CN109208016A - A kind of without phosphorus anti-rust metal detergent and preparation method thereof - Google Patents
A kind of without phosphorus anti-rust metal detergent and preparation method thereof Download PDFInfo
- Publication number
- CN109208016A CN109208016A CN201811143655.9A CN201811143655A CN109208016A CN 109208016 A CN109208016 A CN 109208016A CN 201811143655 A CN201811143655 A CN 201811143655A CN 109208016 A CN109208016 A CN 109208016A
- Authority
- CN
- China
- Prior art keywords
- parts
- rust
- metal detergent
- phosphorus anti
- phosphorus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
- C23G1/26—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention, which discloses, relates to a kind of without phosphorus anti-rust metal detergent and preparation method thereof, the product is made of by weight following raw material: 10-15 parts of nonionic surfactant fatty alcohol polyoxyethylene ether, 10-15 parts of cocoanut fatty acid diethanolamide, 5-10 parts of anionic surfactant sodium dodecylbenzene sulfonate, 10-15 parts of washing assisant, 8-12 parts of chelating agent, 2-5 parts of rust inhibitor, 1-4 parts of defoaming agent, 80-100 parts of water.The without phosphorus anti-rust metal detergent component that the design provides is cheap, from a wealth of sources, easy to operate.With good dissolubility, excellent dirt-removing power and low bubble；It will not damage, corrode the advantages that metal works.Main to be free from the harmful substances such as phosphorus, nitrite and heavy metal, surfactant is biodegradable, is conducive to subsequent sewage treatment, safety and environmental protection.
Description
Technical field
The invention belongs to industrial cleaning fields, are related to a kind of metal cleaner more particularly to a kind of without phosphorus anti-rust cleaning agent
And preparation method thereof.
Background technique
Metal cleaning is one of indispensable process in machining production, mostly according to patent document and market survey
It is the cleaning dirty for machine and equipment surface and oil contaminant and rust, cleaning effect is not high；Metal surface is got rusty in cleaning process；Have
Cleaning agent also have nitrites harmful substance, endanger environment and health of people.With Minute Organic Synthesis technology, biology
The progress of the relevant technologies such as technology, detection technique, chemical cleaning technique are also developed, and are sent out to " green " environmentally friendly direction
Exhibition.Without phosphorus, floride-free cleaning agent will replace phosphorous, fluorine-containing cleaning agent；Aqueous cleaning agent will replace solvent type and emulsion cleaner.
A kind of without phosphorus anti-rust metal detergent is invented in research under this overall background, and satisfaction environmental protection, cleaning effect is good, extends and gets rusty the time extremely
It closes important.
Summary of the invention
For the shortcoming of existing cleaning agent, the present invention provides a kind of moderate foam, and cleaning ability is strong, and antirust is free of
The metal cleaner of the harmful substances such as phosphorus, nitrite.
To achieve the above object, the without phosphorus anti-rust metal detergent of invention, which is characterized in that by weight include with the following group
Point: 10-15 part of nonionic surfactant fatty alcohol polyoxyethylene ether, 10-15 parts of cocoanut fatty acid diethanolamide, it is negative from
5-10 parts of sub- surfactant neopelex, 10-15 parts of washing assisant, 8-12 parts of chelating agent, rust inhibitor 2-5
Part, 1-4 parts of defoaming agent, 80-100 parts of water.
Cocoanut fatty acid diethanolamide referred to as 6501, main function are thickening, foam stabilizing and improve dirt-removing power.
The amount for properly increasing detergent 6501 is the selection for reducing cost at present.It can be effectively reduced using the 6501 of 1:1.5 metering
The usage amount of thickener, foam stablize the cleaning drawback of two kinds of surfactant compounds of supplement.Rust inhibitor plurality of reagents is pressed
It is matched according to different schemes, test effect preferably goes out reagent and compounded.
The without phosphorus anti-rust metal detergent that the design provides has advantage compared with prior art:
(1) component is cheap, from a wealth of sources, easy to operate；
(2) there is excellent dirt-removing power and foam stability；It will not damage, corrode the advantages that metal works；
(3) main to be free from the harmful substances such as phosphorus, nitrite and heavy metal, surfactant is biodegradable, is conducive to
Subsequent sewage treatment, safety and environmental protection.
Detailed description of the invention
Fig. 1 is preparing metal cleaning agent implementation steps.
Fig. 2 is that rustless property tests 30h test piece effect.
