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CN109427812A - Semiconductor structure and its manufacturing method - Google Patents

Semiconductor structure and its manufacturing method Download PDF

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Publication number
CN109427812A
CN109427812A CN201710751228.8A CN201710751228A CN109427812A CN 109427812 A CN109427812 A CN 109427812A CN 201710751228 A CN201710751228 A CN 201710751228A CN 109427812 A CN109427812 A CN 109427812A
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CN
China
Prior art keywords
layer
conductive layer
hole
lamination
conductive
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Pending
Application number
CN201710751228.8A
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Chinese (zh)
Inventor
吴冠纬
刘注雍
张耀文
杨怡箴
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Macronix International Co Ltd
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Macronix International Co Ltd
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Priority to CN201710751228.8A priority Critical patent/CN109427812A/en
Publication of CN109427812A publication Critical patent/CN109427812A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B43/00EEPROM devices comprising charge-trapping gate insulators
    • H10B43/20EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels
    • H10B43/23EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels
    • H10B43/27EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels the channels comprising vertical portions, e.g. U-shaped channels
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B43/00EEPROM devices comprising charge-trapping gate insulators
    • H10B43/30EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region

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  • Non-Volatile Memory (AREA)

Abstract

A kind of semiconductor structure includes a substrate, a lamination, a hole and an active structure.Lamination is disposed on the substrate.Lamination is made of multiple conductive layers alternating with each other and multiple insulating layers.The conductive layer includes one i-th layer of conductive layer and the jth layer conductive layer that is arranged in above i-th layer of conductive layer, and i-th layer of conductive layer has thickness ti, jth layer conductive layer is with thickness tj, tjGreater than ti.Hole passes through lamination.Hole has the diameter D for respectively corresponding i-th layer of conductive layer and jth layer conductive layeriWith diameter Dj, DjGreater than Di.Active structure is arranged in hole.Active structure includes a channel layer.The channel layer is arranged along the one side wall of hole, and is isolated with the conductive layer of lamination.

