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CN109349707A - 一种导电手套革及其生产方法 - Google Patents

一种导电手套革及其生产方法 Download PDF

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CN109349707A
CN109349707A CN201811487270.4A CN201811487270A CN109349707A CN 109349707 A CN109349707 A CN 109349707A CN 201811487270 A CN201811487270 A CN 201811487270A CN 109349707 A CN109349707 A CN 109349707A
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吴平
吴月红
吴玉华
张凤
陈利安
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Kunshan Fu Xin New Material Ltd By Share Ltd
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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00Gloves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
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    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
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    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/145Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/202Conductive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51Elastic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00Clothing
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    • D06N2209/04Properties of the materials having electrical or magnetic properties
    • D06N2209/041Conductive
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
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    • D06N2211/12Decorative or sun protection articles
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  • Textile Engineering (AREA)
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  • Dispersion Chemistry (AREA)
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Abstract

本发明公开了一种导电手套革及其生产方法,其特征在于,包括导电面层,所述导电面层的下侧固定贴合有导电粘合层,所述导电粘合层的下侧固定贴合有发泡层,所述发泡层的下侧固定贴合有底布。生产方法一次通过湿法混合配料;湿法贝斯生产;干法混合配料;选好合适的离型纸花纹;干法制作工艺进行生产。优点:通过本发明的方法制成的手套革具有导电功能,手感柔软,弹性好,能够满足人们对高品质的产品的需求。

