CN109266242A - A kind of novel environment-friendly hot melt membrane material and preparation method thereof - Google Patents
A kind of novel environment-friendly hot melt membrane material and preparation method thereof Download PDFInfo
- Publication number
- CN109266242A CN109266242A CN201810864951.1A CN201810864951A CN109266242A CN 109266242 A CN109266242 A CN 109266242A CN 201810864951 A CN201810864951 A CN 201810864951A CN 109266242 A CN109266242 A CN 109266242A
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- China
- Prior art keywords
- glue
- hot melt
- membrane material
- novel environment
- friendly
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/35—Heat-activated
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/10—Adhesives in the form of films or foils without carriers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The present invention provides a kind of novel environment-friendly hot melt membrane material and preparation method thereof, and the hot melt film material selection has the PU glue of hot melt characteristic；The PU glue includes butanone, toluene, acetone, isocyanates；The viscosity of the PU glue is 11000-14000CPS, Gu resultant is 35 soil 1%.The PU glue further includes polyaminobismaleimide, C9 hydrogenated petroleum resin.Hot melt adhesive film high temperature hot melt viscous force of the invention is strong, and hot melting temperature is low, range is big (hot melting temperature is between 80-120 DEG C), not degumming, not residue glue.
Description
Technical field
The invention belongs to ready-made clothes industries and shoe-making industry adhesive material field, and in particular to a kind of novel environment-friendly hot melt
Membrane material and preparation method thereof.
Background technique
Hot melt film is a kind of by heating fusing use, can facilitate the adhesive for carrying out continuity operation.It is using polymerization
Object is directly film-made and is process, there is no any solvent volatile substance not environmentally so being a kind of novel environment-friendly hot melt
Membrane material；2. not only bond it is solid and reliable, it is water-fastness, with more mould proof, ventilative, environmentally friendly, nontoxic；Shoes and clothes be made it is rear because
More beautiful for needle-and-thread-free while very soft, the comfort of human body dress is more preferable；3. hot melt film makes significantly simple in workshop
Change manufacture craft, when saving artificial and while improving production efficiency.
Environmental issue is always the hard defects of ready-made clothes industry and shoe-making industry；The strong glue smell in workshop seriously affects worker
Health, how many families paid heavy cost thus.
Summary of the invention
The technical problems to be solved by the present invention are: traditional pure PU glue film only has the characteristic of hot melt, but it is hot
Fusible power is low, is easy to appear that bonding is insecure to be caused the problem of falling off when bonding on the ready-made clothes fabric of different clothes, and the heat
Melten gel film high-temp. hot melt viscous force is strong, and hot melting temperature is low, range is big (hot melting temperature is between 80-120 DEG C), not degumming, not residue glue.
In order to achieve the above-mentioned object of the invention, The technical solution adopted by the invention is as follows:
A kind of novel environment-friendly hot melt membrane material, it is characterised in that: the hot melt film material selection has hot melt characteristic
PU glue；The PU glue includes butanone 20-30%, toluene 20-25%, acetone 35-40%, isocyanates 10-20%；The PU glue
Viscosity be 11000-14000CPS, solid resultant be 35 soil 1%.
Further, the PU glue further includes polyaminobismaleimide, and additive amount is the 2-5 mass % of PU glue.
Further, the PU glue further includes C9 hydrogenated petroleum resin, and additive amount is the 2-5 mass % of PU glue.
Further, endwise tensile strength M1:30 ± 5KG of the hot melt membrane material, transverse tensile strength TS:35 ±
5KG, elongation percentage E%:600-800%
A kind of preparation method of novel environment-friendly hot melt membrane material, it is characterised in that include the following steps:
(1) PU glue carries out uniform stirring glue；
(2) weight of high-accuracy coating machine release lattice Racine base stock two-sided to 90G is coated 157-170 microns of wet glue from face
Water；
(3) glue coating is dried by 25-30 meters of baking oven；
(4) BOPP film of one layer of 25U is bonded after cooling；
(5) it batches and is placed two days under natural environment, complete to be carried out extracting 25U's with rewinding machine after reflection is mature after glue
BOPP film.
The beneficial effects of the present invention are: a kind of PU glue hot melt adhesive film for clothes heat pressure adhesive, and traditional pure PU
Glue film only has the characteristic of hot melt, but its hot melt viscous force is low, is easy to appear when bonding on the ready-made clothes fabric of different clothes
Bond it is insecure cause the problem of falling off, and hot melt adhesive film high temperature hot melt viscous force is strong, and hot melting temperature is low, big (hot melt is warm for range
Degree is between 80-120 DEG C), not degumming, not residue glue.
Specific embodiment
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate this hair
It is bright, rather than limit the scope of the invention.Under the premise of without departing substantially from technical solution of the invention, the present invention is made
Those of ordinary skill in the art's any change easy to accomplish fall within scope of the presently claimed invention.
