CN109222223A - A kind of wax water-in type cigarette is with quick-fried pearl and preparation method thereof - Google Patents
A kind of wax water-in type cigarette is with quick-fried pearl and preparation method thereof Download PDFInfo
- Publication number
- CN109222223A CN109222223A CN201810989547.7A CN201810989547A CN109222223A CN 109222223 A CN109222223 A CN 109222223A CN 201810989547 A CN201810989547 A CN 201810989547A CN 109222223 A CN109222223 A CN 109222223A
- Authority
- CN
- China
- Prior art keywords
- water
- quick
- fried pearl
- wax
- cigarette
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 104
- 238000002360 preparation method Methods 0.000 title claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 90
- 239000007864 aqueous solution Substances 0.000 claims abstract description 50
- 239000000463 material Substances 0.000 claims abstract description 46
- 150000002632 lipids Chemical class 0.000 claims abstract description 26
- 239000012779 reinforcing material Substances 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 19
- 230000006378 damage Effects 0.000 claims abstract description 14
- 239000003205 fragrance Substances 0.000 claims abstract description 13
- 239000002304 perfume Substances 0.000 claims abstract description 13
- 230000009467 reduction Effects 0.000 claims abstract description 13
- 239000002562 thickening agent Substances 0.000 claims abstract description 6
- 239000001993 wax Substances 0.000 claims description 56
- 239000003292 glue Substances 0.000 claims description 42
- 238000002844 melting Methods 0.000 claims description 35
- 230000008018 melting Effects 0.000 claims description 35
- 239000007788 liquid Substances 0.000 claims description 31
- 230000006870 function Effects 0.000 claims description 28
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 15
- 239000002202 Polyethylene glycol Substances 0.000 claims description 9
- 229920001223 polyethylene glycol Polymers 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 8
- 239000000284 extract Substances 0.000 claims description 8
- 239000003755 preservative agent Substances 0.000 claims description 8
- 241000238631 Hexapoda Species 0.000 claims description 7
- 239000006184 cosolvent Substances 0.000 claims description 7
- 239000006187 pill Substances 0.000 claims description 7
- 230000002335 preservative effect Effects 0.000 claims description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 5
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims description 5
- XPCTZQVDEJYUGT-UHFFFAOYSA-N 3-hydroxy-2-methyl-4-pyrone Chemical compound CC=1OC=CC(=O)C=1O XPCTZQVDEJYUGT-UHFFFAOYSA-N 0.000 claims description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001413 amino acids Chemical class 0.000 claims description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- DTUQWGWMVIHBKE-UHFFFAOYSA-N phenylacetaldehyde Chemical compound O=CCC1=CC=CC=C1 DTUQWGWMVIHBKE-UHFFFAOYSA-N 0.000 claims description 4
- 239000000419 plant extract Substances 0.000 claims description 4
- 229920001610 polycaprolactone Polymers 0.000 claims description 4
- 239000004632 polycaprolactone Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 108010010803 Gelatin Proteins 0.000 claims description 3
- 235000010489 acacia gum Nutrition 0.000 claims description 3
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 239000004203 carnauba wax Substances 0.000 claims description 3
- 235000009508 confectionery Nutrition 0.000 claims description 3
- -1 dihydroactinidiolide Chemical class 0.000 claims description 3
- 229920000159 gelatin Polymers 0.000 claims description 3
- 239000008273 gelatin Substances 0.000 claims description 3
- 235000019322 gelatine Nutrition 0.000 claims description 3
- 235000011852 gelatine desserts Nutrition 0.000 claims description 3
- 239000000230 xanthan gum Substances 0.000 claims description 3
- 235000010493 xanthan gum Nutrition 0.000 claims description 3
- 229920001285 xanthan gum Polymers 0.000 claims description 3
- 229940082509 xanthan gum Drugs 0.000 claims description 3
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 2
- OXQOBQJCDNLAPO-UHFFFAOYSA-N 2,3-Dimethylpyrazine Chemical class CC1=NC=CN=C1C OXQOBQJCDNLAPO-UHFFFAOYSA-N 0.000 claims description 2
- 239000001278 2-(5-ethenyl-5-methyloxolan-2-yl)propan-2-ol Substances 0.000 claims description 2
- AJKVQEKCUACUMD-UHFFFAOYSA-N 2-Acetylpyridine Chemical compound CC(=O)C1=CC=CC=N1 AJKVQEKCUACUMD-UHFFFAOYSA-N 0.000 claims description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 claims description 2
- MSHFRERJPWKJFX-UHFFFAOYSA-N 4-Methoxybenzyl alcohol Chemical compound COC1=CC=C(CO)C=C1 MSHFRERJPWKJFX-UHFFFAOYSA-N 0.000 claims description 2
- 239000005711 Benzoic acid Substances 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 2
- IMKHDCBNRDRUEB-UHFFFAOYSA-N Dihydroactinidiolide Natural products C1CCC(C)(C)C2=CC(=O)OC21C IMKHDCBNRDRUEB-UHFFFAOYSA-N 0.000 claims description 2
- BRHDDEIRQPDPMG-UHFFFAOYSA-N Linalyl oxide Chemical compound CC(C)(O)C1CCC(C)(C=C)O1 BRHDDEIRQPDPMG-UHFFFAOYSA-N 0.000 claims description 2
- HYMLWHLQFGRFIY-UHFFFAOYSA-N Maltol Natural products CC1OC=CC(=O)C1=O HYMLWHLQFGRFIY-UHFFFAOYSA-N 0.000 claims description 2
- YKVWPZJHENXDAJ-VOTSOKGWSA-N Megastigmatrienone Chemical compound CC1=CC(=O)CC(C)(C)C1\C=C\C=C YKVWPZJHENXDAJ-VOTSOKGWSA-N 0.000 claims description 2
- 244000061176 Nicotiana tabacum Species 0.000 claims description 2
- 239000005662 Paraffin oil Substances 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 244000299461 Theobroma cacao Species 0.000 claims description 2
- 235000009470 Theobroma cacao Nutrition 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 229940069765 bean extract Drugs 0.000 claims description 2
