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CN100554395C - Low-concentration water-saving laundry detergent and preparation method thereof - Google Patents

Low-concentration water-saving laundry detergent and preparation method thereof Download PDF

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Publication number
CN100554395C
CN100554395C CNB2007101790356A CN200710179035A CN100554395C CN 100554395 C CN100554395 C CN 100554395C CN B2007101790356 A CNB2007101790356 A CN B2007101790356A CN 200710179035 A CN200710179035 A CN 200710179035A CN 100554395 C CN100554395 C CN 100554395C
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ether
aliphatic alcohol
alcohol polyethenoxy
water
polyethenoxy
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CN101186863A (en
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张辉
冯秀节
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Beijing green umbrella Technology Co.,Ltd.
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BEIJING LUSAN CHEMICAL Co Ltd
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Abstract

本发明涉及低浓度节水型洗衣液及其制备方法。本发明按重量份数比由下列组分组成:短支链型脂肪醇聚氧乙烯(7)醚0.1~10、脂肪醇聚氧乙烯(3)醚0.1~10、脂肪醇聚氧乙烯(5)醚0.1~5、脂肪醇聚氧乙烯(7)醚0.1~14、脂肪醇聚氧乙烯(9)醚0.1~14、70%脂肪醇聚氧乙烯醚硫酸钠1.0~14、柠檬酸钠0.001~5、纯碱0.001~5、碳酸钾0.001~5、硼砂0.001~5、荧光增白剂0.001~0.5、香精0.1~0.4、离子水70~85。本发明以低水污溶性非离子表面活性剂为主,与亲水性非离子,阴离子表面活性剂复合,既有好的去污力,又减少了使用量,还有较高的表现粘度,洗涤后漂洗两次比普通洗衣粉漂洗液的残留量还低,可大大节省水电等资源。The invention relates to a low-concentration water-saving laundry detergent and a preparation method thereof. The present invention consists of the following components in parts by weight: short-chain branched fatty alcohol polyoxyethylene (7) ether 0.1-10, fatty alcohol polyoxyethylene (3) ether 0.1-10, fatty alcohol polyoxyethylene (5 ) ether 0.1~5, fatty alcohol polyoxyethylene (7) ether 0.1~14, fatty alcohol polyoxyethylene (9) ether 0.1~14, 70% fatty alcohol polyoxyethylene ether sodium sulfate 1.0~14, sodium citrate 0.001 ~5, soda ash 0.001~5, potassium carbonate 0.001~5, borax 0.001~5, fluorescent whitening agent 0.001~0.5, essence 0.1~0.4, ionized water 70~85. The present invention is based on low water-pollution-soluble nonionic surfactants, compounded with hydrophilic nonionic and anionic surfactants, which not only has good detergency, but also reduces the amount of use, and has higher apparent viscosity. After washing, rinsing twice has a lower residual amount than ordinary washing powder rinsing liquid, which can greatly save resources such as water and electricity.

Description

Low concentration water-saving type clothes washing agent and preparation method thereof
Technical field
The present invention relates to household chemicals, relate in particular to low concentration water-saving type clothes washing agent and preparation method thereof.
Background technology
Washing liquid has become the requisite in the daily life, and cleaning clothes needs washing liquid, but needs repeatedly rinsing during rinsing clothes, could the clothing rinsing is clean, thereby consumed a large amount of water, wasted water resources, increased the work or the working strength of people and washing machine etc.This is owing to used the exhibiting high surface promoting agent in the washing liquid in the market, can form a large amount of foams, and is difficult for disappearing, and it is clean to be difficult to rinsing.
Washing liquid is compared with washing powder, owing to can not add too much auxiliary agent, therefore must increase detersive power by the content that improves tensio-active agent, but anti-hard water of general anion surfactant and antiredeposition are poor, therefore detersive power is not high, and nonionogenic tenside commonly used, though anti-hard water, antiredeposition is good, but go solid dirt ability relatively poor, therefore, generally adopt the compound detersive power that improves of more anion surfactant and nonionogenic tenside, but the surfactant dissolves degree is limited, must add dispersion agent and solubility promoter, and dispersion agent, the increase of solubility promoter can reduce apparent viscosity, and appearance effect is bad, this must add thickening material again, and can reduce detersive power like this, therefore, must strengthen the consumption of tensio-active agent again once more, and then cause the wasting of resources and washing after stain quantity discharged to increase, and it is clean to be difficult for rinsing.
