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CN109505187A - A kind of quick anaerobic fermentation biogas residue of stalk can make paper pulp - Google Patents

A kind of quick anaerobic fermentation biogas residue of stalk can make paper pulp Download PDF

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Publication number
CN109505187A
CN109505187A CN201811213664.0A CN201811213664A CN109505187A CN 109505187 A CN109505187 A CN 109505187A CN 201811213664 A CN201811213664 A CN 201811213664A CN 109505187 A CN109505187 A CN 109505187A
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CN
China
Prior art keywords
biogas residue
paper pulp
straw
stalk
days
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811213664.0A
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Chinese (zh)
Inventor
徐范
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Heilongjiang Xu Sheng Agricultural Science And Technology Co Ltd
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Heilongjiang Xu Sheng Agricultural Science And Technology Co Ltd
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Priority to CN201811213664.0A priority Critical patent/CN109505187A/en
Publication of CN109505187A publication Critical patent/CN109505187A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P5/00Preparation of hydrocarbons or halogenated hydrocarbons
    • C12P5/02Preparation of hydrocarbons or halogenated hydrocarbons acyclic
    • C12P5/023Methane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biotechnology (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Paper (AREA)

Abstract

The present invention relates to a kind of quick anaerobic fermentation biogas residues of stalk can make paper pulp.Mainly solve the problems, such as that paper grade pulp need to be largely wastage of material timber resources using timber.The following steps are included: (1) is by fresh food leaf vegetables expression separation at grass juice factor and careless slag;Straw is shredded and is steeped two days with clear water;(2) food leaf vegetables juice, cutted straw are poured into closed container, water is added not have cutted straw, when pH value reaches 6.8-7, closed container lid opens aperture connection plastic flexible pipe, seals, and after being kept for 36 degree of coolant-temperature gage, fermentation three days, hose valves is opened, exhaust gas is discharged, reseals;(3) the 4th days production biogas is opened needle tubing valve and is lighted in hose opening with fire, takes out biogas residue straw section within the 7th day, cleans biogas residue through clear water secondary, forms paper pulp after biogas residue is beaten.The quick anaerobic fermentation biogas residue of the stalk, which can make paper pulp, can save a large amount of timber and bamboo material, and papermaking cost is cheaper, greatly improve the fiber utilization rate of non-timber.

