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CN100567013C - Plastic pipe marking belt - Google Patents

Plastic pipe marking belt Download PDF

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Publication number
CN100567013C
CN100567013C CNB2007100545376A CN200710054537A CN100567013C CN 100567013 C CN100567013 C CN 100567013C CN B2007100545376 A CNB2007100545376 A CN B2007100545376A CN 200710054537 A CN200710054537 A CN 200710054537A CN 100567013 C CN100567013 C CN 100567013C
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China
Prior art keywords
plastic tube
pigment
base material
tube sign
resin
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Application number
CNB2007100545376A
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Chinese (zh)
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CN101318422A (en
Inventor
张振宇
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Jiaozuo Zhuoli Film Material Co ltd
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Jiaozuo Zhuoli Stamping Material Co ltd
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Priority to CNB2007100545376A priority Critical patent/CN100567013C/en
Publication of CN101318422A publication Critical patent/CN101318422A/en
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Abstract

The invention discloses a plastic pipe marking tape, which consists of a base material and a coloring layer on the base material, wherein the coloring layer comprises the following components in percentage by weight: 17-24% of resin, 1-2.5% of polyethylene wax, 15-17.5% of filler, 5-7.5% of pigment, 0.5-1.5% of dispersing agent and 48-55% of solvent. The plastic pipe marking tape manufactured by adopting the technical scheme of the invention is characterized in that the coloring layer not only has a coloring function, but also has an excellent adhesion function, the coloring layer can be well adhered to a printing substrate, is not easy to fall off, has strong scratch resistance, overcomes the defect that a complex structure of adding a bonding layer on the coloring layer is adopted in some technical documents, simplifies the product structure and the production process, reduces the production cost, and does not reduce the product performance.