Description

一种导电手套革及其生产方法
技术领域
本发明涉及一种导电手套革及其生产方法,属于合成革技术领域。
背景技术
目前,合成革产品逐渐成为未来流行的趋势,合成革已广泛用于生产箱包、服装、鞋类等产品。现在人们对皮革的美观程度越来越关注,为了使合成革能够满足人们对革面美感的需求,会对皮革进行压花、喷涂料等处理,使合成革的表面花型饱满、高亮、透感。现有技术中,合成革主要是由基布层、湿法贝斯层、干法贴面层构成,合成革的压花、喷涂料处理中存在很多技术困难,加工出来的成品表面易出现亮度低、立体感差等缺陷,不能满足人们对高品质的需求。
发明内容
本发明所要解决的技术问题是克服现有技术的缺陷,提供一种导电手套革及其生产方法,具有导电功能,手感柔软,弹性好。
为解决上述技术问题,本发明提供一种导电手套革,包括导电面层,所述导电面层的下侧固定贴合有导电粘合层,所述导电粘合层的下侧固定贴合有发泡层,所述发泡层的下侧固定贴合有底布。
进一步的,所述导电面层采用带有导电功能的干法面层。采用干法导电面层主要的优点是赋予皮革表面有优秀的耐水解和抗刮性。
进一步的,所述导电粘合层采用带有导电功能的干法粘合层。采用干法导电粘合层的优点是能够使面层跟湿法发泡层有更强的粘合性和导电性。
进一步的,所述发泡层采用湿法发泡层。湿法发泡层的主要优点是赋予皮革具有肉感、弹性和花纹饱满。
进一步的,所述底布采用弹力底布。采用弹力底布能够使手套革有很好的弹性和延展性。
进一步的,所述导电面层厚度为0.02-0.05㎜、导电粘合层厚度为0.02-0.05㎜、发泡层厚度为0.20-0.40㎜,底布厚度为0.30-0.50㎜。
一种导电手套革的生产方法,包括如下步骤:
(1)湿法混合配料:
a、将5-10kg二甲基甲酰胺加0.5-2kg色浆高速搅拌60-90分钟,过滤待用,记为a料;
b、将40-100kg二甲基甲酰胺加20-30kg木粉搅拌30分钟,静置20-45分钟后与a料搅拌均匀待用,记为b料;
c、聚氨酯湿法树脂100kg分别加入a料、b料搅拌20-40分钟后脱泡并过滤密封待用,记为c料;
(2)湿法贝斯生产:在准备好的弹力底布上面涂刮c料,调整好张力,在18-30%的二甲基甲酰胺水溶液中凝固并进行水洗、烘干后得到一种湿法贝斯,车速控制在10-20m/min;
(3)干法混合配料:
3.1):将聚氨酯面层树脂、二甲基甲酰胺、助剂、有导电功能的色浆混合后高速搅拌均匀,搅拌时间15-20分钟,制得干法面料,过滤密封待用;
3.2):将聚氨酯粘合层树脂、二甲基甲酰胺、助剂、有导电功能的色浆高速搅拌均匀,搅拌时间15-20分钟,制得粘合料,过滤密封待用;
(4):选好合适的离型纸花纹;
(5):干法制作工艺:
5.1):在选好的离型纸上面均匀涂覆所述干法面料进行烘干,干燥温度为120-130℃左右,在制得的面层干膜上面均匀涂覆配制好的所述粘合料,在半干情况下贴上预备好的湿法贝斯,干燥温度为130-140℃,烘干、冷却后与离型纸分离;
5.2):生产线速为10~20米/分钟。
本发明所达到的有益效果:
通过本发明的方法制成的手套革具有导电功能,手感柔软,弹性好,能够满足人们对高品质的产品的需求;而且,制备方法简单,节省时间,能够大大的提高生产效率。
附图说明
图1是本发明的导电手套革结构示意图。
具体实施方式
下面结合附图对本发明作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案,而不能以此来限制本发明的保护范围。
如图1所示,一种导电手套革,包括导电面层1,所述导电面层1的下侧固定贴合有导电粘合层2,所述导电粘合层2的下侧固定贴合有发泡层3,所述发泡层3的下侧固定贴合有底布4。
本实施例中,所述导电面层1采用带有导电功能的干法面层。采用干法导电面层主要的优点是赋予皮革表面有优秀的耐水解和抗刮性。
本实施例中,所述导电粘合层2采用带有导电功能的干法粘合层。采用干法导电粘合层的优点是能够使面层跟湿法发泡层有更强的粘合性和导电性。
本实施例中,所述发泡层3采用湿法发泡层。湿法发泡层的主要优点是赋予皮革具有肉感、弹性和花纹饱满。
本实施例中,所述底布4采用弹力底布。采用弹力底布能够使手套革有很好的弹性和延展性。
本实施例中,所述导电面层厚度为0.02-0.05㎜、导电粘合层厚度为0.02-0.05㎜、发泡层厚度为0.20-0.40㎜,底布厚度为0.30-0.50㎜。
实施例1,一种导电手套革的生产方法,包括如下步骤:
(1)湿法混合配料:
a、将5kg二甲基甲酰胺加0.5kg色浆高速搅拌60分钟,过滤待用,记为a料;
b、将40kg二甲基甲酰胺加20kg木粉搅拌30分钟,静置20分钟后与a料搅拌均匀待用,记为b料;
c、聚氨酯湿法树脂100kg分别加入a料、b料搅拌20分钟后脱泡并过滤密封待用,记为c料;
(2)湿法贝斯生产:在准备好的弹力底布上面涂刮c料,调整好张力,在18-30%的二甲基甲酰胺水溶液中凝固并进行水洗、烘干后得到一种湿法贝斯,车速控制在10m/min;
(3)干法混合配料:
3.1):将聚氨酯面层树脂、二甲基甲酰胺、助剂、有导电功能的色浆混合后高速搅拌均匀,搅拌时间15分钟,制得干法面料,过滤密封待用;
3.2):将聚氨酯粘合层树脂、二甲基甲酰胺、助剂、有导电功能的色浆高速搅拌均匀,搅拌时间15分钟,制得粘合料,过滤密封待用;
(4):选好合适的离型纸花纹;
(5):干法制作工艺:
5.1):在选好的离型纸上面均匀涂覆所述干法面料进行烘干,干燥温度为120℃左右,在制得的面层干膜上面均匀涂覆配制好的所述粘合料,在半干情况下贴上预备好的湿法贝斯,干燥温度为130℃,烘干、冷却后与离型纸分离;
5.2):生产线速为10米/分钟。
实施例2,一种导电手套革的生产方法,包括如下步骤:
(1)湿法混合配料:
a、将8kg二甲基甲酰胺加1kg色浆高速搅拌75分钟,过滤待用,记为a料;
b、将80kg二甲基甲酰胺加25kg木粉搅拌30分钟,静置30分钟后与a料搅拌均匀待用,记为b料;
c、聚氨酯湿法树脂100kg分别加入a料、b料搅拌30分钟后脱泡并过滤密封待用,记为c料;
(2)湿法贝斯生产:在准备好的弹力底布上面涂刮c料,调整好张力,在25%的二甲基甲酰胺水溶液中凝固并进行水洗、烘干后得到一种湿法贝斯,车速控制在15m/min;
(3)干法混合配料:
3.1):将聚氨酯面层树脂、二甲基甲酰胺、助剂、有导电功能的色浆混合后高速搅拌均匀,搅拌时间18分钟,制得干法面料,过滤密封待用;
3.2):将聚氨酯粘合层树脂、二甲基甲酰胺、助剂、有导电功能的色浆高速搅拌均匀,搅拌时间18分钟,制得粘合料,过滤密封待用;
(4):选好合适的离型纸花纹;
(5):干法制作工艺:
5.1):在选好的离型纸上面均匀涂覆所述干法面料进行烘干,干燥温度为125℃左右,在制得的面层干膜上面均匀涂覆配制好的所述粘合料,在半干情况下贴上预备好的湿法贝斯,干燥温度为135℃,烘干、冷却后与离型纸分离;
5.2):生产线速为15米/分钟。
实施例3,一种导电手套革的生产方法,包括如下步骤:
(1)湿法混合配料:
a、将10kg二甲基甲酰胺加2kg色浆高速搅拌90分钟,过滤待用,记为a料;
b、将100kg二甲基甲酰胺加30kg木粉搅拌30分钟,静置45分钟后与a料搅拌均匀待用,记为b料;
c、聚氨酯湿法树脂100kg分别加入a料、b料搅拌40分钟后脱泡并过滤密封待用,记为c料;
(2)湿法贝斯生产:在准备好的弹力底布上面涂刮c料,调整好张力,在18-30%的二甲基甲酰胺水溶液中凝固并进行水洗、烘干后得到一种湿法贝斯,车速控制在20m/min;
(3)干法混合配料:
3.1):将聚氨酯面层树脂、二甲基甲酰胺、助剂、有导电功能的色浆混合后高速搅拌均匀,搅拌时间20分钟,制得干法面料,过滤密封待用;
3.2):将聚氨酯粘合层树脂、二甲基甲酰胺、助剂、有导电功能的色浆高速搅拌均匀,搅拌时间20分钟,制得粘合料,过滤密封待用;
(4):选好合适的离型纸花纹;
(5):干法制作工艺:
5.1):在选好的离型纸上面均匀涂覆所述干法面料进行烘干,干燥温度为130℃左右,在制得的面层干膜上面均匀涂覆配制好的所述粘合料,在半干情况下贴上预备好的湿法贝斯,干燥温度为140℃,烘干、冷却后与离型纸分离;
5.2):生产线速为20米/分钟。
以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明技术原理的前提下,还可以做出若干改进和变形,这些改进和变形也应视为本发明的保护范围。