- 235000013871 bee wax Nutrition 0.000 claims description 2
- 239000012166 beeswax Substances 0.000 claims description 2
- 235000010233 benzoic acid Nutrition 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- IMKHDCBNRDRUEB-LLVKDONJSA-N dihydroactinidiolide Chemical compound C1CCC(C)(C)C2=CC(=O)O[C@@]21C IMKHDCBNRDRUEB-LLVKDONJSA-N 0.000 claims description 2
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 2
- 235000020710 ginseng extract Nutrition 0.000 claims description 2
- 125000005456 glyceride group Chemical group 0.000 claims description 2
- 229960004275 glycolic acid Drugs 0.000 claims description 2
- 239000004310 lactic acid Substances 0.000 claims description 2
- 235000014655 lactic acid Nutrition 0.000 claims description 2
- 150000002596 lactones Chemical class 0.000 claims description 2
- 229940043353 maltol Drugs 0.000 claims description 2
- 229940041616 menthol Drugs 0.000 claims description 2
- 239000004200 microcrystalline wax Substances 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- 229940100595 phenylacetaldehyde Drugs 0.000 claims description 2
- 229920001308 poly(aminoacid) Polymers 0.000 claims description 2
- 230000036299 sexual function Effects 0.000 claims description 2
- PQDRXUSSKFWCFA-CFNZNRNTSA-N solanone Chemical compound CC(=O)CC[C@@H](C(C)C)\C=C\C(C)=C PQDRXUSSKFWCFA-CFNZNRNTSA-N 0.000 claims description 2
- PQDRXUSSKFWCFA-UHFFFAOYSA-N solanone Natural products CC(=O)CCC(C(C)C)C=CC(C)=C PQDRXUSSKFWCFA-UHFFFAOYSA-N 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims description 2
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 claims description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims 2
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 235000013399 edible fruits Nutrition 0.000 claims 1
- 229920001038 ethylene copolymer Polymers 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 125000000623 heterocyclic group Chemical group 0.000 claims 1
- 229960000448 lactic acid Drugs 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 229940005605 valeric acid Drugs 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 15
- 239000003546 flue gas Substances 0.000 abstract description 15
- 239000002775 capsule Substances 0.000 abstract description 14
- 230000002829 reductive effect Effects 0.000 abstract description 8
- 239000004615 ingredient Substances 0.000 abstract description 6
- 239000000796 flavoring agent Substances 0.000 abstract description 4
- 235000019634 flavors Nutrition 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000000779 smoke Substances 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- 230000007794 irritation Effects 0.000 abstract 1
- 239000011162 core material Substances 0.000 description 34
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 15
- 239000002904 solvent Substances 0.000 description 7
- 208000004880 Polyuria Diseases 0.000 description 6
- 230000035619 diuresis Effects 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 230000001737 promoting effect Effects 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 241000208125 Nicotiana Species 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 3
- OVBFMEVBMNZIBR-UHFFFAOYSA-N -2-Methylpentanoic acid Natural products CCCC(C)C(O)=O OVBFMEVBMNZIBR-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 235000010443 alginic acid Nutrition 0.000 description 2
- 229920000615 alginic acid Polymers 0.000 description 2
- 150000004781 alginic acids Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000000686 essence Substances 0.000 description 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 229960003511 macrogol Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- 235000010199 sorbic acid Nutrition 0.000 description 2
- 239000004334 sorbic acid Substances 0.000 description 2
- 229940075582 sorbic acid Drugs 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000005770 Eugenol Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000006679 Mentha X verticillata Nutrition 0.000 description 1
- 235000002899 Mentha suaveolens Nutrition 0.000 description 1
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 1
- 244000021150 Orbignya martiana Species 0.000 description 1
- 235000014643 Orbignya martiana Nutrition 0.000 description 1
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000021028 berry Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 230000000622 irritating effect Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cosmetics (AREA)
Abstract
A kind of wax water-in type cigarette is with quick-fried pearl, for skin-core structure, it is made of crust and inner core, crust is the composition of wax, long chain lipid material, reinforcing material, inner core is aqueous solution, it is made of water and water-solubility function auxiliary agent, wherein water-solubility function auxiliary agent is one kind or their compositions of thickener, soluble perfume fragrance, harm reduction functional material.The beneficial effects of the present invention are: 1) it is applicable to vast water-soluble, alcohol-soluble flavors and fragrances, is greatly expanded the application range of essence；2) water outlet is discharged after pinching brokenly, can be increased smoke moisture, soft flue gas, be reduced irritation；3) harmful ingredients in flue gas burst size can be reduced；4) aqueous solution is encapsulated using wax material, unique wall material formula (such as addition reinforcing material), on the one hand assign quick-fried pearl suitable crushing strength, so that quick-fried pearl has good resist processing, on the other hand when can prevent unused well in capsule moisture spilling, ensured storage, the service life of capsule.