Description

Plastic tube sign belt
Technical field
The invention belongs to a kind of hot transfer printing plastic tube sign colour band, the online sign that is particularly useful for plastic tubes such as electric wire, water pipe, natural gas tube, line pipe production comprises that pipeline specification model, date of manufacture, manufacturer etc. are digital, the sign of Word message.
Background technology
The application of plastic lined piping tubing such as electric wire, water pipe, natural gas tube is quite general on the market now, numeral, Word messages such as pipeline surface mark specifications and models, date of manufacture, manufacturer will be used hot transfer printing plastic tube sign belt, existing abroad this type of commodity selling, but still belong to blank at home.External imported product selling at exorbitant prices, and have technical deficiency, base material and dyed layer adhesive force are not enough, and defective such as come off, scratch resistance is not strong is arranged easily.
Summary of the invention
The purpose of this invention is to provide and a kind ofly can on plastic lined piping tubing such as electric wire, water pipe, natural gas tube, realize complete transfer printing, and on stock, be difficult for rubbing coming off, carrier there is extensive adaptability, scratch-resistant, humidity, sun-resistant hot transfer printing plastic tube sign colour band.
For achieving the above object, the present invention adopts following technical scheme: a kind of plastic tube sign belt, be made up of the dyed layer on base material and the base material, described dyed layer comprises following component by weight percentage: resin 17-24%, Tissuemat E 1~2.5%, filler 15~17.5%, pigment 5~7.5%, dispersant 0.5~1.5%, solvent 48~55%.
Described resin is that modified polyester resin, PVC stick with paste resin and modified rosin fat, and three ingredients constitute total weight percent are respectively modified polyester resin 10-13%, PVC and stick with paste resin 5-7%, modified rosin fat 2-4%.
Described Tissuemat E is a micronizing wax.
Described filler can be calcium carbonate or talcum powder or super-fine silicon micro-powder.
Described pigment can be black pigment or red pigment, blue pigment, viridine green, yellow uitramarine, and black is iron black or dim with carbon black, the red pigment red, and blue pigment is blue or green blue with phthalein, viridine green phthalein viridescent, yellow uitramarine aniline yellow.
Described dispersant is poly-hydroxy acid salt or APEO or organic-silicon-modified polyoxyethylene ester.
Described solvent is MEK and dimethylbenzene, and two ingredients constitute percentage by weights are respectively MEK 33-38.5%, dimethylbenzene 15-16.5%.
Described base material is that the BOPET material of 12~14 μ m constitutes by thickness.
The plastic tube sign belt that adopts technical solutions according to the invention to make, be characterized in that dyed layer not only has colouring function, has fabulous adhesion function simultaneously, dyed layer can stick on the printed substrate well, difficult drop-off, scratch resistance are strong, have overcome to adopt the labyrinth that adds one deck adhesive layer on dyed layer again in some technical literature, have simplified product structure and production technology, reduced production cost, and properties of product do not reduce.
The specific embodiment
Further specify the present invention below in conjunction with example.
Composition of the present invention is mainly base material and dyed layer, and base material is BOPET, and dyed layer comprises following component: resin 17-24%, Tissuemat E 1~2.5%, filler 15~17.5%, pigment 5~7.5%, dispersant 0.5~1.5%, solvent 48~55%.
In the said components, resin is that the main body composition of dyed layer plays skeleton function, and Tissuemat E is even for guaranteeing the dyed layer smooth surface, scratch-resistant, and dispersant is the dispersion effect that is used to improve pigment, filler.Resin is that modified polyester resin, PVC stick with paste resin and modified rosin fat, and three ingredients constitute total weight percent are respectively modified polyester resin 10-13%, PVC and stick with paste resin 5-7%, modified rosin fat 2-4%.Tissuemat E is a micronizing wax.Filler can be calcium carbonate or talcum powder or super-fine silicon micro-powder.Pigment can be black pigment or red pigment, blue pigment, viridine green, yellow uitramarine, and black is iron black or dim with carbon black, the red pigment red, and blue pigment is blue or green blue with phthalein, viridine green phthalein viridescent, yellow uitramarine aniline yellow.Dispersant is poly-hydroxy acid salt or APEO or organic-silicon-modified polyoxyethylene ester.Solvent is MEK and dimethylbenzene, and two ingredients constitute percentage by weights are respectively MEK 33-38.5%, dimethylbenzene 15-16.5%.
Technology of the present invention is as follows:
By above-mentioned prescription, earlier resin dissolves in solvent, add other components, by sand mill system is uniformly dispersed, particle diameter is below 10 μ m, by coating apparatus the pigmented finiss that makes is coated on the BOPET film, coating thickness is 10~12 μ m, dries rolling under 50~80 ℃ of conditions, cut, just obtain the plastic tube sign colour band.
This dyed layer sensible heat function admirable, transferring rate is good, the temperature wide accommodation, in 80~180 ℃ scope, can observe clear transfer printing, and the carrier of undertaking the printing of is had good bonding force, and transfer printing writing neat in edge does not have hair, adhesive force is good, scratch-resistant, humidity, sun-resistant, and minimum can adapt to various character information carriers such as No. 8 Chinese, English, Arabic numerals.
Be the component tabulation of some embodiment below:
Embodiment 1
Figure C20071005453700051
Embodiment 2
Embodiment 3
Among the embodiment 1~3, base material is that thickness is the BOPET of 12 μ m, and the thickness of dyed layer is 10 μ m.
Embodiment 4
Embodiment 5
Figure C20071005453700055
Embodiment 6
Figure C20071005453700056
Among the embodiment 4~6, base material is that thickness is the BOPET of 12 μ m, and the thickness of dyed layer is 11 μ m.
Embodiment 7
Figure C20071005453700061
Embodiment 8
Figure C20071005453700062
Embodiment 9
Figure C20071005453700063
Among the embodiment 7~9, base material is that thickness is the BOPET of 12 μ m, and the thickness of dyed layer is 12 μ m.
Embodiment 10
Figure C20071005453700064
Embodiment 11
Figure C20071005453700065
Embodiment 12
Figure C20071005453700066
Among the embodiment 10~12, base material is that thickness is the BOPET of 13 μ m, and the thickness of dyed layer is 10 μ m.
Embodiment 13
Figure C20071005453700071
Embodiment 14
Figure C20071005453700072
Embodiment 15
Figure C20071005453700073
Among the embodiment 13~15, base material is that thickness is the BOPET of 13 μ m, and the thickness of dyed layer is 11 μ m.
Embodiment 16
Embodiment 17
Figure C20071005453700075
Embodiment 18
Figure C20071005453700076
Among the embodiment 16~18, base material is that thickness is the BOPET of 13 μ m, and the thickness of dyed layer is 12 μ m.
Embodiment 19
Embodiment 20
Figure C20071005453700082
Embodiment 21
Figure C20071005453700083
Among the embodiment 19~21, base material is that thickness is the BOPET of 14 μ m, and the thickness of dyed layer is 10 μ m.
Embodiment 22
Embodiment 23
Figure C20071005453700085
Embodiment 24
Figure C20071005453700086
Among the embodiment 22~24, base material is that thickness is the BOPET of 14 μ m, and the thickness of dyed layer is 11 μ m.
Embodiment 25
Figure C20071005453700091
Embodiment 26
Figure C20071005453700092
Embodiment 27
Figure C20071005453700093
Among the embodiment 25~27, base material is that thickness is the BOPET of 14 μ m, and the thickness of dyed layer is 12 μ m.