Embodiment 1
A kind of novel environment-friendly hot melt membrane material, it is characterised in that: the hot melt film material selection has hot melt characteristic
PU glue；The PU glue includes butanone 25%, toluene 22.5%, acetone 37.5%, isocyanates 15%；The viscosity of the PU glue is
11000-14000CPS, Gu resultant is 35 soil 1%.The PU glue further includes the poly- amino span of the 3 mass % relative to PU glue
Carry out acid imide, the C9 hydrogenated petroleum resin of the 3 mass % relative to PU glue.
A kind of preparation method of novel environment-friendly hot melt membrane material, it is characterised in that include the following steps:
(1) PU glue carries out uniform stirring glue；
(2) weight of high-accuracy coating machine release lattice Racine base stock two-sided to 90G is coated 157-170 microns of wet glue from face
Water；
(3) glue coating is dried by 25-30 meters of baking oven；
(4) BOPP film of one layer of 25U is bonded after cooling；
(5) it batches and is placed two days under natural environment, complete to be carried out extracting 25U's with rewinding machine after reflection is mature after glue
BOPP film.
Embodiment 2
A kind of novel environment-friendly hot melt membrane material, it is characterised in that: the hot melt film material selection has hot melt characteristic
PU glue；The PU glue includes butanone 30%, toluene 20%, acetone 40%, isocyanates 10%；The viscosity of the PU glue is
11000-14000CPS, Gu resultant is 35 soil 1%.The PU glue further includes the poly- amino span of the 5 mass % relative to PU glue
Carry out acid imide, the C9 hydrogenated petroleum resin of the 2 mass % relative to PU glue.
A kind of preparation method of novel environment-friendly hot melt membrane material, it is characterised in that include the following steps:
(1) PU glue carries out uniform stirring glue；
(2) weight of high-accuracy coating machine release lattice Racine base stock two-sided to 90G is coated 157-170 microns of wet glue from face
Water；
(3) glue coating is dried by 25-30 meters of baking oven；
(4) BOPP film of one layer of 25U is bonded after cooling；
(5) it batches and is placed two days under natural environment, complete to be carried out extracting 25U's with rewinding machine after reflection is mature after glue
BOPP film.
Embodiment 3
A kind of novel environment-friendly hot melt membrane material, it is characterised in that: the hot melt film material selection has hot melt characteristic
PU glue；The PU glue includes butanone 20%, toluene 25%, acetone 35%, isocyanates 20%；The viscosity of the PU glue is
11000-14000CPS, Gu resultant is 35 soil 1%.The PU glue further includes the poly- amino span of the 2 mass % relative to PU glue
Carry out acid imide, the C9 hydrogenated petroleum resin of the 5 mass % relative to PU glue.
Endwise tensile strength M1:30 ± 5KG of the hot melt membrane material, transverse tensile strength TS:35 ± 5KG, elongation percentage
E%:600-800%
A kind of preparation method of novel environment-friendly hot melt membrane material, it is characterised in that include the following steps:
(1) PU glue carries out uniform stirring glue；
(2) weight of high-accuracy coating machine release lattice Racine base stock two-sided to 90G is coated 157-170 microns of wet glue from face
Water；
(3) glue coating is dried by 25-30 meters of baking oven；
(4) BOPP film of one layer of 25U is bonded after cooling；
(5) it batches and is placed two days under natural environment, complete to be carried out extracting 25U's with rewinding machine after reflection is mature after glue
BOPP film.
Comparative example 1
It is same as Example 1, in addition to not including amino bismaleimide, C9 hydrogenated petroleum resin.
Comparative example 2
It is same as Example 1, in addition to not including amino bismaleimide.
Comparative example 3
It is same as Example 1, in addition to not including C9 hydrogenated petroleum resin.
Table 1
Claims (5)
1. a kind of novel environment-friendly heats membrane material, it is characterised in that: the hot melt film material selection has the PU of hot melt characteristic
Glue；The PU glue includes butanone 20-30%, toluene 20-25%, acetone 35-40%, isocyanates 10-20%；The PU glue
Viscosity is 11000-14000CPS, Gu resultant is 35 soil 1%.
2. novel environment-friendly according to claim 1 heats membrane material, it is characterised in that: the PU glue further includes poly- amino
Bismaleimide, additive amount are the 2-5 mass % of PU glue.
3. novel environment-friendly according to claim 2 heats membrane material, it is characterised in that: the PU glue further includes C9 hydrogenation
Petropols, additive amount are the 2-5 mass % of PU glue.
4. novel environment-friendly according to claim 3 heats membrane material, it is characterised in that: the longitudinal direction of the hot melt membrane material
Tensile strength M1:30 ± 5KG, transverse tensile strength TS:35 ± 5KG, elongation percentage E%:600-800%.
