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CN109811381A - Pre-impregnation device is electroplated in plastic parts electro-plating method and plastic parts - Google Patents

Pre-impregnation device is electroplated in plastic parts electro-plating method and plastic parts Download PDF

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Publication number
CN109811381A
CN109811381A CN201910230681.3A CN201910230681A CN109811381A CN 109811381 A CN109811381 A CN 109811381A CN 201910230681 A CN201910230681 A CN 201910230681A CN 109811381 A CN109811381 A CN 109811381A
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CN
China
Prior art keywords
plastic parts
conductive
hanger
electroplating bath
prepreg solution
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Pending
Application number
CN201910230681.3A
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Chinese (zh)
Inventor
梁天野
戴怡培
韩学兵
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Yangjiang Sanwei Technology Co ltd
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Yangjiang Sanwei Technology Co ltd
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Priority to CN201910230681.3A priority Critical patent/CN109811381A/en
Publication of CN109811381A publication Critical patent/CN109811381A/en
Pending legal-status Critical Current

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Abstract

The present invention provides a kind of plastic parts electro-plating method and plastic parts plating pre-impregnation device, plastic parts electro-plating method includes initial rinsing method, initial rinsing method includes placing step and electrolysis step, and placing step includes: that hanger and plastic parts are immersed in prepreg solution, and hanger connects the anode electricity of power supply;Electrolysis step includes: to be powered, and is electrolysed to prepreg solution;Pre-impregnation device includes electroplating bath, electrolytic zinc-coated steel sheet and conductive supporting component, and electroplating bath is provided with conduct piece, conduct piece is used to be powered to prepreg solution, conduct piece connection anode electricity for loading prepreg solution on electroplating bath;Electrolytic zinc-coated steel sheet protrudes into prepreg solution;Conductive supporting component is used to support electrolytic zinc-coated steel sheet, is immersed in electrolytic zinc-coated steel sheet firmly in prepreg solution, and conductive supporting component connects negative electricity;In prepreg solution electrolytic process, the anion transport in prepreg solution provides electronics to hanger and plastic parts, so that form a negative electricity environment on hanger and plastic parts, to more sink palladium, reduces the quick-fried hook shedding phenomenon of hanger.

Description

Pre-impregnation device is electroplated in plastic parts electro-plating method and plastic parts
Technical field
The present invention relates to field of electroplating, it is specifically related to a kind of plastic parts electro-plating method and plastic parts plating pre-impregnation device.
Background technique
It, before plating, must be in advance in plastic product since plastics are insulators in the plating production process of plastic product Surface formed one layer of conduct piece (metallic film), for the metallic film as underlying metal, plastic cement products just can be carried out plating, and The process for forming metallic film is exactly palladium activation.Before carrying out the palladium activation of plastic parts, in order to protect the palladium water in electroplating bath, Before not allowing in the chrome liquor pollution palladium water remained on the product on hanger and hanger and pretreatment procedure of process hanger and The moisture dilution palladium liquid taken out of when product on hanger, needs to carry out preimpregnation work in hydrochloric acid to the product on hanger and hanger Sequence is fallen remaining chrome liquor reduction, and the moisture on hanger and product is neutralized, then carry out palladium activation procedure.
In existing preimpregnation process, usually the product on hanger and hanger is put into pre- immersion trough, is put in pre- immersion trough The prepreg solution set designs the preimpregnation time using hydrochloric acid as main component, completes after presoaking, then hanger is hung out preimpregnation by overhead traveling crane Slot moves to palladium slot and carries out palladium activation.During presoaking this, the remaining chrome liquor of product can be restored on hanger and hanger, water Branch is neutralized, but even across preimpregnation process, in subsequent processing, since palladium (Pd+) is cation, in heavy palladium process In, palladium ion fails preferably to be attached on hanger and product, and the product on hanger and hanger is still very easy to occur quick-fried Hook shedding phenomenon (chemical nickel fails to consolidate on hanger gib head completely), causes impurity to pollute subsequent electroplating work procedure, product table Face easily forms husky point, forms defective products.
