CN109266270A - Adhesive, preparation method and application - Google Patents
Adhesive, preparation method and application Download PDFInfo
- Publication number
- CN109266270A CN109266270A CN201710581898.XA CN201710581898A CN109266270A CN 109266270 A CN109266270 A CN 109266270A CN 201710581898 A CN201710581898 A CN 201710581898A CN 109266270 A CN109266270 A CN 109266270A
- Authority
- CN
- China
- Prior art keywords
- parts
- rubber
- adhesive
- acryloxypropyl
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 47
- 239000000853 adhesive Substances 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 58
- 229920001971 elastomer Polymers 0.000 claims abstract description 57
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 39
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 21
- 239000006229 carbon black Substances 0.000 claims abstract description 21
- DGXAGETVRDOQFP-UHFFFAOYSA-N 2,6-dihydroxybenzaldehyde Chemical compound OC1=CC=CC(O)=C1C=O DGXAGETVRDOQFP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- -1 (methyl) acryloyloxypropyl Chemical group 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims description 24
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 20
- 229910000077 silane Inorganic materials 0.000 claims description 19
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 238000004073 vulcanization Methods 0.000 claims description 8
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 claims description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 7
- 239000002131 composite material Substances 0.000 claims description 7
- URDOJQUSEUXVRP-UHFFFAOYSA-N 3-triethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C(C)=C URDOJQUSEUXVRP-UHFFFAOYSA-N 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 238000004026 adhesive bonding Methods 0.000 claims description 4
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 4
- RMKZLFMHXZAGTM-UHFFFAOYSA-N [dimethoxy(propyl)silyl]oxymethyl prop-2-enoate Chemical compound CCC[Si](OC)(OC)OCOC(=O)C=C RMKZLFMHXZAGTM-UHFFFAOYSA-N 0.000 claims description 3
- XDQWJFXZTAWJST-UHFFFAOYSA-N 3-triethoxysilylpropyl prop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C=C XDQWJFXZTAWJST-UHFFFAOYSA-N 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- OZWKZRFXJPGDFM-UHFFFAOYSA-N tripropoxysilane Chemical compound CCCO[SiH](OCCC)OCCC OZWKZRFXJPGDFM-UHFFFAOYSA-N 0.000 claims 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract description 6
- 230000002035 prolonged effect Effects 0.000 abstract 1
- RNFHYRYYUYDKTR-UHFFFAOYSA-N pyridine;styrene Chemical compound C1=CC=NC=C1.C=CC1=CC=CC=C1 RNFHYRYYUYDKTR-UHFFFAOYSA-N 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000032683 aging Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000013007 heat curing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- JZYAVTAENNQGJB-UHFFFAOYSA-N 3-tripropoxysilylpropyl 2-methylprop-2-enoate Chemical compound CCCO[Si](OCCC)(OCCC)CCCOC(=O)C(C)=C JZYAVTAENNQGJB-UHFFFAOYSA-N 0.000 description 1
- HGEKXQRHZRDGKO-UHFFFAOYSA-N 3-tripropoxysilylpropyl prop-2-enoate Chemical compound CCCO[Si](OCCC)(OCCC)CCCOC(=O)C=C HGEKXQRHZRDGKO-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 229920006247 high-performance elastomer Polymers 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/06—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/50—Additional features of adhesives in the form of films or foils characterized by process specific features
- C09J2301/504—Additional features of adhesives in the form of films or foils characterized by process specific features process of pretreatment for improving adhesion of rubber on metallic surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides an adhesive, a preparation method and application thereof. The adhesive comprises the following components in parts by weight: 20-30 parts of carboxylated nitrile rubber; 20-30 parts of butadiene styrene-pyridine rubber; 80-100 parts of resorcinol-formaldehyde resin; 150-400 parts of toluene; 2-4 parts of (methyl) acryloyloxypropyl trialkoxysilane; 2-4 parts of glycidoxypropyltrialkoxysilane; 1-4 parts of carbon black; 10-30 parts of nano aluminum oxide. The adhesive disclosed by the invention has good thermal conductivity and heat resistance, so that the service life of rubber can be effectively prolonged.