Description

Semiconductor structure and its manufacturing method
Technical field
The present invention relates to a kind of semiconductor structure and its manufacturing methods.It include compensatory lamination the present invention is more particularly directed to one kind The semiconductor structure and its manufacturing method of structure.
Background technique
In order to reduce volume, reduce weight, increase power density and improve portability etc. reason, three-dimensional (3D) half Conductor structure is developed.In the typical process of some 3 D semiconductor structures, it can be formed and be stacked in including multiple layers On substrate, and one or more holes and/or channel are subsequently formed across lamination.Since technique limits, described hole and/or channel There may be inclined side wall, thus, along a vertical direction of hole and/or channel, size and area are gradually changed.This can The deviation on some equipment energy characteristics, the deviation especially on electric properties can further be caused.With the number in lamination middle layer Mesh increases, which may will become the problem of will affect device performance and operation.
Summary of the invention
The present invention be directed to the offer of compensatory laminated construction, which compensates for along the one vertical of hole and/or channel Influence caused by different sizes and area on direction.
According to some embodiments, a kind of semiconductor structure is provided.Such semiconductor structure includes a substrate, a lamination, one Hole and an active structure.Lamination is disposed on the substrate.Lamination is by multiple conductive layers and multiple insulating layer structures alternating with each other At.The conductive layer includes one i-th layer of conductive layer and the jth layer conductive layer that is arranged in above i-th layer of conductive layer, and i-th layer is led Electric layer has thickness ti, jth layer conductive layer is with thickness tj, tjGreater than ti.Hole passes through lamination.Hole, which has, respectively corresponds i-th The diameter D of layer conductive layer and jth layer conductive layeriWith diameter Dj, DjGreater than Di.Active structure is arranged in hole.Active structure packet Include a channel layer.The channel layer is arranged along the one side wall of hole, and is isolated with the conductive layer of lamination.
According to some embodiments, a kind of manufacturing method of semiconductor structure is provided.Such manufacturing method includes the following steps. Firstly, forming a lamination on a substrate.Lamination is made of multiple sacrificial layers alternating with each other and multiple insulating layers.The sacrifice Layer includes one i-th layer of sacrificial layer and the jth layer sacrificial layer being formed in above i-th layer of sacrificial layer, and i-th layer of sacrificial layer has thickness ti, jth layer sacrificial layer is with thickness tj, tjGreater than ti.A hole is formed across lamination.Hole, which has, respectively corresponds i-th layer of sacrifice The diameter D of layer and jth layer sacrificial layeriWith diameter Dj, DjGreater than Di.An active structure is formed in hole.Active structure includes one Channel layer.The channel layer is formed along the one side wall of hole, and is separated with the sacrificial layer of lamination.
More preferably understand to have to the above-mentioned and other aspect of the present invention, hereafter spy enumerates embodiment, and cooperates appended attached Detailed description are as follows for figure:
Detailed description of the invention
Fig. 1 shows according to the embodiment one illustrative semiconductor structure.
Fig. 2 shows another exemplary semiconductor's structures according to the embodiment.
Fig. 3 shows the influence of the diameter and passage length of hole on the one hand.
Fig. 4 A~4B shows the influence of the diameter of hole on the other hand.
Fig. 5 A~5H shows an illustrative manufacturing method of semiconductor structure according to the embodiment.
[symbol description]
100,200: semiconductor structure
102: substrate
104,204: lamination
106、106(0)、106(1)、106(2)、106(3)、...、106(i)、...、106(j)、...、106(n-2)、 106(n-1)、206(0)、206(1)、206(2)、206(3)、...、206(i)、...、206(j)、...、206(n-2)、206 (n-1): conductive layer
108: insulating layer
110: coating
112: hole
114: active structure
116: channel layer
118: accumulation layer
120: insulating materials
122: conducting element
304: lamination
306(0)、306(1)、306(2)、306(3)、...、306(i)、...、306(j)、...、306(n-2)、306(n- 1): sacrificial layer
352: ion implantation technology
354: opening
356: metal material
358: high dielectric constant material
360: ion implantation technology
362: conducting element
Ai、Aj: conductive area
Di、Dj: diameter
G(1)、G(2)、...、Group
L0、L1、L2、L3、...、Li、...、Lj、...、Ln-2、Ln-1、L’0、L’1、L’2、L’3、...、L’i、...、L ’j、...、L’n-2、L’n-1: passage length
t0、t1、t2、t3、...、ti、...、tj、...、tn-2、tn-1、t’0、t’1、t’2、t’3、...、t’i、...、t ’j、...、t’n-2、t’n-1: thickness