Description

A kind of quick anaerobic fermentation biogas residue of stalk can make paper pulp
Technical field
The present invention relates to pulp technology for making paper more particularly to a kind of quick anaerobic fermentation biogas residue of stalk can make paper pulp work Skill.
Background technique
At present in pulp technology for making paper, most of papermaking raw material are also made using timber, bamboo wood and mineral fibres etc. The high molecular material obtained with petroleum cracking.Paper product currently used for writing, printing, packaging with plant fiber is mainly still main Raw material is made, this has resulted in a large amount of wastes of timber, bamboo timber resource, wood pulp accounting in paper pulp in the existing paper industry in China 22%, secondary stock accounting 63%, non-wood pulp only accounting 15%, in this way if it can greatly improve non-wood pulp ratio, so that it may significantly Reduce waste and the reasonable utilization of timber resources.
Summary of the invention
The invention reside in overcome existing paper grade pulp present in background technique need to largely using timber be raw material significantly The problem of wasting timber resources, and paper pulp can be made by providing a kind of quick anaerobic fermentation biogas residue of stalk.The stalk is quickly detested Aerobe fermentation biogas residue can make paper pulp, the use of food leaf grass and stalk be papermaking raw material, can save a large amount of timber and bamboo wood is former Material, more tends to papermaking raw material use rationally, papermaking cost is cheaper, greatly improves the fiber utilization rate of non-timber.
The present invention solves the problems, such as that it can reach by following technical solution: a kind of quick anaerobic fermentation biogas residue of stalk can be made Make paper pulp, comprising the following steps:
(1) fresh food leaf grass meal is broken, grass juice factor and careless slag are then separated by mechanical expression;Straw is shredded into 0.5-0.6 Careless section is first steeped two days with clear water;
(2) food leaf grass juice factor obtained in step 1) is poured into 10 liters of closed containers, then pours the straw shredded into closed container, Water did not had cutted straw, tight with black plastic bag when pH value reaches 6.8-7, and closed container lid opens aperture connection plastic flexible pipe, and plastics are soft Guan Shangyou control valve;Pipe is sealed at lid, it is air tight, coolant-temperature gage 36-40 degree is kept, after fermentation three days, by plastic flexible pipe Valve is opened, and exhaust gas is discharged, is resealed;
(3) the 4th days production biogas is opened needle tubing valve and is lighted in hose opening with fire, takes out biogas residue straw section within the 7th day, warp Clear water cleans biogas residue secondary, forms paper pulp after biogas residue is beaten.
It is careless (azolla filliculoidas) to eat leaf, alias: food leaf vegetables, azolla filliculoidas, albumen dish, amino acid grass, amino sauerkraut.Perennial root Herbaceous plant, polygonaceae Rumex.Eat in careless (azolla filliculoidas) plant of leaf it is high containing protein, it is vitamin, 18 kinds of amino acid, SOD, different The multiple beneficials such as flavones, potassium, selenium, chlorophyll, chlorogenic acid, rheum emodin element and minerals are a kind of novel high-protein plants.
The shortcomings that producing paper pulp simultaneously using food leaf vegetables production fermentation grass juice factor, break traditional methane tank and anaerobic fermentation Deficiency, traditional biogas field oxen and horses excrement, biogas slurry belong to black, and papermaking is unhygienic, the invention belongs to eat leaf grass and stalk inoculation, replace Oxen and horses excrement forms stalk Rapid Fermentation biogas residue production pulp technology.
The present invention can have the following beneficial effects: the quick anaerobic fermentation natural pond of stalk of the present invention compared with above-mentioned background technique Slag can make paper pulp, be papermaking raw material using food leaf grass and rice straw, while food leaf grass produces fermentation grass juice factor Paper pulp is produced, the utilization scope of food leaf grass has been widened, has saved a large amount of timber and bamboo material, papermaking raw material is made to use more to become In reasonable, papermaking cost is cheaper, greatly improves the fiber utilization rate of non-timber.The present invention is efficiently provided using food leaf vegetables grass Source, overall process are pollution-free.And the utilization of biogas biogas residue is improved, accomplish waste utilization, saves resource.
Specific embodiment:
Below in conjunction with specific embodiment, the invention will be further described:
Embodiment 1
(1) it with fresh food leaf vegetables, is smashed with crusher, grass juice factor and careless slag is then separated by mechanical expression;Straw is cut Broken 0.5 centimeter careless section, is first steeped two days with clear water;
(2) then food leaf vegetables juice 0.5kg obtained in step 1) will be poured into 10 liters of plastic barrels, will be fallen by cutted straw 0.3kg Into plastic barrel, 3kg water level is at 8 liters, tight with black plastic bag when pH value reaches 7.0, and plastic drum lid is twisted sternly, and plastic drum lid is opened small Hole connects the needle tubing of injection, and seals pipe at lid, air tight, is kept for 36 degree of coolant-temperature gage, the fermentation three days bottles that rise later will Injection needle pipe valve is opened, and exhaust gas is discharged, is resealed;
(3) the 4th days production biogas is opened needle tubing valve and is lighted with fire, takes out biogas residue straw section within the 7th day, through clear water that biogas residue is clear It washes secondary, is smashed to grind with wall-breaking machine to form paper pulp;
(4) step (3) paper pulp is evenly coated on felt, paper can be formed after dry.
Embodiment 2
(1) it with fresh food leaf vegetables, is smashed with crusher, grass juice factor and careless slag is then separated by mechanical expression;Straw is cut Broken 0.5 centimeter careless section, is first steeped two days with clear water;
(2) then food leaf vegetables juice 1kg obtained in step 1) will be poured into 10 liters of plastic barrels, will be poured by cutted straw 0.6kg Plastic barrel injects 6kg water level at 8 liters, and tight with black plastic bag when pH value reaches 7.0, plastic drum lid is twisted sternly, and plastic drum lid is opened Aperture connects the needle tubing of injection, and seals pipe at lid, air tight, is kept for 40 degree of coolant-temperature gage, and rise bottle after fermenting three days, Injection needle pipe valve is opened, exhaust gas is discharged, is resealed;
(3) the 4th days production biogas is opened needle tubing valve and is lighted with fire, takes out biogas residue straw section within the 7th day, through clear water that biogas residue is clear It washes secondary, is smashed to grind with wall-breaking machine to form paper pulp;
(4) step (3) paper pulp is evenly coated on felt, paper can be formed after dry.
Comparative example:
Similarly tested respectively with cow dung and straw, biogas slurry and straw, clear water and straw, with the same room temperature feelings of embodiment 1 Under condition, using cow dung, biogas slurry, clear water as 10 days no abnormality seens of container of raw material, biogas could be generated within 10 days or more, illustrate to eat leaf grass With stalk inoculation, food leaf grass anaerobic fermentation inoculation is fast, production gas is fast, yield is high, and generation biogas is tasteless, and biogas slurry is not muddy, biogas residue Odorless has tart flavour, tests pH value 4.5-5 through chemical test paper, cleans biogas residue through clear water secondary, is beaten biogas residue with wall-breaking machine After be evenly coated on felt, paper can be formed after dry, biogas residue can replace the raw materials such as timber to make paper, and biogas residue can also make Organic granular fertilizer.
10kg food leaf grass 100kg stalk 1000kg water of the present invention can produce paper pulp 50kg.Production efficiency is substantially increased, is promoted The economic value of stalk.