Description
Technical field
The invention belongs to technical field of cigarettes, and in particular to a kind of wax water-in type cigarette is with quick-fried pearl and preparation method thereof.
Background technique
In recent years, cigarette is included with the cigarette of quick-fried pearl (also referred to as cigarette capsule) in cigarette market ever more popular, cigarette is with quick-fried pearl
It is added in cigarette filter as a kind of cigarette new material, consumer can squeeze broken cigarette with quick-fried pearl when aspirating, provide to discharge
There is the essence of peat-reek, reaches abundant cigarette perfume, strengthen style, establish the effects of interactive.
In the prior art, cigarette uses quick-fried pearl usually using oil soluble perfume and as the lipid solvent of essence diluent as inner core
Material, and using natural glues such as gelatin, Arabic gum, alginic acids as outer wall materials.When preparation, respectively by inner core material and work
Pass through coaxial double-layer water dropper for the aqueous solution of outer wall materials, instill into protection liquid, in protection liquid, outer wall materials cooling is solidifying
Gu obtaining cigarette with quick-fried pearl after washed, dry to form the concentric spherical capsule of " oil-in-water ".But this kind of cigarette is with quick-fried pearl
There are still some problems: (1) per se with certain intrinsic smell, the coordination with flue gas cigarette perfume exists centainly asks lipid solvent
Topic, may cover the fragrance of additional essence to a certain extent.(2) existing essence spice for cigarette is greatly water-soluble object
Matter, cannot be dissolved in lipid solvent, therefore the essence type that can be applied with quick-fried pearl of such cigarette and range are substantially reduced, and can be selected
And applicable essence type is extremely limited, and is unfavorable for popularization and application of the cigarette with quick-fried pearl in cigarette brand.(3) these cigarettes are with quick-fried pearl
In lipid solvent can be overflowed after pinching brokenly, be easy pollution cigarette filter rod tow, or even by filter stick formation paper and tipping paper it is saturating
Outside paper delivery, cigarette exterior quality is influenced, gives the undesirable greasy feeling of consumer.(4) these cigarettes are relatively single with quick-fried pearl function, lead to
Flavoring means are often only used as, and harm reduction function tends not to be integrated in this kind of cigarette in quick-fried pearl.
If exploitation can wrap up the cigarette of water or aqueous solution with quick-fried pearl using water or water solution system as inner core material, then with
Lower advantage: (1) expand the quick-fried pearl essence scope of application of cigarette.Water can dissolve large number of water as a kind of good solvent
Dissolubility essence spice for cigarette can expand essence type and range that cigarette can be applied with quick-fried pearl significantly.(2) moisture feeling is promoted, is reduced
Dry and excitement.Package water or the cigarette of aqueous solution are releasably discharged after racking with quick-fried pearl, and water has wet flue gas, soft
Flue gas cigarette perfume reduces irritating effect, is remarkably improved cigarette smoking comfort level, promotes moisture feeling, reduces dry sensation and stimulation
Sense.(3) the quick-fried pearl other function of cigarette is assigned, harmful ingredients in flue gas burst size is such as reduced.On the one hand water can dissolve a lot in flue gas
Harmful components (for example, ammonia, HCN etc.), another aspect water can be used as the good solvent of harm reduction additive (such as polyethylene glycol), in turn
Realize the purpose for further decreasing harmful ingredients in flue gas.But not yet occur in the market it is such can be to water or Water-Soluble Core
The quick-fried pearl product of the cigarette that liquid is effectively wrapped up.
In terms of the cigarette of package water or aqueous solution is with quick-fried pearl, patent CN201410428708, which is disclosed, a kind of uses long chain lipid
The method of material (wax class) and flocculation aid as wall material package aqueous solution.In Hubei cigarette in patent CN201410059720 and
CN201410059949 individually discloses a kind of three layers, four-layer structure capsule with diuresis promoting function, and wherein the capsule with diuresis promoting function of three-decker uses seaweed
Sour sodium complex wraps up aqueous essence, then carries out waterproof package with wax；Four-layer structure capsule with diuresis promoting function is on three-decker capsule with diuresis promoting function basis
On, outermost wraps up one layer of alginic acid again, prevents the destruction of wax.Though above-mentioned technology can complete package, the process is more complicated, together
When outer layer wax intensity it is inadequate, yield is not high and easily broken, does not adapt to industrialized production.Patent CN201610513655 is used
Polymerizable bisphenol-A epoxy acrylic resin and other resins utilize wall by coaxial Double-nozzle sprayer dropping preparation method as wall material
Material photopolymer forms compact film, prepares capsule with diuresis promoting function, but due to need using a large amount of photoinitiator and there may be
There is certain influence to the safety of capsule with diuresis promoting function in monomer residue, while the wall material that photopolymerization is formed is usually more crisp, is unfavorable for subsequent
Machine-shaping.