θ: angle
Specific embodiment
A variety of different embodiments are described in detail below in conjunction with appended attached drawing.Appended attached drawing is served only for Describe and explain purpose, rather than limitation purpose.For the sake of clarity, element may and be painted not according to actual ratio.This Outside, some elements and/or component symbol may be omitted from attached drawing.In the present invention, when describing an element in the singular, Also allow to include the case where the more than one element.It is contemplated that the element and feature in an embodiment, it can be advantageous Ground is included in another embodiment, without further elucidated above.
Fig. 1 is please referred to, according to the embodiment one illustrative semiconductor structure 100 is shown.Semiconductor structure 100 includes one Substrate 102, a lamination 104, a hole 112 and an active structure 114.Lamination 104 is arranged on substrate 102.Lamination 104 by Multiple conductive layers 106 (106 (0)~106 (n-1)) alternating with each other and multiple insulating layers 108 are constituted.Conductive layer 106 includes one I-th layer of conductive layer 106 (i) and the jth layer conductive layer 106 (j) being arranged above i-th layer of conductive layer 106 (i), i-th layer of conduction 106 (i) of layer have thickness ti, jth layer conductive layer 106 (j) is with thickness tj, tjGreater than ti.Hole 112 passes through lamination 104.Hole Hole 112 has the diameter D for respectively corresponding i-th layer of conductive layer 106 (i) He jth layer conductive layer 106 (j)iWith diameter Dj, DjIt is greater than Di.Active structure 114 is arranged in hole 112.Active structure 114 includes a channel layer 116.Channel layer 116 is along hole 112 One side wall setting, and be isolated with the conductive layer of lamination 104 106.
In some embodiments, on substrate 102, lamination is further arranged in a coating 110 to the setting of lamination 104 On 104, and hole 112 passes through coating 110 and lamination 104.In some embodiments, the side of substrate 102 and hole 112 Angle, θ between wall is less than 90 °, and e.g., about 87 °.Hole 112 can have the diameter become larger from the bottom up.In some realities It applies in example, the diameter of hole 112 is between 80 nanometers and 130 nanometers.For example, hole 112 can have 80 to receive in bottom The diameter of rice, and there is 130 nanometers of diameter on top.Accordingly, conductive layer 106 can have the thickness gradually to thicken from the bottom up Degree, details will be described in subsequent paragraph.In some embodiments, conductive layer 106 may include a metal material and a Gao Jie electricity Constant material.According to some embodiments, semiconductor structure 100 can be a memory construction.In such embodiments, active structure 114 can further include an accumulation layer 118.Accumulation layer 118 is arranged between channel layer 116 and lamination 104.Accumulation layer 118 may include One trapping layer (is not painted).More specifically, in some embodiments, accumulation layer 118 may include from the side wall of hole 112 sequentially A mask layer (not being painted), a trapping layer (not being painted) and the tunneling layer (not being painted) being arranged, and can be by monoxide-nitrogen Compound-oxide (ONO) lamination is formed.Multiple storage units are by between active structure 114 and the conductive layer 106 of lamination 104 Intersection point is defined, and the storage unit constitutes a part of a 3-dimensional memory cell array.In some embodiments, active structure 114 can further include an insulating materials 120.Insulating materials 120 is filled into the remaining space of hole 112.In some embodiments, One conducting element 122 may be provided on insulating materials 120.In some embodiments, the conductive layer 106 is multiple wordline, is had Source structure 114 is couple to a bit line by conducting element 122.
The configuration detail of conductive layer 106 will be described now.Specifically, conductive layer 106 can be one the 0th layer from the bottom up Conductive layer 106 (0) is to one (n-1)th layer of conductive layer 106 (n-1).0th layer of conductive layer 106 (0) is to (n-1)th layer of 106 (n- of conductive layer 1) it is respectively provided with thickness t0To tn-1, t0≤t1≤...≤tn-2≤tn-1.In addition, in addition, the 0th layer of conductive layer 106 (0) is to (n-1)th Layer conductive layer 106 (n-1) can provide passage length L respectively0To Ln-1, L0≤L1≤...≤Ln-2≤Ln-1.According to some implementations Example, passage length L0To Ln-1It is defined in a vertical direction, in full text of the invention, vertical direction means substantially perpendicular to base One direction of plate 102.To each passage length (L0To Ln-1) it is substantially equal to corresponding thickness (t0To tn-1).In some realities It applies in example, thickness t0To tn-1, it is inconjunction with passage length L0To Ln-1, between 20 nanometers and 60 nanometers.For example, thickness t0With passage length L0It can be 20 nanometers, and thickness tn-1With passage length Ln-1It can be 60 nanometers.
