CN109880034A - A kind of melamine resin and its preparation method and application of anti-finger-marks - Google Patents
A kind of melamine resin and its preparation method and application of anti-finger-marks Download PDFInfo
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- CN109880034A CN109880034A CN201910073000.7A CN201910073000A CN109880034A CN 109880034 A CN109880034 A CN 109880034A CN 201910073000 A CN201910073000 A CN 201910073000A CN 109880034 A CN109880034 A CN 109880034A
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Abstract
The invention discloses a kind of melamine resins and its preparation method and application of anti-finger-marks.The melamine resin of this anti-finger-marks is made by preparation method below: 1) emulsion form matting resin, formalin, polyethylene glycol, melamine and water being added in reaction kettle, the pH for adjusting gained reaction solution is 8.8~9.2；2) reaction solution is heated, when reaction solution, which becomes, to be clarified, caprolactam is added into reaction solution；3) insulation reaction, sampling and testing cloud point terminal stop heating；4) adjusting pH is 8.0~8.7, is discharged, and stands, obtains the melamine resin of anti-finger-marks.The application of the melamine resin of this anti-finger-marks is also disclosed simultaneously.This melamine resin disclosed by the invention has the function of anti-finger-marks, is applied the influence that fingerprint can be eliminated on decorative film adhesive, and ornament materials is made to keep beautiful effect.
Description
Technical field
The present invention relates to a kind of melamine resin, in particular to the melamine resin of a kind of anti-finger-marks and its preparation
Methods and applications.
Background technique
With people's living standard and aesthetic raising, consumption tide is also constantly changing, and many consumers fill household
Exterior material requires fashion, personalization, splendid, and requires environmental protection, cleaning, safety and more good material.Family in the market
Occupying product 80%, the above are decoration artifical board materials.In wood-based plate surface decoration material, decorative film adhesive is to account for world's decoration
A kind of maximum ornament materials of the component of material consumption total amount.Decorative film adhesive be by special titanium art printing paper through printing, be impregnated with, overlay
It forms.Incrustation processing is carried out using decorative film adhesive to wood-based plate, so that it may cover and eliminate the various of artificial plate surface
Defect, and make it have pure and fresh, graceful, harmonious, beautiful appearance.
Melamine-impregnated bond paper is exactly a kind of bond paper of incrustation processing, which is a kind of plain-color base paper
Or printed decoration paper through dipping amino resins (melamine resin and Lauxite) and is dried to a certain extent, with one
The gummed paper for determining resin content and volatile content, through hot pressing can it is mutually glued or with artificial board substrate's gluing.In terms of hot pressing, select
Steel plate it is different, the resin layer of melamine-impregnated bond paper is just heat-set into different shapes, such as: bloom, dumb light, super dumb light,
Pitted skin sets high relief etc..The decorative product that bloom steel plate overlays has light pollution, and the steel plate of dumb light, super dumb light is overlayed into
Decorative product not only eliminate light pollution, and sense of touch has a kind of particle to rustle to feel.However decorative cover is often by people
Both hands contact, to form a kind of finger-marks in decorative cover, if it is highlight surface product, this finger-marks are easy to eliminate,
The beauty of ornament materials is not influenced, but on dumb light, super dumb light product, moisture and grease stain in finger-marks are easy to be filled in
Dumb light, super dumb light male and female face in, thus be part lose matte effect, form a kind of reflective mirror, the moisture in male and female face
Also it is difficult to eliminate with grease stain, from the point of view of reflecting angle, it will be apparent that finger-marks influence the beauty of ornament materials very much, and it is desirable to disappear
Influence except fingerprint to decoration makes its not transferability or attachment fingerprint, keeps the state of combination with decorative surfaces " non-sticky ", can be by trimerization
The ink layer of melamine resin cladding fully demonstrates beautiful, gorgeous effect.The finger marking contains water, inorganic salts, urea, oil etc.
