CN100398599C - Parasiticidal pet collar material and making process of pet collar - Google Patents
Parasiticidal pet collar material and making process of pet collar Download PDFInfo
- Publication number
- CN100398599C CN100398599C CNB2006100962774A CN200610096277A CN100398599C CN 100398599 C CN100398599 C CN 100398599C CN B2006100962774 A CNB2006100962774 A CN B2006100962774A CN 200610096277 A CN200610096277 A CN 200610096277A CN 100398599 C CN100398599 C CN 100398599C
- Authority
- CN
- China
- Prior art keywords
- pet
- deinsectization
- loop material
- item loop
- pet deinsectization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The present invention is parasiticidal pet collar material and the making process of pet collar. The parasiticidal pet collar material includes one active component and one matrix component in the weight ratio of 0.03-0.08 to 1. The active component consists of pentmethrin 0.5-1 weight portions, refined dipterex 1 weight portions, synthetic borneol 1 weight portions, silica 0.5-1 weight portions and adhesive 1 weight portions; and the matrix component consists of PVC 70-75 weight portions, dioctyl phthalate 15-18 weight portions, dibutyl phthalate 7-15 weight portions. The present invention has the advantages of ensured material source, excellent slow release effect, last acting, high parasiticidal effect, etc.
Description
Technical field
The invention belongs to and follow the outside utensil of pet to use the material technology field, more particularly relate to and a kind ofly be used to remove domestic pets such as cat, the verminal pet deinsectization of dog item loop material, and relate to the method for making the deinsectization necklace of this material.
Background technology
The history that cat, dog become domestic pets is of long duration, especially along with the improvement of modern people's living standard and extensiveization that various hobbies are pursued, cat, dog no longer are notional before power official, rich and honour persons' patent as pet, common ordinary citizen's family feeds and keeps a cat, dog is grown with each passing day, yet easily grow, be infected with for example common parasite of various parasites such as flea, lice, tick, mite etc. because cat, dog are external, therefore, remove the ectozoic drug material of pet body not only by veterinary drug production circle paid close attention to, and paid attention to by pet owners.
Before, mainly take on cat, the external various as the aforementioned parasitic effects of dog of removing by the fluent material of liniment, clean-out system, spray, injection and so on, because this material does not have slow releasing function, therefore only can play the effect in a period of time, so after medication very short time entozoa again can superinfection, must be regularly or dispenser aperiodically, thereby trouble not only, and the health of cat, dog produced adverse influence, for example the intramuscular injection meeting undermines all the other internal organs.
Given this, the various necklace through impregnation medicine post-treatment gained that is worn on cat, dog neck just is seen in market, and this necklace has mitigation, wears once unpacking, and the time length can reach 1-2 month, is subjected to pet master's welcome.
At present, the item that commercially available Pet neck ring is processed as pharmaceutical compositions with amitraz, diazine Nong sterilant is enclosed leading, also almost like this abroad, and for example France's dimension gram pharmaceutical factory limited-liability company produces diazine Nong necklace is arranged.Though diazine Nong is the moderate toxicity sterilant, pure product are liquid colourless, odorless, control cotton, vegetables, rice grub and subterranean pest-insect are had good function, but pet is had susceptibility, pet especially cat is worn this necklace and can show irritated phenomenon.
The method of making necklace at present is mainly pickling process and squeegee process, medicine components is immersed or be applied on the carrier (matrix), the Pet neck ring of Zhi Zuoing in this way, duration of service is short, and when making, can undermine human body, and drug dose is difficult to grasp, drug waste is big, causes the necklace cost height of going on the market.
The applicant has also carried out literature search, and the patent documentation of searching is: A) .CN1425287A, B) .CN1586181A, C) .CN1694618A.