Summary of the invention
The purpose of the present invention is based on above-mentioned prior art situation and provides a kind of wax water-in type cigarette quick-fried pearl and its system
Preparation Method.
The present invention is achieved through the following technical solutions.
A kind of wax water-in type cigarette is with quick-fried pearl, which has skin-core structure with quick-fried pearl, by the crust and 25- of 50 ~ 75 parts by weight
The inner core of 50 parts by weight forms.
Crust is the composition of wax, long chain lipid material, reinforcing material, and three's weight ratio is 1:0.4-2.5:0.4-2.5,
60-110 DEG C of composition fusing point；
Inner core is aqueous solution, is made of water and water-solubility function auxiliary agent, and the two weight ratio is 1:0.001-0.2, wherein water-soluble
Sexual function auxiliary agent is one kind or their compositions of thickener, soluble perfume fragrance, harm reduction functional material.The water solubility function
Cosolvent and preservative can be may also include in auxiliary agent.
The wax is one or more compounds selected from the group below: solid paraffin, microwax, insect wax, beeswax, babassu
Wax.
The long chain lipid material is one or more compounds selected from the group below: the higher aliphatic of 14 ~ 22 carbon atoms
Sour and its corresponding glyceride, 14 ~ 22 carbon atom higher aliphatics.
The reinforcing material be one or more compounds selected from the group below: polycaprolactone, ethylene-acrylic acid copolymer,
Ethylene-vinyl acetate copolymer.
The thickener be xanthan gum, Arabic gum, gelatin, carboxymethyl cellulose, carboxymethyl starch one kind.
The soluble perfume fragrance is preparing essence, natural plant extracts or combinations thereof object.Such component is used in cigarette
After quick-fried pearl pinches brokenly or other external force destroy, it can release, assigning the certain style flavor of cigarette or can enhance cigarette
Style flavor, such as aroma, mint flavored, herbal fragrance, it is burnt it is fragrant and sweet, bake fragrant and sweet, fruity.
The preparing essence is the alcohols such as menthol, benzyl carbinol, linalool oxide, anisyl alcohol, citric acid, benzoic acid,
The carboxylic acids such as methylvaleric acid, myristic acid, lactic acid, hydroxyacetic acid, the aldehyde ketones such as phenylacetaldehyde, vanillic aldehyde, solanone, Megastigmatrienone
Class, the phenols such as eugenol, maltol, the lactones such as dihydroactinidiolide, 2,3- dimethyl pyrazines, 2- acetylpyridine etc. are miscellaneous
The composition of ring class or mentioned component.
The natural plant extracts are tobacco extract, ginseng extract, dried orange peel extracts, cocoa bean extract, water
The composition of berry extract or mentioned component.
The harm reduction functional material is polyethylene glycol, amino acid, amino acid derivativges, polyaminoacid or combinations thereof object, should
Class component cigarette pinched brokenly with quick-fried pearl or other external force destroy after, can release, adsorb or fetter in flue gas nocuousness at
Divide (such as phenol, aldehyde compound), to reduce harmful ingredients in flue gas burst size.
The cosolvent is propylene glycol, glycerol or combinations thereof object.
The quick-fried pearl weight is in 20-60mg, and diameter is in 3-6mm, and crushing strength is in 5-30N.
The present invention also provides a kind of cigarette preparation methods of quick-fried pearl of wax water-in type, include the following steps
(1) preparation of inner core aqueous solution
Water and water-solubility function auxiliary agent are uniformly mixed according to formula rate and obtain aqueous solution.
(2) preparation of crust oiliness glue
Under heating stirring, wax, long chain lipid material, reinforcing material are uniformly mixed according to formula rate, melting obtains oily gum
Liquid.
(3) dripping
The crust oiliness glue of prepared inner core aqueous solution and melting is passed through into metering pump respectively and is pumped into outfit coaxial pair
Layer water dropper pill dripping machine in, aqueous solution, melting crust oiliness glue be pumped into the core passageway of coaxial double-layer water dropper respectively
With outer wall channel, instilled by coaxial double-layer water dropper into protection liquid.Under surface tension effects, aqueous solution, melting it is outer
Skin oiliness glue forms " Water-In-Oil " type concentric spherical drop, and drop internal is aqueous solution, and outer wall is the crust oiliness of melting
Glue.For the cigarette that drop is cooled into package water by protection liquid with quick-fried pearl, separating and washing through sieve can be obtained the cigarette for wrapping up water
With quick-fried pearl.
