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CN109712743A - 180 grades of easily stripped glass fiber covered wires and preparation method thereof - Google Patents

180 grades of easily stripped glass fiber covered wires and preparation method thereof Download PDF

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Publication number
CN109712743A
CN109712743A CN201811607447.XA CN201811607447A CN109712743A CN 109712743 A CN109712743 A CN 109712743A CN 201811607447 A CN201811607447 A CN 201811607447A CN 109712743 A CN109712743 A CN 109712743A
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China
Prior art keywords
glass fiber
copper conductor
grades
covered wires
easily stripped
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CN201811607447.XA
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CN109712743B (en
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汤海峰
张晖
申海波
戴中华
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SHANGHAI YUSHENG SPECIAL WIRE CO Ltd
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SHANGHAI YUSHENG SPECIAL WIRE CO Ltd
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Priority to CN201811607447.XA priority Critical patent/CN109712743B/en
Publication of CN109712743A publication Critical patent/CN109712743A/en
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Abstract

The invention proposes a kind of 180 grades of easily stripped glass fiber covered wires and preparation method thereof, including copper conductor, are coated on the first glass fiber and the second glass fiber and insulating lacquer layer of copper conductor surface;First glass fiber is glass fiber and fiber filament according to 9-13:1-3 progress and silk;Second glass fiber is glass fiber and fiber filament according to 4-6:4-8 progress and silk;First glass fiber uses left hand direction when coating copper conductor;Clockwise direction is used when second glass fiber coats.Electromagnetic wire produced by the present invention has excellent easy-peel performance, operator can will be attached to the insulating layer of copper conductor surface by nail, the insulating layer to fall off (is no more than 1cm fritter at strip, it is unable to the state of fall in flakes), while guaranteeing the adhesion that product needs in process.

Description

180 grades of easily stripped glass fiber covered wires and preparation method thereof
Technical field
The present invention relates to electromagnetic wire technical fields, particularly relate to 180 grades of easily stripped glass fiber covered wires of one kind and its preparation side Method.
Background technique
With the development that deepens continuously of electromagnetism line technology, the demand of winding wire increasingly increases, according to statistics, enameled wire accounting compared with Greatly, winding wire accounts for about 15%.In recent years, urban and rural power grids rapidly develop, to the winding wire demand of generator, transformer will have compared with Big growth, according to incompletely statistics, about 1,670,000 tons of the yield of China's electromagnetic wire industry in 2015,1,560,000 tons of increasings in year-on-year 2014 Grow 7%.In recent years, this data continued to rise.
The glass fibre winding wire of domestic production at present has greater advance in yield, kind.But most products are concentrated In the product that thermal level is low temperature thermal grade in 130 DEG C, 155 DEG C etc..
Since product design tends to minimize, the reduction of volume, it is meant that sacrifice product heat dissipation for cost, to electromagnetic wire Temperature resistant grade propose higher requirement;Continuous requirement of the Product Terminal client to quality simultaneously, needs the use of product With higher service life, the product of high quality becomes the target that market is chased.Since glass fiber covered wire product is in glass Silk external sheath insulated paint, product surface be not it is very smooth, be easy to appear defect point.These defect points, which become, to be influenced to produce The hidden danger of product electrical property.It is doomed to develop on the product of part high request and is fettered.In addition the competition in present market constantly rises Temperature, electromagnetic wire are continuously increased using client in the speed of coiling wire rod, are more wanted to the mechanical of electromagnetic wire using proposition is high It asks.In operation, due to the particularity of product, needs to remove insulating layer exposing conductor and led due to the close adhesion of insulating layer It causes removal process time-consuming and laborious, affects production efficiency.Or insulated paint is easily removed, the influence insulation but meeting large area falls off Performance.There is manufacturing enterprise in assembling process, there is no color to be used as reference in welding for the product of specification of the same race after finger, Maloperation is caused, product quality is influenced;Usual this kind of high-quality product mainstream is still occupied by external large enterprise.To state Interior enterprise sets technical barrier, hinders the development of national enterprise.