Claims (7)

1.一种导电手套革,其特征在于,包括导电面层,所述导电面层的下侧固定贴合有导电粘合层,所述导电粘合层的下侧固定贴合有发泡层,所述发泡层的下侧固定贴合有底布。
2.根据权利要求1所述的导电手套革,其特征在于,所述导电面层采用带有导电功能的干法面层。
3.根据权利要求1所述的导电手套革,其特征在于,所述导电粘合层采用带有导电功能的干法粘合层。
4.根据权利要求1所述的导电手套革,其特征在于,所述发泡层采用湿法发泡层。
5.根据权利要求1所述的导电手套革,其特征在于,所述底布采用弹力底布。
6.根据权利要求1所述的导电手套革,其特征在于,所述导电面层厚度为0.02-0.05㎜、导电粘合层厚度为0.02-0.05㎜、发泡层厚度为0.20-0.40㎜,底布厚度为0.30-0.50㎜。
7.一种导电手套革的生产方法,其特征在于,包括如下步骤:
(1)湿法混合配料:
a、将5-10kg二甲基甲酰胺加0.5-2kg色浆高速搅拌60-90分钟,过滤待用,记为a料;
b、将40-100kg二甲基甲酰胺加20-30kg木粉搅拌30分钟,静置20-45分钟后与a料搅拌均匀待用,记为b料;
c、聚氨酯湿法树脂100kg分别加入a料、b料搅拌20-40分钟后脱泡并过滤密封待用,记为c料;
(2)湿法贝斯生产:在准备好的弹力底布上面涂刮c料,调整好张力,在18-30%的二甲基甲酰胺水溶液中凝固并进行水洗、烘干后得到一种湿法贝斯,车速控制在10-20m/min;
(3)干法混合配料:
3.1):将聚氨酯面层树脂、二甲基甲酰胺、助剂、有导电功能的色浆混合后高速搅拌均匀,搅拌时间15-20分钟,制得干法面料,过滤密封待用;
3.2):将聚氨酯粘合层树脂、二甲基甲酰胺、助剂、有导电功能的色浆高速搅拌均匀,搅拌时间15-20分钟,制得粘合料,过滤密封待用;
(4):选好合适的离型纸花纹;
(5):干法制作工艺:
5.1):在选好的离型纸上面均匀涂覆所述干法面料进行烘干,干燥温度为120-130℃左右,在制得的面层干膜上面均匀涂覆配制好的所述粘合料,在半干情况下贴上预备好的湿法贝斯,干燥温度为130-140℃,烘干、冷却后与离型纸分离;
5.2):生产线速为10~20米/分钟。
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