Ingredient.A large amount of dust, bacterium etc. can be bred by being attached to combination with decorative surfaces for a long time, be contacted repeatedly by hand with ostentatious, very
It is easy to guide to bacterium on human body.Melamine-impregnated bond paper is pressed on substrate through dumb light, super dumb light steel plate hot, finally
One tunic on surface has dumb light, super matte effect.Reduce light pollution, increased comfortable frosted sense of touch, but occur
Fingerprint is difficult to the defect eliminated.
Nowadays, anti-finger-marks technology has begun application in industries such as electronics, glass, metals, but in furniture decoration row
Industry is applied not yet.
Summary of the invention
In order to overcome prior art melamine-impregnated bond paper to have the defects that fingerprint is difficult to eliminate, mesh of the invention
Be a kind of melamine resin and its preparation method and application of anti-finger-marks is provided.
The technical solution used in the present invention is:
A kind of preparation method of the melamine resin of anti-finger-marks, comprising the following steps:
1) by the emulsion form matting resin of 140~180 mass parts, the formalin of 450~500 mass parts, 30~50 matter
The water for measuring the polyethylene glycol of part, the melamine of 380~420 mass parts and 80~150 mass parts is added in reaction kettle, adjusts institute
The pH for obtaining reaction solution is 8.8~9.2；
2) reaction solution is heated, when reaction solution, which becomes, to be clarified, the caprolactam of 40~80 mass parts is added into reaction solution；
3) insulation reaction, sampling and testing cloud point terminal stop heating；
4) adjusting pH is 8.0~8.7, is discharged, and stands, obtains the melamine resin of anti-finger-marks；
In step 1), the preparation method of emulsion form matting resin is: by the polyvinyl alcohol resin of 20~40 mass parts, 0.5
The dispersing agent of~2 mass parts and the water of 50~200 mass parts, which are added in dispersion machine, to be mixed, and the delustring of 10~30 mass parts is added
Powder is dispersed with stirring, and obtains emulsion form matting resin.
Preferably, in the preparation method of emulsion form matting resin, flatting silica is silica flatting silica；Further preferably
, in flatting silica, the partial size of silica is 4.5 μm~5 μm, porosity 1.8mL/g~2.0mL/g.
Preferably, in the preparation method of emulsion form matting resin, dispersing agent is Polyolefin Grafted Maleic Anhydride；It is further excellent
Choosing, dispersing agent is one or both of Research of Grafting Malaic Anhydride Onto Polyethylene, polypropylene grafted maleic anhydride.
Preferably, in the preparation method of emulsion form matting resin, the revolving speed of stirring is 1200r/min~1600r/min, point
The scattered time is 30min~40min.
Preferably, in the preparation method of emulsion form matting resin, the mass parts dosage of each raw material is as follows: 25~35 parts of poly- second
Enol resin, 0.8~1.5 part of dispersing agent, 80~120 parts of water, 15~25 parts of flatting silicas.
Preferably, in the preparation method step 1) of the melamine resin of this anti-finger-marks, raw material dosage used are as follows:
145~160 parts of emulsion form matting resins, 470~490 parts of formalins, 35~45 parts of polyethylene glycol, 385~400 parts of melamines
Amine and 100~120 parts of water.
Preferably, in the preparation method step 1) of the melamine resin of this anti-finger-marks, the quality of formalin is dense
Degree is 35%~40%；It is further preferred that the preparation step 1 of melamine resin) in, the mass concentration of formalin is
36%~38%.
Preferably, in the preparation method step 2) of the melamine resin of this anti-finger-marks, 77 DEG C~79 DEG C are heated to
When, reaction solution starts to become clarification；It is further preferred that reaction solution starts to become clarification when being heated to 78 DEG C.
Preferably, in the preparation method step 2) of the melamine resin of this anti-finger-marks, the additional amount of caprolactam
It is 50~70 parts.
