CN100336756C

CN100336756C - Energy storage light emitting composite stone

Info

Publication number: CN100336756C
Application number: CNB2005101368685A
Authority: CN
Inventors: 朱洪新
Original assignee: Individual
Current assignee: Individual
Priority date: 2004-12-28
Filing date: 2005-12-19
Publication date: 2007-09-12
Anticipated expiration: 2025-12-19
Also published as: CN1821144A

Abstract

The present invention relates to an energy storage luminous composite stone. Transparent or translucent marble, synthetic resins of epoxy resin, unsaturated polyester resin, etc., Yuchanghui energy storage luminous pigment, and other auxiliary materials are cast and shaped by pressing at the temperature lower than 60 DEG C, wherein the composite stone comprises 85% to 92% of marble, 6.5% to 12% of synthetic resin, 0.7% to 1% of Yuchanghui energy storage luminous pigment and 0.03% to 0.06% anti-settling agent, the total amount is 100%, and the particle size diameter of the marble is less than 5cm. The prepared stone has a function of absorbing external energy for self luminescence, and the power consumption is less; the present invention can be widely used for various decorations and advertising buildings and have the green lighting effect. The present invention can save a large quantity of energy sources for the society, replace lighting fittings of public places, and prevent theft.

Description

Energy storage light emitting composite stone

Affiliated technical field

The present invention relates to a kind of building and finishing material, particularly a kind of synthesizing marble material.

Background technology

Existing synthesizing marble material for utilizing the natural marble waste material, makes the building stone diversification of varieties, makes rational use of resources, and promotes environmental protection, reduces the exploitation of lithotome, and aspects such as conservation of nature landscape have positive effect.Adopt unsaturated polyester resin to be bonded because of it more, exist color and luster bright-coloured inadequately, problems such as decorative pattern instability, still not ideal enough as finishing material, so bright finishing material at a kind of night occurs.Chinese patent ZL87200699 number " bright marbling decorative sheet at night " also is a kind of synthesizing marble material, and that is by stratum basale, flower-pattern layer, formations such as luminous bisque and protective layer.Its luminous bisque causes the light powder by zinc sulphide to be formed, the stratum basale cement material, and method for making is same as the working method of concrete precast element.Because its base material is based on inorganic cement, has just added causing the light powder, the texture of stone material and color and luster are still bright-coloured inadequately, and the layering method for processing also makes complex manufacturing technology.

Also have a kind of printing opacity marble in the natural marble, be transparent or semitransparent state, loosely organized, intensity is little, and hardness is below 40HSD, and calcium carbonate content is more than 90%, and its structural strength deficiency is in order to make construction substrate.How utilizing its light transmission features, overcome the defective of undercapacity, also is a field of accomplishing something.On the other hand, aspect configuration of the light of public building and advertisement light fixture, consume a large amount of energy, very incompatible with China Energy resources shortage present situation.

Summary of the invention

The objective of the invention is to avoid above-mentioned weak point of the prior art, and a kind of lovely luster is provided, have luminous effect and decoration functions and energy-conservation synthesizing marble material.

Purpose of the present invention can reach by following measure:

A kind of energy storage light emitting composite stone, it is the synthesis stone that comprises that marble and synthetic resins are pressed into, in the material that adds compacting, also comprise the energy-accumulating luminous pigment of a kind of surplus long brightness, the marble that is adopted is a kind of transparent or semitransparent marble, and be no more than under 60 ℃ of temperature, form by comprising that following each component presses to execute to make by proportioning:

Transparent or semitransparent marble stone flour 85%～92%

Resins, epoxy or unsaturated polyester resin 6.5%～12%

The energy-accumulating luminous pigment 0.7%～1% of surplus long brightness

Dispersion agent 0.02%～0.04%

Other auxiliary material 0.5%～1.5%

Total amount 100%

In the set of dispense ratio of above-mentioned synthesis stone, be that the energy-accumulating luminous pigment of surplus long brightness is 8～12 parts under 100 the situation in described synthetic resins deal, described other auxiliary material comprises that promotor is 1～8 part, other pigment is 0～0.5 part, and the organic solvent that adds when compacting has 5～15 parts; The color of other pigment that is added will be consistent with the color of the energy-accumulating luminous pigment of surplus long brightness.

In the composition proportioning of above-mentioned synthesis stone, also include 0.03%～0.06% anti-settling agent, this anti-settling agent can be an aerosil.

Transparent or semitransparent marble described in the stone material is a kind of crushed stone, and its particle size diameter size is at 10mm～50mm.

Marble component described in the stone material comprises that also content is at the transparent or semitransparent marble stone flour of 100 orders below 5%～800 purposes.

The present invention has following advantage:

1. utilize the loose useless transparent translucent marble of producer's depleted, be made into energy storage light emitting composite stone of the present invention, have and to absorb outside energy and self luminous function presents self color at Liang Chu, in the dark then send versicolor light, reveal multicoloured decorative effect.At the material as lamppost, the light of the inside excites the energy-saving luminous material in the stone material by the stone material of printing opacity especially, and illumination effect is better.