Above-mentioned document A) introduced kind of plant flea-repellent neck ring and preparation method thereof, it is to extract active princlple with industrial ethyl acetate from Lysimachia foenum-graecum, make the Lysimachia foenum-graecum acetic acid ethyl acetate extract, mix with the litsea cubeba oil of citral content more than 80% again, make carrier, the mixed solution of Lysimachia foenum-graecum acetic acid ethyl acetate extract and litsea cubeba oil is adsorbed onto on the carrier with perlite, vermiculite or diatomite, get solid material, add deodorant tune again, in the permeability cell of packing into, get necklace.Though this technical scheme has environmentally safe, the strong point of not having injury in pet, but have following shortcoming: the one, because the growth of Lysimachia foenum-graecum is subjected to regional restriction, be suitable for Yunnan Province of China, Guizhou, Guangxi plantation, what be subject to therefore that starting material ensure pining down; The 2nd, the processing and fabricating cycle is tediously long, only Lysimachia foenum-graecum mummification and time of being soaked in the ethyl acetate need be reached 20-28h, and the equipment input is expensive as will use reactor, retort or the like; The 3rd, making step is loaded down with trivial details, is not suitable for suitability for industrialized production, in for example solid material is packed into necklace of being made by leather or the permeability cell that is made of plastics, and the step that annulus is made at two ends is all needed manual finishing; The 4th, medicine with can't organically combine together as leather, the plastics permeability cell of carrier, belong to indirect repellent, effect can be inferior, therefore, market is not seen so far the product in this time.
Above-mentioned document B) disclosed is a kind of pet with hair and ectozoal natural drug necklace of furbearer and preparation method thereof killed, this technical scheme is by document A) same applicant recommended, have the applicant equally to document A) mentioned advantage and deficiency in the narration.
Above-mentioned document C) promotion domestic animal necklace, belt or armour, do not reach and be used to remove parasitic material in the necklace and with removing the technology enlightenment that parasitic materials processing becomes necklace.
In addition, the applicant be also noted that by French Merial to China file an application and granted notification number be CN1225167C, name be called with the N-phenylpyrazole be principal constituent be used for controlling flea and controlling tick control collar of dog and cat, it is to take on active substance (prescription 1 of Instructions Page 9 and prescription 2) alone as the single composition of N-phenylpyrazole of long-acting veterinary injection, though can show its alleged effect (the 8th page in specification sheets), the sealing preservation period of the necklace of making can be subjected to corresponding influence; Patent and concrete making method.
Summary of the invention
Task of the present invention be to provide a kind of starting material source that can fully ensure, that active substance release is satisfactory for result, can integrate smoked kill and stomach toxicity and the effect of tagging, action time is worn in unpacking and long pet deinsectization item loop material working lipe is preserved in sealing.
Task of the present invention also is to provide a kind of method of making the deinsectization necklace, and this method can shorten process period, the equipment of use simple, can satisfy industrial mass production.
Task of the present invention is finished like this, a kind of pet deinsectization item loop material, it comprises active constituent and matrix component, and described active constituent is that the raw material by following weight part ratio constitutes: 1 part of pentmethrin 0.5-1 part, 1 part of refining dipterex, 1 part of borneolum syntheticum, silicon-dioxide 0.5-1 part, binding agent; Described matrix component is that the raw material by following weight part ratio constitutes, polyvinyl chloride (PVC) 70-75 part, dioctyl phthalate (DOP) 15-18 part, dibutyl phthalate 7-15 part, wherein: the weight part ratio of active constituent and matrix component is 0.03-0.08: 1.
Also include pigment 0.5-1 part in the matrix component of the present invention, described pigment is any one in EG transparent red, 9GF fluorescent yellow, the 3G fluorescence green.
Polyvinyl chloride of the present invention (PVC) is a medical polyvinyl, and described binding agent is a medical starch.
An also task of the present invention is finished like this, a kind of method of making the deinsectization necklace, and it may further comprise the steps:
A) produce active material, by weight, earlier with pentmethrin and silicon-dioxide absorption, together pulverize with borneolum syntheticum, refining dipterex then and sieve, mixing, add binding agent again, obtain granular active material through granulation, drying, stand-by;
B) produce the matrix material, by weight, polyvinyl chloride and dioctyl phthalate (DOP), dibutyl phthalate are mediated,, obtain granular matrix material again by the forcing machine heating plasticizing, stand-by;
C) produce compound, active material is mixed by weight with the matrix material, obtain compound;
D) molded, the item that compound is put on the injection moulding machine is molded and shaped in the ring mould, obtain finished product deinsectization necklace, pack.
In one embodiment of this invention, the absorption described in the step a) is to place container to stir fully pentmethrin and silicon-dioxide, and pentmethrin is received in the silicon-dioxide; Described sieving to crossing the 40-60 mesh sieve.