Summary of the invention
The first object of the present invention be to provide it is a kind of reduction hanger and hanger on product there is the modeling of quick-fried hook shedding phenomenon Pre-impregnation device is electroplated in glue part.
The second object of the present invention be to provide it is a kind of reduction hanger and hanger on product there is the modeling of quick-fried hook shedding phenomenon Glue part electro-plating method.
In order to realize the first above-mentioned purpose, plastic parts plating pre-impregnation device provided by the invention includes electroplating bath, multiple Electrolytic zinc-coated steel sheet and conductive supporting component, electroplating bath are provided with conduct piece, conduct piece is used for pre- for loading prepreg solution on electroplating bath Immersion liquid is powered, conduct piece connection anode electricity;Multiple electrolytic zinc-coated steel sheets protrude into the prepreg solution of electroplating bath;Conductive supporting component includes at least Two conductive supports and conductive hanging tube, the both ends of conductive hanging tube are connect with conductive support respectively, and conductive support will be conductive Hanging tube is erected on electroplating bath, and conductive supporting component connects negative electricity, and conductive hanging tube connects electrolytic zinc-coated steel sheet.
It can be seen that electroplating bath is provided with prepreg solution, the plastic parts on hanger and hanger is immersed in prepreg solution, hanger It is also fully immersed in prepreg solution, is powered by conduct piece to prepreg solution, and conductive with contact position, that is, hanger gib head of plastic parts Part connection anode electricity, while the electrolytic zinc-coated steel sheet protruded into prepreg solution connects negative electricity, after energization, during prepreg solution electrolysis, in advance On cation transport to electrolytic zinc-coated steel sheet in immersion liquid, in conjunction with electronics;On anion transport to hanger and hanger in prepreg solution Plastic parts, and electronics is provided, so that hanger and plastic parts all form a negative electricity environment, during next heavy palladium (Pd+), by It is cation in palladium ion, palladium ion is towards moving on the hanger and plastic parts of negative electricity environment, so that palladium ion is more fully It sinks on hanger and plastic parts, the heavy nickel of chemical nickel, heavy nickel is further carried out to hanger and plastic parts by dispergation, chemical nickel engineering Also more completely, due to also having the presence of palladium ion on hanger gib head, hanger gib head has also been sufficiently carried out the anti-of chemical nickel It answers, so that hanger gib head and plastic parts are not easy the quick-fried hook shedding phenomenon of hanger occur, to reduce in following electroplating process Since the quick-fried hook of hanger causes electroplate liquid impurity to pollute, plastic cement plating piece sand point bad phenomenon is reduced.
Further embodiment is that conductive support includes the first support tube and the second support tube, the first support tube and second Support tube vertically connects, and the second support tube is connected between the first support tube and conductive hanging tube, and the first support tube level is erected at On electroplating bath, conductive hanging tube is horizontally disposed.
As it can be seen that the first support tube level is erected on electroplating bath, the first support tube is vertical with the second support tube to be connect, and the Two support tubes are connected between the first support tube and conductive hanging tube, can adjust putting for conductive hanging tube by rotating the first support tube Height is set, electrolysis degree is conveniently adjusted.
Further embodiment is that conductive hanging tube is arranged in electroplating bath, and the top opening of conductive hanging tube and electroplating bath is arranged There is spacing.
As it can be seen that conductive hanging tube and electroplating bath top opening are provided with spacing, just since electrolytic zinc-coated steel sheet is connected on conductive hanging tube It is fully immersed in prepreg solution in electrolytic zinc-coated steel sheet.
Further embodiment is that multiple conductive hooks are arranged on conductive hanging tube, between every two adjacent conductive hook Spacing is equal, and conductive hook connects electrolytic zinc-coated steel sheet.
As it can be seen that electrolytic zinc-coated steel sheet is hung on conductive hanging tube by conductive hook, the spacing between every two adjacent conductive hook Equal, so that in electroplating bath, the corresponding region of each electrolytic zinc-coated steel sheet is identical, and electrolysis effectiveness is more evenly more preferable, is attached to hanger and modeling Electronics on glue part is also more uniform.
