 b , a buffer layer 404 is formed on the patterned protective film 402 and the substrate 400 . Next, an amorphous silicon layer 406 is formed on the buffer layer 404, as shown in FIG. 4c.

如图4d所示,对非晶硅层406进行准分子激光退火工艺408,以将非晶硅层406转化为多晶硅层(406a,406b)。As shown in FIG. 4d, an excimer laser annealing process 408 is performed on the amorphous silicon layer 406 to convert the amorphous silicon layer 406 into a polysilicon layer (406a, 406b).

如图4e所示,将多晶硅层(406a,406b)图案化,而形成图案化多晶硅层406’a与406b。其中,位于开关薄膜晶体管区域I内的多晶硅层406’a作为后续形成的开关薄膜晶体管的第一有源层,而位于驱动薄膜晶体管区域II内的多晶硅层406b则作为后续形成的驱动薄膜晶体管的第二有源层。但是,在准分子激光退火工艺408中,因为图案化保护膜402可以反射部分激光能量的缘故,所以导致图案化多晶硅层406’a与406b具有不同结晶效果。换句话说,由于图案化多晶硅层406’a直接受到准分子激光能量照射的缘故,所以具有较大尺寸的晶粒(grain),而其电子迁移率大约为100cm2/V-s。另一方面,由于图案化保护膜402吸收部分激光能量的缘故,因而上方的图案化多晶硅层406’a的晶粒尺寸较小,但是晶粒均一性(uniformity)却增加,而其电子迁移率大约小于100cm2/V-s。As shown in FIG. 4e, the polysilicon layers (406a, 406b) are patterned to form patterned polysilicon layers 406'a and 406b. Among them, the polysilicon layer 406'a located in the switching thin film transistor region I is used as the first active layer of the subsequently formed switching thin film transistor, and the polysilicon layer 406b located in the driving thin film transistor region II is used as the first active layer of the subsequently formed driving thin film transistor. second active layer. However, in the excimer laser annealing process 408 , because the patterned protective film 402 can reflect part of the laser energy, the patterned polysilicon layers 406 ′ a and 406 b have different crystallization effects. In other words, since the patterned polysilicon layer 406'a is directly irradiated by the excimer laser energy, it has larger grains, and its electron mobility is about 100 cm 2 /Vs. On the other hand, since the patterned protective film 402 absorbs part of the laser energy, the grain size of the upper patterned polysilicon layer 406'a is smaller, but the grain uniformity (uniformity) is increased, and its electron mobility About less than 100cm 2 /Vs.

如图4f所示,形成栅极介电层410,以覆盖第一有源层与第二有源层等图案化多晶硅层以及缓冲层402。As shown in FIG. 4f , a gate dielectric layer 410 is formed to cover the patterned polysilicon layer such as the first active layer and the second active layer and the buffer layer 402 .

接着,如图4g所示,依次进行后续工艺,以形成栅极(412,414)、层间介电层416、导线418、覆盖层420、及透明电极(像素电极)424,由于此部分并非本发明重点,在此省略说明。最后,完成有机电激发光元件4000,包括开关薄膜晶体管与驱动薄膜晶体管。上述开关薄膜晶体管包括栅极412、栅极介电层410与第一有源层;另外,上述驱动薄膜晶体管包括栅极414、栅极介电层410与第二有源层。其中,第一有源层包括通道区406’d、轻掺杂漏极(lightly doped drain)406’b、源/漏极406’c;第二有源层包括通道区406c与源/漏极406d。Then, as shown in FIG. 4g, subsequent processes are performed sequentially to form gates (412, 414), interlayer dielectric layers 416, wires 418, covering layers 420, and transparent electrodes (pixel electrodes) 424. Since this part is not The key points of the present invention are omitted here. Finally, the organic electroluminescent device 4000 is completed, including the switching thin film transistor and the driving thin film transistor. The switching thin film transistor includes a gate 412 , a gate dielectric layer 410 and a first active layer; in addition, the driving thin film transistor includes a gate 414 , a gate dielectric layer 410 and a second active layer. Wherein, the first active layer includes channel region 406'd, lightly doped drain (lightly doped drain) 406'b, source/drain 406'c; the second active layer includes channel region 406c and source/drain 406d.

第4实施例4th embodiment

图5a~5g为绘示本发明又一优选实施例中有机电激发光元件的制造方法的剖面图。5a-5g are cross-sectional views illustrating a method for manufacturing an organic electroluminescence device in another preferred embodiment of the present invention.