In another embodiment of the present invention, the exsiccant temperature described in the step a) is＜60 ℃, particle water content＜3%, and described particulate diameter is 3-6mm.
In an also embodiment of the present invention, the kneading described in the step b) is that kneader is mediated, and kneading time and temperature are respectively 6-10 minute and 90-120 ℃ and add pigment when mediating.
In an embodiment more of the present invention, the temperature of the heating plasticizing described in the step b) is 90-120 ℃, and described particulate diameter is 3-6mm.
In another embodiment of the present invention, molded and shaped temperature is 120-140 ℃ described in the step d), and the time is 1-3 minute.
One of the present invention's advantage compared with the prior art, all raw materials all can fully ensure the source by commercially available acquisition; Two owing to used and have volatile borneolum syntheticum, so have the good slow release effect, the use of unpacking back is sustainable more than 3 months, can continue more than 2 years under the sealed state; Three, have the selecting with producing good stomach toxicity, contact poison effect of volatile refining dipterex to parasite, pentmethrin and refining dipterex is shared, can produce excellent smoked kill effect to parasite; Four, method steps is few, preparation time is short, and need not use harsh such as reactor, retort kind equipment and only need conventional device can satisfy the mass production requirement.
Description of drawings
Fig. 1 is the structure iron of the embodiment of the invention 1,2 resulting deinsectization necklaces.
Fig. 2 is the structure iron of the embodiment of the invention 3 resulting deinsectization necklaces.
Fig. 3 is the structure iron of the embodiment of the invention 4 resulting deinsectization necklaces.
Embodiment
Embodiment 1:
A) produce active material, take by weighing 0.6 part of the pentmethrin produced by the Chinese Shanghai Westen and Chinese Tranditional Medicine Pharamacentic Factory, directly by 0.6 part of the silicon-dioxide of commercially available acquisition, then both being put into container fully stirs, until pentmethrin all being absorbed by silicon-dioxide, and then will be absorbed with the silicon-dioxide of pentmethrin and 1 part of borneolum syntheticum and refining dipterex and together for example preferably adopt by the safe and sound pharmaceutical machine of Jiangsu Province, China Changzhou company limited for 1 part and produce by shredding unit, the omnipotent Highefficientpulverizer of the 30B type of selling is pulverized, cross 60 mesh sieves, produce by the super good drying plant of Jiangsu Province, China Changzhou company limited with mixer instance such as preferred use again, the CH trough type mixing machine of selling or employing Jiangyin City, Jiangsu Province, China Yongchang medicine machine works produce, the CHJ-V high efficient mixed machine of selling mixes, when mixing, add such as producing by Weifang, Chinese Shandong Sheng Tai pharmaceutcal corporation, Ltd, 1 part of the medical starch of selling, granulate with granulator, granulator is as adopting the super good drying plant of Jiangsu Province, China Changzhou company limited to produce, the YK series Pendulargranulator of selling, under＜60 ℃ of temperature, be dried to water ratio＜3% by loft drier then, obtain particle diameter and be the particulate state active material of 3～6mm, stand-by;
B) produce the matrix material, the parts by weights another name is got 72 parts of medical grade polyvinyl chloride, 16 parts of dioctyl phthalate (DOP)s, 12 parts of dibutyl phthalates, for example produce by Zhangjagang City, Jiangsu Province, China Great Wall machinofacture company limited with kneader by preferred employing, the SHR-100A kneader of selling was mediated 10 minutes under 90 ℃ of temperature, in kneading process, add 0.6 part of ED transparent red, send the forcing machine heating plasticizing then, plasticization temperature is 95 ℃, obtaining particle diameter is the particulate state matrix material of 3～6mm, stand-by, this particulate state matrix material is intended for the carrier of active material;
C) produce compound, take by weighing 0.04 part of active material, 1 part in matrix material by weight, and, obtain compound both mixings;
D) molded, by being installed on the item ring mould compression molding on the injection moulding machine, obtaining after 120 ℃, 2 minutes by color shown in Figure 1 is the finished product deinsectization necklace that is applicable to cat of transparent red, packs then with compound.