2. use in Advertisement with decorative lamp, the energy saves energy is because power consumption seldom, can be widely used on the communal facility for example sign fire prevention, fire escape etc.Effect with green illumination.

Automatically 3. luminous under the situation of not having illumination, can be society and save a large amount of energy, reduce the light pollution of architecture ensemble.

4. be applied to the decoration of the various building materials in public place, can replace light fixture, in the environment that " does not have the thief all over the world " now, can reduce the incident generation that destroys buildings because of the pilferage light fixture.

Accident as situation about having a power failure under, can be luminous automatically, guiding people safe escape reduces the generation of disaster.

Description of drawings

Fig. 1 is the structural representation of stone material of the present invention, and Fig. 2 is the effect synoptic diagram that this stone material is applied to the cleat stanchion barrier, and Fig. 3 is the synoptic diagram that this stone material is applied to door and window.

Embodiment

Select a kind of transparent translucent marble, as base material, sieve through fragmentation, choose crushed stone and 100 order to 800 purpose stone flours that particle size diameter is no more than 5cm, it is evenly mixed to press proportioning and transparent type Resins, epoxy or unsaturated polyester resin, and adding proportion is 3.7 the energy-accumulating luminous pigment of surplus long brightness, with other auxiliary material, in the middle of, transparent translucent marble (crushed stone and stone flour) 2400Kgs, synthetic resins 170Kgs～180Kgs, solvent ketone, ethyl ketone 20Kgs, the energy-accumulating luminous pigment 15Kgs～20Kgs of surplus long brightness, promotor 5Kgs, anti-settling agent gas phase SiO ₂(white carbon black) 0.5Kgs～1Kgs also can add dispersion agent 0.3Kgs.Raw material mixes back layering casting compression moulding, can make 1M ³Rough stone block.In the whole course of processing, temperature must not be above 60 ℃.Prepared waste gauge lattice are thick 0.8M, wide 1.2M, long 1.8M～3.2M; Also can directly make sheet material, thickness is 1.2cm～2cm, wide 1.2M, long 1.2M～3M.Can be made into building board with above-mentioned stone material through cutting processing, post on cleat stanchion railing, door and window, the public building, hurdle and materials for wall etc. also can be made into the buildings of intermediate hollow, when mid-with light, also can pass through the lath adhesive method, make shape comparatively complicated fixedly build the thing moulding.

Claims

1. energy storage light emitting composite stone, it is the synthesis stone that comprises that marble and synthetic resins are pressed into, it is characterized in that, in the material that adds compacting, also comprise the energy-accumulating luminous pigment of a kind of surplus long brightness, the marble that is adopted is a kind of transparent or semitransparent marble, and is being no more than under 60 ℃ of temperature, by comprising that following each component forms by the proportioning compacting:

Transparent or semitransparent marble stone flour 85%～92%

Resins, epoxy or unsaturated polyester resin 6.5%～12%

The energy-accumulating luminous pigment 0.7%～1% of surplus long brightness

Dispersion agent 0.02%～0.04%

Other auxiliary material 0.5%～1.5%

Total amount 100%.

2. energy storage light emitting composite stone according to claim 1, it is characterized in that, in the set of dispense ratio of described synthesis stone, be under 100 the situation in described synthetic resins deal, the energy-accumulating luminous pigment of surplus long brightness is 8～12 parts, described other auxiliary material comprises 1～8 part of promotor, 0～0.5 part of other pigment, and the organic solvent that adds when compacting has 5～15 parts.

3. energy storage light emitting composite stone according to claim 1 and 2 is characterized in that, in the composition proportioning of described synthesis stone, also includes 0.03%～0.06% anti-settling agent, and this anti-settling agent is selected aerosil.

4. energy storage light emitting composite stone according to claim 1 and 2 is characterized in that, the transparent or semitransparent marble described in the stone material is a kind of crushed stone, and its particle size diameter size is at 10mm～50mm.

5. energy storage light emitting composite stone according to claim 3 is characterized in that, the transparent or semitransparent marble described in the stone material is a kind of crushed stone, and its particle size diameter size is at 10mm～50mm.

6. energy storage light emitting composite stone according to claim 1 and 2 is characterized in that, the marble component described in the stone material comprises that also content is at 100 orders below 5%～transparent or semitransparent marble flour of 800 purposes.

7. energy storage light emitting composite stone according to claim 3 is characterized in that, the marble component described in the stone material comprises that also content is at 100 orders below 5%～transparent or semitransparent marble flour of 800 purposes.

8. energy storage light emitting composite stone according to claim 4 is characterized in that, the marble component described in the stone material comprises that also content is at 100 orders below 5%～transparent or semitransparent marble flour of 800 purposes.