Description
Technical field
The present invention relates to a kind of adhesives, and in particular to a kind of adhesive and preparation method and application.
Background technique
With the rapid development of rubber industry, rubber composite material is widely used.Rubber composite material is in rubber
It is compounded with a variety of different framework materials in gum base materials and increases material, to meet certain purposes or service performance.It obtains
High performance rubber composite material, other than selecting suitable framework material, the quality of adhesive be also rubber composite material at
The key of function.Adhesive for use product under severe conditions when remain that framework material is integrated with rubber, thus
The effect for preferably playing framework material extends the service life of rubber product to improve the quality of rubber product.
With rubber composite product type increase and the expansion of application field, the requirement to adhering technique are more and more severe
It carves.Currently, the bonding of rubber and metal relies primarily on heat cure adhesive, a variety of rubber and various metals can be suitable for
Bonding.However, rubber is by alternate stress effect and outside after using conventional heat cure adhesive bonding rubber and metal
When portion's high temperature action, the heat inside rubber can not transmit heat dissipation in time, to can accelerate the aging of rubber, for high temperature item
The stator rubber used under part is especially prominent.Therefore, expect a kind of adhesive with thermal conductive resin and heat resistance.
Summary of the invention
The present invention provides a kind of adhesive and preparation method and application, which has good thermal conductivity and heat-resisting
Property, so as to effectively improve the service life of rubber.
The present invention provides a kind of adhesive, the component including following parts by weight:
20-30 parts of carboxylated nitrile rubber；
20-30 parts of butadiene-styrene-vinyl pyridine rubber；
80-100 parts of resorcinol-formaldehyde resin；
150-400 parts of toluene；
2-4 parts of (methyl) acryloxypropyl trialkoxy silane；
2-4 parts of glycidol the third oxygen propyl group trialkoxy silane；
1-4 parts of carbon black；
10-30 parts of nano aluminium oxide.
In the present invention, carboxylated nitrile rubber (i.e. carboxy nitrile rubber, abbreviation XNBR) is that by butadiene, acrylonitrile and have
Machine acid (such as acrylic acid) ternary polymerization forms；The introducing of carboxyl increases the polarity of rubber, increases between phenolic resin
Compatibility, and make rubber that there is high-intensitive and good cementability and resistance to ag(e)ing, improve wearability, the tearing of rubber
Intensity and oil resistivity.In concrete scheme of the invention, the mass content of acrylonitrile can be 30- in the carboxylated nitrile rubber
40%, Mooney viscosity can be 40-75.
In the present invention, butadiene-styrene-vinyl pyridine rubber is the terpolymer of vinylpyridine, butadiene and styrene, pyridine groups
Introducing increase the polarity of rubber, be conducive to improve metal and the direct adhesive force of rubber；In concrete scheme of the invention
In, the mass content of styrene can be 18-20% in the butadiene-styrene-vinyl pyridine rubber, and the mass content of vinylpyridine can be
13-15%, Mooney viscosity can be 40-75.
In concrete scheme of the invention, the softening point of the resorcinol-formaldehyde resin can be 80-110 DEG C；Have
The resorcinol-formaldehyde resin of the softening point range can increase the adhesive property of adhesive.
In concrete scheme of the invention, (methyl) the acryloxypropyl trialkoxy silane is selected from acryloyl-oxy third
Base trimethoxy silane, acryloxypropyl triethoxysilane, acryloxypropyl tripropoxy silane, methacryloxypropyl
In propyl trimethoxy silicane, methacryloxypropyl triethoxysilane and methacryloxypropyl tripropoxy silane
At least one.Above-mentioned specific (methyl) acryloxypropyl trialkoxy silane can significantly increase rubber and glue to substrate
Knot property.
Further, the partial size of the nano aluminium oxide can be 20-80nm, and specific surface area can be 20-200m2/g。
Above-mentioned specific nano aluminium oxide is added in adhesive, can make rubber that there is thermal conduction characteristic, while can be improved rubber
Heat resistance.