Claims (3)

1. a kind of quick anaerobic fermentation biogas residue of stalk can make paper pulp, comprising the following steps:
(1) fresh food leaf grass meal is broken, grass juice factor and careless slag are then separated by mechanical expression;Straw is shredded into 0.5-0.6 Careless section is first steeped two days with clear water;
(2) food leaf grass juice factor obtained in step 1) is poured into 10 liters of closed containers, then pours the straw shredded into closed container, Water did not had cutted straw, tight with black plastic bag when pH value reaches 6.8-7, and closed container lid opens aperture connection plastic flexible pipe, and plastics are soft Guan Shangyou control valve;Pipe is sealed at lid, it is air tight, coolant-temperature gage 36-40 degree is kept, after fermentation three days, by plastic flexible pipe Valve is opened, and exhaust gas is discharged, is resealed;
(3) the 4th days production biogas is opened needle tubing valve and is lighted in hose opening with fire, takes out biogas residue straw section within the 7th day, warp Clear water cleans biogas residue secondary, forms paper pulp after biogas residue is beaten.
2. the quick anaerobic fermentation biogas residue of a kind of stalk according to claim 1 can make paper pulp, it is characterised in that: will Step (3) paper pulp is evenly coated on felt, can form paper after dry.
3. the quick anaerobic fermentation biogas residue of a kind of stalk according to claim 1 can make paper pulp, it is characterised in that: close Closing container is plastic barrel.
CN201811213664.0A 2018-10-18 2018-10-18 A kind of quick anaerobic fermentation biogas residue of stalk can make paper pulp Pending CN109505187A (en)

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CN201811213664.0A CN109505187A (en) 2018-10-18 2018-10-18 A kind of quick anaerobic fermentation biogas residue of stalk can make paper pulp

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110862145A (en) * 2019-12-03 2020-03-06 山东省农业科学院农业资源与环境研究所 Method for acidifying milk cow manure sewage by using cucurbit vegetable straws
CN112281530A (en) * 2020-09-22 2021-01-29 黑龙江进化树生物科技有限公司 Method for making paper by using straw biogas residues
CN116622781A (en) * 2023-06-13 2023-08-22 河北沼阳环境科技有限公司 Method for producing biogas and biological fiber slurry by anaerobic fermentation of crop straw

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1920168A (en) * 2006-09-18 2007-02-28 同济大学 Method of preparing pulp by anaerobic fermenting Spartina alterniflora and cooking soda, anthraquinone and fermented Spartina alterniflora
CN101659760A (en) * 2009-09-08 2010-03-03 东北农业大学 Biogas residue fiber mulch film and manufacturing method thereof
US20130071900A1 (en) * 2011-09-21 2013-03-21 Shell Oil Company Process for processing a lignocellulosic material
CN103757058A (en) * 2014-01-28 2014-04-30 福建农林大学 Method for preparing biogas through co-fermentation of energy grass and macroalgae
CN104605153A (en) * 2015-02-06 2015-05-13 福建农林大学 Method for comprehensive utilization of energy grass in fields of feeds, biogas and paper pulp
CN104690066A (en) * 2015-02-06 2015-06-10 福建农林大学 Comprehensive utilization method of energy grass
CN106636218A (en) * 2017-03-16 2017-05-10 福建农林大学 Method for preparing biogas and paper pulp from energy grass

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1920168A (en) * 2006-09-18 2007-02-28 同济大学 Method of preparing pulp by anaerobic fermenting Spartina alterniflora and cooking soda, anthraquinone and fermented Spartina alterniflora
CN101659760A (en) * 2009-09-08 2010-03-03 东北农业大学 Biogas residue fiber mulch film and manufacturing method thereof
US20130071900A1 (en) * 2011-09-21 2013-03-21 Shell Oil Company Process for processing a lignocellulosic material
CN103757058A (en) * 2014-01-28 2014-04-30 福建农林大学 Method for preparing biogas through co-fermentation of energy grass and macroalgae
CN104605153A (en) * 2015-02-06 2015-05-13 福建农林大学 Method for comprehensive utilization of energy grass in fields of feeds, biogas and paper pulp
CN104690066A (en) * 2015-02-06 2015-06-10 福建农林大学 Comprehensive utilization method of energy grass
CN106636218A (en) * 2017-03-16 2017-05-10 福建农林大学 Method for preparing biogas and paper pulp from energy grass

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110862145A (en) * 2019-12-03 2020-03-06 山东省农业科学院农业资源与环境研究所 Method for acidifying milk cow manure sewage by using cucurbit vegetable straws
CN112281530A (en) * 2020-09-22 2021-01-29 黑龙江进化树生物科技有限公司 Method for making paper by using straw biogas residues
CN116622781A (en) * 2023-06-13 2023-08-22 河北沼阳环境科技有限公司 Method for producing biogas and biological fiber slurry by anaerobic fermentation of crop straw

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Application publication date: 20190322