5. a kind of preparation method of novel environment-friendly hot melt membrane material, it is characterised in that include the following steps:
(1) PU glue carries out uniform stirring glue；
(2) weight of high-accuracy coating machine release lattice Racine base stock two-sided to 90G is coated 157-170 microns of wet glues from face；
(3) glue coating is dried by 25-30 meters of baking oven；
(4) BOPP film of one layer of 25U is bonded after cooling；
(5) it batches and is placed two days under natural environment, the BOPP for extract 25U with rewinding machine after glue completes reflection maturation is thin
Film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810864951.1A CN109266242A (en) | 2018-08-01 | 2018-08-01 | A kind of novel environment-friendly hot melt membrane material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810864951.1A CN109266242A (en) | 2018-08-01 | 2018-08-01 | A kind of novel environment-friendly hot melt membrane material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109266242A true CN109266242A (en) | 2019-01-25 |
Family
ID=65148238
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810864951.1A Pending CN109266242A (en) | 2018-08-01 | 2018-08-01 | A kind of novel environment-friendly hot melt membrane material and preparation method thereof |
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Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4132747A (en) * | 1974-12-28 | 1979-01-02 | Sumitomo Bakelite Company Limited | Heat-resistant molding resin composition |
| EP0362772A2 (en) * | 1988-10-05 | 1990-04-11 | National Starch and Chemical Investment Holding Corporation | Self-fixturing structural adhesives |
| JPH05335434A (en) * | 1992-06-02 | 1993-12-17 | Mitsui Petrochem Ind Ltd | Manufacture of box type resin molded object for semiconductor device |
| CN1479768A (en) * | 2000-12-08 | 2004-03-03 | ��Ԩ��ѧ��ҵ��ʽ���� | Material for insulating substrate, printed circuit board, laminate, copper foil with resin, copper-clad laminate, polymide film, film for TAB and prepreg |
| CN104830264A (en) * | 2015-05-22 | 2015-08-12 | 佛山市高明恒祥化工树脂有限公司 | Manufacturing method of solvent-type hydrolysis-resistant cold-resistant low-melting-point high-crystallization-speed polyurethane hot-melt adhesive |
| CN105538871A (en) * | 2016-02-04 | 2016-05-04 | 四川汇利实业有限公司 | Dry-type lamination process for preparing composite film |
| CN105710955A (en) * | 2014-12-05 | 2016-06-29 | 北京林业大学 | Methylene diphenyl isocyanate (MDI) light high-strength fiber board and manufacturing method |
| CN106564256A (en) * | 2015-10-13 | 2017-04-19 | 东莞市鼎盛塑胶膜有限公司 | A shaping method adopting printed film-high-brightness particle film integrated contraposition overprinting |
| CN107418478A (en) * | 2017-05-02 | 2017-12-01 | 佛山市精信汇明科技有限公司 | One kind can coating solvent type dual-component polyurethane PUR |
| CN108250993A (en) * | 2018-01-23 | 2018-07-06 | 苏州世华新材料科技有限公司 | A kind of no base material low-temp reaction type Hot melt adhesive tape and its with glue and preparation method |
-
2018
- 2018-08-01 CN CN201810864951.1A patent/CN109266242A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4132747A (en) * | 1974-12-28 | 1979-01-02 | Sumitomo Bakelite Company Limited | Heat-resistant molding resin composition |
| EP0362772A2 (en) * | 1988-10-05 | 1990-04-11 | National Starch and Chemical Investment Holding Corporation | Self-fixturing structural adhesives |
| JPH05335434A (en) * | 1992-06-02 | 1993-12-17 | Mitsui Petrochem Ind Ltd | Manufacture of box type resin molded object for semiconductor device |
| CN1479768A (en) * | 2000-12-08 | 2004-03-03 | ��Ԩ��ѧ��ҵ��ʽ���� | Material for insulating substrate, printed circuit board, laminate, copper foil with resin, copper-clad laminate, polymide film, film for TAB and prepreg |
| CN105710955A (en) * | 2014-12-05 | 2016-06-29 | 北京林业大学 | Methylene diphenyl isocyanate (MDI) light high-strength fiber board and manufacturing method |
| CN104830264A (en) * | 2015-05-22 | 2015-08-12 | 佛山市高明恒祥化工树脂有限公司 | Manufacturing method of solvent-type hydrolysis-resistant cold-resistant low-melting-point high-crystallization-speed polyurethane hot-melt adhesive |
| CN106564256A (en) * | 2015-10-13 | 2017-04-19 | 东莞市鼎盛塑胶膜有限公司 | A shaping method adopting printed film-high-brightness particle film integrated contraposition overprinting |
| CN105538871A (en) * | 2016-02-04 | 2016-05-04 | 四川汇利实业有限公司 | Dry-type lamination process for preparing composite film |
| CN107418478A (en) * | 2017-05-02 | 2017-12-01 | 佛山市精信汇明科技有限公司 | One kind can coating solvent type dual-component polyurethane PUR |
| CN108250993A (en) * | 2018-01-23 | 2018-07-06 | 苏州世华新材料科技有限公司 | A kind of no base material low-temp reaction type Hot melt adhesive tape and its with glue and preparation method |
Non-Patent Citations (1)
| Title |
|---|
| 石军等: "《热熔胶黏剂实用手册》", 31 May 2004, 化学工业出版社 * |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190125 |
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| RJ01 | Rejection of invention patent application after publication |