The present invention also provides the preparation methods of above-mentioned adhesive, include the following steps:
1) by 20-30 parts of carboxylated nitrile rubber, 20-30 parts of butadiene-styrene-vinyl pyridine rubber, 80-100 parts of resorcinol-formaldehyde resin and
150-400 parts of toluene are uniformly mixed, and obtain the first mixture；
2) by 2-4 parts of (methyl) acryloxypropyl trialkoxy silane, glycidol the third oxygen propyl group trialkoxy silane
2-4 parts, 1-4 parts of carbon black and 10-30 parts of nano aluminium oxide are uniformly mixed, and obtain the second mixture；
3) first mixture and second mixture are uniformly mixed, obtain described adhesive.
The present invention also provides application of the above-mentioned adhesive on metal and rubber adhesion.
The present invention also provides a kind of adhesive bonding methods, include the following steps:
On metal base by the coating of any of the above-described described adhesive, the first vulcanization is then carried out, on metal base shape
At coating；
Rubber is placed on the coating, the second vulcanization is then carried out, rubber composite material is made.
Further, the temperature of first vulcanization is 150-160 DEG C, time 5-10min；The temperature of second vulcanization
Degree is 150-160 DEG C, time 20-30min.
Implementation of the invention, at least has the advantage that
1, the thermal coefficient of adhesive of the invention is 0.85-1.15W/mK, and the resistance to boiling water time is 640-720h,
Bonding metal can in time pass out the heat inside rubber with when rubber, it is therefore prevented that rubber aging at high temperature, from
And effectively improve the service life of rubber.
2, the adhesion strength of adhesive of the invention is 0.72-0.95MPa, can ensure that rubber and metal are not easy to take off
From.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with the embodiment of the present invention, to this
Technical solution in inventive embodiments is clearly and completely described, it is clear that described embodiment is that a part of the invention is real
Example is applied, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making creation
Property labour under the premise of every other embodiment obtained, shall fall within the protection scope of the present invention.
Embodiment 1
The adhesive of the present embodiment is grouped as by the group of following parts by weight:
20 parts of carboxylated nitrile rubber；
20 parts of butadiene-styrene-vinyl pyridine rubber；
80 parts of resorcinol-formaldehyde resin；
150 parts of toluene；
2 parts of acryloxypropyl trimethoxy silane；
2 parts of trialkoxy silane of the third oxygen propyl group of glycidol；
1 part of carbon black；
10 parts of nano aluminium oxide；
Wherein, the mass content of acrylonitrile is 30% in carboxylated nitrile rubber, Mooney viscosity 40；Benzene in butadiene-styrene-vinyl pyridine rubber
The mass content of ethylene is 18%, and the mass content of vinylpyridine is 13%, Mooney viscosity 40；Resorcinol-formaldehyde tree
The softening point of rouge is 80 DEG C；Nano aluminium oxide is White crystal powder, partial size 20nm, specific surface area 200m2/g；Carbon black is
High-carbon black pigment.
The step of preparing above-mentioned adhesive are as follows:
1) by 20 parts of carboxylated nitrile rubber, 20 parts of butadiene-styrene-vinyl pyridine rubber, 80 parts of resorcinol-formaldehyde resin and 150 parts of toluene
It is uniformly mixed, obtains the first mixture；
2) by 2 parts of acryloxypropyl trimethoxy silane, 2 parts of the third oxygen propyl group of glycidol trialkoxy silane, carbon black 1
Part is uniformly mixed with 10 parts of nano aluminium oxide, obtains the second mixture；
3) above-mentioned first mixture and the second mixture are mixed, stirs evenly at room temperature, above-mentioned adhesive is made.
Embodiment 2
The adhesive of the present embodiment is grouped as by the group of following parts by weight:
30 parts of carboxylated nitrile rubber；
30 parts of butadiene-styrene-vinyl pyridine rubber；
100 parts of resorcinol-formaldehyde resin；
400 parts of toluene；
4 parts of methacryloxypropyl triethoxysilane；
4 parts of trialkoxy silane of the third oxygen propyl group of glycidol；
4 parts of carbon black；
30 parts of nano aluminium oxide；
Wherein, the mass content of acrylonitrile is 40% in carboxylated nitrile rubber, Mooney viscosity 75；Benzene in butadiene-styrene-vinyl pyridine rubber
The mass content of ethylene is 20%, and the mass content of vinylpyridine is 15%, Mooney viscosity 75；Resorcinol-formaldehyde tree
The softening point of rouge is 110 DEG C；Nano aluminium oxide is White crystal powder, partial size 80nm, specific surface area 20m2/g；Carbon black is
High-carbon black pigment.