Embodiment 2:
A) produce active material, take by weighing 0.7 part of the pentmethrin produced by the Chinese Shanghai Westen and Chinese Tranditional Medicine Pharamacentic Factory, directly by 0.7 part of the silicon-dioxide of commercially available acquisition, then both being put into container fully stirs, until pentmethrin all being absorbed by silicon-dioxide, and then will be absorbed with the silicon-dioxide of pentmethrin and 1 part of borneolum syntheticum and refining dipterex and together for example preferably adopt by the safe and sound pharmaceutical machine of Jiangsu Province, China Changzhou company limited for 1 part and produce by shredding unit, the omnipotent Highefficientpulverizer of the 30B type of selling is pulverized, cross 50 mesh sieves, produce by the super good drying plant of Jiangsu Province, China Changzhou company limited with mixer instance such as preferred use again, the CH trough type mixing machine of selling or employing Jiangyin City, Jiangsu Province, China Yongchang medicine machine works produce, the CHJ-V high efficient mixed machine of selling mixes, when mixing, add such as producing by Weifang, Chinese Shandong Sheng Tai pharmaceutcal corporation, Ltd, 1 part of the medical starch of selling, granulate with granulator, granulator is as adopting the super good drying plant of Jiangsu Province, China Changzhou company limited to produce, the YK series Pendulargranulator of selling, under＜60 ℃ of temperature, be dried to water ratio＜3% by loft drier then, obtain particle diameter and be the particulate state active material of 3～6mm, stand-by;
B) produce the matrix material, the parts by weights another name is got 73 parts of medical grade polyvinyl chloride, 17 parts of dioctyl phthalate (DOP)s, 10 parts of dibutyl phthalates, for example produce by Zhangjagang City, Jiangsu Province, China Great Wall machinofacture company limited with kneader by preferred employing, the SHR-100A Huang that sells closes machine and mediated 8 minutes under 100 ℃ of temperature, in kneading process, add 0.8 part of 9GF fluorescent yellow, send the forcing machine heating plasticizing then, plasticization temperature is 100 ℃, obtaining particle diameter is the particulate state matrix material of 3～6mm, stand-by, this particulate state matrix material is intended for the carrier of active material;
C) produce compound, take by weighing 0.05 part of active material, 1 part in matrix material by weight, and, obtain compound both mixings;
D) molded, by being installed on the item ring mould compression molding on the injection moulding machine, obtaining structure after 130 ℃, 2 minutes is the finished product deinsectization necklace that is applicable to cat of fluorescent yellow by color shown in Figure 1 equally, packs then with compound.
Embodiment 3:
A) produce active material, take by weighing 0.9 part of the pentmethrin produced by the Chinese Shanghai Westen and Chinese Tranditional Medicine Pharamacentic Factory, direct silica 1 part by commercially available acquisition, then both being put into container fully stirs, until pentmethrin all being absorbed by silicon-dioxide, and then will be absorbed with the silicon-dioxide of pentmethrin and 1 part of borneolum syntheticum and refining dipterex and together for example preferably adopt by the safe and sound pharmaceutical machine of Jiangsu Province, China Changzhou company limited for 1 part and produce by shredding unit, the omnipotent Highefficientpulverizer of the 30B type of selling is pulverized, cross 40 mesh sieves, produce by the super good drying plant of Jiangsu Province, China Changzhou company limited with mixer instance such as preferred use again, the CH trough type mixing machine of selling or employing Jiangyin City, Jiangsu Province, China Yongchang medicine machine works produce, the CHJ-V high efficient mixed machine of selling mixes, when mixing, add such as producing by Weifang, Chinese Shandong Sheng Tai pharmaceutcal corporation, Ltd, 1 part of the medical starch of selling, granulate with granulator, granulator is as adopting the super good drying plant of Jiangsu Province, China Changzhou company limited to produce, the YK series Pendulargranulator of selling, under＜60 ℃ of temperature, be dried to water ratio＜3% by loft drier then, obtain particle diameter and be the particulate state active material of 3～6mm, stand-by;
B) produce the matrix material, the parts by weights another name is got 74 parts of medical grade polyvinyl chloride, 15 parts of dioctyl phthalate (DOP)s, 11 parts of dibutyl phthalates, for example produce by Zhangjagang City, Jiangsu Province, China Great Wall machinofacture company limited with kneader by preferred employing, the SHR-100A Huang that sells closes machine and mediated 7 minutes under 110 ℃ of temperature, in kneading process, add 0.5 part of 3G fluorescence green, send the forcing machine heating plasticizing then, plasticization temperature is 110 ℃, obtaining particle diameter is the particulate state matrix material of 3～6mm, stand-by, this particulate state matrix material is intended for the carrier of active material;
C) produce compound, take by weighing 0.07 part of active material, 1 part in matrix material by weight, and, obtain compound both mixings;
D) molded, by being installed on the item ring mould compression molding on the injection moulding machine, obtaining after 135 ℃, 3 minutes by color shown in Figure 2 is the finished product deinsectization necklace that is applicable to dog of fluorescence green, packs then with compound.
