CN109652228A - A kind of High-concentration laundry detergent and its preparation method and application - Google Patents
A kind of High-concentration laundry detergent and its preparation method and application Download PDFInfo
- Publication number
- CN109652228A CN109652228A CN201910072951.2A CN201910072951A CN109652228A CN 109652228 A CN109652228 A CN 109652228A CN 201910072951 A CN201910072951 A CN 201910072951A CN 109652228 A CN109652228 A CN 109652228A
- Authority
- CN
- China
- Prior art keywords
- laundry detergent
- concentration laundry
- surfactant
- concentration
- detergent according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003599 detergent Substances 0.000 title claims abstract description 65
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 102000004190 Enzymes Human genes 0.000 claims abstract description 16
- 108090000790 Enzymes Proteins 0.000 claims abstract description 16
- 240000003377 Shepherdia canadensis Species 0.000 claims abstract description 16
- 235000018324 Shepherdia canadensis Nutrition 0.000 claims abstract description 16
- 239000000284 extract Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002738 chelating agent Substances 0.000 claims abstract description 14
- 239000003755 preservative agent Substances 0.000 claims abstract description 14
- 230000002335 preservative effect Effects 0.000 claims abstract description 14
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- 239000006254 rheological additive Substances 0.000 claims abstract description 13
- 239000003381 stabilizer Substances 0.000 claims abstract description 13
- 108091005804 Peptidases Proteins 0.000 claims abstract description 12
- 239000004365 Protease Substances 0.000 claims abstract description 12
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims abstract description 12
- 239000003513 alkali Substances 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- 239000003960 organic solvent Substances 0.000 claims abstract description 11
- 239000000686 essence Substances 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- 150000002191 fatty alcohols Chemical class 0.000 claims description 20
- -1 olefin sulfonate Chemical class 0.000 claims description 13
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 11
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 11
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 10
- 235000011152 sodium sulphate Nutrition 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 239000002736 nonionic surfactant Substances 0.000 claims description 9
- 239000003945 anionic surfactant Substances 0.000 claims description 8
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 7
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 229930182470 glycoside Natural products 0.000 claims description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 230000003213 activating effect Effects 0.000 claims description 4
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
- 239000004280 Sodium formate Substances 0.000 claims description 2
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 2
- 239000001110 calcium chloride Substances 0.000 claims description 2
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- BEGBSFPALGFMJI-UHFFFAOYSA-N ethene;sodium Chemical group [Na].C=C BEGBSFPALGFMJI-UHFFFAOYSA-N 0.000 claims description 2
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 2
- 239000001509 sodium citrate Substances 0.000 claims description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 2
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims description 2
- 235000019254 sodium formate Nutrition 0.000 claims description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 2
- FQANRCWINZEGNW-UHFFFAOYSA-N 3-chloro-4-methyl-1,2-thiazole Chemical group CC1=CSN=C1Cl FQANRCWINZEGNW-UHFFFAOYSA-N 0.000 claims 1
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 claims 1
- 102000002322 Egg Proteins Human genes 0.000 claims 1
- 108010000912 Egg Proteins Proteins 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 125000005233 alkylalcohol group Chemical group 0.000 claims 1
- SMWDFEZZVXVKRB-UHFFFAOYSA-N anhydrous quinoline Natural products N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- 238000002242 deionisation method Methods 0.000 claims 1
- 235000014103 egg white Nutrition 0.000 claims 1
- 210000000969 egg white Anatomy 0.000 claims 1
- 229930182478 glucoside Natural products 0.000 claims 1
- 150000008131 glucosides Chemical class 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 150000004702 methyl esters Chemical class 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- 238000009826 distribution Methods 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 description 29
- 238000005406 washing Methods 0.000 description 19
- 238000012360 testing method Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 238000002474 experimental method Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- 235000019483 Peanut oil Nutrition 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000000312 peanut oil Substances 0.000 description 3
- 235000013555 soy sauce Nutrition 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 239000000419 plant extract Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 101710093543 Probable non-specific lipid-transfer protein Proteins 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 208000030961 allergic reaction Diseases 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000009781 safety test method Methods 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000041 toxicology testing Toxicity 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to daily chemical products technical field, a kind of High-concentration laundry detergent and its preparation method and application is disclosed.High-concentration laundry detergent of the present invention includes soapberry extract, surfactant, organic solvent, alkali protease, enzyme stabilizers, chelating agent, rheology modifier, preservative, essence and deionized water.The present invention is by being combined into a kind of High-concentration laundry detergent for soapberry extract and a variety of suitable group distribution, it not only has higher stability, but also has higher submissive performance and bright color performance, nonirritant to skin safe, usage amount is lower, and clean power is stronger.