Summary of the invention
The present invention proposes 180 grades of easily stripped glass fiber covered wires of one kind and preparation method thereof, solves operation in the prior art The problem of Shi Buyi removes insulated paint or easily removes insulated paint but influence insulating layer attachment.
The technical scheme of the present invention is realized as follows:
A kind of 180 grades of easily stripped glass fiber covered wires including copper conductor, are coated on the first glass fiber of copper conductor surface With the second glass fiber and insulating lacquer layer;
First glass fiber is glass fiber and fiber filament according to 9-13:1-3 progress and silk;
Second glass fiber is glass fiber and fiber filament according to 4-6:4-8 progress and silk;
First glass fiber uses left-handed direction (counterclockwise) when coating copper conductor;
Dextrorotation (clockwise) direction is used when second glass fiber coats.
The copper conductor selects copper content >=99.97% as a preferred technical solution, and oxygen content is lower than 10PPM's High-purity oxygen-free copper is as conductor blank (the oxygen-containing figureofmerit of conventional oxygen-free copper is≤30PPM).It is using the advantages of oxygen-free copper: a, The crystal grain of oxygen-free copper is smaller, and smooth surface is easily obtained after drawing, is an important factor for guaranteeing properties of product.B, oxygen-free copper Resistivity it is smaller, calorific value is smaller in the product course of work, improves the service life of product.C, the ductility of oxygen-free copper Preferably, after annealing acts on, product has excellent ductility, more preferably meets the use of high-speed winding.
First glass fiber is that glass fiber and fiber filament carry out simultaneously according to 11:2 as a preferred technical solution, Silk;Second glass fiber is glass fiber and fiber filament according to 5:6 progress and silk.
First glass fiber is glass fiber and fiber filament according to 9:3 progress and silk as a preferred technical solution,; Second glass fiber is glass fiber and fiber filament according to 5:7 progress and silk.
First glass fiber is that glass fiber and fiber filament carry out simultaneously according to 13:2 as a preferred technical solution, Silk;Second glass fiber is glass fiber and fiber filament according to 4:5 progress and silk.
The outermost layer of the envelope curve is red polyester (epoxy) resin layer as a preferred technical solution,.
As a preferred technical solution, polyester (epoxy) resin layer of the red prepare it is as follows: orchil use Xylene solvent carries out preliminarily diluted, is filtered with strainer;Carry out concentration proportioning later, orchil and xylene solvent Mass ratio is controlled in 1.5%-2.5%.
A kind of preparation method of 180 grades of easily stripped glass fiber covered wires, comprising:
(1) utilize doubling winder, glass fiber and fiber filament carried out and silk according to 9-13:1-3, formed first packet roll into a ball to With;
By glass fiber and fiber filament is carried out according to 4-6:4-8 and silk, and it is stand-by to form second packet group;
(2) left-handed direction (counterclockwise) is used when first packet group cladding copper conductor;It is adopted when second packet group cladding With dextrorotation (clockwise) direction;It will be on the copper conductor for being coated on operation of glass fiber closed seamless;
(4) the coating insulated paint that multi-pass is carried out to the copper conductor after cladding, enters in baker toast later;
Before last time enters baker, the coating of orchil is carried out, out after baking oven, obtains red wrapped product line.
The copper conductor is produced as follows as a preferred technical solution: oxygen-free copper bar being put into big wire drawing machine draws Pull out process, after anneal by 2000 Ampere currents.It anneals for (2000 amperes) of high current and is able to satisfy the requirement of high-speed production;It is existing Row speed of production per second is 27 meters, that is, is wanted in 1620 ms/min per minute, and the annealing of high current meets wanting for high-speed production It asks, so that product has excellent flexibility.