Embodiment 4:
A) produce active material, take by weighing 1 part of the pentmethrin produced by the Chinese Shanghai Westen and Chinese Tranditional Medicine Pharamacentic Factory, direct silica 1 part by commercially available acquisition, then both being put into container fully stirs, until pentmethrin all being absorbed by silicon-dioxide, and then will be absorbed with the silicon-dioxide of pentmethrin and 1 part of borneolum syntheticum and refining dipterex and together for example preferably adopt by the safe and sound pharmaceutical machine of Jiangsu Province, China Changzhou company limited for 1 part and produce by shredding unit, the omnipotent Highefficientpulverizer of the 30B type of selling is pulverized, cross 40 mesh sieves, produce by the super good drying plant of Jiangsu Province, China Changzhou company limited with mixer instance such as preferred use again, the CH trough type mixing machine of selling or employing Jiangyin City, Jiangsu Province, China Yongchang medicine machine works produce, the CHJ-V high efficient mixed machine of selling mixes, when mixing, add such as producing by Weifang, Chinese Shandong Sheng Tai pharmaceutcal corporation, Ltd, 1 part of the medical starch of selling, granulate with granulator, granulator is as adopting the super good drying plant of Jiangsu Province, China Changzhou company limited to produce, the YK series Pendulargranulator of selling, under＜60 ℃ of temperature, be dried to water ratio＜3% by loft drier then, obtain particle diameter and be the particulate state active material of 3～6mm, stand-by;
B) produce the matrix material, the parts by weights another name is got 75 parts of medical grade polyvinyl chloride, 18 parts of dioctyl phthalate (DOP)s, 7 parts of dibutyl phthalates, the SHR-100A Huang that is is for example produced and sold by Zhangjagang City, Jiangsu Province, China Great Wall machinofacture company limited by preferred employing with kneader closes machine and mediated 6 minutes under 120 ℃ of temperature, send the forcing machine heating plasticizing then, plasticization temperature is 115 ℃, obtaining particle diameter is the particulate state matrix material of 3～6mm, stand-by, this particulate state matrix material is intended for the carrier of active material;
C) produce compound, take by weighing 0.08 part of active material, 1 part in matrix material by weight, and, obtain compound both mixings;
D) molded, compound by being installed on the item ring mould compression molding on the injection moulding machine, is obtained structural shape equally by the shown in Figure 3 and finished product deinsectization necklace that dog is worn that is applicable to that be nothing (basis) look after 140 ℃, 3 minutes.Pack then.
In the above-described embodiments, employed pentmethrin (mosquito-killing chrysanthemum ester Niewenjuzhi), roll up Ka0075 in " the Chinese Chemicals complete works " third edition of being write by Chemical Industry Press's tissue, to the test of contaminating of large and small white mouse, not seeing has toxicity symptom with 200 times concentration; 2005 editions People's Republic of China's veterinary drug allusion quotations " veterinary drug instruction manual " Dipterex that the China veterinary drug allusion quotation council compiles is safer to horse, cat, dog, can be used for the dog parasiticide.Point out that at 2005 editions Pharmacopoeias of the People's Republic of China that Chinese Pharmacopoeia Commission writes borneolum syntheticum has volatility, so the deinsectization necklace is safe and effective.
In the above-described embodiments, the general pharmacy corporation of employed equipment all possesses easy grasp, helps the industrialization volume production.
In the above-described embodiments, related matrix blanking aperture is little, the porosity height, and degree of drawing is strong, has the excellent drug slow releasing function, and is long to the lasting drug effect of removing the fleece zooparasite.