Description
Technical field
The present invention relates to daily chemical products technical field, in particular to a kind of High-concentration laundry detergent and preparation method thereof and answer
With.
Background technique
With world economy integration and trade globalization development, articles for washing towards energy-saving and environmental protection, efficiently, temperature
With it is easy to use, and meet safety and the direction of environmental requirement is developed.The active matter content of High-concentration laundry detergent is in 30%-
60%, when in use, it is only necessary to add the 1/3-1/2 of ordinary liquid laundry detergent, corresponding effect can be reached, not only may be used in this way
With energy-saving and environmental protection, production, transport and packing cost can also be greatly reduced.Be concentrated liquid detergent energy-saving and environmental protection, efficiently
Etc. significant advantage, so that more and more businessmans is strengthened research and development capabilities in the field, it is numerous and confused to release concentrated type liquid detergent.
Current concentrated type liquid detergent mostly lays particular stress on dirt-removing power, and after the stability of liquid detergent itself and clothing are washed
The research dynamics of compliance and bright chroma etc. is not high, so that the stability of High-concentration laundry detergent, submissive performance and bright coloured silk
It can be insufficient.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of High-concentration laundry detergent and preparation method thereof, so that the height
Concentration liquid detergent has higher stability；
Another object of the present invention is that a kind of High-concentration laundry detergent and preparation method thereof is provided, so that described highly concentrated
Contracting liquid detergent has higher submissive performance；
Another object of the present invention is that a kind of High-concentration laundry detergent and preparation method thereof is provided, so that described highly concentrated
Contracting liquid detergent has higher bright color performance；
It is answered another object of the present invention is that providing above-mentioned High-concentration laundry detergent in the correlation prepared in daily chemical products
With.
For achieving the above object, the invention provides the following technical scheme:
A kind of High-concentration laundry detergent, including soapberry extract, surfactant, organic solvent, alkali protease, enzyme are steady
Determine agent, chelating agent, rheology modifier, preservative, essence and deionized water.
Wherein, the soapberry extract can be bought by commercially available approach, such as be purchased from hundred bright moral biochemistry (seas
Door) Co., Ltd, name of product: soapberry extract；
Preferably, by percentage to the quality, the High-concentration laundry detergent includes 0.01-10% soapberry extract, 45-
65% surfactant, 1-7% organic solvent, 0.1-2% alkali protease, 0.2-2% enzyme stabilizers, 0.05-2.5% chelating
Agent, 0.2-4% rheology modifier, 0.05-0.8% preservative, 0.1-1% essence and 5-50% deionized water.
In the specific embodiment of the invention, the High-concentration laundry detergent includes 10% soapberry extract, 40% surface
It is activating agent, 1% organic solvent, 0.1% alkali protease, 0.2% enzyme stabilizers, 0.05% chelating agent, 0.2% rheology modified
Agent, 0.05% preservative, 0.1% essence and 43.3% deionized water；
Or including 5% soapberry extract, 50% surfactant, 2% organic solvent, 1% alkali protease, 1% enzyme
Stabilizer, 2% chelating agent, 2% rheology modifier, 0.4% preservative, 0.5% essence and 33.1% deionized water；
Or including 0.01% soapberry extract, 65% surfactant, 3% organic solvent, 2% alkali protease, 2%
Enzyme stabilizers, 2.5% chelating agent, 4% rheology modifier, 0.8% preservative, 1% essence and 15.69% deionized water.