Further embodiment is that the setting height of conductive hook is not higher than the water level of prepreg solution.
As it can be seen that the setting height of conductive hook is not higher than the water level of prepreg solution, so that electrolytic zinc-coated steel sheet is fully immersed in preimpregnation In liquid, so that prepreg solution electric current is bigger in electrolytic process, electrolysis is more thorough, makes electronics adhesion effect on hanger and plastic parts More preferably.
Further embodiment is that electroplating bath is in cuboid, and the quantity of conductive supporting component is two, two conductive supporting groups Part is respectively close to electroplating bath along the length direction of electroplating bath and two inner sidewalls that are oppositely arranged, and two conductive supporting components are by leading Line connection, electric conductor are arranged between two groups of conductive supporting components.
Multiple electrolytic zinc-coated steel sheets are respectively arranged with as it can be seen that being oppositely arranged on two inner sidewalls in electroplating bath, hanger and plastic parts exist In electrolytic process between the electrolytic zinc-coated steel sheet of two inner sidewalls, keep current distribution in electroplating bath more uniform, so that electrolysis effectiveness is more It is good.
Further embodiment is that electroplating bath is conductive plated slot, is provided with conductive plummer on the lateral wall of electroplating bath, leads Electric part is arranged on conductive plummer.
As it can be seen that conductive plummer is arranged on the lateral wall of electroplating bath, conduct piece is arranged on conductive plummer, convenient for leading Electric part is electrically connected, and is realized and is powered to the prepreg solution in electroplating bath.
The second purpose to realize the present invention, a kind of plastic parts electro-plating method provided by the invention, electro-plating method include: according to Secondary progress pre-treatment step, initial rinsing method, palladium activation step and electroless nickel step;
Initial rinsing method includes placing step and electrolysis step;
Placing step includes:
Plastic parts on hanger and hanger is immersed in prepreg solution;
Hanger connects the anode electricity of power supply;
Electrolysis step includes:
It is powered, prepreg solution is electrolysed.
It can be seen that the plastic parts on hanger and hanger is immersed in prepreg solution, it is powered by conduct piece to prepreg solution, And conduct piece connection anode electricity, after energization, the plastic parts on anion transport to hanger and hanger in prepreg solution, and provide electricity Son, so that forming a negative electricity environment on hanger and plastic parts, during next heavy palladium (Pd+), palladium ion sinks to hanger hook Head further carries out the heavy nickel of chemical nickel to hanger gib head and plastic parts by dispergation, chemical nickel engineering, due on hanger gib head Presence with palladium ion, hanger gib head also have the reaction of chemical nickel, so that hanger gib head and plastic parts are not easy hanger occur Quick-fried hook shedding phenomenon reduces plastic cement plating to reduce in following electroplating process since the quick-fried hook of hanger causes electroplate liquid impurity to pollute Part sand point bad phenomenon.
Further embodiment is that pre-impregnation device is electroplated by plastic parts and carries out plastic parts electro-plating method, prepreg solution is hydrochloric acid The placement step of solution, plastic parts electro-plating method includes:
Plastic parts on hanger and hanger is immersed in the prepreg solution in electroplating bath;
Hanger connects the anode electricity of power supply, the negative electricity of the electrolytic zinc-coated steel sheet connection power supply in electroplating bath.
Detailed description of the invention
Fig. 1 is the structure chart of plastic parts plating pre-impregnation device embodiment of the present invention.
The invention will be further described with reference to the accompanying drawings and embodiments.