Summary of the invention
The objective of the invention is to overcome deficiency of the prior art, two kinds of low concentration water-saving type clothes washing agents and preparation method thereof are provided, the present invention is based on the low water solubility nonionogenic tenside, with the wetting ability nonionic, anion surfactant is compound, and good detersive power is promptly arranged, reduced usage quantity again, also have higher viscosity, twice of post rinsing of washing is also lower than the residual quantity of common washing powder rinsing three times, can save resources such as water power greatly.
The objective of the invention is to be achieved through the following technical solutions:
A kind of low concentration water-saving type clothes washing agent, form by following component by ratio of weight and the number of copies:
Aliphatic alcohol polyethenoxy (7) ether 0.1~14
Aliphatic alcohol polyethenoxy (9) ether 0.1~14
Aliphatic alcohol polyethenoxy (3) ether 0.1~10
70% polyoxyethylenated alcohol sodium sulfate 1.0~14
Soda ash 0.001~5
Salt of wormwood 0.001~5
Borax 0.001~5
Aliphatic alcohol polyethenoxy (5) ether 0.1~5
Trisodium Citrate 0.001~5
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.1~10
White dyes 0.001~0.5
Essence 0.1~0.4
Deionized water 70~85.
Its preparation method is: by ratio of weight and the number of copies, with 70~85 parts of deionized waters wherein 30~40% be heated to 65 ℃~75 ℃, in the addingization material still, under agitation add short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.1~10 then successively, aliphatic alcohol polyethenoxy (3) ether 0.1~10, aliphatic alcohol polyethenoxy (5) ether 0.1~5, aliphatic alcohol polyethenoxy (7) ether 0.1~14, aliphatic alcohol polyethenoxy (9) ether 0.1~14,70% polyoxyethylenated alcohol sodium sulfate 1.0~14, after Trisodium Citrate 0.001~5 stirs, add remaining deionized water, all after the dissolving, add soda ash 0.001~5, salt of wormwood 0.001~5, borax 0.001~5, white dyes 0.001~0.5 stirring and dissolving, when being cooled to 35 ℃~45 ℃, adding essence 0.1~0.4 stirs, filter with 200 order filtering nets, get low concentration water-saving type clothes washing agent.
A kind of low concentration water-saving type clothes washing agent, form by following component by ratio of weight and the number of copies:
Aliphatic alcohol polyethenoxy (7) ether 0.1~14
Aliphatic alcohol polyethenoxy (9) ether 0.1~14
Aliphatic alcohol polyethenoxy (3) ether 0.1~10
70% polyoxyethylenated alcohol sodium sulfate 1.0~14
Soda ash 0.001~5
Salt of wormwood 0.001~5
Borax 0.001~5
Trisodium Citrate 0.001~5
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.1~10
White dyes 0.001~0.5
Essence 0.1~0.4
Deionized water 70~85.
Its preparation method is: by ratio of weight and the number of copies, with 70~85 parts of deionized waters wherein 30~40% be heated to 65 ℃~75 ℃, in the addingization material still, under agitation add short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.1~10 then successively, aliphatic alcohol polyethenoxy (3) ether 0.1~10, aliphatic alcohol polyethenoxy (7) ether 0.1~14, aliphatic alcohol polyethenoxy (9) ether 0.1~14,70% polyoxyethylenated alcohol sodium sulfate 1.0~14, after Trisodium Citrate 0.001~5 stirs, add remaining deionized water, all after the dissolving, add soda ash 0.001~5, salt of wormwood 0.001~5, borax 0.001~5, white dyes 0.001~0.5 stirring and dissolving, when being cooled to 35 ℃~45 ℃, adding essence 0.1~0.4 stirs, filter with 200 order filtering nets, get low concentration water-saving type clothes washing agent.
The invention has the beneficial effects as follows: detersive power of the present invention reaches national sector standard QB1224-1991 requirement.Surfactant content of the present invention is less than 13%, and solid content is less than 20%.Processable of the present invention is good, and detersive power is good, and foaming is few, can reduce the rinsing number of times, and water-saving performance is good, can reduce the work or the working strength of people and washing machine.The present invention is satisfying under the condition of detersive power, than standard washing powder water saving 1/4~1/3, lacks rinsing once than common washing powder.