The baking in the step (4) is 6 times as a preferred technical solution, and recycles progress.
Before last 1 enters baker, the orchil modulated is coated, by the high temperature action of burner hearth, orchil Middle solvent components volatilization, dye moiety uniform fold obtain red winding wire finished product in resin surface.In this stage, to guarantee The adequacy and uniformity of product baking, the baker temperature control are improved to 5 temperature controls by 3 original temperature controls, and temperature is wanted Seeking range is 400 DEG C~460 DEG C.
A kind of preparation method of 180 grades of red easily stripped glass fiber covered wires, comprising:
S1: production conductor;Oxygen-free copper bar put into big wire drawing machine and carry out continuous wire drawing processing, in drawing die Under the action of tool and wire drawing liquid, after being up to 2000 amperes of current annealing, obtainAnaerobic copper conductor, anaerobic The smooth no pit in the surface of copper conductor;
S2: it is rolled into a ball by glass fiber and fiber filament according to 11:2 and 5:6 mode and at silk packet stand-by.
S3: above-mentioned silk packet group is respectively placed in lapping head device;It makes two bites at a cherry around packet mode, lower layer's lapping direction To be left-handed to using the glass fiber of 11:2;Upper end lapping direction is dextrorotation to using the glass fiber of 5:6;By around The high speed rotation (1600RPM) in packet header, will be on the anaerobic copper conductor for being coated on operation of glass fiber closed seamless;
S4: by the anaerobic copper conductor for coating glass fiber by felt device for painting, storing the function of painting using felt, Apply paint to glass fiber surface;The japanning of the 1st passage is coated, 2 passages are toasted;The 3rd passage is painted again, baking 4;
Step S5: before the 6th passage enters baker, being coated with orchil, will be in orchil by the heat of baker Solvent components vapor away, dye paste part is uniformly retained on resin, formed required for product;In this stage, dry Furnace temperature control is 5 temperature controls, and the claimed range of temperature is 400 DEG C~460 DEG C;
Wherein: orchil belong to using xylene solvent carry out preliminarily diluted, service precision be 100 mesh precision strainer into Row filtering;Concentration proportioning is carried out later, and the mass ratio control of orchil and xylene solvent is in 1.5%-2.5%.
Beneficial effect
(1) there is excellent easy-peel performance, operator can be removed the insulating layer for being attached to copper conductor surface by nail, For the insulating layer to fall off at strip, strip is that will not fall off at sheet no more than 1cm fritter, influence the attachment of insulating layer Property.
(2) excellent adhesion and drawing effect;After product stretched 20%, glass fiber covering should not crack and expose Bare copper wire;After 10 times of conductor diameters are wound, glass fiber layer should not crack and expose bare copper wire product.
(3) specific visual color difference;The color of normal product is golden yellow;When user's winding multi-strand equivalent specifications are wrapped When product, it cannot be distinguished in connection, influence the accuracy being conductively connected.The invention product colour is red product, in routine In visual situation, it can accomplish effectively to identify and distinguish between.
(4) excellent electric durability energy;It is >=450V to the index request of resistance to electricity in professional standard, passes through the technology to simultaneously silk It improves and the improvement of wrapped cladding, the resistance to electric effect of the product of acquisition can meet >=2500V.Much higher than professional standard requirement and Guarantee enough surpluses that product uses.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
For the present invention using insulated paint by forming hard resin after high-temperature baking, cured resin layer is coated on glass fibre Outside silk layer, and glass fiber closely coats oxygen-free copper, forms electromagnetic wire product.
The present invention can also insulated paint outer layer in upper one layer of red polyester (epoxy) resin layer, in this way convenient for ginseng It examines, reduces maloperation.