Specific embodiment
Referring to Fig. 1, plastic parts plating pre-impregnation device of the invention includes electroplating bath 1, multiple electrolytic zinc-coated steel sheets 2 and conductive supporting group Multiple electrolytic zinc-coated steel sheets 2 are erected in electroplating bath 1 by part 3, conductive supporting component 3.Electroplating bath 1 is for loading prepreg solution, on electroplating bath 1 It is provided with conduct piece 4, is powered by conduct piece 4 to prepreg solution, conduct piece 4 connects the anode electricity of power supply, and electrolytic zinc-coated steel sheet 2 connects The negative electricity of power supply.Electroplating bath 1 is provided with prepreg solution, and prepreg solution is hydrochloric acid solution, and the plastic parts on hanger and hanger soaks Bubble is powered to prepreg solution in prepreg solution, through conduct piece 4, and conduct piece 4 connects positive electricity, while protruding into the electricity in prepreg solution It solves plate 2 and connects negative electricity, after energization, during prepreg solution electrolysis, on the cation transport to electrolytic zinc-coated steel sheet 2 in prepreg solution, with Electronics combines;The plastic parts on anion transport to hanger and hanger in prepreg solution, and electronics is provided, so that hanger and plastic cement A negative electricity environment is formed on part, during next heavy palladium (Pd+), palladium ion direction has hanger and the modeling of negative electricity environment Moved on glue part, and palladium ion is sunk on hanger and plastic parts, further by dispergation, chemical nickel engineering to hanger gib head with Plastic parts carries out the heavy nickel of chemical nickel, and due to also having the presence of palladium ion on hanger gib head, hanger gib head also has the anti-of chemical nickel Answer so that hanger gib head and plastic parts are not easy the quick-fried hook shedding phenomenon of hanger occur, thus reduce in following electroplating process due to The quick-fried hook of hanger causes electroplate liquid impurity to pollute, and reduces plastic cement plating piece sand point bad phenomenon.
In the present embodiment, electroplating bath 1 is in cuboid, and electroplating bath 1 is conductive plated slot 1.Electroplating bath 1 is in electroplating bath 1 Width direction on and two lateral walls that are oppositely arranged on be respectively arranged with conductive plummer 5, be provided with and lead on conductive plummer 5 Electric part 4, the conduct piece 4 can be to fly palladium seat, and conduct piece 4 connects the anode electricity of rectifier.
In the present embodiment, conductive supporting component 3 is used to support electrolytic zinc-coated steel sheet 2, and electrolytic zinc-coated steel sheet 2 is made firmly to be immersed in preimpregnation In liquid.Conductive supporting component 3 includes two conductive supports 30 and conductive hanging tube 31, and conductive hanging tube 31 is long strip type, and conduction is hung The both ends of pipe 31 along its length are connect with conductive support 30 respectively, and conductive hanging tube 31 is erected at plating by conductive support 30 On slot 1.Conductive support 30 includes the first support tube 32 and the second support tube 33, the first support tube 32 and the second support tube 33 Vertical connection, the second support tube 33 are connected between the first support tube 32 and conductive hanging tube 31, and the first support tube 32 is horizontal to be set up On electroplating bath 1, so that the second support tube 33 is arranged along the vertical direction, and in the present embodiment, conductive hanging tube 31 is also along plating The length direction of slot 1 is horizontally disposed, the placing height of conductive hanging tube 31 can be adjusted, to adjust by rotating the first support tube 32 Immersion degree of the whole electrolytic zinc-coated steel sheet 2 in prepreg solution, is conveniently adjusted electrolysis degree.Conductive hanging tube 31 is arranged in electroplating bath 1, conductive The top opening of hanging tube 31 and electroplating bath 1 is provided with spacing, which can be 10cm~15cm.In the present embodiment, conductive to hang Multiple conductive hooks 34 are set on pipe 31, and the spacing between every two adjacent conductive hook 34 is equal, and electrolytic zinc-coated steel sheet 2 passes through conduction Hook 34 is hung on conductive hanging tube 31, and electrolytic zinc-coated steel sheet 2 and conductive hook 34 correspond, and the setting height of conductive hook 34 Not higher than the water level of prepreg solution, electrolytic zinc-coated steel sheet 2 is fully immersed in prepreg solution, is made in electrolytic process, and prepreg solution electric current is bigger, electricity Solution is more thorough, keeps electronics adhesion effect on hanger and plastic parts more preferable.Electrolytic zinc-coated steel sheet 2 in electroplating bath 1 is placed equidistant with, and is made each The corresponding region of electrolytic zinc-coated steel sheet 2 is identical, and electrolysis effectiveness is more evenly more preferable, and the electronics being attached on hanger and plastic parts is also more uniform. Conductive supporting component 3 connects the negative electricity of rectifier, so that electrolytic zinc-coated steel sheet 2 also connects the negative electricity of rectifier.