As long as being capable of providing compensation function, so that deviation is fallen within the acceptable range, thickness t0To tn-1, it is inconjunction with logical Road length L0To Ln-1, can configure in any suitable manner.In some embodiments, as shown in Figure 1, each conductive layer 106 It is thicker than the conductive layer 106 for being located at 106 lower section of each conductive layer.In other words, t0< t1< ... < tn-2< tn-1.Change speech It, L0< L1< ... < Ln-2< Ln-1
In further embodiments, conductive layer 106 divides for multiple groups, and the conductive layer 106 in each group has identical Thickness, and be thicker than the conductive layer 106 in the group below each group.In such embodiments, for 0 To at least integer an i, t among n-2i=ti+1.In other words, at least integer an i, L among 0 to n-2i=Li+1
Referring to figure 2., show this kind of embodiment one of special category.In this special category, conductive layer 106 are divided into multiple groups, the thickness having the same of conductive layer 106 in each group, and are thicker than positioned at each group Conductive layer 106 in the group of lower section.For example, conductive layer 106 can be divided intoA group, electricity are each group Including m conductive layer, t '0=t '1=...=t 'm-1< t 'm... < t 'n-m=...=t 'n-2=t 'n-1.In other words, conductive layer 106 can be divided intoA group, L '0=L '1=...=L 'm-1< ... < L 'n-m=...=L 'n-2=L 'n-1.In Fig. 2 institute In the semiconductor structure 200 shown, m 2.In other words, in lamination 204, conductive layer 206 (0) to 206 (n-1) is divided intoA group Group G (1) arrivesGroup G (1) is arrivedAmong each include two among conductive layer 206 (0) to 206 (n-1), t '0= t’1< t '2=t '3< ... < t 'n-2=t 'n-1, L '0=L '1< L '2=L '3< ... < L 'n-2=L 'n-1
According to the lamination of above-described embodiment, such as lamination 104 or 204, referred to as compensatory laminated construction in the present invention.? On the one hand, biggish hole diameter means lesser electric field, to have lower program/erase speed and more poor volume Journey/erasing ability.This is reflected in trend shown in Fig. 3.In contrast, biggish passage length causes biggish electric field, thus There are higher program/erase speed and preferable program/erase ability.Therefore, in semiconductor structure according to the embodiment, It influences, can be compensated by biggish passage length caused by program/erase operation of the biggish hole diameter for device, It is reached by thicker conductive layer.Thus, it is possible to provide preferable stability.
In addition, biggish hole diameter means that the conductive area of corresponding conductive layer is smaller, to reduce conductance (conductance).For example, as shown in Figure 4 A and 4 B shown in FIG., hole 1122 corresponds to conductive layer 106 (j) with biggish Diameter Dj.Therefore, the conductive area A of conductive layer 106 (j)jLess than the conductive area A of conductive layer 106 (i)i.This is unfavorable for being arranged Electric current in the conductive layer of higher position (higher position) passes through, as shown in Figure 4 A and 4 B shown in FIG..It for example, is word in conductive layer In the case where line, it may occur however that the attenuating (degradation) of word line resistance.However, such case can be by the thickness of conductive layer Degree is compensated.In other words, influence caused by conductance of the biggish hole diameter for conductive layer, can be by thicker conductive layer Thickness is compensated.
Referring now to Fig. 5 A~5H, an illustrative manufacturing method of semiconductor structure according to the embodiment is shown.Figure 5A~5H is painted by replacing the technique of sacrificial layer to form semiconductor structure as shown in Figure 1.However, other techniques can also be used In formation semiconductor structure according to the embodiment.For example, it can directly be formed by multiple conductive layers alternating with each other and more The lamination that a insulating layer is constituted, and not formed sacrificial layer.It is further possible to form other semiconductor junctions according to the embodiment Structure, such as semiconductor structure shown in Fig. 2.