Compare the drug effect lasting effect that has shown in the following table by pickling process, the resulting pet deinsectization of squeegee process necklace in the pet deinsectization necklace that the foregoing description obtains and the prior art.
Claims (10)
1. pet deinsectization item loop material, it is characterized in that it comprises active constituent and matrix component, described active constituent is that the raw material by following weight part ratio constitutes: 1 part of pentmethrin 0.5-1 part, 1 part of refining dipterex, 1 part of borneolum syntheticum, silicon-dioxide 0.5-1 part, binding agent; Described matrix component is that the raw material by following weight part ratio constitutes, polyvinyl chloride 70-75 part, dioctyl phthalate (DOP) 15-18 part, dibutyl phthalate 7-15 part, and wherein: the weight part ratio of active constituent and matrix component is 0.03-0.08: 1.
2. pet deinsectization item loop material according to claim 1 is characterized in that also including in the described matrix component pigment 0.5-1 part, and described pigment is any one in EG transparent red, 9GF fluorescent yellow, the 3G fluorescence green.
3. pet deinsectization item loop material according to claim 1 is characterized in that described polyvinyl chloride is a medical polyvinyl, and described binding agent is a medical starch.
4. the making method of a pet deinsectization item loop material as claimed in claim 1 is characterized in that it may further comprise the steps:
A) produce active material, by weight, earlier with pentmethrin and silicon-dioxide absorption, together pulverize with borneolum syntheticum, refining dipterex then and sieve, mixing, add binding agent again, obtain granular active material through granulation, drying, stand-by;
B) produce the matrix material, by weight, polyvinyl chloride and dioctyl phthalate (DOP), dibutyl phthalate are mediated,, obtain granular matrix material again by the forcing machine heating plasticizing, stand-by;
C) produce compound, active material is mixed by weight with the matrix material, obtain pet deinsectization item loop material.
5. the making method of pet deinsectization item loop material according to claim 4 is characterized in that the absorption described in the step a) is to place container to stir fully pentmethrin and silicon-dioxide, receives in the silicon-dioxide pentmethrin; Described sieving to crossing the 40-60 sieve.
6. the making method of pet deinsectization item loop material according to claim 4 is characterized in that the exsiccant temperature described in the step a) is＜60 ℃, particle water content＜3%, and described particulate diameter is 3-6mm.
7. the making method of pet deinsectization item loop material according to claim 4 is characterized in that the kneading described in the step b) is that kneader is mediated, and kneading time and temperature were respectively 6-10 minute and 90-120 ℃.
8. the making method of pet deinsectization item loop material according to claim 4, the temperature that it is characterized in that the heating plasticizing described in the step b) is 90-120 ℃, described particulate diameter is 3-6mm.
9. the making method of pet deinsectization item loop material according to claim 4 is characterized in that temperature molded and shaped described in the step d) is 120-140 ℃, and the time is 1-3 minute.
10. method of making pet deinsectization necklace with pet deinsectization item loop material as claimed in claim 1 is characterized in that pet deinsectization item loop material is put in the item ring mould on the injection moulding machine molded and shaped, obtains finished product pet deinsectization necklace.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100962774A CN100398599C (en) | 2006-10-07 | 2006-10-07 | Parasiticidal pet collar material and making process of pet collar |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100962774A CN100398599C (en) | 2006-10-07 | 2006-10-07 | Parasiticidal pet collar material and making process of pet collar |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1931916A CN1931916A (en) | 2007-03-21 |
| CN100398599C true CN100398599C (en) | 2008-07-02 |
Family
ID=37877954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100962774A Expired - Fee Related CN100398599C (en) | 2006-10-07 | 2006-10-07 | Parasiticidal pet collar material and making process of pet collar |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100398599C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102009029361A1 (en) * | 2009-09-11 | 2011-03-24 | Bayer Animal Health Gmbh | Reflector with attachment for animal collars |