Specific embodiment
The following further explains the present invention by way of examples:
It compounds rust inhibitor: 50-60mL water, 0.1-0.3mL triethanolamine, 0.06- being added in the silicate of 40-60mL
0.09g ethylenediamine tetra-acetic acid, 0.30-0.06g sodium molybdate are configured to mixed solution.Pure silicate film forming is uneven, has the gap, right
Its progress is composite modified.Triethanolamine and nitrogen-atoms, oxygen atom in the amide of acid reaction generation can be acted on metal surface and be given birth to
It prevents oxygen gas and water from contacting with metal at coordination compound film, prevents metal rusting.
Compound surfactant: addition water, which is placed on magnetic stirring apparatus, in beaker is heated to 55 DEG C or so, sequentially adds rouge
The stirring of fat alcohol polyoxyethylene ether is completely dissolved addition neopelex to it, and 300-350rpm/min continues to stir
Cocoanut fatty acid diethanolamide is added in 30min, is completely dissolved stopping stirring and is cooled to room temperature compound surfactant is made.
Operating method: compound surfactant and chelating agent are added beaker and add water, are put into 250- on magnetic stirring apparatus
300rpm/min, 40 DEG C of stirring 20min are removed and are cooled to room temperature to form mixed solution.Sodium citrate, sodium metasilicate are put into beaker and add
Water, 200rpm/min stir to form washing assisant, add for a period of time compounding rust inhibitor continue stir 10min formed separately
A kind of mixed solution.Two kinds of mixed solution mixing and water addings stir 20min at 200-250rpm/min and organic silicone oil continuation are added dropwise
Stirring 10min is configured to without phosphorus anti-rust metal detergent.
Specific implementation method is as shown in Fig. 1.
Embodiment 1
15 parts of nonionic surfactant fatty alcohol polyoxyethylene ether, 10 parts of cocoanut fatty acid diethanolamide, anion table
9 parts of face activating agent neopelex, 5 parts of sodium citrate, 5 parts of sodium metasilicate, 10 parts of sodium metasilicate, 3 parts of rust inhibitor,
1 part of silicone oil, 90 parts of water.
Embodiment 2
13 parts of nonionic surfactant fatty alcohol polyoxyethylene ether, 12 parts of cocoanut fatty acid diethanolamide, anion table
10 parts of face activating agent neopelex, 6 parts of sodium citrate, 4 parts of sodium metasilicate, 9 parts of sodium metasilicate, 4 parts of rust inhibitor,
2 parts of silicone oil, 100 parts of water.
Embodiment 3
14 parts of nonionic surfactant fatty alcohol polyoxyethylene ether, 11 parts of cocoanut fatty acid diethanolamide, anion table
8 parts of face activating agent neopelex, 6 parts of sodium citrate, 4 parts of sodium metasilicate, 8 parts of sodium metasilicate, 4 parts of rust inhibitor,
1 part of silicone oil, 100 parts of water.
Rustless property test:
HT200 cast iron, 45 steel test pieces.First four sides, angle and hole of test piece are polished with 180 sand paper bright, be placed in drier to
It washes.It successively scrubs, dry up in industrial naptha, dehydrated alcohol, 50 DEG C of hot water ethyl alcohol, be put into drier cooling.For use
Time is no more than after polishing 15 hours.Six identical grids, first three grid drop are drawn in test piece with the special pencil of ruler
Entering 1 drop diameter is about 3-4mm.Test piece is put into wet surface plate and is covered, 25 DEG C ± 5 DEG C are placed 30h at room temperature.Through surveying
Fixed, 3 grid little or nothing rusty stains extend the time of getting rusty.
Test piece effect is as shown in Fig. 2 after 30h.
Cleaning ability test:
With 2 parts of iundustrial oil, 1 part of industrial vaseline, 1 part of the barium sulfate artificial greasy dirt in 110 DEG C or so stirring and dissolvings.It will be oily
Dirt is dried to bulk, and 100mg is taken uniformly to be applied to metal testing plate surface, weighs coupon weight.Test piece is hung and is immersed in test solution
10min takes out, and is evaporated in an oven, cooling to weigh.Cleaning efficiency=(weight after total weight-cleaning)/gross mass, data such as table 1
It is shown
Table 1: efficiency analysis
| Embodiment | 1 | 2 | 3 |
| Cleaning rate | 92.7% | 95.5% | 93.2% |
There is grease to glue wall when weighing, sticky paper is possible, and there are 2% errors for cleaning energy rate, but cleaning efficiency reaches 90% or more, effect
Ideal reaches antirust, cleans purpose.In accordance with JB-T 4323.2-1999 water base metal cleaning agent test stone.