As shown in Figure 5A, a substrate 102 is provided.Substrate 102 can be silicon substrate.It can carry out ion implantation technology.Form one Lamination 304 on substrate 102, e.g. by depositing operation, lamination 304 by multiple sacrificial layers alternating with each other (306 (0) to 306 (n-1)) and the composition of multiple insulating layers 108.Insulating layer 108 can be formed of oxide, thickness having the same.Sacrificial layer 306 (0) it can be formed to 306 (n-1) by nitride.Sacrificial layer 306 (0) includes one i-th layer of sacrificial layer 306 (i) and shape to 306 (n-1) At the jth layer sacrificial layer 306 (j) above i-th layer of sacrificial layer 306 (i), i-th layer of sacrificial layer 306 (i) has thickness ti, the J layers of sacrificial layer 306 (j) have thickness tj, tjGreater than ti.More specifically, sacrificial layer 306 (0) can be respectively provided with to 306 (n-1) Thickness t0To tn-1, t0≤t1≤...≤tn-2≤tn-1.In fig. 5, sacrificial layer 306 (0) is depicted as sacrificing to 306 (n-1) Each is thicker than the institute below each among the sacrificial layer 306 (0) to 306 (n-1) among layer 306 (0) to 306 (n-1) State sacrificial layer namely t0< t1< ... < tn-2< tn-1.However, in further embodiments, sacrificial layer 306 (0) to 306 (n- 1) there can be the thickness gradually changed in a manner of group.In such embodiments, at least integer an i, t among 0 to n-2i =ti+1.For example, sacrificial layer can be divided intoA group namely each group include m sacrificial layer, t0=t1=... =tm-1< tm... < tn-m=...=tn-2=tn-1.In some embodiments, thickness t0To tn-1Between 20 nanometers and 60 nanometers Between.For example, thickness t0It can be 20 nanometers, and thickness tn-1It can be 60 nanometers.In some embodiments, one can be formed to cover Cap rock 110 is on lamination 304.Coating 110 can be formed of oxide.
As shown in Figure 5 B, it forms a hole 112 and forms a lamination 304, e.g. pass through etch process.For example, hole Hole 112 can have to be about the one side wall of 87 ° of angle tilt.Hole 112 have respectively correspond i-th layer of sacrificial layer 306 (i) and The diameter D of jth layer sacrificial layer 306 (j)iWith diameter Dj, DjGreater than Di.In some embodiments, the diameter of hole 112 is between 80 Between nanometer and 130 nanometers.For example, hole 112 can have 80 nanometers of diameter in bottom, and have 130 to receive on top The diameter of rice.
As shown in Figure 5 C, an active structure 114 is formed in hole 112.Active structure 114 includes a channel layer 116.It is logical Channel layer 116 is formed along the side wall of hole 112, and is separated with the sacrificial layer of lamination 304 306 (0) to 306 (n-1).Channel Layer 116 can be isolated by any suitable insulating materials with lamination 304.In some embodiments, an accumulation layer 118 provide every From function.Accumulation layer 118 may include a trapping layer (not being painted).It also specifically says, in some embodiments, accumulation layer 118 can Including be set in sequence from the side wall of hole 112 a mask layer (not being painted), a trapping layer (not being painted a) and tunneling layer is (not It is painted), and can be formed by monoxide-Nitride Oxide (ONO) lamination.According to some embodiments, active structure 114 Formation can be by being initially formed an ONO lamination (that is, accumulation layer 118) on the side wall of hole 112.Then, a polycrystalline is formed Silicon layer thereon, as channel layer 116.A fillable insulating materials 120, such as oxide, to the remaining space of hole 112 In.Therefore, an all around gate (gate-all-around) structure is just formed.In some embodiments, one can further be formed Conducting element 122 is on insulating materials 120.Then, as shown in Figure 5 D, ion implantation technology 352 can be carried out, to provide for position The connection of line.Dopant can be arsenic.
Then, replace sacrificial layer 306 (0) to 306 (n-1) with multiple conductive layers 106.As shown in fig. 5e, an opening is formed 354 pass through lamination 304, e.g. pass through etch process.As illustrated in figure 5f, sacrificial layer 306 (0) is removed to 306 by opening 354 (n-1), e.g. pass through etch process.Then, conductive layer 106 is formed.According to some embodiments, conductive layer 106 may include one Metal material 356 and a high dielectric constant material 358.As depicted in fig. 5g, in some embodiments, high dielectric constant material can be formed The upper side and lower side and circular active structure 114 of material 358 in insulating layer 108.High dielectric constant material 358 can be Al2O3.Then, Metal material 356 is filled into the remainder for removing space caused by sacrificial layer 306 (0) to 306 (n-1).Metal material 356 can be tungsten.In some embodiments, to provide wordline.
In some embodiments, opening 354 provides the source region for being used for semiconductor structure, and can carry out an ion implanting Technique 360, to form source area.Dopant can be arsenic.Then, as illustrated in fig. 5h, be capable of forming a conducting element 362 (namely Source conductive element) in opening 354.
Particular embodiments described above has carried out further in detail the purpose of the present invention, technical scheme and beneficial effects Describe in detail bright, it should be understood that the above is only a specific embodiment of the present invention, is not intended to restrict the invention, it is all Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in protection of the invention Within the scope of.