The step of preparing above-mentioned adhesive are as follows:
1) by 30 parts of carboxylated nitrile rubber, 30 parts of butadiene-styrene-vinyl pyridine rubber, 100 parts of resorcinol-formaldehyde resin and 400 parts of toluene
It is uniformly mixed, obtains the first mixture；
2) by 4 parts of methacryloxypropyl triethoxysilane, 4 parts of the third oxygen propyl group of glycidol trialkoxy silane,
4 parts and 30 parts of nano aluminium oxide of carbon black are uniformly mixed, and obtain the second mixture；
3) above-mentioned first mixture and the second mixture are mixed, stirs evenly at room temperature, above-mentioned adhesive is made.
Embodiment 3
The adhesive of the present embodiment is grouped as by the group of following parts by weight:
25 parts of carboxylated nitrile rubber；
25 parts of butadiene-styrene-vinyl pyridine rubber；
90 parts of resorcinol-formaldehyde resin；
300 parts of toluene；
3 parts of methyl allyl acyloxypropyl trimethoxysilane；
3 parts of trialkoxy silane of the third oxygen propyl group of glycidol；
3 parts of carbon black；
20 parts of nano aluminium oxide；
Wherein, the mass content of acrylonitrile is 35% in carboxylated nitrile rubber, Mooney viscosity 60；Benzene in butadiene-styrene-vinyl pyridine rubber
The mass content of ethylene is 19%, and the mass content of vinylpyridine is 14%, Mooney viscosity 60；Resorcinol-formaldehyde tree
The softening point of rouge is 100 DEG C；Nano aluminium oxide is White crystal powder, partial size 50nm, specific surface area 110m2/g；Carbon black
For high-carbon black pigment.
The step of preparing above-mentioned adhesive are as follows:
1) by 25 parts of carboxylated nitrile rubber, 25 parts of butadiene-styrene-vinyl pyridine rubber, 90 parts of resorcinol-formaldehyde resin and 300 parts of toluene
It is uniformly mixed, obtains the first mixture；
2) by 3 parts of methyl allyl acyloxypropyl trimethoxysilane, 3 parts of the third oxygen propyl group of glycidol trialkoxy silane,
3 parts and 20 parts of nano aluminium oxide of carbon black are uniformly mixed, and obtain the second mixture；
3) above-mentioned first mixture and the second mixture are mixed, stirs evenly at room temperature, above-mentioned adhesive is made.
Embodiment 4
The adhesive of the present embodiment is grouped as by the group of following parts by weight:
30 parts of carboxylated nitrile rubber；
30 parts of butadiene-styrene-vinyl pyridine rubber；
100 parts of resorcinol-formaldehyde resin；
400 parts of toluene；
4 parts of methacryloxypropyl triethoxysilane
4 parts of trialkoxy silane of the third oxygen propyl group of glycidol；
4 parts of carbon black；
30 parts of nano aluminium oxide；
Wherein, the mass content of acrylonitrile is 37% in carboxylated nitrile rubber, Mooney viscosity 55；Benzene in butadiene-styrene-vinyl pyridine rubber
The mass content of ethylene is 19%, and the mass content of vinylpyridine is 15%, Mooney viscosity 70；Resorcinol-formaldehyde tree
The softening point of rouge is 90 DEG C；Nano aluminium oxide is White crystal powder, partial size 60nm, specific surface area 150m2/g；Carbon black is
High-carbon black pigment.
The step of preparing above-mentioned adhesive are as follows:
1) by 30 parts of carboxylated nitrile rubber, 30 parts of butadiene-styrene-vinyl pyridine rubber, 100 parts of resorcinol-formaldehyde resin and 400 parts of toluene
It is uniformly mixed, obtains the first mixture；
2) by 4 parts of methacryloxypropyl triethoxysilane, 4 parts of the third oxygen propyl group of glycidol trialkoxy silane,
4 parts and 30 parts of nano aluminium oxide of carbon black are uniformly mixed, and obtain the second mixture；
3) above-mentioned first mixture and the second mixture are mixed, stirs evenly at room temperature, above-mentioned adhesive is made.