In the present embodiment, the quantity of conductive supporting component 3 is two, and two conductive supporting components 3 are respectively close to plating Length direction and the two inner sidewalls setting that is oppositely arranged of the slot 1 along electroplating bath 1, two conductive supporting components 3 are connected by conducting wire 35 It connects, electric conductor is arranged between two groups of conductive supporting components 3, and during electrolysis, hanger and plastic parts are located at 1 edge of electroplating bath Between the length direction of electroplating bath 1 and two inner sidewalls being oppositely arranged, keep current distribution in electroplating bath 1 more uniform, so that electric It is more preferable to solve effect.
In the present embodiment, conductive hanging tube 31 is titanium clad copper tube, and electrolytic zinc-coated steel sheet 2 is iridium titanium alloy electrolytic zinc-coated steel sheet 2.
A kind of plastic parts electro-plating method of the invention, electro-plating method include the pre-treatment step successively carried out, initial rinsing method, Palladium activation step, dispergation step and electroless nickel step;Pre-treatment step include pre-treatment deoiling step, roughening treatment step, Reduction treatment step;
Initial rinsing method includes placing step and electrolysis step;
Placing step includes:
Plastic parts on hanger and hanger is immersed in prepreg solution;
Hanger connects the anode electricity of power supply;
Electrolysis step includes:
It is powered, prepreg solution is electrolysed.
Plastic parts on hanger and hanger is immersed in prepreg solution, is powered by conduct piece to prepreg solution, and conduct piece Connection anode electricity, after energization, the plastic parts on anion transport to hanger and hanger in prepreg solution, and electronics is provided, so that A negative electricity environment is formed on hanger and plastic parts, during next heavy palladium (Pd+), palladium ion sinks to hanger gib head, into one Step carries out the heavy nickel of chemical nickel to hanger gib head and plastic parts by dispergation, chemical nickel engineering, due to also having palladium on hanger gib head The presence of ion, hanger gib head also have the reaction of chemical nickel so that hanger gib head and plastic parts be not easy the quick-fried hook of hanger occur it is de- Powder phenomenon reduces plastic cement plating piece sand point to reduce in following electroplating process since the quick-fried hook of hanger causes electroplate liquid impurity to pollute Bad phenomenon.
Pre-impregnation device is electroplated by plastic parts and carries out plastic parts electro-plating method, prepreg solution is hydrochloric acid solution, plastic parts plating Initial rinsing method in method includes placing step and electrolysis step;
Placing step includes:
Plastic parts on hanger and hanger is immersed in the prepreg solution in electroplating bath;
To the conduct piece connection anode electricity on electroplating bath, the electrolytic zinc-coated steel sheet in electroplating bath connects negative electricity;
Electrolysis step includes:
It is powered, prepreg solution is electrolysed.
Since electroplating bath is conductive plated slot, when the plastic parts on hanger and hanger is immersed in prepreg solution, electroplating bath On conduct piece connection anode electricity, while electroplating bath and conduct piece in electroplating bath hanger and plastic parts be powered, make to hang Tool and plastic parts connection anode electricity, electrolytic zinc-coated steel sheet connects negative electricity, thus during be electrolysed prepreg solution, in prepreg solution it is positive from Son moves on electrolytic zinc-coated steel sheet, in conjunction with electronics;The plastic parts on anion transport to hanger and hanger in prepreg solution, and provide Electronics, so that hanger and plastic parts all form a negative electricity environment, so that preferably heavy palladium, more completely carries out chemical nickel plating, To reduce quick-fried hook shedding phenomenon.