Embodiment 1
A kind of 180 grades of easily stripped glass fiber covered wires including copper conductor, are coated on the first glass fiber of copper conductor surface With the second glass fiber and insulating lacquer layer.Wherein, the first glass fiber is that glass fiber and fiber filament carry out simultaneously according to 9:3 Silk;Second glass fiber is glass fiber and fiber filament according to 5:7 progress and silk;
First glass fiber uses left-handed direction (counterclockwise) when coating copper conductor;
Dextrorotation (clockwise) direction is used when second glass fiber coats.
It is specific the preparation method is as follows:
Step S1: production conductor;Oxygen-free copper bar put into big wire drawing machine and carry out continuous wire drawing processing, drawing Under the action of draft tool and wire drawing liquid, after being up to 2000 amperes of current annealing, obtain Soft copper blank, copper base The defects of smooth no pit in the surface of material;The precision of die size and the pipe of wire drawing liquid concentration and pH value are paid attention to during this Control.
Step S2: frame mode 9:3 and the 5:7 mode after glass fiber and fiber filament are proved repeatedly according to technical staff And it is rolled into a ball at silk packet stand-by.
Step S3: above-mentioned silk packet group is respectively placed in lapping head device (existing apparatus).It is complete in two times around packet mode Be at, lower layer's lapping direction it is left-handed to (counter clockwise direction), use the glass fiber of 9:3;Upper end lapping direction be dextrorotation to (clockwise direction) uses the glass fiber of 5:7.It is by the high speed rotation (1600RPM) of taping head, glass fiber is tight On the close seamless anaerobic copper conductor for being coated on operation.
Step S4: the copper of closed seamless winding glass fiber is passed through into felt device for painting, is painted using the storage of felt Function applies paint to glass fiber surface.After conventional device for painting is coating 1, into carrying out baking-curing in burner hearth.It makes a living This product is produced, the coating method of insulated paint is changed, coats the insulated paint of 1 passage, is toasted 2~3 times.Purpose is control Adhesion index is in the range of requiring.Concrete operations are the japanning of the 1st passage, toast 2 passages;The 3rd passage is painted again, baking 4 Road.Namely japanning passage is twice;Baking 6 times.
Step S5: before the 6th passage enters baker, it is coated with the orchil proportionally modulated, passes through baker Heat vapors away the solvent components in orchil, and dye paste part is uniformly retained on resin, required for formation Product.In this stage, for the adequacy and uniformity for guaranteeing product baking, baker temperature control is improved to five by 3 original temperature controls Point temperature control, the claimed range of temperature are 400 DEG C~460 DEG C.
Wherein: orchil belongs to high temperature resistant dyestuff, to guarantee last coloring performance and Color uniformity, the system of dyestuff Standby that xylene solvent need to be used to carry out preliminarily diluted, service precision is that the strainer of 100 mesh precision is filtered;Concentration is carried out later The mass ratio of proportion, orchil and xylene solvent is controlled in 1.5%-2.5%.It can guarantee the performance of final product and outer It sees and requires.Mass ratio control is 2% in the present embodiment.
Since client requires the insulating layer for being attached to conductive surface to be easily removed in use, while also to guarantee product The adhesion needed in process.That is insulating layer the adhesion of conductor cannot be very good, can not be bad, to have Performance easy to process.To solve this particular/special requirement, do not stop to manufacture experimently through technical staff, obtains glass fiber and filametntary adaptation ratio Example breaks conventional production method in conjunction with the improvement of japanning mode, obtains the product for meeting processing performance.Obtain the approval of client And favorable comment.
Embodiment 2
A kind of 180 grades of easily stripped glass fiber covered wires including copper conductor, are coated on the first glass fiber of copper conductor surface With the second glass fiber and insulating lacquer layer.Wherein, the first glass fiber is that glass fiber and fiber filament are carried out according to 11:2 And silk;Second glass fiber is glass fiber and fiber filament according to 5:6 progress and silk;
First glass fiber uses left-handed direction (counterclockwise) when coating copper conductor;
Dextrorotation (clockwise) direction is used when second glass fiber coats.