The crust oiliness glue temperature of step (3) melting is at 70-110 DEG C, and coaxial double-layer water dropper water dropper temperature is in 70-100
DEG C, 20-80 DEG C of temperature of inner core aqueous solution.
Step (3) protect liquid density≤0.85g/mL L, 10-30 DEG C of temperature.
Step (3) protect liquid be 90%-100%(percentage by volume) ethanol water, paraffin oil one kind.
Step (3) coaxial double-layer water dropper is made of interior water dropper and outer water dropper, interior water dropper internal diameter 0.2 ~ 2.0mm, outer diameter 1.2-
3.0mm, outer water dropper internal diameter 2.5-5.5mm, outer diameter 3.5-6.5mm.
The beneficial effects of the present invention are: (1) with the cigarette of in the prior art package lipid solvent with quick-fried pearl compared with, the present invention is mentioned
For the quick-fried pearl of cigarette of wax water-in type a kind of be applicable to vast water-soluble, alcohol-soluble flavors and fragrances, be greatly expanded essence
Application range；(2) cigarette of package water discharges water outlet after being pinched brokenly with quick-fried pearl, can increase smoke moisture, soft flue gas, reduce thorn
Swash property；(3) harmful ingredients in flue gas burst size can be reduced, on the one hand the water of release has preferable dissolubility, when flue gas passes through
The harmful components in partial fume are dissolved, on the other hand, the function harm reduction material added in quick-fried pearl can further decrease in flue gas
Harmful components burst size；(4) aqueous solution is encapsulated using wax material, unique wall material formula (such as addition reinforcing material),
On the one hand it assigns quick-fried pearl suitable crushing strength, so that quick-fried pearl has good resist processing, on the other hand can prevent well
When unused in capsule moisture spilling, ensured storage, the service life of capsule；(5) a kind of wax packet provided by the invention
The cigarette of water type is simple with quick-fried pearl preparation method, with existing equipment good compatibility.
Detailed description of the invention
Fig. 1 is the production process schematic diagram that pill dripping machine (existing known device) used in the present invention produces cigarette capsule,
In figure: 1- core material tank, 2- wall material tank, 3- metering pump, 4- coaxial double-layer water dropper, 5- core passageway, 6- outer wall channel, 7- are protected
Liquid, 8- sieve are protected, 9- protects liquid refrigerant tank, 10- circulating pump, and 11- protects liquid return pipe.
Specific embodiment
The present invention is described further with reference to embodiments (attached drawing):
Embodiment 1
1. a kind of wax water-in type cigarette has skin-core structure with quick-fried pearl, is made of crust and inner core with quick-fried pearl, the cigarette.
(1) crust: crust be wax, long chain lipid material, reinforcing material composition, 70 DEG C of composition fusing point.Wherein wax
For solid paraffin, long chain lipid material is stearic acid, and reinforcing material is polycaprolactone, and three's weight ratio is 1:2.5:1.5.
(2) inner core: inner core is aqueous solution, is made of 1 part of water and 0.2 part of water-solubility function auxiliary agent.Wherein water-soluble function
Can auxiliary agent be soluble perfume fragrance (tobacco extract), harm reduction functional material (Macrogol 600), cosolvent (propylene glycol)
Composition, proportions 1:0.8:0.2
2. the above-mentioned wax water-in type cigarette preparation method of quick-fried pearl, includes the following steps
(1) preparation of aqueous solution
Water and water-solubility function auxiliary agent (tobacco extract, polyethylene glycol, propylene glycol etc.) are uniformly mixed according to formula and obtain water
Property solution.
Water: 100 parts
Tobacco extract: 10 parts
Macrogol 600: 8 parts
Propylene glycol: 2 parts
(2) preparation of crust oiliness glue
Under heating stirring, by wax (solid paraffin), long chain lipid material (stearic acid), reinforcing material (polycaprolactone) according to formula
Ratio 1:2.5:1.5 is uniformly mixed, and is heated to 80 DEG C of meltings and is obtained crust oiliness glue.
(3) dripping
The crust oiliness glue of aqueous solution, melting is passed through into the pill dripping machine that metering pump is pumped into outfit coaxial double-layer water dropper respectively
In, aqueous solution, melting crust oiliness glue be pumped into core passageway and the outer wall channel of coaxial double-layer water dropper respectively, pass through
Coaxial double-layer water dropper is instilled into protection liquid.Under surface tension effects, aqueous solution, melting crust oiliness glue formed together
Heart spherical droplets, drop internal are aqueous solution, and outer wall is the crust oiliness glue of melting.Drop is protected after entering protection liquid
But, the cigarette for forming package water uses quick-fried pearl to liquid cooling, and separating and washing through sieve can be obtained the cigarette for wrapping up water with quick-fried pearl.
The crust oiliness glue temperature of melting is at 80 DEG C, and coaxial double-layer water dropper water dropper temperature is at 80 DEG C.
Protection liquid be ethyl alcohol, 10 DEG C of temperature.