Preferably, the surfactant be selected from sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxyethylene ether -9,
Fatty alcohol polyoxyethylene ether -7, fatty acid methyl ester ethoxylate, alkyl glycosides, dodecyl benzene sulfonic acid, α-sodium olefin sulfonate
One or more of.
In the specific implementation process, the surfactant be anionic surfactant and nonionic surfactant,
Anionic surfactant in sodium sulfate of polyethenoxy ether of fatty alcohol, dodecyl benzene sulfonic acid, α-sodium olefin sulfonate one
Kind or two kinds, nonionic surfactant be selected from fatty alcohol polyoxyethylene ether -9, fatty alcohol polyoxyethylene ether -7, fatty acid methyl ester
One or both of ethoxylate, alkyl glycosides；The anionic surfactant: nonionic surfactant mass ratio
For (1-2): (1-3)；
Preferably, anionic surfactant: nonionic surfactant mass ratio is 1:(1.5-2.5)；
In the specific embodiment of the invention, the anionic surfactant: nonionic surfactant mass ratio is
1:3,1:1.5 or 2:1；The anionic surfactant is sodium sulfate of polyethenoxy ether of fatty alcohol+dodecyl benzene sulfonic acid two
Kind, sodium sulfate of polyethenoxy ether of fatty alcohol are a kind of or α-sodium olefin sulfonate is a kind of；The nonionic surfactant is fatty alcohol
- 9 one kind of polyoxyethylene ether, two kinds of alkyl glycosides+fatty acid methyl ester ethoxylate or fatty acid methyl ester ethoxylate are a kind of；
One of in the specific embodiment of the invention, the surfactant selection is following:
(1) sodium sulfate of polyethenoxy ether of fatty alcohol: dodecyl benzene sulfonic acid, fatty alcohol polyoxyethylene ether -9=5:1:9；
(2) sodium sulfate of polyethenoxy ether of fatty alcohol, alkyl glycosides, fatty acid methyl ester ethoxylate=6:5:4；
(3) α-sodium olefin sulfonate: fatty acid methyl ester ethoxylate=2:3；
(4) sodium sulfate of polyethenoxy ether of fatty alcohol: dodecyl benzene sulfonic acid, fatty alcohol polyoxyethylene ether -9=5:5:5；
(5) sodium sulfate of polyethenoxy ether of fatty alcohol, alkyl glycosides, fatty acid methyl ester ethoxylate=3:5:4；
Preferably, the organic solvent is propylene glycol and/or ethyl alcohol；When organic solvent is propylene glycol and two kinds of ethyl alcohol
When, the two volume ratio is without limitation but preferably 1:1.
Preferably, the alkali protease is EFFECTENZTMP 100 and/or Sacinase Ultra16XL.
Preferably, the enzyme stabilizers are selected from one or more of calcium chloride, magnesium chloride, sodium formate.
Preferably, the chelating agent is sodium ethylene diamine tetracetate and/or sodium citrate；The rheology modifier is chlorination
Sodium.
Preferably, the preservative is selected from one of methylchloroisothiazandnone, methylisothiazolinone, BIT 20
Or it is two or more.
High-concentration laundry detergent safety testing of the present invention is the result shows that sensitization intensity is pierced to have no skin allergic reaction
Swash property test result show no skin irritation, gross activity object content >=45% are met concentration+standard requirements, and have
Standby higher stability has higher submissive performance compared with the control liquid detergent of conventional liquid detergent and different component
With bright color performance.Based on this, the invention proposes the High-concentration laundry detergents to prepare the application in daily chemical products.
In addition, deionized water, chelating agent, table is added the present invention also provides the preparation method of the High-concentration laundry detergent
Face activating agent, rheology modifier, enzyme stabilizers stirring are completely dissolved material；When temperature is at 45 DEG C or less, addition preservative,
Soapberry extract, alkali protease, stirring make material be uniformly mixed and be completely dissolved, obtain the High-concentration laundry detergent.