Preparation method, it is same with embodiment 1.Wherein the control of the mass ratio of orchil and xylene solvent is 1.5%.Implement The scheme of example 2 will be better than the scheme of embodiment 1.Electromagnetic wire obtained has excellent easy-peel performance, and operator can by nail Will be attached to the insulating layer removal of copper conductor surface, for the insulating layer to fall off at strip, strip is small no more than 1cm Block, will not fall in flakes.
180 grades obtained above red easily stripped glass fiber covered wire performances meet claimed below:
Embodiment 3
A kind of 180 grades of easily stripped glass fiber covered wires including copper conductor, are coated on the first glass fiber of copper conductor surface With the second glass fiber and insulating lacquer layer.Wherein, the first glass fiber is that glass fiber and fiber filament are carried out according to 13:2 And silk;Second glass fiber is glass fiber and fiber filament according to 4:5 progress and silk;
First glass fiber uses left-handed direction (counterclockwise) when coating copper conductor;
Dextrorotation (clockwise) direction is used when second glass fiber coats.
Preparation method, it is same with embodiment 1.Wherein the control of the mass ratio of orchil and xylene solvent is 2.5%.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of 180 grades of easily stripped glass fiber covered wires, including copper conductor, be coated on copper conductor surface the first glass fiber and Second glass fiber and insulating lacquer layer;It is characterized in that,
First glass fiber is glass fiber and fiber filament according to 9-13:1-3 progress and silk;
Second glass fiber is glass fiber and fiber filament according to 4-6:4-8 progress and silk;
First glass fiber uses left hand direction when coating copper conductor;
Clockwise direction is used when second glass fiber coats.
2. a kind of 180 grades of easily stripped glass fiber covered wires according to claim 1, which is characterized in that the copper conductor is selected Copper content >=99.97%, and high-purity oxygen-free copper of the oxygen content lower than 10PPM is as conductor blank.
3. a kind of 180 grades of easily stripped glass fiber covered wires according to claim 1, which is characterized in that the envelope curve it is outermost Layer is red polyester (epoxy) resin layer.
4. a kind of 180 grades of easily stripped glass fiber covered wires according to claim 3, which is characterized in that the polyester of the red Preparing for (epoxy) resin layer is as follows: orchil carries out preliminarily diluted using xylene solvent, is filtered with strainer;Later Concentration proportioning is carried out, the mass ratio control of orchil and xylene solvent is in 1.5%-2.5%.
5. a kind of preparation method of 180 grades of easily stripped glass fiber covered wires characterized by comprising
(1) doubling winder is utilized, by glass fiber and fiber filament is carried out according to 9-13:1-3 and silk, and it is stand-by to form first packet group;
By glass fiber and fiber filament is carried out according to 4-6:4-8 and silk, and it is stand-by to form second packet group;
(2) left hand direction is used when first packet group cladding copper conductor;Clockwise direction is used when second packet group cladding;It will Glass fiber closed seamless is coated on the copper conductor of operation;
(4) the coating insulated paint that multi-pass is carried out to the copper conductor after cladding, enters in baker toast later;
Before last time enters baker, the coating of orchil is carried out, out after baking oven, obtains red wrapped product line.
6. a kind of 180 grades of easily stripped glass fiber covered wires according to claim 5 are prepared, which is characterized in that described Copper conductor is produced as follows: oxygen-free copper bar is put into big wire drawing machine and carries out drawing process, after moved back by 2000 Ampere currents Fire.
7. a kind of 180 grades of easily stripped glass fiber covered wires according to claim 5 are prepared, which is characterized in that step (4) operation for coating insulated paint is as follows: the copper conductor after cladding being passed through felt device for painting, is painted using the storage of felt Function applies paint to glass fiber surface;
The insulated paint of 1 passage is coated, is toasted 2~3 times;The 3rd passage is painted again, baking 4.