Claims (6)
1. a kind of without phosphorus anti-rust metal detergent, which is characterized in that by weight include following components: nonionic surfactant
10-15 parts of fatty alcohol polyoxyethylene ether, 10-15 parts of cocoanut fatty acid diethanolamide, anionic surfactant dodecane
5-10 parts of base benzene sulfonic acid sodium salt, 10-15 parts of washing assisant, 8-12 parts of chelating agent, 2-5 parts of rust inhibitor, 1-4 parts of defoaming agent, water
80-100 parts.
2. without phosphorus anti-rust cleaning agent according to claim 1, which is characterized in that by weight include following components: it is non-from
13 parts of sub- surfactant fatty alcohol polyoxyethylene ether, 12 parts of cocoanut fatty acid diethanolamide, anionic surfactant
10 parts of neopelex, 10 parts of washing assisant, 9 parts of chelating agent, 4 parts of rust inhibitor, 2 parts of defoaming agent, 100 parts of water.
3. without phosphorus anti-rust metal detergent according to claim 1 or 2, which is characterized in that the washing assisant is lemon
Sour sodium and sodium metasilicate.
4. without phosphorus anti-rust metal detergent according to claim 1 or 2, which is characterized in that the chelating agent is metasilicic acid
Sodium.
5. without phosphorus anti-rust metal detergent according to claim 1 or 2, which is characterized in that the defoaming agent is organosilicon
Oily defoaming agent.
6. without phosphorus anti-rust metal detergent according to claim 1 or 2, which is characterized in that the corrosion inhibiter be silicate,
Triethanolamine, ethylenediamine tetra-acetic acid, sodium molybdate compound mixed liquor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811143655.9A CN109208016A (en) | 2018-09-29 | 2018-09-29 | A kind of without phosphorus anti-rust metal detergent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811143655.9A CN109208016A (en) | 2018-09-29 | 2018-09-29 | A kind of without phosphorus anti-rust metal detergent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109208016A true CN109208016A (en) | 2019-01-15 |
Family
ID=64982095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811143655.9A Pending CN109208016A (en) | 2018-09-29 | 2018-09-29 | A kind of without phosphorus anti-rust metal detergent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109208016A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110564522A (en) * | 2019-08-28 | 2019-12-13 | 南通科星化工有限公司 | Phosphorus-free cleaning agent |
| CN111117806A (en) * | 2019-12-20 | 2020-05-08 | 安徽遨信网络科技有限公司 | High-speed rail car body outer surface cleaning agent and preparation method thereof |
| CN111441059A (en) * | 2020-05-20 | 2020-07-24 | 上海涤宝科技有限公司 | Environment-friendly liquid cleaning agent and preparation method and application thereof |
| CN111961541A (en) * | 2020-08-24 | 2020-11-20 | 上海斯瑞文特种油品科技有限公司 | Environment-friendly metal surface cleaning agent and preparation method thereof |
| CN112831792A (en) * | 2021-02-03 | 2021-05-25 | 杭州道玛科技有限公司 | Phosphorus-free antirust metal cleaning agent and preparation method thereof |
| CN114621826A (en) * | 2022-03-30 | 2022-06-14 | 苏州科锐德节能环境科技有限公司 | Environment-friendly oil-separating type battery shell heavy oil stain cleaning agent |
| CN114790413A (en) * | 2022-04-18 | 2022-07-26 | 广东丽臣奥威实业有限公司 | Surfactant composition for efficiently removing oil |
| CN115029708A (en) * | 2022-06-15 | 2022-09-09 | 中国日用化学研究院有限公司 | Low-foam alkali-resistant water-based metal cleaner |
| CN116121761A (en) * | 2022-12-20 | 2023-05-16 | 上海锝堡塑胶科技有限公司 | Environment-friendly cleaning agent and preparation process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106939422A (en) * | 2017-05-17 | 2017-07-11 | 南通科星化工有限公司 | A kind of without phosphorus cleaning agent and preparation method thereof |
| CN107673489A (en) * | 2017-11-14 | 2018-02-09 | 昌邑市龙港无机硅有限公司 | A kind of recirculated water corrosion inhibiting and descaling agent |
| CN107779893A (en) * | 2017-11-30 | 2018-03-09 | 微普安全科技（徐州）股份有限公司 | A kind of aqua type metal cleaner and preparation method thereof |
-
2018
- 2018-09-29 CN CN201811143655.9A patent/CN109208016A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106939422A (en) * | 2017-05-17 | 2017-07-11 | 南通科星化工有限公司 | A kind of without phosphorus cleaning agent and preparation method thereof |