Preferably, in the preparation method step 2) of the melamine resin of this anti-finger-marks, insulation reaction is at 85 DEG C
~95 DEG C of reaction 50min~100min；It is further preferred that insulation reaction is in 88 DEG C~92 DEG C reaction 60min~90min.
Preferably, in the preparation method step 3) of the melamine resin of this anti-finger-marks, cloud point terminal is that sample exists
There is cloud point in 30 DEG C of water.
Further, in the preparation method step 3) of the melamine resin of this anti-finger-marks, the test method of cloud point
Are as follows: take the resin sample drop in a drop (0.05mL) reaction kettle into 0 DEG C of water, observation resin sample liquid is in 0 DEG C of water
It is no to be atomized；Successively cloud point situation of the test sample in 0 DEG C, 10 DEG C, 20 DEG C and 30 DEG C water, after there is cloud point for 30 DEG C,
Resin sample and water are mixed by 1:3 mass ratio, whether 20 DEG C of re-test mixed liquor cloudiness occur, judges reaction with this
Terminal.After reaching cloud point terminal, stop heating, cooling.The crosslinking degree of resin liquid is judged by test cloud point, if handed over
Connection degree is inadequate, which dissolves each other as water.
Preferably, in the preparation method step 1) He step 4) of the melamine resin of this anti-finger-marks, pH points are adjusted
Do not refer to that the independent hydroxide solution for selecting alkali metal adjusts pH；It is further preferred that the hydroxide solution of alkali metal is
Sodium hydroxide solution；The preferred mass concentration range of sodium hydroxide solution is 15%~25%.
Preferably, in the preparation method step 4) of the melamine resin of this anti-finger-marks, the time of standing is at least
2h；It is further preferred that the time stood is 3h~5h.
A kind of melamine resin of anti-finger-marks, is prepared by above-mentioned method.
Application of the melamine resin of this anti-finger-marks in furniture decoration.
Preferably, the melamine resin of this anti-finger-marks is preparing the application in decorative film adhesive, signified decoration
Bond paper is melamine-impregnated bond paper.
Further, the method for preparing decorative film adhesive is: bond paper is impregnated to the melamine of above-mentioned anti-finger-marks
Then resin is formed by steel plate development, obtain the decorative film adhesive of anti-finger-marks.
Preferably, it in the method for preparing decorative film adhesive, is suppressed using bloom steel plate, obtains a kind of internal dumb light, table
The decorative film adhesive of face bloom.
Preferably, it in the method for preparing decorative film adhesive, is suppressed using dumb light, super dumb light steel plate, obtains a kind of inside
Dumb light, the decorative film adhesive of external also dumb light.
The beneficial effects of the present invention are:
This melamine resin disclosed by the invention has the function of anti-finger-marks, is applied on decorative film adhesive
The influence that fingerprint can be eliminated makes ornament materials keep beautiful effect.
Specific embodiment
The contents of the present invention are described in further detail below by way of specific embodiment.Original used in embodiment
Material unless otherwise specified, can be obtained from routine business approach." part " of dosage mentioned in embodiment refers both to " mass parts ".It is real
Applying silica flatting silica partial size used in example is 4.5 μm~5 μm, porosity 1.8mL/g~2.0mL/g.
Embodiment 1
The melamine resins of the anti-finger-marks of embodiment 1 the preparation method is as follows:
One, emulsion form matting resin is prepared
The constitutive material of emulsion form matting resin are as follows: 20 parts of silica flatting silica, 30 parts of polyvinyl alcohol resin, 1 part it is poly-
Vinyl Graft maleic anhydride, 100 parts of water.
It is first put into polyvinyl alcohol resin, Research of Grafting Malaic Anhydride Onto Polyethylene and water in dispersion machine, delustring is then added batch-wise
Powder disperses 30min in the case where revolving speed is 1400r/min, forms emulsion form matting resin.