More specifically, sequentially adding deionized water, chelating agent, surfactant, rheology modifier, enzyme stabilizers, stir
20-40 minutes, it is completely dissolved material；When temperature is at 45 DEG C or less, preservative, plant extracts, alkali protease is added,
Stirring 10-30 minutes, makes material be uniformly mixed and be completely dissolved, obtains the High-concentration laundry detergent.
From the above technical scheme, the present invention is by being combined into one for soapberry extract and a variety of suitable group distribution
Kind High-concentration laundry detergent, not only has higher stability, but also has higher submissive performance and bright color performance, to skin
Safe and non-stimulating property, usage amount is lower, and clean power is stronger.
Specific embodiment
The invention discloses a kind of High-concentration laundry detergent and its preparation method and application, those skilled in the art can be used for reference
Present disclosure is suitably modified realization of process parameters.In particular, it should be pointed out that all similar substitutions and modifications are to this field skill
It is it will be apparent that they are considered as being included in the present invention for art personnel.High-concentration laundry detergent and its system of the present invention
Preparation Method and application be described by embodiment, related personnel obviously can not depart from the content of present invention, spirit and
Liquid-crystal composition described herein and its preparation method and application is modified in range or appropriate changes and combinations, realizing and
Using the technology of the present invention.
In the specific embodiment of the invention, it is related to comparative test, each test group is other than due difference, remaining test
Environment and raw material etc. are consistent.
Just a kind of High-concentration laundry detergent provided by the present invention and its preparation method and application is described further below.
Embodiment 1: High-concentration laundry detergent and comparative example described in preparation liquid of the present invention
By table 1-2 (soapberry extract, essence are identical with deionized water each group) and table 3, (unit of table 3 is quality percentage
Than) shown in formula table ingredient, sequentially add deionized water, chelating agent, surfactant, rheology modifier, enzyme stabilizers, stir
It mixes 20-40 minutes, is completely dissolved material；When temperature is at 45 DEG C or less, preservative, plant extracts, basic protein is added
Enzyme stirs 10-30 minutes, so that material is uniformly mixed and is completely dissolved, obtain the High-concentration laundry detergent.
1 embodiment sorting table of table
2 comparative example sorting table of table
The formula table (%) of 3 embodiment and comparative example of table
Embodiment 2: stability test
Test sample: the liquid detergent of the liquid detergent of embodiment 1-6, comparative example 1-5；
Test method: QB/T 1224-2012
It is heat-resisting: to be kept for 24 hours in (40 ± 2) DEG C, restore to room temperature to observe it and whether there is or not significant changes before experiment；
It is cold-resistant: to be kept for 24 hours in (- 5 ± 2) DEG C, restore to room temperature to observe it and whether there is or not significant changes before experiment；
Test result is shown in Table 4；
Table 4
As can be seen from Table 3, the Soapberry liquid laundry detergent of comparative example can occur unstable under hotter and colder environment
Phenomenon shows that the adaptation of soapberry extract and each auxiliary material can not keep stablizing under hotter and colder environment, and of the invention
Six embodiments maintain higher stability.
Embodiment 3: submissive performance test
Test sample: the liquid detergent of embodiment 1-6, the liquid detergent of comparative example 4-5, commercial source Superconcentrated washing liquid A
(surface-active contents are greater than 45%)；
Experimental procedure:
Pre-treatment: being cut into the cloth of experiment the cloth of 8x8cm, impregnates 30min with 1%NaOH solution, is machine-washed with laundry
35min is washed, centrifugal dehydration is dried (105 DEG C).
Each test sample is weighed respectively to be flushed into respectively respectively with control liquid detergent 5g, respectively with the 250ppm hard water of 1000ml
Terg-O-Tometer cylinder in, every cylinder is put into 6 cloths, washed 20min (30 DEG C, 120r/min) with Terg-O-Tometer, 2L from
Water rinses 1 time, dries (105 DEG C, 1h), circulation washing, baking step 10 times.
Restore to cloth to room temperature, subjectivity is carried out by pliability of the sense of touch to cloth by 10 Specialty Experiment personnel and is commented
Point, standard is shown in Table 5:
Table 5
It takes the average value of each sample score to compare, judges the submissive performance of each sample, the low then soft effect of score
It becomes apparent from.