Claims (10)

1. a kind of semiconductor structure, comprising:
One substrate;
One lamination, on the substrate, which is made of multiple conductive layers alternating with each other and multiple insulating layers, described to lead for setting Electric layer includes one i-th layer of conductive layer and the jth layer conductive layer that is arranged in above i-th layer of conductive layer, i-th layer of conductive layer tool There is thickness ti, the jth layer conductive layer is with thickness tj, tjGreater than ti
One hole, passes through the lamination, which has the diameter D for respectively corresponding i-th layer of conductive layer and the jth layer conductive layeriWith Diameter Dj, DjGreater than Di;And
One active structure is arranged in the hole, which includes:
One channel layer is arranged along the one side wall of the hole, and is isolated with the conductive layer of the lamination.
2. semiconductor structure as described in claim 1, wherein the hole has the diameter become larger from the bottom up, described to lead Electric layer has the thickness gradually to thicken from the bottom up.
3. semiconductor structure as claimed in claim 2, wherein respectively the conductive layer is thicker than below described respectively conductive layer The conductive layer.
4. semiconductor structure as claimed in claim 2, wherein the conductive layer is divided into multiple groups, it is respectively described in the group Conductive layer thickness having the same, and it is thicker than the conductive layer in the group below described respectively group.
5. semiconductor structure as claimed in claim 2, wherein the conductive layer is divided into multiple groups, each institute in the group Conductive layer thickness having the same is stated, and is thicker than the conductive layer in the group below described respectively group.
6. semiconductor structure as described in claim 1, wherein one the 0th layer of conductive layer of the conductive layer from the bottom up is to one N-1 layers of conductive layer, the 0th layer of conductive layer provide passage length L to (n-1)th layer of conductive layer respectively0To Ln-1, L0≤L1≤…≤ Ln-2≤Ln-1
7. semiconductor structure as claimed in claim 6, wherein L0< L1< ... < Ln-2< Ln-1
8. semiconductor structure as claimed in claim 6, wherein at least integer an i, L among 0 to n-2i=Li+1
9. semiconductor structure as claimed in claim 6, wherein the conductive layer is divided intoA group, L0=L1=...= Lm-1< ... < Ln-m=...=Ln-2=Ln-1
10. a kind of manufacturing method of semiconductor structure, comprising:
Form a lamination on a substrate, which is made of multiple sacrificial layers alternating with each other and multiple insulating layers, described sacrificial Domestic animal layer includes one i-th layer of sacrificial layer and the jth layer sacrificial layer being formed in above i-th layer of sacrificial layer, i-th layer of sacrificial layer tool There is thickness ti, the jth layer sacrificial layer is with thickness tj, tjGreater than ti
A hole is formed across the lamination, which has the diameter for respectively corresponding i-th layer of sacrificial layer and the jth layer sacrificial layer DiWith diameter Dj, DjGreater than Di;And
An active structure is formed in the hole, which includes:
One channel layer is formed along the one side wall of the hole, and is separated with the sacrificial layer of the lamination.
CN201710751228.8A 2017-08-28 2017-08-28 Semiconductor structure and its manufacturing method Pending CN109427812A (en)

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CN110265404A (en) * 2019-06-28 2019-09-20 长江存储科技有限责任公司 For the laminated construction of three-dimensional storage, three-dimensional storage and preparation method thereof
CN110289259A (en) * 2019-06-27 2019-09-27 长江存储科技有限责任公司 3D memory device and its manufacturing method
CN110349971A (en) * 2019-06-28 2019-10-18 长江存储科技有限责任公司 For the laminated construction of three-dimensional storage, three-dimensional storage and preparation method thereof

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CN110265404A (en) * 2019-06-28 2019-09-20 长江存储科技有限责任公司 For the laminated construction of three-dimensional storage, three-dimensional storage and preparation method thereof
CN110349971A (en) * 2019-06-28 2019-10-18 长江存储科技有限责任公司 For the laminated construction of three-dimensional storage, three-dimensional storage and preparation method thereof
CN110265404B (en) * 2019-06-28 2020-10-23 长江存储科技有限责任公司 Laminated structure for three-dimensional memory, three-dimensional memory and preparation method thereof

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Application publication date: 20190305