| CN107673489A (en) * | 2017-11-14 | 2018-02-09 | 昌邑市龙港无机硅有限公司 | A kind of recirculated water corrosion inhibiting and descaling agent |
| CN107779893A (en) * | 2017-11-30 | 2018-03-09 | 微普安全科技（徐州）股份有限公司 | A kind of aqua type metal cleaner and preparation method thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110564522A (en) * | 2019-08-28 | 2019-12-13 | 南通科星化工有限公司 | Phosphorus-free cleaning agent |
| CN111117806A (en) * | 2019-12-20 | 2020-05-08 | 安徽遨信网络科技有限公司 | High-speed rail car body outer surface cleaning agent and preparation method thereof |
| CN111441059A (en) * | 2020-05-20 | 2020-07-24 | 上海涤宝科技有限公司 | Environment-friendly liquid cleaning agent and preparation method and application thereof |
| CN111961541A (en) * | 2020-08-24 | 2020-11-20 | 上海斯瑞文特种油品科技有限公司 | Environment-friendly metal surface cleaning agent and preparation method thereof |
| CN112831792A (en) * | 2021-02-03 | 2021-05-25 | 杭州道玛科技有限公司 | Phosphorus-free antirust metal cleaning agent and preparation method thereof |
| CN114621826A (en) * | 2022-03-30 | 2022-06-14 | 苏州科锐德节能环境科技有限公司 | Environment-friendly oil-separating type battery shell heavy oil stain cleaning agent |
| CN114790413A (en) * | 2022-04-18 | 2022-07-26 | 广东丽臣奥威实业有限公司 | Surfactant composition for efficiently removing oil |
| CN115029708A (en) * | 2022-06-15 | 2022-09-09 | 中国日用化学研究院有限公司 | Low-foam alkali-resistant water-based metal cleaner |
| CN115029708B (en) * | 2022-06-15 | 2024-02-27 | 中国日用化学研究院有限公司 | Low-foam alkali-resistant water-based metal cleaning agent |
| CN116121761A (en) * | 2022-12-20 | 2023-05-16 | 上海锝堡塑胶科技有限公司 | Environment-friendly cleaning agent and preparation process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109208016A (en) | A kind of without phosphorus anti-rust metal detergent and preparation method thereof | |
| CN111254447B (en) | Neutral rust removal passivation cleaning agent and use method thereof | |
| CN103710720B (en) | A kind of long-life water base oil removing anti-rust cleaning agent | |
| CN104745322B (en) | A kind of without phosphorus automobile washing liquid and preparation method thereof | |
| CN101476131B (en) | Foamless low temperature degreasing agent | |
| CN104294297A (en) | Water-based metal cleaner and preparation method thereof | |
| CN103014730B (en) | Environment-friendly low-temperature efficient metal cleaner | |
| CN104313622A (en) | Normal-temperature water-based non-phosphorus rust-proof cleaning agent for heavy oil | |
| CN103911625A (en) | Neutral oil removal rust remover and preparation method thereof | |
| CN102477558A (en) | Water-based metal heavy oil stain cleaning agent | |
| CN103374726A (en) | Efficient multipurpose metal cleaning agent | |
| CN101016501A (en) | Special cleaning agent substituting coal oil for bearing and preparing method thereof | |
| CN106555197B (en) | A kind of aqueous cleaning agent and its preparation method and application | |
| CN102925908B (en) | Water-based normal-temperature rustproof spray cleaning agent and preparation method thereof | |
| CN108624237A (en) | A kind of Chemical Millering Polishing liquid and abrasive polishing method | |
| CN109295464A (en) | A kind of multi-functional environment-protection rare earth cleaning agent and preparation method thereof | |
| CN108070872A (en) | A kind of Phosphorus-Free Water-Based Cleaning Agent for Metals | |
| CN100460493C (en) | Environmental protection high concentration low foam rust proof metal cleaning agent and its technology | |
| CN102953071A (en) | Highly-efficiently degreasing and rust-removal surface treating agent for metal | |
| CN106048630A (en) | Strong water-based metal surface oil contamination cleaning agent and preparing method thereof | |
| CN106398903B (en) | A kind of hand-wash laundry liquid easily rinsed and preparation method thereof | |
| CN104451718A (en) | Preparation method of boiler pipe cleaning agent | |
| CN106319538A (en) | Room-temperature metal surface degreaser and preparing method thereof | |
| CN104450238A (en) | Environment-friendly heavy-duty detergent | |
| CN104451755A (en) | High-hardness boiler scale corrosion inhibiting cleaning agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190115 |