如图5a所示,在包括开关薄膜晶体管(switching thin film transistor)区域I与驱动薄膜晶体管(driving thin film transistor)区域II的基板500上形成图案化保护膜502。上述图案化保护膜位于驱动薄膜晶体管区域II内。上述图案化保护膜502包括任何金属材料。As shown in FIG. 5a, a patterned protective film 502 is formed on a substrate 500 including a switching thin film transistor region I and a driving thin film transistor region II. The above-mentioned patterned protective film is located in the region II of the driving thin film transistor. The above-mentioned patterned protection film 502 includes any metal material.

如图5b所示,形成缓冲层504于图案化保护膜502与基板500上方。接着,形成非晶硅层506于缓冲层504上方,如图5c所示。As shown in FIG. 5 b , a buffer layer 504 is formed on the patterned protective film 502 and the substrate 500 . Next, an amorphous silicon layer 506 is formed on the buffer layer 504, as shown in FIG. 5c.

如图5d所示,对非晶硅层506进行准分子激光退火工艺508,以将非晶硅层506转化为多晶硅层(506a,506b)。As shown in FIG. 5d, an excimer laser annealing process 508 is performed on the amorphous silicon layer 506 to convert the amorphous silicon layer 506 into a polysilicon layer (506a, 506b).

如图5e所示,将多晶硅层(506a,506b)图案化,而形成图案化多晶硅层506’a与506b。其中,位于开关薄膜晶体管区域I内的多晶硅层506’a作为后续形成的开关薄膜晶体管的第一有源层,而位于驱动薄膜晶体管区域II内的多晶硅层506b则作为后续形成的驱动薄膜晶体管的第二有源层。但是,在准分子激光退火工艺508中,因为图案化保护膜502散热较其它部分快的缘故,所以导致图案化多晶硅层506’a与506b具有不同结晶效果。换句话说,由于图案化多晶硅层506’a直接受到完整的准分子激光能量照射的缘故,所以具有较大尺寸的晶粒(grain),而其电子迁移率大约为100cm2/V-s。另一方面,图案化保护膜502上方的图案化多晶硅层506’a的晶粒尺寸较小,但是晶粒均一性(uniformity)却增加,而其电子迁移率大约小于100cm2/V-s。As shown in FIG. 5e, the polysilicon layers (506a, 506b) are patterned to form patterned polysilicon layers 506'a and 506b. Among them, the polysilicon layer 506'a located in the switching thin film transistor region I is used as the first active layer of the subsequently formed switching thin film transistor, and the polysilicon layer 506b located in the driving thin film transistor region II is used as the first active layer of the subsequently formed driving thin film transistor. second active layer. However, in the excimer laser annealing process 508, because the patterned protection film 502 dissipates heat faster than other parts, the patterned polysilicon layers 506'a and 506b have different crystallization effects. In other words, since the patterned polysilicon layer 506'a is directly irradiated by the full excimer laser energy, it has larger grains with an electron mobility of about 100 cm 2 /Vs. On the other hand, the patterned polysilicon layer 506'a above the patterned passivation film 502 has a smaller grain size but increased grain uniformity, and its electron mobility is less than about 100 cm 2 /Vs.

如图5f所示,形成栅极介电层510,以覆盖第一有源层与第二有源层等图案化多晶硅层以及缓冲层502。As shown in FIG. 5 f , a gate dielectric layer 510 is formed to cover the patterned polysilicon layer such as the first active layer and the second active layer and the buffer layer 502 .

接着,如图5g所示,依次进行后续工艺,以形成栅极(512,514)、层间介电层516、导线518、覆盖层520、及透明电极(像素电极)524,由于此部分并非本发明重点,在此省略说明。最后,完成有机电激发光元件5000,包括开关薄膜晶体管与驱动薄膜晶体管。上述开关薄膜晶体管包括栅极512、栅极介电层510与第一有源层;另外,上述驱动薄膜晶体管包括栅极514、栅极介电层510与第二有源层。其中,第一有源层包括通道区506’d、轻掺杂漏极(lightly doped drain)506’b、源/漏极506’c;第二有源层包括通道区506c与源/漏极506d。Next, as shown in FIG. 5g, subsequent processes are performed sequentially to form gates (512, 514), interlayer dielectric layers 516, wires 518, covering layers 520, and transparent electrodes (pixel electrodes) 524. Since this part is not The key points of the present invention are omitted here. Finally, the organic electroluminescent element 5000 is completed, including the switching thin film transistor and the driving thin film transistor. The switching thin film transistor includes a gate 512 , a gate dielectric layer 510 and a first active layer; in addition, the driving thin film transistor includes a gate 514 , a gate dielectric layer 510 and a second active layer. Wherein, the first active layer includes channel region 506'd, lightly doped drain (lightly doped drain) 506'b, source/drain 506'c; the second active layer includes channel region 506c and source/drain 506d.