Finally it is emphasized that the above description is only a preferred embodiment of the present invention, it is not intended to restrict the invention, it is right For those skilled in the art, the present invention can have various change and change, all within the spirits and principles of the present invention, Any modification, equivalent substitution, improvement and etc. done, should all be included in the protection scope of the present invention.

Claims (9)

1. pre-impregnation device is electroplated in plastic parts characterized by comprising
Electroplating bath, the electroplating bath are provided with conduct piece for loading prepreg solution on the electroplating bath, the conduct piece for pair The prepreg solution is powered, the conduct piece connection anode electricity;
Multiple electrolytic zinc-coated steel sheets, multiple electrolytic zinc-coated steel sheets protrude into the prepreg solution of the electroplating bath;
Conductive supporting component, the conductive supporting component include at least two conductive supports and conductive hanging tube, the conductive extension The both ends of pipe are connect with the conductive support respectively, and the conductive hanging tube is erected at the electroplating bath by the conductive support On, the conductive supporting component connects the negative electricity, and the conduction hanging tube connects the electrolytic zinc-coated steel sheet.
2. pre-impregnation device is electroplated in plastic parts according to claim 1, it is characterised in that:
The conductive support includes the first support tube and the second support tube, and first support tube and second support tube hang down Direct-connected to connect, second support tube is connected between first support tube and the conductive hanging tube, the first support tube water Flatrack is located on the electroplating bath, and the conduction hanging tube is horizontally disposed.
3. pre-impregnation device is electroplated in plastic parts according to claim 2, it is characterised in that:
The conduction hanging tube is arranged in the electroplating bath, between the top opening of the conduction hanging tube and the electroplating bath is provided with Away from.
4. pre-impregnation device is electroplated in plastic parts according to claim 3, it is characterised in that:
Multiple conductive hooks are set on the conduction hanging tube, the spacing between every two adjacent conductive hook is equal, described to lead Electrolytic zinc-coated steel sheet described in cable address hook connects.
5. pre-impregnation device is electroplated in plastic parts according to claim 4, it is characterised in that:
The setting height of the conductive hook is not higher than the water level of the prepreg solution.
6. pre-impregnation device is electroplated in plastic parts according to claim 5, it is characterised in that:
The electroplating bath is in cuboid, and the quantity of the conductive supporting component is two, two conductive supporting component difference Length direction close to the electroplating bath along the electroplating bath and two inner sidewalls that are oppositely arranged, two conductive supporting components It is connected by conducting wire, electric conductor setting is between the conductive supporting component described in two groups.
7. pre-impregnation device is electroplated in plastic parts according to any one of claims 1 to 6, it is characterised in that:
The electroplating bath is conductive plated slot, is provided with conductive plummer on the lateral wall of the electroplating bath, the conduct piece is set It sets on the conductive plummer.
8. plastic parts electro-plating method, it is characterised in that:
The plastic cement electro-plating method includes: successively to carry out pre-treatment step, initial rinsing method, palladium activation step and chemical nickel plating step Suddenly;
The initial rinsing method includes placing step and electrolysis step;
The placement step includes:
Plastic parts on hanger and hanger is immersed in prepreg solution;
The anode electricity of the hanger connection power supply;
The electrolysis step includes:
It is powered, the prepreg solution is electrolysed.
9. plastic parts electro-plating method according to claim 8, it is characterised in that:
Pre-impregnation device is electroplated by plastic parts and carries out the initial rinsing method, the prepreg solution is hydrochloric acid solution, the plastic parts electricity The placement step of electroplating method includes:
The plastic parts on the hanger and the hanger is immersed in the prepreg solution in electroplating bath;
The anode of the hanger connection power supply is electric, the negative electricity of the electrolytic zinc-coated steel sheet connection power supply in the electroplating bath.
CN201910230681.3A 2019-03-26 2019-03-26 Pre-impregnation device is electroplated in plastic parts electro-plating method and plastic parts Pending CN109811381A (en)

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Publication number Priority date Publication date Assignee Title
CN111501075A (en) * 2020-05-06 2020-08-07 清远敏惠汽车零部件有限公司 Plastic electroplating pretreatment process

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Application publication date: 20190528