Embodiment 2
1. a kind of wax water-in type cigarette has skin-core structure with quick-fried pearl, is made of crust and inner core with quick-fried pearl, the cigarette.
(1) crust: crust be wax, long chain lipid material, reinforcing material composition, 80 DEG C of composition fusing point.Wherein wax
For Brazil wax, long chain lipid material is tristerin, and reinforcing material is ethylene-acrylic acid copolymer, three's weight
Than for 1:1:1
(2) inner core: inner core is aqueous solution, is made of 100 parts of water and 1 part of water-solubility function auxiliary agent.Wherein water-solubility function helps
Agent is soluble perfume fragrance (preparing essence) and xanthan gum (thickener), and the two weight ratio is 8:2.
2. the above-mentioned wax water-in type cigarette preparation method of quick-fried pearl, includes the following steps
(1) preparation of aqueous solution
Water and water-solubility function auxiliary agent are uniformly mixed according to formula and obtain aqueous solution.
(2) preparation of crust oiliness glue
Under heating stirring, by wax (Brazil wax), long chain lipid material (tristerin), reinforcing material (ethylene-propylene
Acid copolymer) it is uniformly mixed according to formula rate 1:1:1,90 DEG C are heated to, melting obtains oiliness glue.
(3) dripping
The crust oiliness glue of aqueous solution, melting is passed through into the pill dripping machine that metering pump is pumped into outfit coaxial double-layer water dropper respectively
In, aqueous solution, melting crust oiliness glue be pumped into core passageway and the outer wall channel of coaxial double-layer water dropper respectively, pass through
Coaxial double-layer water dropper is instilled into protection liquid.Under surface tension effects, aqueous solution, melting crust oiliness glue formed together
Heart spherical droplets, drop internal are aqueous solution, and outer wall is the crust oiliness glue of melting.Drop is protected after entering protection liquid
But, the cigarette for forming package water uses quick-fried pearl to liquid cooling, and separating and washing through sieve can be obtained the cigarette for wrapping up water with quick-fried pearl.
The crust oiliness glue temperature of melting is at 90 DEG C, and coaxial double-layer water dropper water dropper temperature is at 90 DEG C.
Protection liquid be 95% ethyl alcohol, 20 DEG C of temperature.
Embodiment 3
1. a kind of wax water-in type cigarette has skin-core structure with quick-fried pearl, is made of crust and inner core with quick-fried pearl, the cigarette.
(1) crust: crust be wax, long chain lipid material, reinforcing material composition, 95 DEG C of composition fusing point.Wherein wax
For insect wax, long chain lipid material is octadecyl alcolol, and reinforcing material is ethylene-vinyl acetate copolymer, and three's weight ratio is 30:25:
50.
(2) inner core: inner core is aqueous solution, is made of 100 parts of water and 10 parts of water-solubility function auxiliary agents.Wherein water-solubility function helps
Agent is soluble perfume fragrance (preparing essence), harm reduction functional material (polyethylene glycol), cosolvent (glycerol), preservative are (conventional
Preservative, sorbic acid), their ratio is 2:7:1:0.03
2. the above-mentioned cigarette preparation method of quick-fried pearl, includes the following steps
(1) preparation of aqueous solution
Water and water-solubility function auxiliary agent (preparing essence, polyethylene glycol, glycerol, conventional preservatives etc.) are uniformly mixed according to formula
Obtain aqueous solution.
(2) preparation of oiliness glue
Under heating stirring, by wax (insect wax), long chain lipid material (octadecyl alcolol), reinforcing material (ethylene-vinyl acetate copolymer)
It is uniformly mixed according to formula rate, melting obtains oiliness glue.
(3) dripping
The crust oiliness glue of aqueous solution, melting is passed through into the pill dripping machine that metering pump is pumped into outfit coaxial double-layer water dropper respectively
In, aqueous solution, melting crust oiliness glue be pumped into core passageway and the outer wall channel of coaxial double-layer water dropper respectively, pass through
Coaxial double-layer water dropper is instilled into protection liquid.Under surface tension effects, aqueous solution, melting crust oiliness glue formed together
Heart spherical droplets, drop internal are aqueous solution, and outer wall is the crust oiliness glue of melting.Drop is protected after entering protection liquid
But, the cigarette for forming package water uses quick-fried pearl to liquid cooling, and separating and washing through sieve can be obtained the cigarette for wrapping up water with quick-fried pearl.
The crust oiliness glue temperature of melting is at 100 DEG C, and coaxial double-layer water dropper water dropper temperature is at 100 DEG C
Protecting liquid is that light paraffinic is oily, 20 DEG C of temperature
Embodiment 4
1. a kind of wax water-in type cigarette has skin-core structure with quick-fried pearl, is made of crust and inner core with quick-fried pearl, the cigarette.
(1) crust: crust is the composition of wax, long chain lipid material, reinforcing material.Wherein wax is insect wax, long chain lipid
Material is 20 acid, and reinforcing material is ethylene-acrylic acid copolymer, and three's weight ratio is 1:0.67:1.67.