图6为绘示本发明优选实施例中用于显示影像的系统。在此,此系统为可以是显示面板620、平面面板元件640或电子元件600。上述有机电激发光元件可以装配于显示面板而做成有机电激发光二极管面板。如图6所示,显示面板620包含有机电激发光元件610,例如图2f、3f与4g分别所示的有机电激发光元件2000、3000与4000。在其它实施例中,平面面板元件640可由显示面板620与控制器630所构成。在其它实施例中,显示面板620也可以构成众多电子元件的一部分(例如,在此为电子元件600)。一般而言,电子元件600可以包含平面面板元件640,而平面面板元件640具有显示面板620、控制器630与输入元件650。而且,输入元件650与平面面板元件640耦接,且提供输入信号(例如,影像信号)至显示面板620以产生影像。电子元件600可以是移动电话、数码相机、个人数字助理(personal digitalassistant;PDA)、笔记本计算机、台式计算机、电视、车上显示器或可携式DVD播放机。FIG. 6 is a diagram illustrating a system for displaying images in a preferred embodiment of the present invention. Here, the system can be the display panel 620 , the flat panel component 640 or the electronic component 600 . The above-mentioned organic electroluminescent element can be assembled in a display panel to be made into an organic electroluminescent diode panel. As shown in FIG. 6 , the display panel 620 includes an organic electroluminescent device 610 , such as the organic electroluminescent devices 2000 , 3000 and 4000 shown in FIGS. 2 f , 3 f and 4 g respectively. In other embodiments, the planar panel element 640 may be composed of the display panel 620 and the controller 630 . In other embodiments, the display panel 620 may also constitute a part of many electronic components (for example, the electronic component 600 here). Generally speaking, the electronic component 600 may include a flat panel component 640 , and the flat panel component 640 has a display panel 620 , a controller 630 and an input component 650 . Moreover, the input element 650 is coupled to the planar panel element 640 and provides an input signal (eg, an image signal) to the display panel 620 to generate an image. The electronic component 600 may be a mobile phone, a digital camera, a personal digital assistant (personal digital assistant, PDA), a notebook computer, a desktop computer, a television, a car monitor, or a portable DVD player.

综上所述,本发明几个优选实施例通过准分子激光退火(excimer laseranneal;ELA)步骤,在缓冲层上或下、或在栅极绝缘层上增加额外的保护膜或金属膜,造成用于开关的薄膜晶体管(switching TFT)与用于驱动的薄膜晶体管(driving TFT)具有不同的结晶效果。结果,具有上述不同的结晶效果的薄膜晶体管的有源矩阵型有机电激发光元件则会有较均匀的驱动电流,而避免产生颜色不均(Mura)的缺陷。In summary, several preferred embodiments of the present invention use an excimer laser anneal (excimer laser anneal; ELA) step to add an additional protective film or metal film on or below the buffer layer, or on the gate insulating layer, resulting in The switching TFT and the driving TFT have different crystallization effects. As a result, the active-matrix organic electroluminescent element of the thin film transistor having the above-mentioned different crystallization effects will have a more uniform driving current, and avoid the defect of uneven color (Mura).

Claims (26)