The application effect of each adhesive of table 1
| Adhesive | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Thermal coefficient (W/mK) | 0.85 | 1.132 | 0.942 | 0.896 |
| Adhesion strength (MPa) | 0.72 | 0.95 | 0.87 | 0.81 |
| Resistance to boiling water time (h) | 640 | 720 | 700 | 680 |
Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Pipe present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that: its according to
So be possible to modify the technical solutions described in the foregoing embodiments, or to some or all of the technical features into
Row equivalent replacement；And these are modified or replaceed, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (10)
1. a kind of adhesive, which is characterized in that the component including following parts by weight:
20-30 parts of carboxylated nitrile rubber；
20-30 parts of butadiene-styrene-vinyl pyridine rubber；
80-100 parts of resorcinol-formaldehyde resin；
150-400 parts of toluene；
2-4 parts of (methyl) acryloxypropyl trialkoxy silane；
2-4 parts of glycidol the third oxygen propyl group trialkoxy silane；
1-4 parts of carbon black；
10-30 parts of nano aluminium oxide.
2. adhesive according to claim 1, which is characterized in that the mass content of acrylonitrile in the carboxylated nitrile rubber
For 30-40%, Mooney viscosity 40-75.
3. adhesive according to claim 1, which is characterized in that the mass content of styrene is in the butadiene-styrene-vinyl pyridine rubber
18-20%, the mass content of vinylpyridine are 13-15%, Mooney viscosity 40-75.
4. adhesive according to claim 1, which is characterized in that the softening point of the resorcinol-formaldehyde resin is 80-
110℃。
5. adhesive according to claim 1, which is characterized in that (methyl) the acryloxypropyl trialkoxy silane
Selected from acryloxypropyl trimethoxy silane, acryloxypropyl triethoxysilane, acryloxypropyl tripropoxy silicon
Alkane, methyl allyl acyloxypropyl trimethoxysilane, methacryloxypropyl triethoxysilane and methacryloxypropyl third
At least one of base tripropoxy silane.
6. adhesive according to claim 1, which is characterized in that the partial size of the nano aluminium oxide is 20-80nm, compares table
Area is 20-200m2/g。
7. the preparation method of any described adhesive of claim 1 to 6, which comprises the steps of:
1) by 20-30 parts of carboxylated nitrile rubber, 20-30 parts of butadiene-styrene-vinyl pyridine rubber, 80-100 parts of resorcinol-formaldehyde resin and toluene
150-400 parts are uniformly mixed, and obtain the first mixture；
2) by 2-4 parts of (methyl) acryloxypropyl trialkoxy silane, glycidol the third oxygen propyl group trialkoxy silane 2-4
Part, 1-4 parts of carbon black and 10-30 parts of nano aluminium oxide are uniformly mixed, and obtain the second mixture；
3) first mixture and second mixture are uniformly mixed, obtain described adhesive.
8. application of any described adhesive of claim 1 to 6 on metal and rubber adhesion.
9. a kind of adhesive bonding method, which comprises the steps of:
On metal base by any described adhesive coating of claim 1 to 6, the first vulcanization is then carried out, in metal base
Upper formation coating；
Rubber is placed on the coating, the second vulcanization is then carried out, rubber composite material is made.