8. a kind of 180 grades of easily stripped glass fiber covered wires according to claim 5 are prepared, which is characterized in that described Baker temperature control is 5 temperature controls, and the claimed range of temperature is 400 DEG C~460 DEG C.
9. a kind of 180 grades of easily stripped glass fiber covered wires according to claim 5 are prepared, which is characterized in that described Baking in step (4) is 6 times, and recycles progress.
10. a kind of preparation method of 180 grades of red easily stripped glass fiber covered wires characterized by comprising
S1: production conductor;Oxygen-free copper bar put into big wire drawing machine and carry out continuous wire drawing processing, in drawing mould and Under the action of wire drawing liquid, after being up to 2000 amperes of current annealing, obtainAnaerobic copper conductor, oxygen-free copper are led The smooth no pit in the surface of body;
S2: it is rolled into a ball by glass fiber and fiber filament according to 11:2 and 5:6 mode and at silk packet stand-by.
S3: above-mentioned silk packet group is respectively placed in lapping head device;It makes two bites at a cherry around packet mode, lower layer's lapping direction is a left side Rotation direction uses the glass fiber of 11:2;Upper end lapping direction is dextrorotation to using the glass fiber of 5:6;Pass through taping head 1600RPM rotation, will be on the anaerobic copper conductor for being coated on operation of glass fiber closed seamless;
S4: by the anaerobic copper conductor for coating glass fiber by felt device for painting, the function of the storage paint of felt, coating are utilized Paint glass fiber surface;The japanning of the 1st passage is coated, 2 passages are toasted;The 3rd passage is painted again, baking 4;
Step S5: before the 6th passage enters baker, being coated with orchil, will be molten in orchil by the heat of baker Agent composition vapors away, and dye paste part is uniformly retained on resin, product required for being formed;In this stage, baker control Wen Weiwu point temperature control, the claimed range of temperature are 400 DEG C~460 DEG C;
Wherein: orchil, which belongs to, carries out preliminarily diluted using xylene solvent, and service precision is that the strainer of 100 mesh precision carried out Filter;Concentration proportioning is carried out later, and the mass ratio control of orchil and xylene solvent is in 1.5%-2.5%.
CN201811607447.XA 2018-12-27 2018-12-27 180-grade easily-stripped glass fiber covered wire and preparation method thereof Active CN109712743B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08249942A (en) * 1995-03-14 1996-09-27 Toshiba Corp Insulated conductor
CN1490824A (en) * 2003-08-27 2004-04-21 马仕兴 Silicon rubber heat resistant wire for heating coil
CN101582311A (en) * 2008-05-12 2009-11-18 卢之云 Processing process of polyester glass sintering copper flat wire
CN203260346U (en) * 2013-05-25 2013-10-30 南通明光电线有限公司 Transformer/motor-used double-glass fiber-wrapped round wire
CN103490542A (en) * 2013-09-25 2014-01-01 苏州贯龙电磁线股份有限公司 Electromagnetic wire for motor coil winding
CN105427925A (en) * 2014-09-17 2016-03-23 江苏金苇电气科技有限公司 Mica cable with good thermal insulation performance

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08249942A (en) * 1995-03-14 1996-09-27 Toshiba Corp Insulated conductor
CN1490824A (en) * 2003-08-27 2004-04-21 马仕兴 Silicon rubber heat resistant wire for heating coil
CN101582311A (en) * 2008-05-12 2009-11-18 卢之云 Processing process of polyester glass sintering copper flat wire
CN203260346U (en) * 2013-05-25 2013-10-30 南通明光电线有限公司 Transformer/motor-used double-glass fiber-wrapped round wire
CN103490542A (en) * 2013-09-25 2014-01-01 苏州贯龙电磁线股份有限公司 Electromagnetic wire for motor coil winding
CN105427925A (en) * 2014-09-17 2016-03-23 江苏金苇电气科技有限公司 Mica cable with good thermal insulation performance

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