Two, the melamine resin of anti-finger-marks is prepared
1) by 150 parts of emulsion form matting resins, the formalin of 486 parts of 37wt%, 40 parts of polyethylene glycol, 395 parts
Melamine and 110 parts of water are added in reaction kettle, are 9.0 with the pH that 20wt% sodium hydroxide solution adjusts gained reaction solution；
2) for heating reaction solution to 78 DEG C, reaction solution becomes clarification, and 60 parts of caprolactam is added into reaction solution；
3) 90 DEG C of heat preservation 80min, sampling and testing cloud point terminal stop adding after sample cloud point occurs in 30 DEG C of water
Heat, cooling；
4) adjusting pH with 20wt% sodium hydroxide solution is 8.5, and discharging stands 3h, obtains the trimerization of anti-finger-marks
Melamine resin.
Embodiment 2
The melamine resins of the anti-finger-marks of embodiment 2 the preparation method is as follows:
One, emulsion form matting resin is prepared
The constitutive material of emulsion form matting resin are as follows: 25 parts of silica flatting silica, 25 parts of polyvinyl alcohol resin, 1 part it is poly-
Vinyl Graft maleic anhydride, 100 parts of water.
It is first put into polyvinyl alcohol resin, polypropylene grafted maleic anhydride and water in dispersion machine, delustring is then added batch-wise
Powder disperses 30min in the case where revolving speed is 1600r/min, forms emulsion form matting resin.
Two, the melamine resin of anti-finger-marks is prepared
1) by 145 parts of emulsion form matting resins, the formalin of 490 parts of 37wt%, 45 parts of polyethylene glycol, 400 parts
Melamine and 120 parts of water are added in reaction kettle, are 9.2 with the pH that 20wt% sodium hydroxide solution adjusts gained reaction solution；
2) for heating reaction solution to 78 DEG C, reaction solution becomes clarification, and 55 parts of caprolactam is added into reaction solution；
3) 90 DEG C of heat preservation 70min, sampling and testing cloud point terminal stop adding after sample cloud point occurs in 30 DEG C of water
Heat, cooling；
4) adjusting pH with 20wt% sodium hydroxide solution is 8.7, and discharging stands 3h, obtains the trimerization of anti-finger-marks
Melamine resin.
Embodiment 3
The melamine resins of the anti-finger-marks of embodiment 3 the preparation method is as follows:
One, emulsion form matting resin is prepared
The constitutive material of emulsion form matting resin are as follows: 15 parts of silica flatting silica, 35 parts of polyvinyl alcohol resin, 1 part it is poly-
Propylene graft maleic anhydride, 110 parts of water.
It is first put into polyvinyl alcohol resin, polypropylene grafted maleic anhydride and water in dispersion machine, delustring is then added batch-wise
Powder disperses 40min in the case where revolving speed is 1400r/min, forms emulsion form matting resin.
Two, the melamine resin of anti-finger-marks is prepared
1) by 160 parts of emulsion form matting resins, the formalin of 480 parts of 37wt%, 35 parts of polyethylene glycol, 395 parts
Melamine and 110 parts of water are added in reaction kettle, are 8.8 with the pH that 20wt% sodium hydroxide solution adjusts gained reaction solution；
2) for heating reaction solution to 78 DEG C, reaction solution becomes clarification, and 65 parts of caprolactam is added into reaction solution；
3) 90 DEG C of heat preservation 90min, sampling and testing cloud point terminal stop adding after sample cloud point occurs in 30 DEG C of water
Heat, cooling；
4) adjusting pH with 20wt% sodium hydroxide solution is 8.5, and discharging stands 3h, obtains the trimerization of anti-finger-marks
Melamine resin.
By Examples 1 to 3, finally resulting melamine resin is tested for the property, and the results are shown in Table 1.
The melamine the performance test results of 1 embodiment of table
Application examples 1
The bond paper of the melamine resin dipping of this anti-finger-marks, available one kind are suppressed by bloom steel plate
Internal dumb light, the decorative film adhesive of surface bloom.Internal dumb light can reduce light pollution, and surface bloom can eliminate finger-marks,
And the feeling of frosted can be showed.