| CN103858790B (en) * | 2014-03-11 | 2016-08-17 | 甘肃省疾病预防控制中心 | A kind of dog device of insect protected necklace and preparation method thereof |
| CN106280097B (en) * | 2016-08-16 | 2018-04-06 | 浙江汪洋高分子材料有限公司 | A kind of multifunctional mosquito-proof PVC material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4265876A (en) * | 1978-03-07 | 1981-05-05 | Shell Internationale Research Maatschappij B.V. | Animal ear-tags, their manufacture and their use |
| BE887740A (en) * | 1981-03-02 | 1981-07-01 | S P R L Pharmanova | PEST CONTROL COLLARS |
| CN1246276A (en) * | 1998-08-07 | 2000-03-08 | 辉瑞产品公司 | Animal neck strap containing new gel formula for controlling arthropod infesting |
| CN1463588A (en) * | 2002-06-25 | 2003-12-31 | 西南民族学院 | Slow release cattle suspension decoration for mosquito and fly repelling |
| CN1547429A (en) * | 2001-08-28 | 2004-11-17 | �����ι�˾ | Insect control device for prolonged treatment of animals containing coumaphos and diazinon |
-
2006
- 2006-10-07 CN CNB2006100962774A patent/CN100398599C/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4265876A (en) * | 1978-03-07 | 1981-05-05 | Shell Internationale Research Maatschappij B.V. | Animal ear-tags, their manufacture and their use |
| BE887740A (en) * | 1981-03-02 | 1981-07-01 | S P R L Pharmanova | PEST CONTROL COLLARS |
| CN1246276A (en) * | 1998-08-07 | 2000-03-08 | 辉瑞产品公司 | Animal neck strap containing new gel formula for controlling arthropod infesting |
| CN1547429A (en) * | 2001-08-28 | 2004-11-17 | �����ι�˾ | Insect control device for prolonged treatment of animals containing coumaphos and diazinon |
| CN1463588A (en) * | 2002-06-25 | 2003-12-31 | 西南民族学院 | Slow release cattle suspension decoration for mosquito and fly repelling |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1931916A (en) | 2007-03-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102771670A (en) | Artificial diet for predative natural enemy insect-true bugs | |
| CN1059510A (en) | Multipurpose slow-released composite flower fertilizer and manufacture method | |
| CN101956244A (en) | Method for preparing anti-mosquito and ultraviolet-resistant polypropylene fiber | |
| CN100398599C (en) | Parasiticidal pet collar material and making process of pet collar | |
| CN105981652A (en) | Experimental animal particle litter added with Chinese herbal medicine and preparation method of experimental animal particle litter | |
| CN103815205B (en) | Feed additive manufactured from orange peel and rice bran for beta-xanthophyll-rich and VE-rich eggs | |
| CN102599066A (en) | Animal particle packing as well as production method and application of animal particle packing | |
| CN106212296A (en) | A kind of production technology of zeolite cat litter | |
| JP4537708B2 (en) | Microspheres containing pleuromutilin derivatives | |
| CN101773565B (en) | Preparation and feeding active function of compound Chinese herbal medicine | |
| CN104926443A (en) | Preparation method of organic compound fertilizer | |
| CN104871888B (en) | A kind of desinsection farm network and preparation method thereof | |
| CN107501875B (en) | A kind of agricultural biodegradable dedicated capsaicine master batch of mulch | |
| CN102863274A (en) | Cynanchum komarovii composite organic fertilizer and preparation method | |
| CN101366376B (en) | Niclosamide controlled release dispersing agent for killing blood fluke cercaria and preparation method thereof | |
| CN109043145A (en) | A kind of antibacterial type benzoic acid type intestinal sustained releasing acidulant and preparation method thereof | |
| TW201912028A (en) | An insect repellent masterbatch composition and a method for producing insect repellent masterbatch | |
| CN107156197A (en) | A kind of ecological, environmental protective agricultural insecticide and preparation method thereof | |
| CN107334000A (en) | Fish meal and preparation method thereof | |
| CN1063201A (en) | Agent of preventing livestock nibbling tree and production method thereof | |
| CN102302008A (en) | Metalaxyl and azoxystrobin compound pesticide preparation | |
| US20230345934A1 (en) | Solid Composite Matrix for Prolonged Delivery of Active Agents | |
| CN101720857A (en) | Medicinal fish feed for preventing fish diseases | |
| CN104814958A (en) | Water-soluble coated granule containing amoxicillin and preparation method thereof | |
| CN114766521A (en) | Mosquito-repelling insect-expelling p-dichlorobenzene mothproof mildew-proof ball agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080702 Termination date: 20101007 |