(2) inner core: inner core is aqueous solution, is made of 100 parts of water and 10 parts of water-solubility function auxiliary agents.Wherein water-solubility function helps
Agent is soluble perfume fragrance (preparing essence), harm reduction functional material (polyethylene glycol), cosolvent (glycerol), preservative are (conventional
Preservative such as sorbic acid), their ratio is 2:7:1:0.03
2. the above-mentioned wax water-in type cigarette preparation method of quick-fried pearl, includes the following steps
(1) preparation of aqueous solution
Water and water-solubility function auxiliary agent (preparing essence, polyethylene glycol, glycerol, preservative etc.) are uniformly mixed according to formula and obtained
Aqueous solution.
(2) preparation of oiliness glue
Under heating stirring, wax (insect wax), long chain lipid material (20 acid), reinforcing material (ethylene-acrylic acid copolymer) are pressed
It is uniformly mixed according to formula rate, melting obtains oiliness glue.
(3) dripping
The crust oiliness glue of aqueous solution, melting is passed through into the pill dripping machine that metering pump is pumped into outfit coaxial double-layer water dropper respectively
In, aqueous solution, melting crust oiliness glue be pumped into core passageway and the outer wall channel of coaxial double-layer water dropper respectively, pass through
Coaxial double-layer water dropper is instilled into protection liquid.Under surface tension effects, aqueous solution, melting crust oiliness glue formed together
Heart spherical droplets, drop internal are aqueous solution, and outer wall is the crust oiliness glue of melting.Drop is protected after entering protection liquid
But, the cigarette for forming package water uses quick-fried pearl to liquid cooling, and separating and washing through sieve can be obtained the cigarette for wrapping up water with quick-fried pearl.
The crust oiliness glue temperature of melting is at 100 DEG C, and coaxial double-layer water dropper water dropper temperature is at 100 DEG C.
Protecting liquid is that light paraffinic is oily, 30 DEG C of temperature.
Embodiment 5
The present embodiment is reference examples, and only skin material is different from embodiment 4, remaining is completely the same with embodiment 4.Difference exists
Reinforcing material is not added in crust.
Crust selects the composition of wax (insect wax) and long chain lipid material (20 acid), and the two weight ratio is 1:1.67.
Cigarette prepared by each embodiment is evaluated with capsule performance and is compared
1. the quick-fried pearl performance evaluation of cigarette
(1) cigarette uses weight method with quick-fried pearl weight, weighs at least 20.
(2) cigarette uses vernier caliper measurement with quick-fried pearl diameter, measures at least 20.
(3) cigarette is measured with quick-fried pearl crushing strength and is measured using home-built equipment, and device core includes being connected with manograph
Electronic balance and top link push strut, push strut at the uniform velocity squeezes the quick-fried pearl being placed on balance platform when measurement, passes through
Recorder records the variation tendency of pressure and the active force of quick-fried pearl rupture moment, can measure the crushing strength of quick-fried pearl.Measurement
At least 10.
(4) the quick-fried pearl harm reduction performance evaluation of cigarette: making an addition to cigarette with quick-fried pearl for cigarette, is measured after pinching brokenly quick-fried pearl using smoking machine
Main flume harmful components burst size calculates main flume harmful components burst size compared with compareing cigarette (not pinching brokenly quick-fried pearl)
Reduced rate.
2. the quick-fried pearl Evaluation results of cigarette
Cigarette is shown in Table 1 with quick-fried pearl Evaluation results.
Cigarette with simple grain weight in quick-fried pearl (embodiment 1-4) in 22 ~ 61mg, 3.4 ~ 4.9mm of diameter, the cigarette weight of quick-fried pearl and
Size is mainly influenced by coaxial double-layer water dropper size.
Cigarette has suitable crushing strength with quick-fried pearl (embodiment 1-4), and crushing strength can be pinched in 7-20N by consumer
It breaks and does not influence processing performance.
Cigarette shows that quick-fried pearl can reduce harmful ingredients in flue gas release in embodiment 1-4 with quick-fried pearl harm reduction Evaluation results
Amount.Wherein, due to being added to polyethylene glycol in quick-fried pearl in embodiment 1,3,4, the reducing effect of Pyrogentisinic Acid is significant；For ammonia and
HCN can be also effectively reduced since the two has higher dissolubility in water.
The quick-fried pearl performance evaluation of table 1
In addition, 5 crust of embodiment is not added with reinforcing material for the effect of Contrast enhanced material, it is not added with reinforcing material preparation
Cigarette with the crushing strength of quick-fried pearl be only 3 ~ 5N, it is easily broken in process, and cigarette prepared by embodiment 1-4 is with quick-fried pearl
For (wall material formula example provided by the invention) crushing strength in 7-20N, crushing strength is suitable for being not only suitable processing, and can be with
The content of release package is preferably pinched brokenly by consumer.
The cigarette of embodiment 1-4 preparation within the protection scope of the present invention percentage of water loss only 2-5% in 30 days with quick-fried pearl is right
The water holding capacity of package is outstanding；And the cigarette of embodiment 5 is up to 29% with percentage of water loss in quick-fried pearl 30 days, the holding to the water of package
Ability is poor.