Claims (8)

1, a kind of plastic tube sign belt, form by the dyed layer on base material and the base material, it is characterized in that described dyed layer comprises following component by weight percentage: resin 17-24%, Tissuemat E 1~2.5%, filler 15~17.5%, pigment 5~7.5%, dispersant 0.5~1.5%, solvent 48~55%.
2, plastic tube sign belt as claimed in claim 1, it is characterized in that described resin is that modified polyester resin, PVC stick with paste resin and modified rosin fat, three ingredients constitute total weight percent are respectively modified polyester resin 10-13%, PVC and stick with paste resin 5-7%, modified rosin fat 2-4%.
3, plastic tube sign belt as claimed in claim 1 is characterized in that described Tissuemat E is a micronizing wax.
4, plastic tube sign belt as claimed in claim 1 is characterized in that described filler can be calcium carbonate or talcum powder or super-fine silicon micro-powder.
5, plastic tube sign belt as claimed in claim 1, it is characterized in that described pigment can be black pigment or red pigment, blue pigment, viridine green, yellow uitramarine, black is iron black or dim with carbon black, the red pigment red, blue pigment is blue or green blue with phthalein, viridine green phthalein viridescent, the yellow uitramarine aniline yellow.
6, plastic tube sign belt as claimed in claim 1 is characterized in that described dispersant is poly-hydroxy acid salt or APEO or organic-silicon-modified polyoxyethylene ester.
7, plastic tube sign belt as claimed in claim 1 is characterized in that described solvent is MEK and dimethylbenzene, and two ingredients constitute percentage by weights are respectively MEK 33-38.5%, dimethylbenzene 15-16.5%.
8,, it is characterized in that described base material is that the BOPET material of 12~14 μ m constitutes by thickness as the arbitrary described plastic tube sign belt of claim 1 to 7.
CNB2007100545376A 2007-06-08 2007-06-08 Plastic pipe marking belt Active CN100567013C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2007100545376A CN100567013C (en) 2007-06-08 2007-06-08 Plastic pipe marking belt

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Application Number Priority Date Filing Date Title
CNB2007100545376A CN100567013C (en) 2007-06-08 2007-06-08 Plastic pipe marking belt

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CN100567013C true CN100567013C (en) 2009-12-09