It is pressed with finger on the decorative film adhesive surface of the application example, fingerprint disappears in 3s, will not leave behind finger-marks.
Application examples 2
The bond paper that the melamine resin dipping of this anti-finger-marks is suppressed by the steel plate of dumb light or super dumb light, can be with
Obtain a kind of internal dumb light, the decorative film adhesive of external also dumb light.Double dumb lights reduce light pollution, and even if in finger-marks
Water oil component, which remains in external dumb light relief region, forms reflective surface, but internal dumb light can weaken reflective surface, to make hand
Finger mark is unobvious.
It is pressed with finger on the decorative film adhesive surface of the application example, fingerprint disappears in 5s, will not leave behind finger-marks.
Claims (10)
1. a kind of preparation method of the melamine resin of anti-finger-marks, it is characterised in that: the following steps are included:
1) by the emulsion form matting resin of 140~180 mass parts, the formalin of 450~500 mass parts, 30~50 mass parts
Polyethylene glycol, the melamine of 380~420 mass parts and the water of 80~150 mass parts be added in reaction kettle, it is anti-to adjust gained
Answering the pH of liquid is 8.8~9.2；
2) reaction solution is heated, when reaction solution, which becomes, to be clarified, the caprolactam of 40~80 mass parts is added into reaction solution；
3) insulation reaction, sampling and testing cloud point terminal stop heating；
4) adjusting pH is 8.0~8.7, is discharged, and stands, obtains the melamine resin of anti-finger-marks；
The preparation method of step 1) the emulsion form matting resin is: by the polyvinyl alcohol resin of 20~40 mass parts, 0.5~2
The dispersing agent of mass parts and the water of 50~200 mass parts, which are added in dispersion machine, to be mixed, and the flatting silica of 10~30 mass parts is added
It is dispersed with stirring, obtains emulsion form matting resin.
2. a kind of preparation method of the melamine resin of anti-finger-marks according to claim 1, it is characterised in that: step
1) in the preparation method of the emulsion form matting resin, flatting silica is silica flatting silica.
3. a kind of preparation method of the melamine resin of anti-finger-marks according to claim 1, it is characterised in that: step
1) in the preparation method of the emulsion form matting resin, dispersing agent is Polyolefin Grafted Maleic Anhydride.
4. a kind of preparation method of the melamine resin of anti-finger-marks according to claim 1, it is characterised in that: step
1) in the preparation method of the emulsion form matting resin, the revolving speed of stirring is 1200r/min~1600r/min, the time of dispersion
For 30min~40min.
5. a kind of preparation method of the melamine resin of anti-finger-marks according to claim 1, it is characterised in that: step
1) in, the mass concentration of formalin is 35%~40%.
6. a kind of preparation method of the melamine resin of anti-finger-marks according to claim 1, it is characterised in that: step
2) in, when being heated to 77 DEG C~79 DEG C, reaction solution starts to become clarification.
7. a kind of preparation method of the melamine resin of anti-finger-marks according to claim 1, it is characterised in that: step
3) in, insulation reaction is in 85 DEG C~95 DEG C reaction 50min~100min.
8. a kind of preparation method of the melamine resin of anti-finger-marks according to claim 7, it is characterised in that: step
3) in, cloud point terminal is that sample cloud point occurs in 30 DEG C of water.
9. a kind of melamine resin of anti-finger-marks, it is characterised in that: be by method according to any one of claims 1 to 8
It is prepared.
10. a kind of application of the melamine resin of anti-finger-marks as claimed in claim 9 in furniture decoration.