Embodiment
Provide embodiments of the invention and preparation method below
A kind of low concentration water-saving type clothes washing agent, form by following component by ratio of weight and the number of copies:
Aliphatic alcohol polyethenoxy (7) ether 0.1~14
Aliphatic alcohol polyethenoxy (9) ether 0.1~14
Aliphatic alcohol polyethenoxy (3) ether 0.1~10
70% polyoxyethylenated alcohol sodium sulfate 1.0~14
Soda ash 0.001~5
Salt of wormwood 0.001~5
Borax 0.001~5
Aliphatic alcohol polyethenoxy (5) ether 0.1~5
Trisodium Citrate 0.001~5
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.1~10
White dyes 0.001~0.5
Essence 0.1~0.4
Deionized water 70~85.
Embodiment 1:
The 100kg low concentration water-saving type clothes washing agent, form by following component:
Aliphatic alcohol polyethenoxy (7) ether 6kg
Aliphatic alcohol polyethenoxy (9) ether 1kg
Aliphatic alcohol polyethenoxy (3) ether 0.3kg
70% polyoxyethylenated alcohol sodium sulfate 4kg
Soda ash 0.3kg
Carbonic acid 2kg
Borax 1kg
Aliphatic alcohol polyethenoxy (5) ether 1.5kg
Trisodium Citrate 1kg
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.3kg
White dyes 0.8kg
Essence 0.2kg
Deionized water 82.6kg.
The low concentration water-saving type clothes washing agent detersive power of present embodiment reaches national sector standard QB1224-1991 requirement.
Surfactant content: 11.9%;
Viscosity: greater than 60 seconds (25 ℃, be coated with 4 glasss);
Water-saving performance: than standard washing powder water saving 1/4~1/3.
Embodiment 2:
The 100kg low concentration water-saving type clothes washing agent, form by following component:
Aliphatic alcohol polyethenoxy (7) ether 0.1kg
Aliphatic alcohol polyethenoxy (9) ether 11kg
Aliphatic alcohol polyethenoxy (3) ether 0.6kg
70% polyoxyethylenated alcohol sodium sulfate 1kg
Soda ash 0.001kg
Salt of wormwood 3kg
Borax 0.001kg
Aliphatic alcohol polyethenoxy (5) ether 0.5kg
Trisodium Citrate 1kg
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.1kg
White dyes 0.02kg
Essence 0.1kg
Deionized water 82.578kg.
The low concentration water-saving type clothes washing agent detersive power of present embodiment reaches national sector standard QB1224-1991 requirement.
Surfactant content: 12.9%;
Viscosity: greater than 60 seconds (25 ℃, be coated with 4 glasss);
Water-saving performance: than standard washing powder water saving 1/4~1/3.
Embodiment 3:
The 100kg low concentration water-saving type clothes washing agent, form by following component:
Aliphatic alcohol polyethenoxy (7) ether 1kg
Aliphatic alcohol polyethenoxy (9) ether 0.1kg
Aliphatic alcohol polyethenoxy (3) ether 1kg
70% polyoxyethylenated alcohol sodium sulfate 4kg
Soda ash 0.001kg
Salt of wormwood 0.001kg
Borax 0.001kg
Aliphatic alcohol polyethenoxy (5) ether 0.1kg
Trisodium Citrate 5kg
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 8kg
White dyes 0.5kg
Essence 0.4kg
Deionized water 79.897kg.
The low concentration water-saving type clothes washing agent detersive power of present embodiment reaches national sector standard QB1224-1991 requirement.
Surfactant content: 12.9%;
Viscosity: less than 45 seconds (25 ℃, be coated with 4 glasss);
Water-saving performance: than standard washing powder water saving 1/4~1/3.