Result judgement method: when the towel pliability scoring of test sample washing is lower than the towel that standard liquid detergent washs
When, then judging test sample has submissive effect.
Each test sample is subjected to submissive performance test, is as a result listed in the table below 6.
Table 6
6 result of table explanation, relative to commercially available Superconcentrated washing liquid and comparative example 4 and comparative example 5, liquid detergent of the present invention
Keep the scoring of softness performance significant lower, wherein the scoring of embodiment 1-3 is lower compared to the scoring of embodiment 4-6, this
Show that liquid detergent of the present invention can make clothing more compliant.
Embodiment 4: bright coloured silk performance test
1. experiment reagent and material:
Cotton clothes and socks, standard liquid detergent, test sample and control liquid detergent are the same as embodiment 2, the common dirt of life
Stain；
2. experimental facilities: washing machine
3. experimental procedure:
The 3.1 common spots of life: seasoning (soy sauce) eats grease stain (peanut oil), protide spot (milk), fruit/vegetable
Juice stain (catsup)
3.2 spot precoating treatments:
1. on clothing choose 3 diameters be about 4cm border circular areas, respectively smear 0.5mL soy sauce+0.5mL peanut oil+
0.5mL milk+1g catsup, and smeared uniformly with spoon, 1h is stood under sunlight, to spot aging.
2. on socks choose 2 diameters be about 4cm border circular areas, respectively smear 0.5mL soy sauce+0.5mL peanut oil+
0.5mL milk+1g catsup, and smeared uniformly with spoon, 1h is stood under sunlight, to spot aging.
Remarks: the processing mode of every clothing (socks) need to be consistent as far as possible, be needed with the clothing that different detergent wash
Carry out distinguishing identifier.
3.3 clothes washing
3.3.1 washing procedure: using identical water quality, same model washing machine, and washing machine selection " supper-fast washing 2kg " is washed
Program is washed, main leaching requirement 32L is rinsed 1 time, is washed duration 23min, is dried, and step 3 time is dried in recycling washing.
3.3.2 it washs: one handled through 3.2 methods colored clothing and more colored socks being put into washing machine respectively
In, all detergent samples are added in washing experiment with 10g/ times for dosage, are washed by 3.3.1 washing procedure.
3.3.3 to clothing and the dry recovery of socks to room temperature, by 10 Specialty Experiment personnel by vision to the bright of clothing
Color degree carries out sensory evaluation scores, and standard is shown in Table 7:
Table 7
It takes the average value of each sample score to compare, judges the bright color performance of each sample, the high then bright color effect of score
It becomes apparent from.
4. result judgement method: when the bright chroma of clothing of test sample washing is higher than towel/clothing of standard liquid detergent washing
When object, then judging test sample has bright color effect.
Embodiment 1-6 and comparative example 4 and comparative example 5 are subjected to bright color performance test, 8 is as a result listed in the table below, purchases city
Sell the Superconcentrated washing liquid A (surface-active contents are greater than 45%) in source.
Table 8
8 result of table explanation, relative to commercially available Superconcentrated washing liquid and comparative example 4 and comparative example 5, liquid detergent of the present invention
Keep the scoring of the bright color performance of clothing significantly higher, wherein the scoring of embodiment 1-3 is higher compared to the scoring of embodiment 4-6, this
Show that liquid detergent of the present invention can make clothing more highlight coloured silk.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (12)
1. a kind of High-concentration laundry detergent, which is characterized in that including soapberry extract, surfactant, organic solvent, alkaline egg
White enzyme, enzyme stabilizers, chelating agent, rheology modifier, preservative, essence and deionized water.
2. High-concentration laundry detergent according to claim 1, which is characterized in that by percentage to the quality, including 0.01-10% without
Suffer from seed extract, 45-65% surfactant, 1-7% organic solvent, 0.1-2% alkali protease, 0.2-2% enzyme stabilizers,
0.05-2.5% chelating agent, 0.2-4% rheology modifier, 0.05-0.8% preservative, 0.1-1% essence and 5-50% deionization
Water.