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| CN201910073000.7A CN109880034B (en) | 2019-01-25 | 2019-01-25 | Anti-fingerprint melamine resin and preparation method and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910073000.7A CN109880034B (en) | 2019-01-25 | 2019-01-25 | Anti-fingerprint melamine resin and preparation method and application thereof |
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| CN109880034A true CN109880034A (en) | 2019-06-14 |
| CN109880034B CN109880034B (en) | 2021-09-28 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113756136A (en) * | 2021-08-03 | 2021-12-07 | 江苏博大新材料科技股份有限公司 | Fingerprint-resistant high-glossiness impregnated decorative paper and preparation method and application thereof |
| CN116117943A (en) * | 2023-01-16 | 2023-05-16 | 点金新型材料研究院(厦门)有限公司 | Anti-fingerprint skin-feel matte melamine veneer and manufacturing method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102260447A (en) * | 2010-12-14 | 2011-11-30 | 上海凯鑫森产业投资控股有限公司 | Thermosetting coating for fabric-foil sub-gloss release film and preparation method thereof |
| CN103648767A (en) * | 2011-04-05 | 2014-03-19 | Lg电子株式会社 | Panel with anti-fingerprint property and manufacturing method thereof |
| JP2015202584A (en) * | 2014-04-11 | 2015-11-16 | 日本電気硝子株式会社 | Melamine decorative board |
| CN105131223A (en) * | 2015-08-21 | 2015-12-09 | 山东大唐宅配家居有限公司 | Melamine modified resin adhesive for flax chip shaving boards, and preparation method thereof |
| CN108395802A (en) * | 2018-03-28 | 2018-08-14 | 江阴恒兴涂料有限公司 | A kind of adjustable transparent electrophoretic coating of gloss delustring and preparation method thereof |
| CN108467656A (en) * | 2018-03-28 | 2018-08-31 | 江阴恒兴涂料有限公司 | A kind of coating process of the adjustable transparent electrophoretic coating of gloss delustring |
-
2019
- 2019-01-25 CN CN201910073000.7A patent/CN109880034B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102260447A (en) * | 2010-12-14 | 2011-11-30 | 上海凯鑫森产业投资控股有限公司 | Thermosetting coating for fabric-foil sub-gloss release film and preparation method thereof |
| CN103648767A (en) * | 2011-04-05 | 2014-03-19 | Lg电子株式会社 | Panel with anti-fingerprint property and manufacturing method thereof |
| JP2015202584A (en) * | 2014-04-11 | 2015-11-16 | 日本電気硝子株式会社 | Melamine decorative board |
| CN105131223A (en) * | 2015-08-21 | 2015-12-09 | 山东大唐宅配家居有限公司 | Melamine modified resin adhesive for flax chip shaving boards, and preparation method thereof |
| CN108395802A (en) * | 2018-03-28 | 2018-08-14 | 江阴恒兴涂料有限公司 | A kind of adjustable transparent electrophoretic coating of gloss delustring and preparation method thereof |
| CN108467656A (en) * | 2018-03-28 | 2018-08-31 | 江阴恒兴涂料有限公司 | A kind of coating process of the adjustable transparent electrophoretic coating of gloss delustring |
Non-Patent Citations (1)
| Title |
|---|
| 宁军丽 等: "《简论哑光漆漆面汗潜手印显现》", 《江苏警官学院学报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113756136A (en) * | 2021-08-03 | 2021-12-07 | 江苏博大新材料科技股份有限公司 | Fingerprint-resistant high-glossiness impregnated decorative paper and preparation method and application thereof |
| CN116117943A (en) * | 2023-01-16 | 2023-05-16 | 点金新型材料研究院(厦门)有限公司 | Anti-fingerprint skin-feel matte melamine veneer and manufacturing method thereof |
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| CN109880034B (en) | 2021-09-28 |
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Denomination of invention: The invention relates to an anti fingerprint melamine resin and a preparation method and application thereof Effective date of registration: 20220507 Granted publication date: 20210928 Pledgee: China Co. truction Bank Corp Foshan branch Pledgor: GUANGDONG TIANYUAN HUIBANG NEW MATERIAL CO.,LTD. Registration number: Y2022980005179 |