In the component of the present invention, aliphatic alcohol polyethenoxy (3) ether (English name abbreviation AEO-3), aliphatic alcohol polyethenoxy (5) ether (English name abbreviation AEO-5), aliphatic alcohol polyethenoxy (7) ether (English name abbreviation AEO-7), aliphatic alcohol polyethenoxy (9) ether (English name abbreviation AEO-9) etc. are nonionogenic tenside, and greasy dirt is had well emulsify, solublization.Wherein aliphatic alcohol polyethenoxy (3) ether is the water-insoluble tensio-active agent, but compound with other tensio-active agent, water soluble can increase surfactivity greatly, increases the perviousness and the power of deoiling, and can also increase viscosity.Aliphatic alcohol polyethenoxy (5) ether, aliphatic alcohol polyethenoxy (7) ether are the low water solubility tensio-active agent, and emulsification greasy dirt power is strong, and aliphatic alcohol polyethenoxy (9) ether is the hydrophilic surfactant active, can decontamination.To be 70% polyoxyethylenated alcohol sodium sulfate (English name abbreviation AES) be anti-hard water anion surfactant preferably to concentration, and it is strong to remove the solid dirt.White dyes (English name abbreviation CF-351) can improve the appearance effect of solution, can increase the whiteness behind the clothes washing again.Short-chain branch type aliphatic alcohol polyethenoxy (7) ether (English name abbreviation XL-70) has very strong infiltration decontamination promoter action.
Its preparation method is: 30~40% of deionized water 7 is heated to 65 ℃~75 ℃, in the addingization material still, under agitation add short-chain branch type aliphatic alcohol polyethenoxy (7) ether then successively, aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (5) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether, polyoxyethylenated alcohol sodium sulfate (concentration 70%), after Trisodium Citrate stirs, add remaining deionized water, all after the dissolving, add soda ash, salt of wormwood, borax, the white dyes stirring and dissolving, when being cooled to 35 ℃~45 ℃, adding essence stirs, filter with 200 order filtering nets, get low concentration water-saving type clothes washing agent.
It is noted that: the entire operation process must guarantee the quality of deionized water, and Fe can not be arranged 2+, Mg 2+, Ca 2+Plasma is brought into and is precipitated.Soda ash, salt of wormwood, borax if any impurity should first dissolution filter after usefulness again, can not have mechanical impurity band to go into.Entire operation clean environment health, dustproof.
A kind of low concentration water-saving type clothes washing agent, form by following component by ratio of weight and the number of copies:
Aliphatic alcohol polyethenoxy (7) ether 0.1~14
Aliphatic alcohol polyethenoxy (9) ether 0.1~14
Aliphatic alcohol polyethenoxy (3) ether 0.1~10
70% polyoxyethylenated alcohol sodium sulfate 1.0~14
Soda ash 0.001~5
Salt of wormwood 0.001~5
Borax 0.001~5
Trisodium Citrate 0.001~5
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.1~10
White dyes 0.001~0.5
Essence 0.1~0.4
Deionized water 70~85.
Embodiment 4:
The 100kg low concentration water-saving type clothes washing agent, form by following component:
Aliphatic alcohol polyethenoxy (7) ether 2kg
Aliphatic alcohol polyethenoxy (9) ether 2.5kg
Aliphatic alcohol polyethenoxy (3) ether 0.3kg
70% polyoxyethylenated alcohol sodium sulfate 10kg
Soda ash 0.3kg
Salt of wormwood 2kg
Borax 1kg
Trisodium Citrate 1kg
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.3kg
White dyes 0.02kg
Essence 0.2kg
Deionized water 80.38kg.
The low concentration water-saving type clothes washing agent detersive power of present embodiment reaches national sector standard QB1224-1991 requirement.
Surfactant content: 11.9%;
Viscosity: less than 45 seconds (25 ℃, be coated with 4 glasss);
Water-saving performance: than standard washing powder water saving 1/4~1/3.
In the component of the present invention, anion surfactants such as aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether have well emulsify, increase the effect of living greasy dirt.Wherein aliphatic alcohol polyethenoxy (3) ether is the water-insoluble tensio-active agent, but compound with other tensio-active agent, water soluble can increase surfactivity greatly, increases the perviousness and the power of deoiling, and can also increase viscosity.Aliphatic alcohol polyethenoxy (7) ether is the low water solubility tensio-active agent, and emulsification greasy dirt power is strong, and aliphatic alcohol polyethenoxy (9) ether is the hydrophilic surfactant active, can decontamination.Polyoxyethylenated alcohol sodium sulfate (concentration is 70%) is an anti-hard water anion surfactant preferably, and it is strong to remove the solid dirt.White dyes can improve the appearance effect of solution, can increase the whiteness behind the clothes washing again.Short-chain branch type aliphatic alcohol polyethenoxy (7) ether has very strong infiltration decontamination promoter action.Do not contain aliphatic alcohol polyethenoxy (5) ether in the component of the present invention.
