CN101125763A

CN101125763A - Method of manufacturing golden metal glaze material

Info

Publication number: CN101125763A
Application number: CNA2007100356656A
Authority: CN
Inventors: 杨梦雄; 杨春辉
Original assignee: HUNAN QUANXIANG CERAMICS CO Ltd
Current assignee: HUNAN QUANXIANG CERAMICS CO Ltd
Priority date: 2007-08-31
Filing date: 2007-08-31
Publication date: 2008-02-20
Anticipated expiration: 2027-08-31
Also published as: CN100537486C

Abstract

The invention relates to a preparation method of golden glaze and frit. The frit is produced by quick roasting in the oxidizing atmosphere under 1160-1200 DEG C and the glaze is clinquant under normal light and more clinquant and resplendent under bright light. The frit comprises borax and three carbonates (zinc, lithium and barium) and is also added with quartz, potassium feldspar, a little bit of clay and a plurality of colorant. When in preparation, borax and carbonates are first made into fusion cake, after being crushed, the fusion cake together with quartz, potassium feldspar, clay and colorant are ball grinded until being screened by 250 mesh. The operation thickness of the glaze layer is 0.1-0.3 mm; the roasted product is very bright, like gold in the extreme and is very popular with customers.

Description

A kind of making method of golden metal glaze material

Technical field

The present invention relates to a kind of making method of golden metal glaze material.

Background technology

In the porcelain industry, the moulding of base substrate is no doubt important, the more apparent prominent position of the allotment of glaze, the base substrate of same moulding often produces Different Effects because of the different visions to the human consumer of overglaze, people like the porcelain beautiful design, but prefer glittering, the porcelain of resplendent and magnificent visual effect, the glaze that the sort of smooth amorous photo people, color can reflect often obtains unusual decorative effect, and this also is current a kind of fashion.

Summary of the invention

The objective of the invention is to prepare and a kind ofly can in 1160～1200 ℃ of oxidizing atmospheres, burn till golden yellow metal overglaze glaze fast, described golden yellow metal glaze is meant that the glaze of definite composition carries out heat treated, produce color harmony pool outer appearnce like gold the same under irradiate light just as glittering, the more apparent magnificent rich and honour personal value of golden wall splendidness.The making method of the so-called a kind of golden metal glaze material of the present invention, concrete steps are as follows:

1, get the raw materials ready by following prescription--

A、Na ₂B ₄O ₇.10H ₂O 30～35％，

Quartz 20～25%,

Potassium felspar sand 15～20%,

ZnO 1～3％，

Triphane 5～6%,

BaCO ₃ 4～7％，

Clay 5～8%,

Fe ₂O ₃ 5～8％，

MnO ₂ 5～10％，

CuO 1～2%; Perhaps

B、Na ₂B ₄O ₇.10H ₂O 20～30％，

Quartz 30～40%,

ZnO 1～3％，

Triphane 10～15%,

BaCO ₃ 4～7％，

Clay 5～7%,

Fe ₂O ₃ 3～5％，

MnO ₂ 10～15％，

CuO 4～7％，

Cr ₂O ₃ 1～2.5％；

Each component percentage composition sum is 100%;

2, the material that contains carbonate and crystal water in will preparing burden is made into frit;

3, get that above-mentioned frit powder minces and all the other ball mills of preparing burden are milled to that screenings is less than 0.4% promptly behind 250 mesh sieves.

The glaze layer thickness that the present invention suits is 0.1～0.3mm.

Embodiment

Example one is got the raw materials ready by following prescription: Na ₂B ₄O ₇.10H ₂O 30%, quartz 20%, potassium felspar sand 17%, ZnO2%, triphane 4%, BaCO ₃5%, clay 6%, tinting material Fe ₂O ₃7%, MnO ₂8%, CuO 1%; The carbonate of borax and lithium, barium, zinc is made frit earlier, go into ball mill with other raw material again after the pulverizing and be milled to 250 screen residues and be less than 0.4% and promptly get required glaze.During glazing, control glaze layer thickness about 0.15mm, go into rapidity burn till in 1160～1200 ℃ oxidizing atmosphere, fire in the roller kiln after, the gained glaze is glittering, golden wall splendidness, gives a kind of luxurious gorgeous impression of people.

Example two is got the raw materials ready by following prescription: Na ₂B ₄O ₇.10H ₂O 25%, quartz 35%, ZnO 2%, triphane 6%, BaCO ₃5%, clay 6%, tinting material Fe ₂O ₃4%, MnO ₂12%, CuO 3.5%, Cr ₂o ₃1.5%; Borax and three kinds of carbonate are made frit earlier, go into ball milling with other raw material again after the pulverizing, cross 250 screen residues to the ball milling thing and be less than 0.4% and promptly get required glaze.During glazing, control glaze layer thickness is at 0.1～0.2mm, go into to burn till fast roller kiln under 1160～1200 ℃ oxidizing atmosphere, fire back gained glaze golden light flicker, look over so as to check unforgettable.

Claims

1. the making method of a golden metal glaze material, it comprises that prescription batching-making frit-ball milling sieves, wherein making frit is that the raw material that contains carbonate and crystal water in the batching is made frit, it is to get that above-mentioned frit powder minces and the excess material is gone into the ball mill ball milling to through 250 mesh sieves that ball milling sieves, and it is characterized in that:

(1) gets the raw materials ready by following prescription

A、Na ₂B ₄O ₇.10H ₂O?30～35％，

Quartz 20～25%,

Potassium felspar sand 15～20%,

ZnO 1～3％，

Triphane 3～6%,

BaCO ₃ 4～7％，

Clay 5～8%,

Fe ₂O ₃ 5～8％，

MnO ₂ 5～10％，

CuO 1～2%; Perhaps

B、Na ₂B ₄O ₇.10H ₂O?20～30％，

Quartz 30～40%,

ZnO 1～3％，

Triphane 10～15%,

BaCO ₃ 4～7％，

Clay 5～7%,

Fe ₂O ₃ 3～5％，

MnO ₂ 10～15％，

CuO 4～7％，

Cr ₂O ₃ 1～2.5％；

Each component percentage composition sum is 100%;

(2) make frit: the raw material that carbon containing is joined root and crystal water in will preparing burden according to ordinary method is made frit;

(3) ball milling sieves: get that above-mentioned frit is pulverized and excess material goal is milled to through 250 screen residues and is less than 0.4% promptly according to ordinary method.