3. High-concentration laundry detergent according to claim 1 or claim 2, which is characterized in that the surfactant is selected from poly alkyl alcohol
Ethylene oxide ether sodium sulfate, fatty alcohol polyoxyethylene ether -9, fatty alcohol polyoxyethylene ether -7, fatty acid methyl ester ethoxylate, alkane
One or more of base glucosides, dodecyl benzene sulfonic acid, α-sodium olefin sulfonate.
4. High-concentration laundry detergent according to claim 1 or claim 2, which is characterized in that the surfactant is anionic surface
Activating agent and nonionic surfactant, wherein anionic surfactant: nonionic surfactant mass ratio is (1-2):
(1-3), anionic surfactant are selected from sodium sulfate of polyethenoxy ether of fatty alcohol, dodecyl benzene sulfonic acid, α-sodium olefin sulfonate
One or both of, nonionic surfactant is selected from fatty alcohol polyoxyethylene ether -9, fatty alcohol polyoxyethylene ether -7, fat
One or both of sour methyl ester ethoxylates, alkyl glycosides.
5. High-concentration laundry detergent according to claim 1 or claim 2, which is characterized in that the organic solvent is propylene glycol and/or second
Alcohol.
6. High-concentration laundry detergent according to claim 1 or claim 2, which is characterized in that the alkali protease is EFFECTENZTM
P 100 and/or Sacinase Ultra 16XL.
7. High-concentration laundry detergent according to claim 1 or claim 2, which is characterized in that the enzyme stabilizers are selected from calcium chloride, chlorination
One or more of magnesium, sodium formate.
8. High-concentration laundry detergent according to claim 1 or claim 2, which is characterized in that the chelating agent is sodium ethylene diamine tetracetate
And/or sodium citrate.
9. High-concentration laundry detergent according to claim 1 or claim 2, which is characterized in that the rheology modifier is sodium chloride.
10. High-concentration laundry detergent according to claim 1 or claim 2, which is characterized in that the preservative is selected from methyl chloroisothiazole
One or more of quinoline ketone, methylisothiazolinone, BIT 20.
11. High-concentration laundry detergent described in claim 1-10 any one is preparing the application in daily chemical products.
12. the preparation method of High-concentration laundry detergent described in claim 1, which is characterized in that deionized water, chelating agent, table is added
Face activating agent, rheology modifier, enzyme stabilizers stirring are completely dissolved material；When temperature is at 45 DEG C or less, addition preservative,
Soapberry extract, alkali protease, stirring make material be uniformly mixed and be completely dissolved, obtain the High-concentration laundry detergent.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110331049A (en) * | 2019-06-24 | 2019-10-15 | 上海发凯化工有限公司 | Surface activator composition and preparation method thereof containing alkyl glycosides |
| CN110508550A (en) * | 2019-09-04 | 2019-11-29 | 北京英特莱科技有限公司 | A kind of method of clean and maintenance special safety protective gear |
| CN110652604A (en) * | 2019-11-22 | 2020-01-07 | 北京英特莱科技有限公司 | Method for removing harmful substances on protective clothing of firefighter |
| CN113278475A (en) * | 2021-05-06 | 2021-08-20 | 广州市加茜亚化妆品有限公司 | Thixotropic laundry bead body and preparation method thereof |
-
2019
- 2019-01-25 CN CN201910072951.2A patent/CN109652228A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110331049A (en) * | 2019-06-24 | 2019-10-15 | 上海发凯化工有限公司 | Surface activator composition and preparation method thereof containing alkyl glycosides |
| CN110508550A (en) * | 2019-09-04 | 2019-11-29 | 北京英特莱科技有限公司 | A kind of method of clean and maintenance special safety protective gear |
| CN110652604A (en) * | 2019-11-22 | 2020-01-07 | 北京英特莱科技有限公司 | Method for removing harmful substances on protective clothing of firefighter |
| CN113278475A (en) * | 2021-05-06 | 2021-08-20 | 广州市加茜亚化妆品有限公司 | Thixotropic laundry bead body and preparation method thereof |
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