Its preparation method is: 30~40% of deionized water is heated to 65 ℃~75 ℃, in the addingization material still, under agitation add short-chain branch type aliphatic alcohol polyethenoxy (7) ether then successively, aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether, polyoxyethylenated alcohol sodium sulfate (concentration 70%), after Trisodium Citrate stirs, add remaining deionized water, all after the dissolving, add soda ash, salt of wormwood, borax, the white dyes stirring and dissolving, when being cooled to 35 ℃~45 ℃, adding essence stirs, filter with 200 order filtering nets, get low concentration water-saving type clothes washing agent.。
It is noted that: the entire operation process must guarantee the quality of deionized water, and Fe can not be arranged 2+, Mg 2+, Ca 2+Plasma is brought into and is precipitated.Soda ash, salt of wormwood, borax if any impurity should first dissolution filter after usefulness again, can not have mechanical impurity band to go into.Entire operation clean environment health, dustproof.

Claims (8)

1, a kind of low concentration water-saving type clothes washing agent is characterized in that, is made up of following component by ratio of weight and the number of copies:
Aliphatic alcohol polyethenoxy (7) ether 0.1~14
Aliphatic alcohol polyethenoxy (9) ether 0.1~14
Aliphatic alcohol polyethenoxy (3) ether 0.1~10
70% polyoxyethylenated alcohol sodium sulfate 1.0~14
Soda ash 0.001~5
Salt of wormwood 0.001~5
Borax 0.001~5
Aliphatic alcohol polyethenoxy (5) ether 0.1~5
Trisodium Citrate 0.001~5
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.1~10
White dyes 0.001~0.5
Essence 0.1~0.4
Deionized water 70~85.
2, low concentration water-saving type clothes washing agent according to claim 1 is characterized in that, is made up of following component by ratio of weight and the number of copies:
Aliphatic alcohol polyethenoxy (7) ether 6
Aliphatic alcohol polyethenoxy (9) ether 1
Aliphatic alcohol polyethenoxy (3) ether 0.3
70% polyoxyethylenated alcohol sodium sulfate 4
Soda ash 0.3
Salt of wormwood 2
Borax 1
Aliphatic alcohol polyethenoxy (5) ether 1.5
Trisodium Citrate 1
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.3
White dyes 0.8
Essence 0.2
Deionized water 82.6.
3, low concentration water-saving type clothes washing agent according to claim 1 is characterized in that, is made up of following component by ratio of weight and the number of copies:
Aliphatic alcohol polyethenoxy (7) ether 0.1
Aliphatic alcohol polyethenoxy (9) ether 11
Aliphatic alcohol polyethenoxy (3) ether 0.6
70% polyoxyethylenated alcohol sodium sulfate 1
Soda ash 0.001
Salt of wormwood 3
Borax 0.001
Aliphatic alcohol polyethenoxy (5) ether 0.5
Trisodium Citrate 1
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.1
White dyes 0.02
Essence 0.1
Deionized water 82.578.
4, low concentration water-saving type clothes washing agent according to claim 1 is characterized in that, is made up of following component by ratio of weight and the number of copies:
Aliphatic alcohol polyethenoxy (7) ether 1
Aliphatic alcohol polyethenoxy (9) ether 0.1
Aliphatic alcohol polyethenoxy (3) ether 1
70% polyoxyethylenated alcohol sodium sulfate 4
Soda ash 0.001
Salt of wormwood 0.001
Borax 0.001
Aliphatic alcohol polyethenoxy (5) ether 0.1
Trisodium Citrate 5
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 8
White dyes 0.5
Essence 0.4
Deionized water 79.897.