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101908296A (en) * 2009-06-03 2010-12-08 扬州腾飞电缆电器材料有限公司 Anti-counterfeiting identification tape
CN102431327B (en) * 2011-09-09 2013-06-12 杭州天地数码科技有限公司 Waterborne date printing ribbon and preparation method thereof
CN104015515B (en) * 2014-06-06 2016-04-13 东莞市瀛通电线有限公司 A kind of preparation method of heat transfer printing earphone cord and goods
CN104151676A (en) * 2014-08-28 2014-11-19 山东鲁燕色母粒有限公司 Preparation method of polyethylene water supply pipe blue identification specially-use material
CN104725706B (en) * 2015-04-01 2017-03-22 亚大塑料制品有限公司 Polyethylene pipe color marking color strip
CN107384012B (en) * 2017-08-22 2020-11-03 河南卓立膜材料股份有限公司 Cold-printed cable coding tape and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5017428A (en) * 1987-02-07 1991-05-21 Pelikan Aktiengesellschaft Multiple impression thermal transfer ribbon
CN1052450A (en) * 1990-11-29 1991-06-26 天津光电通信公司 At thermosensitive ribbon for transfer print surface of non-absorbent matter
CN1485217A (en) * 2002-09-29 2004-03-31 张振宇 Blanching pattern mark carbon band
CN1485379A (en) * 2002-09-29 2004-03-31 张振宇 Printing ink paint
CN1485384A (en) * 2002-09-29 2004-03-31 张振宇 Resin paint
CN1683166A (en) * 2004-04-16 2005-10-19 焦作市卓立烫印材料有限公司 Character-stamping carbon foil

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5017428A (en) * 1987-02-07 1991-05-21 Pelikan Aktiengesellschaft Multiple impression thermal transfer ribbon
CN1052450A (en) * 1990-11-29 1991-06-26 天津光电通信公司 At thermosensitive ribbon for transfer print surface of non-absorbent matter
CN1485217A (en) * 2002-09-29 2004-03-31 张振宇 Blanching pattern mark carbon band
CN1485379A (en) * 2002-09-29 2004-03-31 张振宇 Printing ink paint
CN1485384A (en) * 2002-09-29 2004-03-31 张振宇 Resin paint
CN1683166A (en) * 2004-04-16 2005-10-19 焦作市卓立烫印材料有限公司 Character-stamping carbon foil

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Owner name: HENAN ZHUOLI IMAGING TECHNOLOGY CO., LTD.

Free format text: FORMER NAME: ZHUOLI THERMOPRINTING MATERIAL CO., LTD., JIANZUO CITY

CP03 Change of name, title or address

Address after: 454003 No. 2758 Shenzhou Road, hi tech Zone, Henan, Jiaozuo

Patentee after: Henan Zhuoli Imaging Technology Co., Ltd.

Address before: 454003 No. 2 Shenzhou Road, hi tech Zone, Henan, Jiaozuo

Patentee before: Zhuoli Thermoprinting Material Co., Ltd., Jianzuo City

TR01 Transfer of patent right

Effective date of registration: 20191205

Address after: No. 959, Nanhai West Road, Jiaozuo demonstration area, Henan Province (in the hospital of Henan Zhuoli membrane materials Co., Ltd.)

Patentee after: Jiaozuo Zhuoli membrane materials Co., Ltd

Address before: 454003 No. 2758 Shenzhou Road, hi tech Zone, Henan, Jiaozuo

Patentee before: Henan Zhuoli Imaging Technology Co., Ltd.

TR01 Transfer of patent right
CP03 Change of name, title or address

Address after: 454000 No. 959, Nanhai West Road, demonstration zone, Jiaozuo City, Henan Province

Patentee after: Jiaozuo Zhuoli film material Co.,Ltd.

Address before: No. 959, Nanhai West Road, Jiaozuo demonstration area, Henan Province, 454000

Patentee before: Jiaozuo Zhuoli membrane materials Co.,Ltd.

CP03 Change of name, title or address