10. adhesive bonding method according to claim 9, which is characterized in that the temperature of first vulcanization is 150-160 DEG C,
Time is 5-10min；The temperature of second vulcanization is 150-160 DEG C, time 20-30min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710581898.XA CN109266270B (en) | 2017-07-17 | 2017-07-17 | Adhesive, preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710581898.XA CN109266270B (en) | 2017-07-17 | 2017-07-17 | Adhesive, preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109266270A true CN109266270A (en) | 2019-01-25 |
| CN109266270B CN109266270B (en) | 2021-08-03 |
Family
ID=65152431
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710581898.XA Active CN109266270B (en) | 2017-07-17 | 2017-07-17 | Adhesive, preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109266270B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110862592A (en) * | 2019-11-28 | 2020-03-06 | 北京石油化工学院 | Alumina/carboxylic butyronitrile composite material and preparation method thereof |
| CN110982156A (en) * | 2019-12-24 | 2020-04-10 | 海隆石油产品技术服务（上海）有限公司 | Easily-bonded high-filling polyolefin sheet material and preparation method and application thereof |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1050725A (en) * | 1989-06-12 | 1991-04-17 | 斯塔米卡本公司 | Improved adhesive latex |
| CN1412244A (en) * | 2001-10-12 | 2003-04-23 | 中国石油化工股份有限公司 | Toughened thermosetting resin and its preparation method |
| CN101368078A (en) * | 2008-09-19 | 2009-02-18 | 航天材料及工艺研究所 | Adhesive for bonding and mending cork wood and formulation method thereof |
| JP2010199626A (en) * | 2010-06-03 | 2010-09-09 | Nitto Denko Corp | Adhesive film for die bonding, and semiconductor device using the same |
| CN101838437A (en) * | 2010-05-31 | 2010-09-22 | 山东金麒麟集团有限公司 | Modified phenolic resin, preparation process thereof and brake pad cementing agent prepared by using same |
| CN102115653A (en) * | 2009-12-31 | 2011-07-06 | 比亚迪股份有限公司 | Binding agent composition, preparation method and application thereof |
| CN102627927A (en) * | 2012-03-26 | 2012-08-08 | 黑龙江省科学院石油化学研究院 | Medium temperature curing high temperature resistant phenolic adhesive |
| CN103481210A (en) * | 2013-09-05 | 2014-01-01 | 宁波大华砂轮有限公司 | Adhesive for grinding wheel meshes and preparation method of adhesive |
| US8835563B2 (en) * | 2011-03-25 | 2014-09-16 | Exxonmobil Chemical Patents Inc. | Block copolymers from silylated vinyl terminated macromers |
| CN104169383A (en) * | 2012-03-08 | 2014-11-26 | 日立化成株式会社 | Adhesive sheet and method for manufacturing semiconductor device |
| CN105238298A (en) * | 2015-09-25 | 2016-01-13 | 安徽大松树脂有限公司 | High-performance modified chloroprene rubber adhesive |
| CN105482243A (en) * | 2014-09-19 | 2016-04-13 | 中国石油化工股份有限公司 | Phenolic resin composition and foaming material and moulding material prepared therefrom |
| CN106833460A (en) * | 2015-12-03 | 2017-06-13 | 中国石油天然气股份有限公司 | Adhesive and preparation method and application thereof |
-
2017
- 2017-07-17 CN CN201710581898.XA patent/CN109266270B/en active Active
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1050725A (en) * | 1989-06-12 | 1991-04-17 | 斯塔米卡本公司 | Improved adhesive latex |
| CN1412244A (en) * | 2001-10-12 | 2003-04-23 | 中国石油化工股份有限公司 | Toughened thermosetting resin and its preparation method |
| CN101368078A (en) * | 2008-09-19 | 2009-02-18 | 航天材料及工艺研究所 | Adhesive for bonding and mending cork wood and formulation method thereof |
| CN102115653A (en) * | 2009-12-31 | 2011-07-06 | 比亚迪股份有限公司 | Binding agent composition, preparation method and application thereof |
| CN101838437A (en) * | 2010-05-31 | 2010-09-22 | 山东金麒麟集团有限公司 | Modified phenolic resin, preparation process thereof and brake pad cementing agent prepared by using same |
| JP2010199626A (en) * | 2010-06-03 | 2010-09-09 | Nitto Denko Corp | Adhesive film for die bonding, and semiconductor device using the same |
| US8835563B2 (en) * | 2011-03-25 | 2014-09-16 | Exxonmobil Chemical Patents Inc. | Block copolymers from silylated vinyl terminated macromers |
| CN104169383A (en) * | 2012-03-08 | 2014-11-26 | 日立化成株式会社 | Adhesive sheet and method for manufacturing semiconductor device |
| CN102627927A (en) * | 2012-03-26 | 2012-08-08 | 黑龙江省科学院石油化学研究院 | Medium temperature curing high temperature resistant phenolic adhesive |