5, a kind of low concentration water-saving type clothes washing agent is characterized in that, is made up of following component by ratio of weight and the number of copies:
Aliphatic alcohol polyethenoxy (7) ether 0.1~14
Aliphatic alcohol polyethenoxy (9) ether 0.1~14
Aliphatic alcohol polyethenoxy (3) ether 0.1~10
70% polyoxyethylenated alcohol sodium sulfate 1.0~14
Soda ash 0.001~5
Salt of wormwood 0.001~5
Borax 0.001~5
Trisodium Citrate 0.001~5
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.1~10
White dyes 0.001~0.5
Essence 0.1~0.4
Deionized water 70~85.
6, low concentration water-saving type clothes washing agent according to claim 5 is characterized in that, is made up of following component by ratio of weight and the number of copies:
Aliphatic alcohol polyethenoxy (7) ether 2
Aliphatic alcohol polyethenoxy (9) ether 2.5
Aliphatic alcohol polyethenoxy (3) ether 0.3
70% polyoxyethylenated alcohol sodium sulfate 10
Soda ash 0.3
Salt of wormwood 2
Borax 1
Trisodium Citrate 1
Short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.3
White dyes 0.02
Essence 0.2
Deionized water 80.38.
7, a kind of low concentration water-saving type clothes washing agent preparation method as claimed in claim 1, it is characterized in that: by ratio of weight and the number of copies, with 70~85 parts of deionized waters wherein 30~40% be heated to 65 ℃~75 ℃, in the addingization material still, under agitation add short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.1~10 then successively, aliphatic alcohol polyethenoxy (3) ether 0.1~10, aliphatic alcohol polyethenoxy (5) ether 0.1~5, aliphatic alcohol polyethenoxy (7) ether 0.1~14, aliphatic alcohol polyethenoxy (9) ether 0.1~14,70% polyoxyethylenated alcohol sodium sulfate 1.0~14, after Trisodium Citrate 0.001~5 stirs, add remaining deionized water, all after the dissolving, add soda ash 0.001~5, salt of wormwood 0.001~5, borax 0.001~5, white dyes 0.001~0.5 stirring and dissolving, when being cooled to 35 ℃~45 ℃, adding essence 0.1~0.4 stirs, filter with 200 order filtering nets, get low concentration water-saving type clothes washing agent.
8, a kind of low concentration water-saving type clothes washing agent preparation method as claimed in claim 5, it is characterized in that: by ratio of weight and the number of copies, with 70~85 parts of deionized waters wherein 30~40% be heated to 65 ℃~75 ℃, in the addingization material still, under agitation add short-chain branch type aliphatic alcohol polyethenoxy (7) ether 0.1~10 then successively, aliphatic alcohol polyethenoxy (3) ether 0.1~10, aliphatic alcohol polyethenoxy (7) ether 0.1~14, aliphatic alcohol polyethenoxy (9) ether 0.1~14,70% polyoxyethylenated alcohol sodium sulfate 1.0~14, after Trisodium Citrate 0.001~5 stirs, add remaining deionized water, all after the dissolving, add soda ash 0.001~5, salt of wormwood 0.001~5, borax 0.001~5, white dyes 0.001~0.5 stirring and dissolving, when being cooled to 35 ℃~45 ℃, adding essence 0.1~0.4 stirs, filter with 200 order filtering nets, get low concentration water-saving type clothes washing agent.
CNB2007101790356A 2007-12-10 2007-12-10 Low-concentration water-saving laundry detergent and preparation method thereof Active CN100554395C (en)

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CN100554395C true CN100554395C (en) 2009-10-28

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Publication number Priority date Publication date Assignee Title
CN102796626B (en) * 2012-08-29 2019-04-26 朱上翔 A kind of activator washed and rinsed for ionic washer low-temperature energy-saving master
CN103666805B (en) * 2012-08-29 2018-06-05 狮王株式会社 Liquid detergent
CN102876517A (en) * 2012-10-30 2013-01-16 葛新 Mineral-element quick clothing cleaning agent
CN109810802B (en) * 2019-01-31 2021-04-30 东莞市嘉宏有机硅科技有限公司 Stain-resistant silk cleaning detergent and preparation method thereof
CN117510972B (en) * 2023-12-21 2024-07-23 河北雄沃防火科技有限公司 Low-carbon environment-friendly foaming agent and preparation method thereof

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