Claims (10)
1. a kind of wax water-in type cigarette is with quick-fried pearl, which is characterized in that the cigarette has skin-core structure with quick-fried pearl, by 50 ~ 75 parts by weight
Crust and the inner core of 25-50 parts by weight composition；
Crust is the composition of wax, long chain lipid material, reinforcing material, and three's weight ratio is 1:0.4-2.5:0.4-2.5, combination
60-110 DEG C of object fusing point；
Inner core is aqueous solution, is made of water and water-solubility function auxiliary agent, and the two weight ratio is 1:0.001-0.2, wherein water-soluble
Sexual function auxiliary agent is one kind or their compositions of thickener, soluble perfume fragrance, harm reduction functional material.
2. a kind of wax water-in type cigarette as described in claim 1 is with quick-fried pearl, which is characterized in that
The wax is one or more compounds selected from the group below: solid paraffin, microwax, insect wax, beeswax, Brazil wax；
The long chain lipid material is one or more compounds selected from the group below: the higher fatty acids of 14 ~ 22 carbon atoms and
Its corresponding glyceride, 14 ~ 22 carbon atom higher aliphatics；
The reinforcing material is one or more compounds selected from the group below: polycaprolactone, ethylene-acrylic acid copolymer, ethylene-
Acetate ethylene copolymer.
3. a kind of wax water-in type cigarette as described in claim 1 is with quick-fried pearl, which is characterized in that
The thickener be xanthan gum, Arabic gum, gelatin, carboxymethyl cellulose, carboxymethyl starch one kind；
The soluble perfume fragrance is preparing essence, natural plant extracts or combinations thereof object；
The harm reduction functional material is polyethylene glycol, amino acid, amino acid derivativges, polyaminoacid or combinations thereof object.
4. a kind of wax water-in type cigarette as claimed in claim 3 is with quick-fried pearl, which is characterized in that
The preparing essence is the alcohols such as menthol, benzyl carbinol, linalool oxide, anisyl alcohol, citric acid, benzoic acid, methyl
The carboxylic acids such as valeric acid, myristic acid, lactic acid, hydroxyacetic acid, the aldoketones such as phenylacetaldehyde, vanillic aldehyde, solanone, Megastigmatrienone, fourth
The phenols such as fragrant phenol, maltol, the lactones such as dihydroactinidiolide, the heterocyclics such as 2,3- dimethyl pyrazines, 2- acetylpyridine
Or the composition of mentioned component；
The natural plant extracts are tobacco extract, ginseng extract, dried orange peel extracts, cocoa bean extract, fruit mention
Take the composition of object or mentioned component.
5. a kind of wax water-in type cigarette as described in claim 1 is with quick-fried pearl, which is characterized in that the water-solubility function auxiliary agent also wraps
Cosolvent and preservative are included.
6. a kind of wax water-in type cigarette as claimed in claim 5 uses quick-fried pearl, which is characterized in that the cosolvent is propylene glycol, sweet
Oil or combinations thereof object.
7. the preparation method of quick-fried pearl of wax water-in type cigarette described in claim 1-6, which comprises the following steps:
(1) preparation of inner core aqueous solution
Water and water-solubility function auxiliary agent are uniformly mixed and obtain aqueous solution；
(2) preparation of crust oiliness glue
Under heating stirring, wax, long chain lipid material, reinforcing material are uniformly mixed according to formula rate, melting obtains crust oil
Property glue；
(3) dripping
The crust oiliness glue of prepared inner core aqueous solution and melting is passed through into metering pump respectively and is pumped into outfit coaxial pair
Layer water dropper pill dripping machine in, inner core aqueous solution, melting crust oiliness glue be pumped into the inner core of coaxial double-layer water dropper respectively
Channel and outer wall channel are instilled by coaxial double-layer water dropper into protection liquid, under surface tension effects, aqueous solution, melting
Crust oiliness glue form " Water-In-Oil " type concentric spherical drop, drop internal is aqueous solution, and outer wall be the crust melted
Oiliness glue；Drop is cooled into the cigarette of package water with quick-fried pearl by protection liquid, and separating and washing through sieve can be obtained package water
Cigarette with quick-fried pearl.
8. a kind of wax water-in type cigarette as claimed in claim 7 preparation method of quick-fried pearl, which is characterized in that
70-110 DEG C of glue temperature of crust oiliness of step (3) melting, 70-100 DEG C of temperature of coaxial double-layer water dropper water dropper, inner core water
20-80 DEG C of solution temperature of property.
9. a kind of wax water-in type cigarette as claimed in claim 7 preparation method of quick-fried pearl, which is characterized in that
Step (3) protect liquid density≤0.85g/mL, 10-30 DEG C of temperature.
10. a kind of wax water-in type cigarette as claimed in claim 7 preparation method of quick-fried pearl, which is characterized in that
It is one kind of the ethanol water of 90%-100% volume ratio, paraffin oil that step (3), which protects liquid,.
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