1. the manufacture method of an organic electroluminescent element comprises:
Substrate is provided, and this substrate comprises the pixel region that contains a plurality of pixels, wherein comprises first element area and second element area in each pixel;
Form amorphous silicon layer in this substrate top;
Form this amorphous silicon layer top of the part of diaphragm in this second element area;
This amorphous silicon layer is carried out quasi-molecule laser annealing technology, to incite somebody to action
This amorphous silicon layer is converted into polysilicon layer; And
This polysilicon layer of pattern, to form the first patterned polysilicon layer at this first element area, and form the second patterned polysilicon layer at this second element area, wherein the crystallite dimension of this first patterned polysilicon layer forms organic electroluminescent element by this greater than this second patterned polysilicon layer.
2. the manufacture method of organic electroluminescent element as claimed in claim 1, wherein this diaphragm comprises with silicon being the material of base material.
3. the manufacture method of organic electroluminescent element as claimed in claim 1, wherein in this quasi-molecule laser annealing technology, this diaphragm is in order to the reflecting part laser energy.
4. the manufacture method of organic electroluminescent element as claimed in claim 1 also comprises:
After the step of this this polysilicon layer of pattern, form gate dielectric, to cover this patterned polysilicon layer.
5. the manufacture method of organic electroluminescent element as claimed in claim 1, the first patterned polysilicon layer that wherein is positioned at this first element area is first active layer, the second patterned polysilicon layer that is positioned at this second element area is second active layer.
6. the manufacture method of organic electroluminescent element as claimed in claim 1 wherein forms the switching thin-film transistor element, and forms the drive thin film transistors element in this second element area in this first element area.
7. the manufacture method at dynamo-electric exciting light element as claimed in claim 6 also comprises: Organic Light Emitting Diode, wherein this Organic Light Emitting Diode forms with this drive thin film transistors element and is electrically connected.
8. the manufacture method of organic electroluminescent element as claimed in claim 1 wherein removes this diaphragm after quasi-molecule laser annealing technology.
9. the manufacture method of organic electroluminescent element as claimed in claim 1 wherein forms first, second patterning amorphous silicon layer earlier above this first, second element area with this amorphous silicon layer pattern after the step above this amorphous silicon layer is formed at this substrate immediately.
10. the manufacture method of organic electroluminescent element as claimed in claim 9, wherein this diaphragm comprises with silicon being the material of base material.
11. the manufacture method of organic electroluminescent element as claimed in claim 9, wherein in this quasi-molecule laser annealing technology, this diaphragm can the reflecting part laser energy.
12. the manufacture method of organic electroluminescent element as claimed in claim 9 also comprises:
After this quasi-molecule laser annealing technology, form gate dielectric, cover polysilicon layer, substrate and this diaphragm that this not protected film covers.
13. the manufacture method of organic electroluminescent element as claimed in claim 9, wherein this first, second patterned polysilicon layer is respectively first active layer that is positioned at this first element area and second active layer that is positioned at this second element area.
14. the manufacture method of organic electroluminescent element as claimed in claim 9 wherein forms the switching thin-film transistor element, and forms the drive thin film transistors element in this second element area in this first element area.
15. the manufacture method of organic electroluminescent element as claimed in claim 14 also comprises:
Organic Light Emitting Diode, wherein this Organic Light Emitting Diode forms with this drive thin film transistors element and is electrically connected.
16. the manufacture method of an organic electroluminescent element comprises:
Substrate is provided, and this substrate comprises the pixel region that contains a plurality of pixels, wherein comprises first element area and second element area in each pixel;
Form the patterning diaphragm in this second element area top;
Form amorphous silicon layer in this substrate and this patterning diaphragm top;
This amorphous silicon layer is carried out quasi-molecule laser annealing technology so that this amorphous silicon layer is converted into polysilicon layer; And
This polysilicon layer of pattern, to form the first patterned polysilicon layer at this first element area, and form the second patterned polysilicon layer at this second element area, wherein the crystallite dimension of this first patterned polysilicon layer forms organic electroluminescent element by this greater than this second patterned polysilicon layer.
17. the manufacture method of organic electroluminescent element as claimed in claim 16, wherein this patterning diaphragm comprises metal material.
18. the manufacture method of organic electroluminescent element as claimed in claim 16, wherein in this quasi-molecule laser annealing technology, this patterning diaphragm has higher heat to pass coefficient.
19. the manufacture method of organic electroluminescent element as claimed in claim 16 also comprises:
After the step of this this polysilicon layer of pattern, form gate dielectric, to cover this patterned polysilicon layer and this substrate.
20. the manufacture method of organic electroluminescent element as claimed in claim 16, wherein this first, second patterned polysilicon layer is respectively first active layer that is positioned at this first element area and second active layer that is positioned at this second element area.
21. the manufacture method of organic electroluminescent element as claimed in claim 16 wherein forms the switching thin-film transistor element, and forms the drive thin film transistors element in this second element area in this first element area.
22. the manufacture method of organic electroluminescent element as claimed in claim 21 also comprises:
Organic Light Emitting Diode, wherein this Organic Light Emitting Diode forms with this drive thin film transistors element and is electrically connected.
23. an image display system comprises:
Organic electroluminescent element comprises:
The top has the substrate of pixel region, and wherein this pixel region comprises pixel a plurality of times, and each time pixel comprises:
Switch region and driving district;
Switching thin-film transistor places this switch region; And
Drive thin film transistors places this driving district, and comprises grid at least, is positioned at the polysilicon layer of this grid below and is positioned at the patterning diaphragm of this polysilicon layer below, and wherein this patterning diaphragm is a metal level and between this polysilicon layer and this substrate.
24. image display system as claimed in claim 23 also comprises display floater, wherein this organic electroluminescent element forms the part of this display floater.
25. image display system as claimed in claim 24 also comprises electronic component, wherein this electronic component comprises:
This display floater; And
Be coupled to the input unit of this display floater, and this input unit is in order to providing input signal to this display floater, thereby this display floater show image.
26. image display system as claimed in claim 25, wherein this electronic component is display or a portable digital versatile disc player on mobile phone, digital camera, personal digital assistant, notebook, desktop computer, TV, the car.
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