| CN103481210A (en) * | 2013-09-05 | 2014-01-01 | 宁波大华砂轮有限公司 | Adhesive for grinding wheel meshes and preparation method of adhesive |
| CN105482243A (en) * | 2014-09-19 | 2016-04-13 | 中国石油化工股份有限公司 | Phenolic resin composition and foaming material and moulding material prepared therefrom |
| CN105238298A (en) * | 2015-09-25 | 2016-01-13 | 安徽大松树脂有限公司 | High-performance modified chloroprene rubber adhesive |
| CN106833460A (en) * | 2015-12-03 | 2017-06-13 | 中国石油天然气股份有限公司 | Adhesive and preparation method and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| D.M.BIELIN´ SKI 等: "Mechanicalpropertiesandfrictionofrubbervulcanizates: Aspects ofcrosslinkstructure", 《ARCHIVES OF CIVIL AND MECHANICAL ENGINEERING》 * |
| 庄光山 等: "橡胶改性酚醛树脂摩擦材料的研究", 《橡胶工业》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110862592A (en) * | 2019-11-28 | 2020-03-06 | 北京石油化工学院 | Alumina/carboxylic butyronitrile composite material and preparation method thereof |
| CN110862592B (en) * | 2019-11-28 | 2022-05-20 | 北京石油化工学院 | Alumina/carboxylic butyronitrile composite material and preparation method thereof |
| CN110982156A (en) * | 2019-12-24 | 2020-04-10 | 海隆石油产品技术服务（上海）有限公司 | Easily-bonded high-filling polyolefin sheet material and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109266270B (en) | 2021-08-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107674608B (en) | Silicone rubber tackifier, liquid two-component addition type silicone rubber prepared from silicone rubber tackifier and application of silicone rubber tackifier | |
| CN111068997B (en) | Preparation method of coating for realizing super-hydrophobic property of condensing heat exchange tube and condensing heat exchange tube | |
| CN1066275A (en) | Cross-linked epoxy functionalized polydiene block polymer, its preparation method, binder composition and starting block copolymer | |
| CN105001422B (en) | A kind of addition-type silicon rubber tackifier and preparation method thereof and addition-type silicon rubber | |
| CN103665461B (en) | A kind of rubber combination | |
| CN106380848A (en) | Low-dielectric-constant high-thermal-conductivity silicone rubber composite material and preparation method thereof | |
| CN106047073B (en) | A kind of graphene oxide based high-temp-resistant bicomponent epoxy resin coating | |
| CN104593579B (en) | With the production technology of the tin bronze tempered bead wire of rubber high adhesion | |
| CN109722216A (en) | A kind of Silante terminated liquid polybutadiene modified organic silicon sealant and preparation method thereof | |
| CN109266270A (en) | Adhesive, preparation method and application | |
| CN110643306B (en) | Special rubber type spot welding sealant for body-in-white and preparation method thereof | |
| CN103408938B (en) | A kind of addition type liquid silicone rubber compound used for manufacturing pad printing rubber head and preparation method thereof | |
| CN114381126A (en) | Organic silicon synthetic leather and preparation method thereof | |
| CN110387128B (en) | Self-adhesive single-component addition type silicone rubber and preparation method thereof | |
| CN105419336B (en) | A kind of high-elongation dealcoholized type room temperature vulcanized silicone rubber and preparation method thereof | |
| CN104497871B (en) | A kind of water base primary coat liquid for steel bead wire plating posttreatment | |
| CN114702786A (en) | Modified heat-resistant epoxy resin composition | |
| CN106833460B (en) | Adhesive and preparation method and application thereof | |
| CN116179114B (en) | Composite rubber adhesive with good heat resistance and preparation method thereof | |
| CN110408205A (en) | A kind of heat-resistant antifriction composition and its preparation method and application | |
| CN111635724A (en) | Epoxy structural adhesive with high elongation at break and preparation method thereof | |
| CN104877623B (en) | A kind of EMI interfaces special-purpose organic silicon bonding agent of the high high rebound degree of bonding | |
| CN114798378A (en) | Carbon sheet and aluminum-silicon composite material thereof | |
| CN116554836A (en) | Lead-acid storage battery sealant and preparation method thereof | |
| CN116463104A (en) | Low-density heat-conducting pouring sealant and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |